Kinetic peculiarities of solid phase reactions:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Chichester [u.a.]
Wiley
1998
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | X, 150 S. graph. Darst. |
| ISBN: | 0471983748 |
Staff View
MARC
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Record in the Search Index
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| adam_text | KINETIC PECULIARITIES OF SOLID PHASE REACTIONS E. YA. DAVYDOV, A. P.
VOROTNIKOV, G. B. PARIYSKII AND G. E. ZAIKOV N.M. EMANUEL INSTITUTE OF
BIOCHEMICAL PHYSICS, RUSSIAN ACADEMY OF SCIENCES, MOSCOW, RUSSIA JOHN
WILEY AND SONS CHICHESTER * NEW YORK * WEINHEIM * BRISBANE * SINGAPORE *
TORONTO CONTENTS FOREWORD VII PREFACE IX INTRODUCTION 1 1. FORMALLY
KINETIC DESCRIPTION OF REACTIONS WITH DISPERSION IN REACTIVITY 5 1.1
KINETICS OF REACTIONS WITH A WIDE SPREAD IN REACTIVITY 5 1.2 KINETICS OF
REACTIONS WITH A NARROW SPREAD IN REACTIVITY 12 1.3 KINETICS OF
RELAXATION IN THE REACTIVITY OF PARTICLES IN SOLIDS 14 1.4 ON THE LIMITS
OF APPROXIMATE METHODS FOR THE DESCRIPTION OF NON-EQUIVALENT KINETICS 18
1.5 POSSIBLE METHODS FOR THE DESCRIPTION OF REACTIONS WITH DISTRIBUTED
KINETIC PARAMETERS 21 2. INFLUENCE OF SPACE-ORIENTATION FACTORS ON
REACTIVITY IN SOLIDS 25 2.1 GEOMETRY OF RADICAL PAIRS 26 2.2 KINETICS OF
THE FORMATION AND DECAY OF RADICAL PAIRS 27 2.3 REACTIONS FOR
SUBSTITUTION WITH PARTICIPATION OF RADICAL PAIRS 29 2.4 INFLUENCE OF
SPATIAL ORIENTATIONS ON CARBENE CHEMISTRY 30 2.5 SPACE-ORIENTATION
EFFECTS IN KINETICS OF LOW-TEMPERATURE DECAY OF CARBENES 33 2.6
INFLUENCE OF SPACE-ORIENTATION FACTORS ON THE SPIN AND CHEMICAL DYNAMICS
OF RADICAL PAIRS 36 3. CONNECTION OF SOLID PHASE KINETICS WITH MOLECULAR
DYNAMICS 51 3.1 ROLE OF MOLECULAR MOBILITY IN THE KINETICS OF REACTIONS
OF RADICAL PAIRS 52 3.2 DYNAMICS OF BIRADICAL FORMATION IN CLUSTER
CARBENE REACTIONS 53 VI CONTENTS 3.3 INFLUENCE OF RELAXATION PROCESSES
ON THE MECHANISM OF BIS-CARBENE REACTIONS IN SOLID POLYMERS 59 3.4
INFLUENCE OF MOLECULAR DYNAMICS ON THE KINETICS OF BIMOLECULAR
REACTIONS: THE COMPENSATION EFFECT 64 3.5 KINETICS OF SOLID PHASE
REACTIONS UNDER LIMITED MOLECULAR MOBILITY 71 4. THE EFFECT OF THE
STRUCTURAL-PHYSICAL MODIFICATION ON THE KINETICS OF RADICAL REACTIONS 79
4.1 THE FILIER EFFECT ON THE KINETICS OF THE TRIPLET CARBENE DECAY IN
POLYMERS 80 4.2 THE FILIER EFFECT ON THE KINETICS OF CARBENE REACTIONS
IN CLUSTERS 85 4.3 THE FILIER EFFECT ON THE KINETICS OF LOW-TEMPERATURE
REACTIONS OF MACRORADICALS 87 5. TUNNELLING IN SOLID PHASE REACTIONS 95
5.1 MODEL OF THERMAL POPULATIONS OF THE HIGHEST VIBRATION LEVELS 96 5.2
MODEL OF THE OSCILLATING POTENTIAL BARRIER 100 5.3 EXPERIMENTAL
ESTIMATION OF HYDROGEN ATOM TUNNELLING PARAMETERS 105 6. THE KINETIC
ISOTOPE EFFECT IN SOLID PHASE REACTIONS 111 6.1 THE INFLUENCE OF THE
SPATIAL FACTOR ON THE KINETIC ISOTOPE EFFECT IN HYDROGEN ATOM TRANSFER
112 6.2 THE KINETIC ISOTOPE EFFECT AND STRUCTURAL RELAXATION 116 6.3 THE
INFLUENCE OF INTERMOLECULAR OSCILLATIONS ON THE KINETIC ISOTOPE EFFECT
118 7. KINETICS OF PHOTOINITIATED REACTIONS IN SOLIDS 127 7.1
APPLICATION OF THE FREE VOLUME MODEL TO ESTIMATIONS OF THE PHOTOCHEMICAL
PROCESS EFFICIENCY 127 7.2 KINETIC INEQUIVALENCE IN PHOTOCHEMICAL
REACTIONS 129 7.3 THE EFFECT OF LIGHT ENERGY ON REACTIVITY 138 7.4 THE
KINETICS OF PHOTORADICAL CHAINS 140 INDEX 145
|
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| id | DE-604.BV012495505 |
| illustrated | Illustrated |
| indexdate | 2025-02-20T06:38:42Z |
| institution | BVB |
| isbn | 0471983748 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008483042 |
| oclc_num | 38478502 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-634 DE-862 DE-BY-FWS |
| owner_facet | DE-19 DE-BY-UBM DE-634 DE-862 DE-BY-FWS |
| physical | X, 150 S. graph. Darst. |
| publishDate | 1998 |
| publishDateSearch | 1998 |
| publishDateSort | 1998 |
| publisher | Wiley |
| record_format | marc |
| spellingShingle | Kinetic peculiarities of solid phase reactions Chimie de l'état solide ram Cinétique chimique ram Chemical kinetics Solid state chemistry Kinetik (DE-588)4030665-3 gnd Festkörperreaktion (DE-588)4154188-1 gnd |
| subject_GND | (DE-588)4030665-3 (DE-588)4154188-1 |
| title | Kinetic peculiarities of solid phase reactions |
| title_auth | Kinetic peculiarities of solid phase reactions |
| title_exact_search | Kinetic peculiarities of solid phase reactions |
| title_full | Kinetic peculiarities of solid phase reactions E. Ya. Davydov ... |
| title_fullStr | Kinetic peculiarities of solid phase reactions E. Ya. Davydov ... |
| title_full_unstemmed | Kinetic peculiarities of solid phase reactions E. Ya. Davydov ... |
| title_short | Kinetic peculiarities of solid phase reactions |
| title_sort | kinetic peculiarities of solid phase reactions |
| topic | Chimie de l'état solide ram Cinétique chimique ram Chemical kinetics Solid state chemistry Kinetik (DE-588)4030665-3 gnd Festkörperreaktion (DE-588)4154188-1 gnd |
| topic_facet | Chimie de l'état solide Cinétique chimique Chemical kinetics Solid state chemistry Kinetik Festkörperreaktion |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008483042&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT davydoveya kineticpeculiaritiesofsolidphasereactions |
Indexes
THWS Schweinfurt Magazin
| Call Number: |
2801 2011:0086 |
|---|---|
| Copy 1 | bestellbar aus dem Magazin Available Place a Hold |