Chemical synthesis using supercritical fluids:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | German |
| Veröffentlicht: |
Weinheim [u.a.]
Wiley-VCH
1999
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XX, 480 S. Ill., graph. Darst. |
| ISBN: | 3527296050 |
Internformat
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| 245 | 1 | 0 | |a Chemical synthesis using supercritical fluids |c ed. by Philip G. Jessop ... |
| 264 | 1 | |a Weinheim [u.a.] |b Wiley-VCH |c 1999 | |
| 300 | |a XX, 480 S. |b Ill., graph. Darst. | ||
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| 650 | 7 | |a Composés organiques - Synthèse |2 ram | |
| 650 | 7 | |a Emulsies |2 gtt | |
| 650 | 7 | |a Extração com fluído supercrítico |2 larpcal | |
| 650 | 7 | |a Fluides supercritiques |2 ram | |
| 650 | 7 | |a Katalyse |2 gtt | |
| 650 | 7 | |a Organometaalverbindingen |2 gtt | |
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| 650 | 7 | |a Synthese (chemie) |2 gtt | |
| 650 | 7 | |a Síntese química |2 larpcal | |
| 650 | 4 | |a High pressure chemistry | |
| 650 | 4 | |a Organic compounds |x Synthesis | |
| 650 | 4 | |a Supercritical fluids | |
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Datensatz im Suchindex
| _version_ | 1804127151104983040 |
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| adam_text | CHEMICAL SYNTHESIS USING SUPERCRITICAL FLUIDS EDITED BY PHILIP G. JESSOP
AND WALTER LEITNER WILEY-VCH WEINHEIM * NEW YORK * CHICHESTER BRISBANE
* SINGAPORE * TORONTO CONTENTS PREFACE V CONTENTS IX LIST OF
CONTRIBUTORS XVII 1 INTRODUCTION 1 1.1 SUPERCRITICAL FLUIDS AS MEDIA FOR
CHEMICAL REACTIONS 1 1.1.1 WHAT IS A SUPERCRITICAL FLUID (SCF)? 1 1.1.2
PRACTICAL ASPECTS OF REACTIONS IN SUPERCRITICAL FLUIDS (SFRS) . 6 1.1.3
MOTIVATION FOR USE OF SCFS IN MODERN CHEMICAL SYNTHESIS . . 9 1.1.4 A
BRIEF HISTORY OF CHEMICAL SYNTHESIS IN SCFS 13 1.1.4.1 DISCOVERY OF SCFS
AND THEIR USE AS SOLVENTS 13 1.1.4.2 EARLY EXAMPLES OF CHEMICAL
REACTIONS IN SCFS 20 1.1.4.3 INDUSTRIAL USE OF SCFS AS REACTION MEDIA 25
REFERENCES 30 1.2 PHASE BEHAVIOR AND SOLUBILITY 37 1.2.1 BASIC PHYSICAL
PROPERTIES OF SUPERCRITICAL FLUIDS 37 1.2.2 PHASE BEHAVIOR IN HIGH
PRESSURE SYSTEMS 41 1.2.2.1 TYPES OF BINARY PHASE DIAGRAMS 41 1.2.2.2
ASYMMETRIE BINARY MIXTURES 43 1.2.3 FACTORS AFFECTING SOLUBILITY IN
SUPERCRITICAL FLUIDS 47 1.2.3.1 SCF SOLVENT 48 1.2.3.2 CHEMICAL
FUNCTIONALITY OF THE SOLUTE 49 1.2.3.3 TEMPERATURE AND PRESSURE EFFECTS
51 REFERENCES 53 ) X CONTENTS 1.3 PHYSICAL PROPERTIES AS RELATED TO
CHEMICAL REACTIONS 54 1.3.1 BEHAVIOR OF DIFFUSION COEFFICIENTS 55 1.3.2
DIFFUSIONAL EFFECTS ON REACTIONS 56 1.3.3 TRANSITION-STATE THEORY
APPLIED TO SCFS 58 1.3.4 DENSITY DEPENDENCE OF TWO COMPETING REACTIONS
62 1.3.5 SOLVATION EFFECTS ON REACTIONS 63 1.3.6 CONCLUSIONS 65
REFERENCES 65 2 EXPERIMENTAL TECHNIQUES 67 2.1 HIGH-PRESSURE REACTION
EQUIPMENT DESIGN 67 2.1.1 INTRODUCTION 67 2.1.2 BASIC EQUIPMENT AND
COMPONENTS 69 2.1.2.1 DESIGN OF THICK-WALLED VESSELS 69 2.1.2.2 CLOSURES
AND CONNECTORS 71 2.1.2.3 TUBING AND FITTINGS *. . 73 2.1.2.4 VALVES 74
2.1.2.5 COMPRESSORS AND PUMPS 76 2.1.2.6 STIRRING AND MIXING 78 2.1.2.7
OPTICAL WINDOWS 78 2.1.3 HIGH PRESSURE SYSTEMS 78 2.1.3.1 SINGLE-BATCH
HIGH-PRESSURE REACTORS 80 2.1.3.2 VIEW CELLS 83 2.1.3.3 SYSTEMS FOR
CONTINUOUS PROCESSING 84 2.1.4 SUMMARY 86 REFERENCES 86 2.2 EXTRACTION
AND RELATED SEPARATION TECHNIQUES 88 2.2.1 GENERAL ASPECTS OF
SUPERCRITICAL FLUIDS AS MASS SEPARATING AGENTS 88 2.2.2 EXTRACTION FROM
SOLIDS 90 2.2.2.1 BASIC PROCESS DESIGN 91 2.2.2.2 PROCESS PARAMETERS 92
2.2.2.3 MODELING THE EXTRACTION 93 2.2.2.4 SOLIDS IN MULTIPLE STAGES AND
COUNTERCURRENT OPERATION IN SFE 95 2.2.2.5 CONTINUOUS EXTRACTION OF
CONTAMINATED SOIL WITH SUPERCRITICAL WATER 95 2.2.3 COUNTERCURRENT
MULTISTAGE EXTRACTION 97 2.2.3.1 BASIC PROCESS DESIGN 98 2.2.3.2 PHASE
EQUILIBRIA 99 2.2.3.3 SEPARATION ANALYSIS WITH RESPECT TO THEORETICAL
STAGES .... 101 2.2.3.4 MULTICOMPONENT PROCESS SIMULATION 102 2.2.3.5
DETERMINATION OF THE HEIGHT (LENGTH) OF A THEORETICAL STAGE . 102
2.2.3.6 DETERMINATION OF COLUMN DIAMETER 103 2.2.4 CHROMATOGRAPHIE
SEPARATION WITH SUPERCRITICAL FLUIDS 104 CONTENTS XI 2.2.4.1 DESIGN OF
SFC APPARATUS 105 2.2.4.2 METHODS FOR SCALE-UP OF CHROMATOGRAPHY 106
2.2.5 CONCLUSION 106 REFERENCES 106 2.3 PRECIPITATION AND
CRYSTALLIZATION TECHNIQUES 108 2.3.1 INTRODUCTION 108 2.3.2
THERMODYNAMICS AND PHASE EQUILIBRIA 109 2.3.2.1 CSS, PGSS AND RESS 109
2.3.2.2 GASP 112 2.3.3 PROCESS BASICS AND REFERENCE SCHEINES 115 2.3.3.1
CRYSTALLIZATION FROM A SUPERCRITICAL SOLUTION (CSS) 115 2.3.3.2
FORMATION OF PARTICLES FROM GAS SATURATED SOLUTION (PGSS). . 115 2.3.3.3
RAPID EXPANSION OF A SUPERCRITICAL SOLUTION (RESS) 117 2.3.3.4
PRECIPITATION BY A GAS OR A SUPERCRITICAL ANTISOLVENT (GASP) . 120 2.3.4
EXAMPLE 123 2.3.5 CONCLUDING REMARKS 125 REFERENCES 125 2.4
MICROEMULSIONS, EMULSIONS AND LATEXES 127 2.4.1 INTRODUCTION 127 2.4.2
INTERFACIAL TENSION 128 2.4.3 MICROEMULSIONS 130 2.4.3.1 PHASE BEHAVIOR
131 2.4.3.2 UV-VIS INDICATORS 132 2.4.3.3 ELECTRON PARAMAGNETIC
RESONANCE TECHNIQUES 133 2.4.3.4 NEUTRON SCATTERING 134 2.4.3.5 ENZYMES
134 2.4.3.6 ORGANIC-C0 2 MICROEMULSIONS 135 2.4.4 EMULSIONS 135 2.4.4.1
ORGANIC-C0 2 EMULSIONS 135 2.4.4.2 WATER-C0 2 EMULSIONS AND C0 2 -WATER
EMULSIONS 137 2.4.5 REACTIONS IN SCF EMULSIONS, MICROEMULSIONS AND
LATEXES . . 140 2.4.5.1 PHASE-TRANSFER REACTIONS BETWEEN WATER AND C0 2
140 2.4.5.2 IN SITU STUDIES OF DISPERSION POLYMERIZATION 142 2.4.6
CONCLUSIONS 143 2.4.7 ACKNOWLEDGMENTS 144 REFERENCES 144 3 SPECTROSCOPY
OF SCF SOLUTIONS 147 3.1 VIBRATIONAL SPECTROSCOPY 147 3.1.1 INTRODUCTION
147 3.1.2 DILUTE SOLUTIONS 148 3.1.2.1 INFRARED SPECTROSCOPY 148 3.1.2.2
RAMAN SPECTROSCOPY 150 XII CONTENTS 3.1.2.3 POLYMER MODIFICATION 151
3.1.2.4 VIBRATIONAL SPECTROSCOPIC STUDIES OF AQUEOUS MICROEMULSIONS IN
SCFS 153 3.1.3 CONCENTRATED SOLUTIONS 154 3.1.4 MONITORING OF FAST
REACTIONS IN SCFS USING TIME-RESOLVED VIBRATIONAL SPECTROSCOPY 156 3.1.5
CONCLUSIONS 161 3.1.6 ACKNOWLEDGMENTS 161 REFERENCES 161 3.2 NMR
SPECTROSCOPY 165 3.2.1 BACKGROUND 165 3.2.2 SOME TOROID PROBE DESIGNS
167 3.2.3 GENERAL PROPERTIES OF SUPERCRITICAL MEDIA 172 3.2.4
MEASUREMENT OF DYNAMIC AND EQUILIBRIUM PROCESSES IN C0 2 . 177 3.2.5
RATE AND SELECTIVITY MEASUREMENTS ASSOCIATED WITH PROPYLENE
HYDROFORMYLATION IN C0 2 184 3.2.6 DIFFUSION AND RELAXATION TIME
MEASUREMENTS *. . 187 3.2.7 NMR OF QUADRUPOLAR NUCLEI IN SUPERCRITICAL
C0 2 188 3.2.8 FUTURE RESEARCH 191 3.2.9 ACKNOWLEDGMENTS 192 REFERENCES
193 3.3 UV, EPR, X-RAY AND RELATED SPECTROSCOPIC TECHNIQUES . . . . 195
3 3.1 UV-VIS 195 3.3.2 FLUORESCENCE 198 3.3.3 ELECTRON PARAMAGNETIC
RESONANCE 199 3.3.4 X-RAY ABSORPTION FINE STRUCTURE 200 3.3.5 X-RAY AND
NEUTRON SCATTERING AND DIFFRACTION 206 3.3.5.1 SMALL ANGLE SCATTERING
207 3.3.5.2 WIDE ANGLE SCATTERING 208 3.3.6 CONCLUSIONS 209 3.3.7
ACKNOWLEDGMENT 209 REFERENCES 209 4 REACTIONS IN SCF 213 4.1 SYNTHESIS
OF INORGANIC SOLIDS 213 4.1.1 HISTORICAL SUMMARY 214 4.1.2 EXPERIMENTAL
TECHNIQUES 216 4.1.3 HYDROTHERMAL CHEMISTRY 226 4.1.3.1 METAL OXIDES 226
4.1.3.2 PHOSPHATES AND SILICATES 229 4.1.3.3 METAL SULFIDES 232 4.1.3.4
OTHER HYDROTHERMAL SYNTHESES 233 4.1.4 SUPERCRITICAL AMINES 234 CONTENTS
XIII 4.1.5 OTHER SOLVENTS 237 4.1.6 CONCLUSIONS 238 REFERENCES 239 4.2
SYNTHESIS OF COORDINATION COMPOUNDS 243 4.2.1 INTRODUCTION 243 4.2.2
STRATEGY 244 4.2.3 CHEMISTRY 245 4.2.4 EQUIPMENT 248 4.2.5 DETAILED
SYNTHESES 252 4.2.5.1 PREPARATION OF CR(CO) 5 (C 2 H 4 ) 253 4.2.5.2
PREPARATION OF CPMN(CO) 2 (N 2 -H 2 ) 255 4.2.5.3 PREPARATION OF
CP*MN(CO) 2 (N 2 -H 2 ) FROM CP*MN(CO) 2 (R| 2 -HSIET 3 ) 256 4.2.6
CONCLUSIONS 257 4.2.7 ACKNOWLEDGMENTS 257 REFERENCES 257 4.3
STOICHIOMETRIC ORGANIC REACTIONS 259 4.3.1 EXPERIMENTAL METHODS 260
4.3.2 SUPERCRITICAL CARBON DIOXIDE . 260 4.3.2.1 DIELS-ALDER REACTIONS
262 4.3.2.2 REDUCTION AND COUPLING 265 4.3.2.3 ESTERIFICATION 266
4.3.2.4 CRACKING AND REARRANGEMENTS 266 4.3.3 SUPERHEATED AND
SUPERCRITICAL WATER 267 4.3.3.1 OXIDATION OF MEDIANE 267 4.3.3.2
CLEAVAGE/HYDROLYSIS 268 4.3.3.3 ELIMINATION REACTIONS 271 4.3.3.4
DIELS-ALDER REACTIONS 272 4.3.3.5 REARRANGEMENT 273 4.3.4 OTHER FLUIDS
275 REFERENCES 276 4.4 PHOTOCHEMICAL AND PHOTO-INDUCED REACTIONS 280
4.4.1 INTRODUCTION 280 4.4.1.1 DEFINITION OF A SUPERCRITICAL FLUID 280
4.4.1.2 SOLVENT PROPERTIES OF SCFS 280 4.4.1.3 SCOPE OF THIS CHAPTER 281
4.4.1.4 EXPERIMENTAL CONSIDERATIONS 282 4.4.2 PHOTOCHEMICAL REACTIONS IN
SUPERCRITICAL FLUID SOLVENTS . . . . 285 4.4.2.1 GEOMETRIE ISOMERIZATION
285 4.4.2.2 PHOTODIMERIZATION 285 4.4.2.3 CARBONYL PHOTOCHEMISTRY 287
4.4.3 PHOTO-INDUCED REACTIONS IN SUPERCRITICAL FLUID SOLVENTS .... 289
4.4.3.1 FREE RADICAL BROMINATIONS OF ALKYL AROMATICS IN SUPERCRITICAL
CARBON DIOXIDE 289 XIV CONTENTS 4.4.3.2 FREE RADICAL CHLORINATION OF
ALKANES IN SUPERCRIUECAL FLUID SOLVENTS 290 4.4.4 CONCLUSIONS 293 4.4.5
ACKNOWLEDGMENTS 294 REFERENCES 294 4.5 POLYMERIZATIONS IN DENSE CARBON
DIOXIDE 297 4.5.1 INTRODUCTION 297 4.5.2 HOMOGENEOUS SOLUTION
POLYMERIZATIONS 300 4.5.2.1 FREE-RADICAL CHAIN GROWTH 300 4.5.2.2
CATIONIC CHAIN GROWTH 303 4.5.3 HETEROGENEOUS POLYMERIZATIONS 305
4.5.3.1 FREE-RADICAL CHAIN GROWTH 305 4.5.3.2 CATIONIC CHAIN GROWTH 317
4.5.4 METAL-CATALYZED POLYMERIZATIONS 319 4.5.4.1 RING-OPENING
METATHESIS POLYMERIZATION 319 4.5.4.2 EPOXIDE-C0 2 COPOLYMERS 319
4.5.4.3 OXIDATIVE COUPLING POLYMERIZATIONS 320 4.5.5 STEP-GROWTH
POLYMERIZATIONS 320 4.5.6 HYBRID SYSTEMS 321 4.5.7 CONCLUSIONS 321 4.5.8
ACKNOWLEDGMENTS 322 REFERENCES 322 4.6 FREE-RADICAL POLYMERIZATION IN
REACTIVE SUPERCRIUECAL FLUIDS . 326 4.6.1 INTRODUCTION 326 4.6.2
EXPERIMENTAL METHODS AND TECHNIQUES 327 4.6.2.1 ON-LINE SPECTROSCOPY 327
4.6.2.2 KINETIC COEFFICIENTS FROM LASER-ASSISTED TECHNIQUES 329 4.6.2.3
CONTMUOUSLY OPERATED HIGH-PRESSURE POLYMERIZATION REACTORS 331 4.6.3
ETHENE HOMOPOLYMERIZATION 333 4.6.3.1 PROPAGATION AND TERMINATION 334
4.6.3.2 CHAIN-TRANSFER TO MONOMER 336 4.6.3.3 CHAIN-TRANSFER TO POLYMER
AND SS-SCISSION 338 4.6.4 ETHENE COPOLYMERIZATIONS 341 4.6.4.1 REACTIVITY
RATIOS FOR COPOLYMERIZATIONS OF ETHENE WITH ACRYLIC ACID ESTERS 341
4.6.4.2 HOMOPROPAGATION AND HOMOTERMINATION KINETICS OF THE COMONOMERS
345 4.6.4.3 MODELING OF HIGH-PRESSURE ETHENE COPOLYMERIZATIONS 347 4.6.5
CONCLUSIONS 348 REFERENCES 348 4.7 METAL-COMPLEX-CATALYZED REACTIONS 351
4.7.1 INTRODUCTION 351 4.7.1.1 POTENTIAL BENEFITS OF USING SUPERCRIUECAL
FLUIDS IN METAL-COMPLEX-CATALYZED REACTIONS 351 CONTENTS XV 4.7.1.2
PRACTICAL CONSIDERATIONS 352 4.7.1.3 SOLUBILITY OF METAL COMPLEXES IN
SCFS . 356 4.7.2 HYDROGENATION AND RELATED REACTIONS 358 4.7.2.1
HYDROGENATION OF C0 2 UNDER SUPERCRITICAL CONDITIONS 358 4.7.2.2
HYDROGENATION OF C=C DOUBLE BONDS 360 4.7.2.3 HYDROGENATION OF IMINES
363 4.7.3 HYDROFORMYLATION 365 4.7.4 C-C COUPLING REACTIONS 369 4.7.4.1
COBALT-CATALYZED CYCLIZATION REACTIONS 369 4.7.4.2 COUPLING REACTIONS
INVOLVING SCC0 2 AS SOLVENT AND SUBSTRATE 370 4.7.4.3 OLEFIN METATHESIS
371 4.7.4.4 PALLADIUM-CATALYZED COUPLING REACTIONS OF ARYL HALIDES. . .
. 373 4.7.4.5 CYCLOPROPANATION 375 4.7.5 OXIDATION 377 4.7.5.1 PEROXIDES
AS OXIDANTS 377 4.7.5.2 MOLECULAR OXYGEN AS OXIDANT 378 4.7.6
POLYMERIZATION . 380 4.7.6.1 POLYMERIZATION OF ALKENES UNDER
SUPERCRITICAL CONDITIONS . . . 380 4.7.6.2 POLYMERIZATION UTILIZING
COMPRESSED C0 2 381 4.7.7 CONCLUSIONS 384 REFERENCES 384 4.8
HETEROGENEOUS CATALYSIS 388 4.8.1 FISCHER-TROPSCH SYNTHESIS 389 4.8.1.1
EXPERIMENTAL 390 4.8.1.2 REACTION PERFORMANCE IN THREE REACTION PHASES
391 4.8.1.3 DIFFUSION BEHAVIOR OF SYNTHESIS GAS 393 4.8.1.4 DIFFUSION
AND REACTION OF THE PRODUCTS 393 4.8.1.5 WAX PRODUCTION: ADDITION OF
HEAVY ALKENE TO THE SUPERCRITICAL PHASE 395 4.8.2 ISOMERIZATION
REACTIONS 398 4.8.3 F-BUTYL ALCOHOL SYNTHESIS BY AIR OXIDATION OF
SUPERCRITICAL ISOBUTANE 399 4.8.4 SUPERCRITICAL PHASE ALKYLATION
REACTIONS OVER SOLID ACID CATALYSTS 403 4.8.5 SYNTHESIS OF FINE
CHEMICALS AND OTHER PRODUCTS 407 4.8.6 CONCLUSIONS 411 REFERENCES 411
4.9 ENZYMATIC CATALYSIS 414 4.9.1 INTRODUCTION 414 4.9.2 ENZYMES 415
4.9.3 ENZYME REACTORS 416 4.9.3.1 BATCH REACTORS 416 4.9.3.2
RECIRCULATING BATCH REACTOR 419 4.9.3.3 EXTRACTIVE BATCH REACTOR 419
4.9.3.4 SEMICONTINUOUS FLOW REACTORS 420 4.9.3.5 CONTINUOUS REACTORS 420
XVI CONTENTS 4.9.4 EXPERIMENTAL RESULTS 421 4.9.4.1 A COMPILATION OF
PUBLISHED EXPERIMENTS 421 4.9.4.2 ENZYME STABILITY IN SUPERCRITICAL
FLUIDS 425 4.9.4.3 THE ROLE OF WATER 428 4.9.4.4 PRESSURE EFFECTS 431
4.9.4.5 MASS TRANSFER EFFECTS 434 4.9.4.6 EFFECTS ON SELECTIVITY 436
4.9.5 DOWNSTREAM PROCESSING AND COSTS 439 4.9.5.1 DOWNSTREAM PROCESSING
SCHEMES 439 4.9.5.2 PROSESSING COST ESTIMATE 441 4.9.6 SUMMARY AND
OUTLOOK 441 REFERENCES 443 4.10 PHASE TRANSFER AND AMMONIUM SALT
CATALYZED REACTIONS . . . 446 4.10.1 INTRODUCTION 446 4.10.2 BACKGROUND
446 4.10.3 PUBLISHED WORK 449 4.10.4 EXPERIMENTAL PROCEDURE 451 4.10.5
RELATED CATALYTIC REACTIONS 452 4.10.6 FUTURE DIRECTIONS 453 REFERENCES
453 APPENDICES 455 APPENDIX A: CONVERSION FACTORS 455 APPENDIX B:
ABBREVIATIONS AND SYMBOLS 457 INDEX 465
|
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| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV012507785 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:28:47Z |
| institution | BVB |
| isbn | 3527296050 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008489696 |
| oclc_num | 42040911 |
| open_access_boolean | |
| owner | DE-20 DE-29T DE-355 DE-BY-UBR DE-703 |
| owner_facet | DE-20 DE-29T DE-355 DE-BY-UBR DE-703 |
| physical | XX, 480 S. Ill., graph. Darst. |
| publishDate | 1999 |
| publishDateSearch | 1999 |
| publishDateSort | 1999 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Chemical synthesis using supercritical fluids ed. by Philip G. Jessop ... Weinheim [u.a.] Wiley-VCH 1999 XX, 480 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Composés organiques - Synthèse ram Emulsies gtt Extração com fluído supercrítico larpcal Fluides supercritiques ram Katalyse gtt Organometaalverbindingen gtt Polymerisatie gtt Processos de separação larpcal Reações químicas larpcal Superkritische media gtt Synthese (chemie) gtt Síntese química larpcal High pressure chemistry Organic compounds Synthesis Supercritical fluids Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Löslichkeit (DE-588)4114435-1 gnd rswk-swf Metallkomplexe (DE-588)4038898-0 gnd rswk-swf Chemische Synthese (DE-588)4133806-6 gnd rswk-swf Reaktionssystem (DE-588)4177124-2 gnd rswk-swf Flüssigkeit (DE-588)4017621-6 gnd rswk-swf Überkritischer Zustand (DE-588)4186602-2 gnd rswk-swf Emulsion (DE-588)4014626-1 gnd rswk-swf Spektroskopie (DE-588)4056138-0 gnd rswk-swf Phase Thermodynamik (DE-588)4263270-5 gnd rswk-swf Chemische Synthese (DE-588)4133806-6 s Flüssigkeit (DE-588)4017621-6 s Überkritischer Zustand (DE-588)4186602-2 s DE-604 Metallkomplexe (DE-588)4038898-0 s 1\p DE-604 Spektroskopie (DE-588)4056138-0 s 2\p DE-604 Löslichkeit (DE-588)4114435-1 s 3\p DE-604 Reaktionssystem (DE-588)4177124-2 s 4\p DE-604 Emulsion (DE-588)4014626-1 s 5\p DE-604 Phase Thermodynamik (DE-588)4263270-5 s 6\p DE-604 Chemische Reaktion (DE-588)4009853-9 s 7\p DE-604 Jessop, Philip G. Sonstige oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008489696&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 6\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 7\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Chemical synthesis using supercritical fluids Composés organiques - Synthèse ram Emulsies gtt Extração com fluído supercrítico larpcal Fluides supercritiques ram Katalyse gtt Organometaalverbindingen gtt Polymerisatie gtt Processos de separação larpcal Reações químicas larpcal Superkritische media gtt Synthese (chemie) gtt Síntese química larpcal High pressure chemistry Organic compounds Synthesis Supercritical fluids Chemische Reaktion (DE-588)4009853-9 gnd Löslichkeit (DE-588)4114435-1 gnd Metallkomplexe (DE-588)4038898-0 gnd Chemische Synthese (DE-588)4133806-6 gnd Reaktionssystem (DE-588)4177124-2 gnd Flüssigkeit (DE-588)4017621-6 gnd Überkritischer Zustand (DE-588)4186602-2 gnd Emulsion (DE-588)4014626-1 gnd Spektroskopie (DE-588)4056138-0 gnd Phase Thermodynamik (DE-588)4263270-5 gnd |
| subject_GND | (DE-588)4009853-9 (DE-588)4114435-1 (DE-588)4038898-0 (DE-588)4133806-6 (DE-588)4177124-2 (DE-588)4017621-6 (DE-588)4186602-2 (DE-588)4014626-1 (DE-588)4056138-0 (DE-588)4263270-5 |
| title | Chemical synthesis using supercritical fluids |
| title_auth | Chemical synthesis using supercritical fluids |
| title_exact_search | Chemical synthesis using supercritical fluids |
| title_full | Chemical synthesis using supercritical fluids ed. by Philip G. Jessop ... |
| title_fullStr | Chemical synthesis using supercritical fluids ed. by Philip G. Jessop ... |
| title_full_unstemmed | Chemical synthesis using supercritical fluids ed. by Philip G. Jessop ... |
| title_short | Chemical synthesis using supercritical fluids |
| title_sort | chemical synthesis using supercritical fluids |
| topic | Composés organiques - Synthèse ram Emulsies gtt Extração com fluído supercrítico larpcal Fluides supercritiques ram Katalyse gtt Organometaalverbindingen gtt Polymerisatie gtt Processos de separação larpcal Reações químicas larpcal Superkritische media gtt Synthese (chemie) gtt Síntese química larpcal High pressure chemistry Organic compounds Synthesis Supercritical fluids Chemische Reaktion (DE-588)4009853-9 gnd Löslichkeit (DE-588)4114435-1 gnd Metallkomplexe (DE-588)4038898-0 gnd Chemische Synthese (DE-588)4133806-6 gnd Reaktionssystem (DE-588)4177124-2 gnd Flüssigkeit (DE-588)4017621-6 gnd Überkritischer Zustand (DE-588)4186602-2 gnd Emulsion (DE-588)4014626-1 gnd Spektroskopie (DE-588)4056138-0 gnd Phase Thermodynamik (DE-588)4263270-5 gnd |
| topic_facet | Composés organiques - Synthèse Emulsies Extração com fluído supercrítico Fluides supercritiques Katalyse Organometaalverbindingen Polymerisatie Processos de separação Reações químicas Superkritische media Synthese (chemie) Síntese química High pressure chemistry Organic compounds Synthesis Supercritical fluids Chemische Reaktion Löslichkeit Metallkomplexe Chemische Synthese Reaktionssystem Flüssigkeit Überkritischer Zustand Emulsion Spektroskopie Phase Thermodynamik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008489696&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT jessopphilipg chemicalsynthesisusingsupercriticalfluids |