Transreactions in condensation polymers:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Weinheim [u.a.]
Wiley-VCH
1999
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturangaben |
| Physical Description: | XXIV, 485 S. Ill., graph. Darst. |
| ISBN: | 3527297901 |
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Record in the Search Index
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| adam_text | TRANSREACTIONS IN CONDENSATION POLYMERS STOYKO FAKIROV (ED.) WILEY-VCH
WEINHEIM * NEW YORK * CHICHESTER * BRISBANE * SINGAPORE * TORONTO
CONTENTS CHAPTER 1 INTERCHANGE REACTIONS IN CONDENSATION POLYMERS AND
THEIR ANALYSIS BY NMR SPECTROSCOPY H. R. KRICHELDORF, Z. DENCHEV 1.
INTRODUCTION 1 2. NUCLEAR MAGNETIC RESONANCE AS AN ANALYTICAL TOOL ( 1
H, 13 C, 15 N AND 29 SI NMR) 3 2.1. BASICS OF THE METHOD 3 2.2. HIGH
RESOLUTION NMR OF POLYMERS 16 3. INTERCHANGE REACTIONS INVOLVING
DIFFERENT FUNCTIONAL GROUPS 32 3.1. REACTIONS TAKING PLACE IN POLYESTERS
INVOLVING ESTER GROUPS . 32 3.2. REACTIONS TAKING PLACE IN POLYAMIDES
INVOLVING AMINE AND AMIDE GROUPS 50 3.3. INTERCHANGE REACTIONS INVOLVING
SI-0 BONDS 57 3.4. INTERCHANGE REACTIONS INVOLVING URETHANE AND UREA
GROUPS .. 66 4. CONCLUDING REMARKS 70 REFERENCES 71 CHAPTER 2 EFFECTS OF
CATALYSTS IN THE REACTIVE BLENDING OF BISPHENOL A POLYCARBONATE WITH
POLY(ALKYLENE TEREPHTHALATE)S F. PILATI, M. FIORINI, C. BERTI 1.
INTRODUCTION 79 1.1. AN OUTLOOK ON REACTIVE BLENDING OF POLYESTERS AND
POLYCARBONATES 79 1.2. BISPHENOL A POLYCARBONATE: AN OVERVIEW 80 1.3.
POLY(ALKYLENE TEREPHTHALATE)S: AN OVERVIEW 82 1.4. BLENDS OF PC AND
POLY(ALKYLENE TEREPHTHALATE)S: A LITERATURE SURVEY 83 X CONTENTS 2.
POSSIBLE REACTIONS OCCURRING DURING MELT-MIXING OF POLYESTERS AND PC 85
2.1. EXCHANGE REACTIONS 86 2.2. SIDE REACTIONS 90 2.3. CATALYST
INHIBITORS 91 3. EVOLUTION OF THE CHEMICAL STRUCTURE DURING MELT-MIXING
92 3.1. APPROACHES TO THE INVESTIGATION OF THE RESULTING CHEMICAL
STRUCTURE 93 3.2. EFFECTS OF CATALYSTS IN THE REACTIVE BLENDING OF
PC/POLYESTER SYSTEMS 100 4. CONCLUSIONS 120 REFERENCES 121 CHAPTER 3
MODEL STUDIES OF TRANSREACTIONS IN CONDENSATION POLYMERS J. DEVAUX 1.
INTRODUCTION 125 2. THEORETICAL 127 2.1. MICROSTRUCTURE OF
COPOLYCONDENSATES FROM TRANSREACTIONS ... 127 2.2. KINETICS OF
TRANSREACTION 133 3. APPLICATION TO THE PC/PBT SYSTEM 136 3.1.
MICROSTRUCTURAL STUDY 136 3.2. KINETIC STUDY 139 3.3. MECHANISM OF THE
PC/PBT TRANSCONDENSATION 143 4. GENERAL DISCUSSION AND CONCLUSION 155
REFERENCES 157 CHAPTER 4 COPOLYMER COMPOSITION: A KEY TO THE MECHANISMS
OF EXCHANGE IN REACTIVE POLYMER BLENDING G. MONTAUDO, C. PUGLISI, F.
SAMPERI 1. INTRODUCTION 159 2. EXCHANGE MECHANISMS OF REACTIVE POLYMERS
IN THE MELT 161 3. EXCHANGE REACTIONS OCCURRING BY INNER-INNER MECHANISM
(CASEL) 165 3.1. CAPPED PBT/PC BLENDS 165 3.2. CAPPED PET/PC BLENDS 170
4. EXCHANGE REACTIONS OCCURRING BY OUTER-INNER MECHANISMS 173 CONTENTS
XI 4.1. PET/PTX BLENDS (CASE2) 173 4.2. PET/PEA BLENDS (CASE3) 174 4.3.
PBT/PC BLENDS (CASE4) 180 4.4. PET/PC BLENDS (CASE4) 182 4.5. NYLON 6/PC
BLENDS (CASE 5) 183 5. CONCLUSIONS 189 APPENDIX MONTE CARLO MODELLING OF
EXCHANGE REACTIONS 190 REFERENCES 191 CHAPTER 5 INTERCHAIN
TRANSESTERIFICATION REACTIONS IN COPOLYESTERS J. ECONOMY, L. A.
SCHNEGGENBURGER, D. FRICH 1. INTRODUCTION AND BACKGROUND 195 2.
SYNTHESIS AND MICROSTRUCTURE 196 3. RANDOMISATION PROCESSES 201 4.
SEQUENCE ORDERING 205 5. ADHESIVE BONDS IN POLYESTERS FORMED BY ITR 209
5.1. LIQUID-CRYSTALLINE COPOLYESTERS 209 5.2. ITR IN THERMOSETTING
POLYESTERS 211 6. MECHANISM OF ADHESIVE BOND FORMATION 214 REFERENCES
216 CHAPTER 6 INHIBITION OF TRANSREACTIONS IN CONDENSATION POLYMERS N.
R. JAMES, S. S. MAHAJAN, S. SIVARAM 1. INTRODUCTION 219 1.1. POLYMER
BLENDS 219 1.2. REACTIVE COMPATIBILISATION 221 1.3. TRANSREACTION DURING
MELT-BLENDING 221 2. CONTROL OF TRANSESTERIFICATION IN POLYESTER BLENDS
226 2.1. INTRODUCTION 226 2.2. INHIBITORS FOR TRANSREACTION IN POLYESTER
AND POLYCARBONATE BLENDS 227 3. METHODS OF ANALYSING TRANSREACTIONS IN
POLYMER BLENDS 233 3.1. IR SPECTROSCOPY 233 XII CONTENTS 3.2. NMR
SPECTROSCOPY 239 3.3. DIFFERENTIAL SCANNING CALORIMETRY 250 3.4.
SIZE-EXCLUSION CHROMATOGRAPHY 262 4. CONCLUSIONS 263 REFERENCES 263
CHAPTER 7 REACTIVE MELT PROCESSING OF ALIPHATIC/AROMATIC POLYAMIDE
BLENDS: EFFECT ON MOLECULAR STRUCTURE, SEMICRYSTALLINE MORPHOLOGY AND
THERMAL PROPERTIES K. L. L. EERSELS, A. M. AERDTS, G. GROENINCKX 1.
GENERAL INTRODUCTION 267 2. INFLUENCE OF THE PROCESSING CONDITIONS ON
THE THERMAL BEHAVIOUR OF PA 46/PA 61 BLENDS 269 2.1. INTRODUCTION 269
2.2. COPRECIPITATION VERSUS MELT-MIXING 273 2.3. INFLUENCE OF PROCESSING
CONDITIONS 275 3. INFLUENCE OF THE BLEND COMPOSITION ON THE THERMAL
BEHAVIOUR OF PA 46/PA 61 BLENDS 278 3.1. CRYSTALLISATION AND MELTING
BEHAVIOUR 278 4. MOLECULAR CHARACTERISATION OF PA 46/PA 61 BLENDS BY
MEANS OF 13 C NMR 281 4.1. THEORETICAL CONSIDERATIONS 283 4.2.
CRYSTALLISATION BEHAVIOUR OF PA 46/PA 61 COPOLYMERS, PREPARED BY
MELT-BLENDING, AS A FUNCTION OF THE EXTRUSION TEMPERATURE, EXTRUSION
TIME, AND BLEND COMPOSITION 287 4.3. MOLECULAR STRUCTURE OF PA 46/PA 61
COPOLYMERS, PREPARED BY MELT-BLENDING, AS A FUNCTION OF THE EXTRUSION
TEMPERATURE, EXTRUSION TIME, AND BLEND COMPOSITION 289 5.
CHARACTERISATION OF TRANSAMIDATION REACTIONS IN PA 46/PA 61 BLENDS USING
GRADIENT ELUTION CHROMATOGRAPHY 293 5.1. INFLUENCE OF MELT-BLENDING
CONDITIONS ON THE DEGREE OF TRANSAMIDATION 295 5.2. INFLUENCE OF
END-GROUPS ON THE DEGREE OF TRANSAMIDATION .... 301 6. MORPHOLOGICAL
STRUCTURE OF MELT PROCESSED PA 46/PA 61 BLENDS .. 302 6.1.
SEMICRYSTALLINE MORPHOLOGY OF MELT PROCESSED PA 46/PA 61 BLENDS 302 6.2.
RELATION BETWEEN THE CRYSTALLINE MORPHOLOGY AND THE MELTING BEHAVIOUR OF
THE PA 46/PA 61 COPOLYMERS 311 CONTENTS XIII 7. GENERAL CONCLUSIONS 312
REFERENCES 315 CHAPTER 8 SEQUENTIAL REORDERING IN CONDENSATION
COPOLYMERS S. FAKIROV, Z. DENCHEV 1. EVIDENCE OF THE OCCURRENCE OF
CHEMICAL INTERACTIONS IN BLENDS OF CONDENSATION POLYMERS 319 1.1.
EVIDENCE DERIVED FROM THE BEHAVIOUR OF THE CRYSTALLINE PHASE 321 1.2.
EVIDENCE DERIVED FROM THE BEHAVIOUR OF THE AMORPHOUS PHASES 324 1.3.
EVIDENCE DERIVED FROM THE BEHAVIOUR OF CRYSTALLINE AND AMORPHOUS PHASES
324 1.4. EVIDENCE DERIVED FROM CHROMATOGRAPHIE METHODS 329 2.
MELTING-INDUCED SEQUENTIAL REORDERING IN CONDENSATION COPOLYMERS 331
2.1. MELTING-INDUCED SEQUENTIAL REORDERING IN CONDENSATION COPOLYMERS
OBTAINED FROM BLENDS OF IMMISCIBLE PARTNERS 333 2.2. MELTING-INDUCED
SEQUENTIAL REORDERING IN CONDENSATION COPOLYMERS OBTAINED FROM BLENDS OF
MISCIBLE PARTNERS 342 3. CRYSTALLISATION-INDUCED SEQUENTIAL REORDERING
IN CONDENSATION COPOLYMERS 347 3.1. EVIDENCE OF CRYSTALLISATION-INDUCED
REORDERING DERIVED FROM THE CRYSTALLINE PHASE BEHAVIOUR 348 3.2.
EVIDENCE OF CRYSTALLISATION-INDUCED REORDERING DERIVED FROM THE
AMORPHOUS PHASE BEHAVIOUR 359 4. MISCIBILITY-INDUCED SEQUENTIAL
REORDERING IN CONDENSATION COPOLYMERS OBTAINED FROM MISCIBLE AND
IMMISCIBLE PARTNERS 364 4.1. BACKGROUND 364 4.2. EXPERIMENTAL
OBSERVATIONS 365 4.3. MODELS AND THERMODYNAMIC CONSIDERATIONS 369 5.
STUDY OF THE SEQUENTIAL ORDER IN CONDENSATION COPOLYMERS BY MEANS OF
SIZE EXCLUSION CHROMATOGRAPHY AFTER SELECTIVE DEGRADATION 373 5.1.
BASICS OF THE SEC TECHNIQUE 374 5.2. SELECTIVE DEGRADATION OF
PC-CONTAINING CONDENSATION COPOLYMERS 377 5.3. SEQUENCE LENGTH
DETERMINATION IN POLY(ETHYLENE TEREPHTHALATE) - BISPHENOL A
POLYCARBONATE RANDOM COPOLYMERS AS REVEALED BY COMBINED NMR AND SEC
STUDIES 378 6. CONCLUSIONS 385 REFERENCES 386 XIV CONTENTS CHAPTER 9
X-RAY ANALYSIS OF TRANSESTERIFICATION IN BLENDS OF THERMOTROPIC
COPOLYESTERS J. BLACKWELL, C. M. MCCULLAGH 1. INTRODUCTION 391 2.
SCATTERING BY APERIODIC POLYMER CHAINS 395 3. X-RAY ANALYSIS OF
COPOLYESTER BLENDS 396 4. KINETICS OF TRANSESTERIFICATION 402 4.1.
RANDOM TRANSESTERIFICATION 403 4.2. TRANSESTERIFICATION KINETICS 405 5.
CONCLUSIONS 408 REFERENCES 409 CHAPTER 10 EFFECTS OF TRANSREACTIONS ON
THE COMPATIBILITY AND MISCIBILITY OF BLENDS OF CONDENSATION POLYMERS M.
XANTHOS, H. WARTH 1. PRINCIPLES OF BLEND COMPATIBILISATION 411 2.
TRANSREACTIONS APPLIED TO BLEND COMPATIBILISATION 412 3. TRANSREACTIONS
APPLIED TO SPECIFIC BINARY BLENDS 416 3.1. POLYESTER/POLYESTER BLENDS
416 3.2. POLYAMIDE/POLYAMIDE BLENDS 422 3.3. POLYAMIDE/POLYESTER BLENDS
423 REFERENCES 424 CHAPTER 11 EFFECT OF TRANSREACTIONS AND ADDITIONAL
CONDENSATION ON STRUCTURE FORMATION AND PROPERTIES OF CONDENSATION
POLYMERS F. J. BALTAE CALLEJA, S. FAKIROV, H. G. ZACHMANN 1. RELATIONSHIP
BETWEEN INTERCHAIN REACTIONS AND STRUCTURE OF CONDENSATION POLYMERS 429
1.1. EFFECT OF INTERCHAIN REACTIONS ON STRUCTURE FORMATION AND
PROPERTIES OF CONDENSATION POLYMERS 429 1.2. STRUCTURE FORMATION IN
BLENDS OF CONDENSATION POLYMERS WITH INTERCHAIN REACTIONS OCCURRING TO
VARIOUS EXTENTS 433 CONTENTS XV 1.3. EFFECT OF POLYMER STRUCTURE AND
MORPHOLOGY ON CHEMICAL INTERACTIONS IN CONDENSATION POLYMERS 443 2.
CHEMICAL INTERACTIONS ON THE INTERFACES AND INTERPHASES OF CONDENSATION
POLYMERS 445 2.1. HOMOCHEMICAL HEALING 445 2.2. HETEROCHEMICAL HEALING
AND HEALING WITH COUPLING AGENTS ... 448 2.3. CHEMICAL HEALING IN
CROSSLINKED POLYAMIDES 449 2.4. TRANSREACTIONS AT THE PHASE BOUNDARY OF
SEMISOLID BLENDS OF CONDENSATION POLYMERS 450 2.5. CHEMICALLY RELEASED
DIFFUSION VIA TRANSREACTIONS IN CONDENSATION POLYMERS 452 3. EFFECT OF
INTERCHAIN REACTIONS IN CONDENSATION POLYMERS ON THEIR MECHANICAL
PROPERTIES 453 3.1. MECHANICAL PROPERTIES AS REVEALED BY TENSILE
EXPERIMENTS ... 453 3.2. MECHANICAL PROPERTIES AS REVEALED BY
MICROHARDNESS 455 4. SOME PRACTICAL ASPECTS OF THE CHEMICAL INTERACTIONS
IN CONDENSATION POLYMERS 467 4.1. COPOLYCONDENSATES RESULTING FROM
SOLID-STATE ADDITIONAL CONDENSATION 467 4.2. COPOLYCONDENSATES RESULTING
FROM TRANSREACTIONS IN THE MELT 467 4.3. COMPATIBILISATION BY MEANS OF
INTERCHANGE REACTIONS 468 4.4. PREPARATION OF LAMINATES FROM FILMS OF
CONDENSATION POLYMERS BY MEANS OF INTERCHAIN REACTIONS 468 4.5.
UPGRADING OF MOLECULAR WEIGHT OF CONDENSATION POLYMERS BY MEANS OF
ADDITIONAL CONDENSATION IN THE SOLID STATE 469 4.6. RECYCLING OF
CONDENSATION POLYMERS BY MEANS OF INTERCHAIN REACTIONS 470 4.7.
IMPROVEMENTS OF THE FINISHED-PRODUCT PROPERTIES 472 REFERENCES 474
AUTHOR INDEX 481 SUBJECT INDEX 483
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| id | DE-604.BV012468527 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:28:07Z |
| institution | BVB |
| isbn | 3527297901 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008462028 |
| oclc_num | 41339393 |
| open_access_boolean | |
| owner | DE-703 DE-526 DE-634 DE-83 |
| owner_facet | DE-703 DE-526 DE-634 DE-83 |
| physical | XXIV, 485 S. Ill., graph. Darst. |
| publishDate | 1999 |
| publishDateSearch | 1999 |
| publishDateSort | 1999 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Transreactions in condensation polymers Stoyko Fakirov (ed.) Weinheim [u.a.] Wiley-VCH 1999 XXIV, 485 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturangaben Alliages de polymères ram Copolymères ram Polymers Polymérisation ram Produits de condensation (chimie) ram Copolymers Polymerization Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Polykondensate (DE-588)4540829-4 gnd rswk-swf Polykondensate (DE-588)4540829-4 s Chemische Reaktion (DE-588)4009853-9 s DE-604 Fakirov, Stoyko 1936- Sonstige (DE-588)115146210 oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008462028&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Transreactions in condensation polymers Alliages de polymères ram Copolymères ram Polymers Polymérisation ram Produits de condensation (chimie) ram Copolymers Polymerization Chemische Reaktion (DE-588)4009853-9 gnd Polykondensate (DE-588)4540829-4 gnd |
| subject_GND | (DE-588)4009853-9 (DE-588)4540829-4 |
| title | Transreactions in condensation polymers |
| title_auth | Transreactions in condensation polymers |
| title_exact_search | Transreactions in condensation polymers |
| title_full | Transreactions in condensation polymers Stoyko Fakirov (ed.) |
| title_fullStr | Transreactions in condensation polymers Stoyko Fakirov (ed.) |
| title_full_unstemmed | Transreactions in condensation polymers Stoyko Fakirov (ed.) |
| title_short | Transreactions in condensation polymers |
| title_sort | transreactions in condensation polymers |
| topic | Alliages de polymères ram Copolymères ram Polymers Polymérisation ram Produits de condensation (chimie) ram Copolymers Polymerization Chemische Reaktion (DE-588)4009853-9 gnd Polykondensate (DE-588)4540829-4 gnd |
| topic_facet | Alliages de polymères Copolymères Polymers Polymérisation Produits de condensation (chimie) Copolymers Polymerization Chemische Reaktion Polykondensate |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008462028&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT fakirovstoyko transreactionsincondensationpolymers |