Biochemistry of plant secondary metabolism:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Sheffield [u.a.]
Sheffield Acad. Press [u.a.]
1999
|
| Edition: | 1. publ. |
| Series: | Annual plant reviews
2 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII, 358 S. graph. Darst. |
| ISBN: | 1841270075 |
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| 245 | 1 | 0 | |a Biochemistry of plant secondary metabolism |c ed. by Michael Wink |
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Record in the Search Index
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| adam_text | Titel: Biochemistry of plant secondary metabolism
Autor: Wink, Michael
Jahr: 1999
Contents
Introduction: biochemistry, role and biotechnology of
secondary metabolites 1
M. WINK
1.1 Introduction 1
I 2 Biosynthesis 2
1.3 Transport, storage and turnover 7
1.4 Costs of secondary metabolism 12
1.5 Role of secondary metabolites and their application in biotechnology 12
References 15
Biochemistry and physiology of alkaloids and betalains 17
M.F. ROBERTS AND D. STRACK
2.1 Introduction 17
2.2 Nicotine and tropane alkaloids 18
2.2.1 Nicotine alkaloids 18
2.2.2 The tropane alkaloids 22
2 3 Pyrrolizidine alkaloids 27
2.3 1 Translocation, accumulation and ecology 29
2.4 Benzylisoquinoline alkaloids 29
2.4.1 The formation of (5)-norcoclaurine 30
2.4.2 Biosynthesis of the tetrahydroberberine alkaloids 30
2.4.3 The route to the protopine and benzophenanthridine alkaloids 33
2.4.4 Biosynthesis of the morphinan alkaloids 35
2 5 Monoterpene indole alkaloids 37
2.5.1 Biosynthesis of indole alkaloid precursors 38
2.5.2 Formation of (fl-strictosidine 40
2.5.3 Deglucosylation of strictosidine 41
2 5 4 Formation of corynanthe-type alkaloids 43
2 5.5 The formation of sarpagan-type alkaloids 43
2.5.6 Formation of aspidosperm-type alkaloids 45
2.5.7 Dimeric indole alkaloids 47
2.6 Ergot alkaloids 48
2 7 Acridone alkaloid biosynthesis 52
2 8 Purine alkaloids 54
2.9 Taxol 55
2 9,1 Biosynthesis of taxanes 56
2.10 Betalains 57
2 10.1 Structures 59
2.10.2 Biosynthesis 61
2.11 Conclusions 68
General reviews 68
References 70
CONTENTS
Biosynthesis of cyanogenic glycosides, glucosinolates and
nonprotein amino acids 79
D. SELMAR
79
80
80
81
87
95
101
107
110
111
111
112
115
119
122
123
124
125
125
126
130
133
135
135
136
Biosynthesis of phenylpropanoids and related compounds 151
M. PETERSEN, D. STRACK AND U. MATERN
4.1 Introduction 151
4.2 General phenylpropanoid pathway and hydroxycinnamate conjugates 151
4.2.1 The phenylalanine/hydroxycinnamate pathway 152
4.2.2 Formation of hydroxycinnamate conjugates 157
4.2.3 Functions of hydroxycinnamate conjugates 158
4.3 Coumarins 161
4.3.1 Current points of interest and classification 161
4.3.2 Simple coumarins 163
4.3.3 Furanocoumarins 167
4.4. Lignans 171
4.4.1 Biosynthesis of monolignols 172
4.4.2 Lignan biosynthesis 176
4 5 Gallotannins and ellagitannins 186
4.5 1 Biosynthesis of fi-glucogallin and 1.2,3,4,6-pentagalloyi-(J-D-glucose 187
4.5.2 Biosynthesis of gallotannins 190
4.5.3 Biosynthesis of ellagitannins 190
4.6 Flavonoids, anthocyanins, proanthocyantdins, condensed tannins and isoflavonoids 191
3.1 Introduction
3.2 Cyanogenic glycosides
3.2.1 General aspects
3.2.2 Structures
3.2.3 Cyanogenesis
3.2.4 Biosynthesis of cyanogenic glucosides
3.2.5 Metabolism of cyanogenic glycosides
3.2.6 Cyanogenic glycosides and foods
3.2.7 Perspectives
3.3 Glucosinolates
3.3.1 General aspects
3.3.2 Structures
3.3.3 Biosynthesis
3.3.4 Mustard oil formation
3.3.5 Ecological significance of glucosinolates
3.3.6 Glucosinolates and nutrition
3.3.7 Conclusion
3.4 Nonprotein amino acids
3.4.1 General apsects
3.4.2 Structures
3.4.3 Biosynthesis and metabolism
3.4.4 Ecological aspects
3.4.5 Perspectives
Acknowledgements
References
CONTENTS XI
4.6.1 Enzymes of flavonoid and anthocyanin biosynthesis 193
4.6.2 Formation of proanthocyanidins and condensed tannins 196
4.6.3 Modificaion of flavonoids and anthocyanins 197
4.6.4 Biosynthesis of isofiavonoids and pterocarpans 199
References 202
Biochemistry of terpenoids: monoterpenes, sesquiterpenes,
diterpenes, sterols, cardiac glycosides and steroid saponins 222
J. GERSHENZON AND W. KREIS
5. i The basic pathway of terpenoid biosynthesis and the formation and function of
C5-CM terpenoid metabolites 222
5.1.1 Introduction 222
5.1.2 Function 224
5.1.3 Biosynthesis 227
5.1.4 Conclusions 249
5.2 Sterols, cardiac glycosides and steroid saponins 251
5.2.1 Sterols 254
5.2.2 Cardiac glycosides 262
5.2.3 Steroid saponins and steroid alkaloids 275
5.2.4 Conclusions 278
Acknowledgements 280
References 280
Chemotaxonomy in relation to molecular pfaylogeny of plants 300
M. WINK AND P.G. WATERMAN
6.1 Introduction 300
6.2 The establishment of chemotaxonomy as a research discipline 300
6.2.1 Amino acids 301
6.2.2 Flavonoids 301
6.2.3 Xanthones 302
6.2.4 Coumarins 303
6.2.5 Fixed oils, fats and waxes 303
6.2.6 Cyclic polyketides 304
6.2.7 Monoterpenes and sesquiterpenes (volatile oils) 304
6.2.8 Iridoids 305
6.2.9 Triterpenes, sterols and carotenoids 305
6.2.10 Nitrogen-containing terpenes 305
6.2.11 Alkaloids 306
6.3 Developments in small molecule chemotaxonomy over the past 25 years 310
6.3.1 Dahlgren s phyfogenetic framework 310
6.3.2 Quantifying chemical data for numerical taxonomy 313
6.3.3 What is the future of small molecule chemotaxonomy? 3! 3
6.4 Molecular biology and plant taxonomy 314
6.5 Comparison between patterns of secondary metabolites and molecular phytogeny 315
6.5.1 Use of molecular markers in plant systematics 315
6.5.2 Distribution of pyrrolizidine alkaloids, cardiac glycosides and glucosinolates
in the plant kingdom 316
6.5.3 Phytochemical traits of the Leguminosae 319
xii CONTENTS
6.5.4 Nitrogen-containing secondary metabolites 322
6.5.5 Nitrogen-free secondary metabolites 328
6 5.6 Quinolizidine alkaloids in the genus Lupinus 332
Acknowledgements 336
References 336
Index 342
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| spelling | Biochemistry of plant secondary metabolism ed. by Michael Wink 1. publ. Sheffield [u.a.] Sheffield Acad. Press [u.a.] 1999 XII, 358 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Annual plant reviews 2 Sekundärstoffwechsel (DE-588)4126827-1 gnd rswk-swf Biochemie (DE-588)4006777-4 gnd rswk-swf Pflanzen (DE-588)4045539-7 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Pflanzen (DE-588)4045539-7 s Sekundärstoffwechsel (DE-588)4126827-1 s DE-604 Biochemie (DE-588)4006777-4 s Wink, Michael 1951- Sonstige (DE-588)124618146 oth Annual plant reviews 2 (DE-604)BV012859776 2 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008530548&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Biochemistry of plant secondary metabolism Annual plant reviews Sekundärstoffwechsel (DE-588)4126827-1 gnd Biochemie (DE-588)4006777-4 gnd Pflanzen (DE-588)4045539-7 gnd |
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| title | Biochemistry of plant secondary metabolism |
| title_auth | Biochemistry of plant secondary metabolism |
| title_exact_search | Biochemistry of plant secondary metabolism |
| title_full | Biochemistry of plant secondary metabolism ed. by Michael Wink |
| title_fullStr | Biochemistry of plant secondary metabolism ed. by Michael Wink |
| title_full_unstemmed | Biochemistry of plant secondary metabolism ed. by Michael Wink |
| title_short | Biochemistry of plant secondary metabolism |
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