Electron transfer in chemistry and biology: an introduction to the theory
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| Main Authors: | , |
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| Format: | Book |
| Language: | English |
| Published: |
Chichester [u.a.]
Wiley
1999
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| Series: | Wiley series in theoretical chemistry
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVI, 357 S. graph. Darst. |
| ISBN: | 0471967491 |
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| 245 | 1 | 0 | |a Electron transfer in chemistry and biology |b an introduction to the theory |c Alexander M. Kuznetsov ; Jens Ulstrup |
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| adam_text | ELECTRON TRANSFER IN CHEMISTRY AND BIOLOGY AN INTRODUCTION TO THE THEORY
ALEXANDER M. KUZNETSOV RUSSIAN ACADEMY OF SCIENCES, MOSCOW, RUSSIA JENS
ULSTRUP TECHNICAL UNIVERSITY OF DENMARK, LYNGBY, DENMARK JOHN WILEY &
SONS CHICHESTER * NEW YORK * WEINHEIM * BRISBANE * SINGAPORE * TORONTO
CONTENTS SERIES PREFACE XIII PREFACE XV 1 INTRODUCTION 1 1.1 ELECTRON
TRANSFER AS A UBIQUITOUS ELEMENTARY PROCESS IN CHEMISTRY AND BIOLOGY 1
1.2 ELECTRON TRANSFER IN RELATION TO OTHER ELECTRONIC AND PARTICLE
TRANSFER PROCESSES 2 1.3 THE PHYSICAL SCENARIO IN THE SIMPLEST CHEMICAL
PROCESS: ELECTRON TRANSFER 6 1.4 SOME HISTORICAL OBSERVATIONS 8
REFERENCES 10 2 SOME THEORETICAL PREREQUISITES 15 2.1 GENERAL 15 2.2
CLASSICAL AND QUANTUM MECHANICAL PARTICLE MOTION 15 2.2.1 THE HARMONIC
OSCILLATOR 17 2.2.2 THE MORSE OSCILLATOR 19 2.3 ELEMENTS OF STATISTICAL
PHYSICS 20 2.3.1 THE PARTITION FUNCTION 21 2.3.2 THE ENERGY 21 2.3.3 THE
GIBBS DISTRIBUTION 21 2.3.4 THE DENSITY MATRIX 22 2.4 THE
BORN-OPPENHEIMER APPROXIMATION AND POTENTIAL ENERGY SURFACES 22 2.5
ELEMENTS OF QUANTUM MECHANICAL PERTURBATION THEORY AND FERMI S GOLDEN
RULE 24 2.6 THE CONDON APPROXIMATION 28 2.7 THE PHYSICAL NATURE OF THE
PERTURBATION AND SOME CONCLUDING OBSERVATIONS 29 REFERENCES 30 VI
CONTENTS THE TUNNEL EFFECT IN PHYSICAL, CHEMICAL AND BIOLOGICAL
PROCESSES 33 3.1 GENERAL 33 3.2 THE PLANE WAVE AND RECTANGULAR BARRIERS
34 3.3 TUNNELLING BETWEEN STATIONARY BOUND STATES 36 3.4 RESONANCE
TUNNELLING AND TUNNELLING THROUGH SPATIALLY FLUCTUATING BARRIERS 39
3.4.1 RESONANCE TUNNELLING 40 3.4.2 TUNNELLING IN STATIONARY, SPATIALLY
RANDOMLY FLUCTUATING BARRIERS 41 3.5 VIBRATIONALLY ASSISTED TUNNELLING
42 3.6 TUNNEL TIMES 45 REFERENCES 47 ELEMENTS OF DIELECTRIC THEORY 49
4.1 GENERAL 49 4.2 NOTES ON LINEAR MEDIUM FIELD RESPONSES 49 4.3
DIELECTRIC MATERIALS 50 4.4 THE ELECTRIC FIELD AND THE ELECTRIC
INDUCTION 51 4.5 THE DIELECTRIC FUNCTION IN VIBRATIONALLY DISPERSIVE
SOLVENTS 53 4.6 NON-LOCAL DIELECTRIC THEORY 57 4.7 CONFIGURATIONAL
FLUCTUATIONS IN DIELECTRICS 60 4.7.1 INERTIAL AND INERTIA-LESS
ENVIRONMENTAL POLARIZATION 60 4.7.2 THE FLUCTUATION-DISSIPATION THEOREM
FOR DIELECTRIC POLARIZATION FLUCTUATIONS 63 4.7.3 FLUCTUATIONS IN LOCAL
DIELECTRICS 64 4.8 NOTES ON MOLECULAR APPROACHES TO AQUEOUS DIELECTRICS
AND DIELECTRIC FLUCTUATIONS 65 4.9 A FEW CONCLUDING NOTES 68 REFERENCES
68 CHARGE TRANSFER IN SOLIDS 71 5.1 GENERAL 71 5.2 THE SIMPLEST
ENVIRONMENTALLY LOCALIZED ELECTRONIC SYSTEM: THE POLARON 72 5.2.1 THE
LARGE POLARON 74 5.2.2 THE SMALL POLARON 75 5.3 LARGE AND SMALL POLARON
DYNAMICS 78 5.4 ELECTRONIC TRANSITIONS BETWEEN LOCALIZED CENTRES IN THE
SOLID STATE 80 5.4.1 THE QUANTUM MECHANICAL TRANSITION PROBABILITY 81
5.4.2 THE SEMI-CLASSICAL FRANCK-CONDON PRINCIPLE 82 5.5 SOME CONCLUDING
NOTES ON POLARON SYSTEMS 84 5.5.1 POLARON FORMATION IN TRANSITION METAL
OXIDES AND RELATED MATERIALS 85 5.5.2 CONDUCTIVITY IN ONE-DIMENSIONAL
MATERIALS 85 5.5.3 CONDUCTIVITY BY SOLITON-DEFECT MOBILITY 86 REFERENCES
87 CONTENTS VLL THE SIMPLEST CHEMICAL PROCESS: ELECTRON TRANSFER 91 6.1
GENERAL 91 6.2 NOTES ON TRANSITION STATE THEORY 91 6.3 FEATURES OF THE
MOLECULAR ELECTRON TRANSFER PROCESS 93 6.4 SYSTEM MODE SPECIFICATION 95
6.5 PHENOMENOLOGICAL SYSTEM MODE SPECIFICATION: THE SOLVENT 97 6.6 THE
ACTIVATION ENERGY AND GIBBS FREE ENERGY 100 6.7 THE SYMMETRY FACTOR AND
THE ACTIVATION GIBBS FREE ENERGY 102 6.8 THE REORGANIZATION ENERGY 105
6.9 THE ELECTRONIC TRANSMISSION COEFFICIENT 108 6.10 THE DIABATIC
ELECTRON TRANSFER RATE CONSTANT AND THE TRANSITION STATE THEORY
REVISITED 110 REFERENCES 111 SOME SELECTED EXPERIMENTAL DATA FOR SIMPLE
ELECTRON TRANSFER REACTIONS 115 7.1 GENERAL 115 7.2 FREE ENERGY
RELATIONS 116 7.3 INTER-REACTANT WORK TERMS 119 7.4 THE MOLECULAR AND
SOLVENT REORGANIZATION GIBBS FREE ENERGIES 121 7.4.1 SIMPLEST DEPENDENCE
ON E^ 1 * S~ L 123 7.4.2 A SIMPLE INTEGRATED APPROACH TO SOLVENT ET
PARAMETERS 123 7.4.3 DECONVOLUTION OF DYNAMIC AND STOCHASTIC SOLVENT
EFFECTS 124 7.5 THE ELECTRONIC TRANSMISSION COEFFICIENT 125 7.5.1 ET
BETWEEN MOLECULES IN FROZEN GLASSY MEDIA 127 7.5.2 CORRELATION BETWEEN
THE ELECTRONIC FACTOR AND LOW-LYING EXCITED STATE ENERGY GAPS 128 7.5.3
A COMPREHENSIVE GROUP OF ELECTRON TUNNEL DATA IN CHEMICAL AND BIOLOGICAL
ET 129 7.6 NOTES ON DISSOCIATIVE CHARGE TRANSFER 129 REFERENCES 132
TOWARDS MORE PRECISE ELECTRON TRANSFER THEORY 135 8.1 ADIABATIC AND
DIABATIC PROCESSES 135 8.2 A NOTE ON THE NATURE OF THE PERTURBATION IN
DIABATIC ET 138 8.3 CLASSICAL NUCLEAR MOTION AND NUCLEAR TUNNELLING 140
8.4 NUCLEAR TUNNEL EFFECTS IN DIABATIC ET REACTIONS 141 8.4.1 NUCLEAR
TUNNELLING IN DISPLACED ONE-DIMENSIONAL OSCILLATORS 142 8.4.2 A
COMBINATION SCHEME FOR HIGH- AND LOW-FREQUENCY NUCLEAR MOTION 144 8.4.3
THE INVERTED GIBBS FREE ENERGY REGION 147 8.5 NUCLEAR TUNNEL EFFECTS IN
VIBRATIONALLY DISPERSIVE SOLVENTS 148 8.6 LOW-TEMPERATURE ELECTRON
TRANSFER AND ENVIRONMENTAL DISPERSION 152 8.7 PARTIALLY AND TOTALLY
ADIABATIC REACTIONS 154 8.8 EXPERIMENTAL INVESTIGATIONS OF CHEMICAL
PROCESSES AT LOW TEMPERATURES AND IN THE INVERTED GIBBS FREE ENERGY
REGION 154 CONTENTS 8.8.1 NUCLEAR TUNNELLING IN PHYSICAL SYSTEMS 154
8.8.2 NUCLEAR TUNNELLING IN CHEMICAL SYSTEMS AT LOW TEMPERATURES AND IN
THE INVERTED GIBBS FREE ENERGY REGION 154 REFERENCES 156 OPTICAL CHARGE
TRANSFER IN ALLOWED AND FORBIDDEN TRANSITIONS 159 9.1 GENERAL 159 9.2
OPTICAL AND THERMAL ELECTRONIC TRANSITIONS 160 9.2.1 QUANTIZATION OF THE
ELECTROMAGNETIC FIELD 160 9.2.2 MODULATION BY A NON-ABSORBING SOLVENT
161 9.2.3 FIELD-MOLECULE PERTURBATIONS 162 9.2.4 TRANSITION
PROBABILITIES FOR LIGHT ABSORPTION AND EMISSION 162 9.2.5 OBSERVABLES
FOR OPTICAL TRANSITIONS. ABSORPTION 164 9.2.6 OBSERVABLES FOR OPTICAL
TRANSITIONS. SPONTANEOUS AND STIMULATED EMISSION 166 9.3 OPTICAL CHARGE
TRANSFER BANDSHAPES 166 9.3.1 THE STRONG-COUPLING LIMIT 168 9.3.2 THE
WEAK-COUPLING LIMIT 170 9.3.3 LOCAL MODE REORGANIZATION 170 9.3.4
TRANSITIONS COUPLED TO RADIATIONLESS EXCITED STATE DECAY. BROAD
LORENTZIAN AND VOIGTIAN BANDSHAPES 171 9.4 SOME OBSERVATIONS ON
EXPERIMENTAL OPTICAL BANDSHAPE ANALYSIS 172 9.4.1 WEAK-COUPLING SYSTEMS
172 9.4.2 STRONG-COUPLING SYSTEMS 173 9.4.2.1 SOLVATOCHROMIC BAND
FEATURES OF THE BETAINES 173 9.4.2.2 CHARGE TRANSFER IN THE [FE(CN) 6 ]
4 * MV 2+ ION PAIR 174 9.4.2.3 PHOTO-INDUCED ET IN THE AQUEOUS [FE(CN)
6 ] 3 - /4 ~ SYSTEM AT HIGH CONCENTRATION 174 9.5 SYMMETRY-FORBIDDEN
TRANSITIONS 175 9.5.1 HERZBERG-TELLER ADIABATIC SEPARATION SCHEMES AND
ORBITALLY SYMMETRY-FORBIDDEN TRANSITIONS 175 9.5.2 SOME OBSERVATIONS OF
TEMPERATURE DEPENDENCE IN HERZBERG-TELLER TRANSITIONS 178 9.6 SOME
CONCLUDING NOTES 178 REFERENCES 179 ELEMENTS OF PROTON AND OTHER
LIGHT-ATOM TRANSFER THEORY 183 10.1 GENERAL 183 10.2 PROTONS IN
MOLECULES 184 10.3 INTERACTIONS OF THE BOUND PROTON WITH THE MOLECULAR,
SOLVENT AND CONFORMATIONAL ENVIRONMENT 185 10.3.1 LOCAL MODE COUPLING
185 10.3.2 COUPLING TO A POLAR CONTINUUM 186 10.3.3 PROTON COUPLING TO A
CONFORMATIONAL MACROMOLECULAR ENVIRONMENT 186 10.3.4 INTERACTIONS
BETWEEN THE PROTON DONOR AND ACCEPTOR FRAGMENTS 187 CONTENTS IX 10.4 THE
BORN-OPPENHEIMER APPROXIMATION AND THE FRANCK-CONDON PRINCIPLE FOR
PROTON TRANSFER 187 10.4.1 THE BORN-OPPENHEIMER APPROXIMATION FOR PROTON
TRANSFER 188 10.4.2 A GENERALIZED FRANCK-CONDON PRINCIPLE 188 10.5
PROTON TRANSFER BETWEEN SPATIALLY FIXED MOLECULAR FRAGMENTS 189 10.5.1
THE PROTON TRANSFER RATE CONSTANT 189 10.5.2 SPECIFIC LIMITING
INTERACTIONS 190 10.6 SOME IMPORTANT PROTON TRANSFER CORRELATIONS: THE
BR0NSTED RELATION AND THE KINETIC DEUTERIUM ISOTOPE EFFECT 192 10.6.1
THE BR0NSTED RELATION 192 10.6.2 TEMPERATURE EFFECTS AND THE KINETIC
DEUTERIUM ISOTOPE EFFECT 194 10.7 FLUCTUATIONAL BARRIER PREPARATION,
RELAXATION AND MOLECULAR SOLVENT EFFECTS 197 10.7.1 FLUCTUATIONAL
BARRIER PREPARATION AND GATED PT 197 10.7.2 SOME RELAXATIONAL SOLVENT
EFFECTS IN FAST CHEMICAL PT 199 10.7.3 MOLECULAR SOLVENT EFFECTS AND PT
200 10.8 SOME NOTES ON UNTRADITIONAL PROTON AND HYDROGEN ATOM TRANSFER
SYSTEMS 203 10.8.1 LOW-TEMPERATURE HYDROGEN ATOM TRANSFER 203 10.8.2
ULTRAFAST PT OF MOLECULAR SYSTEMS IN EXCITED ELECTRONIC STATES 204
10.8.3 HYDROGEN AND HYDRIDE TRANSFER IN TRANSITION METAL COMPLEXES 204
10.8.4 VECTORIAL PT IN BIOLOGICAL SYSTEMS 204 10.8.5 PROTON CONDUCTION
IN SOLIDS 204 REFERENCES 205 11 THE ELECTROCHEMICAL PROCESS 209 11.1
GENERAL 209 11.2 BULK AND SURFACE PROPERTIES OF PURE METALS AND
SEMICONDUCTORS 211 11.2.1 BULK METALS AND SEMICONDUCTORS 211 11.2.2
METAL AND SEMICONDUCTOR SURFACES 212 11.3 THE METAL
ELECTRODE-ELECTROLYTE INTERFACE 214 11.4 THE FUNDAMENTAL ELECTROCHEMICAL
PROCESS AT METAL, SEMIMETAL AND SEMICONDUCTOR ELECTRODES 217 11.4.1
METAL ELECTRODES 220 11.4.2 SEMIMETAL ELECTRODES 222 11.4.3
SEMICONDUCTOR ELECTRODES 223 11.4.4 SOME NOTES ON EXPERIMENTAL
INVESTIGATIONS OF SIMPLE ELECTROCHEMICAL ET REACTIONS AT METAL AND
SEMICONDUCTOR ELECTRODES 224 11.5 FEATURES OF THE ELECTROCHEMICAL
ELECTRON TUNNEL FACTOR 225 11.6 ELECTROCHEMICAL PROCESSES VIA SURFACE
ADSORBATE STATES: AN ELEMENT OF ELECTROCATALYSIS 228 11.7 A NOTE ON
ADIABATIC ELECTROCHEMICAL ELECTRON TRANSFER 229 11.8 A NOTE ON
PERSPECTIVES AND OUTLOOKS IN THE THEORY OF THE FUNDAMENTAL
ELECTROCHEMICAL PROCESS 231 REFERENCES 233 X CONTENTS 12 ELEMENTS OF
LONG-RANGE AND MULTI-LEVEL ELECTRON TRANSFER 237 12.1 MULTI-LEVEL
ELECTRONIC PROCESSES IN CHEMISTRY AND BIOLOGY 237 12.1.1 MULTI-LEVEL
PHYSICAL ELECTRONIC PROCESSES 237 12.1.2 LONG-RANGE AND SUPEREXCHANGE ET
IN CHEMICAL AND BIOLOGICAL SYSTEMS 238 12.1.3 COHERENT MULTI-STEP ET AND
DYNAMICALLY POPULATED INTERME- DIATE STATES 240 12.2 ET ROUTES AND
MOLECULAR GROUP SEPARATION SCHEMES 240 12.2.1 LONG-RANGE ET AND
SPLITTING OF ENERGY EIGENVALUES 241 12.2.2 PERTURBATION SCHEMES AND
LONG-RANGE ET AS A SCATTERING PROCESS 243 12.2.3 NOTES ON EXPERIMENTAL
INVESTIGATIONS OF LONG-RANGE ET IN HOMOGENEOUS SOLUTION 244 12.3
MODULATION OF THE TUNNEL FACTOR AND SELF-CONSISTENT
ELECTRONIC-VIBRATIONAL INTERACTIONS IN LONG-RANGE ET 245 12.3.1
ENVIRONMENTAL WAVE FUNCTION MODULATION IN THE CONDON APPROXIMATION 246
12.4 COHERENT TWO-STEP ELECTRON TRANSFER 249 12.4.1 A NOTE ON
THREE-LEVEL RESONANCE ELECTRON TUNNELLING 250 12.4.2 THE QUASICLASSICAL
APPROXIMATION TO NUCLEAR DYNAMICS IN THREE-LEVEL MOLECULAR ET 250 12.4.3
INTERMEDIATE STATE VIBRATIONAL RELAXATION 252 12.4.4 QUANTUM MECHANICAL
APPROACH TO THREE-LEVEL ET 253 12.4.5 SOME NOTES ON THE OBSERVATION OF
COHERENT MULTI-STEP ET 254 12.5 A FEW OBSERVATIONS ON RELATIONS BETWEEN
THERMAL AND OPTICAL MULTI-LEVEL ELECTRONIC TRANSITIONS 257 12.6
LONG-RANGE ET IN NON-TRADITIONAL INTERFACIAL ELECTROCHEMICAL ET SYSTEMS:
IN SITU STM OF LARGE ADSORBATES AND CONTINUOUS PHASE TRANSITIONS IN
TWO-DIMENSIONAL ELECTROCHEMICAL SURFACE LAYERS 259 12.6.1 IN SITU STM OF
LARGE ADSORBATE MOLECULES 260 12.6.2 CONTINUOUS PHASE TRANSITIONS IN
INTERFACIAL TUNNEL SYSTEMS 263 REFERENCES 265 13 STOCHASTIC VIEWS IN
CHEMICAL RATE THEORY 269 13.1 DYNAMIC AND STOCHASTIC APPROACHES TO
CHEMICAL PROCESSES IN CONDENSED MEDIA 269 13.2 DIFFUSION AND STOCHASTIC
PROCESSES IN EXTERNAL POTENTIALS 271 13.3 REACTIVE ONE-DIMENSIONAL
DIFFUSION ACROSS A BARRIER CLOSE TO EQUILIBRIUM 273 13.4 A VIEW OF
DIABATIC AND ADIABATIC ELECTRON TRANSFER WITH RELAXATION AND DIFFUSION
IN MULTI-DIMENSIONAL ENVIRONMENTAL POLARIZATION MODES 276 13.4.1
POTENTIAL SURFACES SPANNED BY GIBBS FREE ENERGY FLUCTUATIONS 276 13.4.2
IMPLICATIONS OF SINGLE-MODE REACTIVE ENERGY DIFFUSION 279 13.5 SOLVENT
AND MOLECULAR STRUCTURAL FEATURES 281 13.5.1 THE NOTION OF TIME
DEPENDENT FRICTION 281 13.5.2 MOLECULAR HIGH-FREQUENCY NUCLEAR MOTION
283 CONTENTS XI 13.5.3 SOLVENT RELAXATION AND LOCAL LOW-FREQUENCY
NUCLEAR MOTION IN DIABATIC AND ADIABATIC ELECTRON AND PROTON TRANSFER
283 13.5.4 TWO-DIMENSIONAL REACTIVE DIFFUSION 287 13.5.5 CONCLUDING
NOTES ON NON-STATIONARY DIFFUSION AND A FORMAL CORRELATION BETWEEN
DIFFUSION COEFFICIENTS AND SOLUTE-SOLVENT INTERACTION TERMS 289 13.6
NOTES ON MOLECULAR REPRESENTATIONS OF DIFFUSION AND SOLVENT CONTROL 291
13.6.1 NOTES ON NUMERICAL APPROACHES 291 13.6.2 ANALYTICAL FORMALISM IN
THE MEAN SPHERICAL APPROXIMATION 292 13.7 SOME EXPERIMENTAL OBSERVATIONS
295 13.7.1 STEADY-STATE RELAXATION AND VISCOSITY PATTERNS 296 13.7.2
CHARGE TRANSFER CASES IN MULTI-TIME DOMAINS AND MOLECULAR STRUCTURAL
EFFECTS 296 REFERENCES 298 14 ELEMENTS OF CHARGE TRANSFER IN BIOLOGICAL
SYSTEMS 301 14.1 BIOLOGICAL STRUCTURES AND CHARGE TRANSPORT CHAINS 301
14.2 BIOLOGICAL CHARGE TRANSFER SITES IN SOLVATED PROTEIN ENVIRONMENTS
AND BIOLOGICAL ORGANIZATION OF ELECTRON AND PROTON TUNNELLING 304 14.2.1
ELECTRONIC-CONFORMATIONAL INTERACTIONS 304 14.2.2 ELECTROSTATIC AND
SOLVENT INTERACTIONS IN ANISOTROPIC DIELECTRIC MEDIA 306 14.2.3 THE
ELECTRONIC TUNNEL FACTOR 307 14.3 LONG-RANGE ELECTRON TRANSFER IN
SELECTED BIOLOGICAL SYSTEMS 309 14.3.1 ET IN INDIVIDUAL METALLOPROTEINS
310 14.3.1.1 INTRAMOLECULAR ET IN SINGLE-HAEME CYTOCHROMES AND
MYOGLOBINS 310 14.3.1.2 ET AND MOLECULAR RECOGNITION OF THE BLUE COPPER
PROTEINS 312 14.3.1.3 THE MULTI-CENTRE ET HAEMOPROTEINS CYT C$ AND CYT
C-I 313 14.3.2 ORGANIZED ET IN MULTI-CENTRE REDOX ENZYMES AND
SUPRAMOLECULAR PROTEIN COMPLEXES 314 14.3.2.1 THE COPPER OXIDASES 314
14.3.2.2 A VIEW ON MULTI-ET IN THE NITROGENASE ENZYME COMPLEXES 315
14.3.2.3 ET IN THE BACTERIAL PHOTOSYNTHETIC REACTION CENTRES 317 14.4
SELECTED BIOLOGICAL PROTON TRANSFER SYSTEMS 321 14.4.1 LARGE KINETIC
ISOTOPE EFFECTS IN ENZYMATIC PROTON AND HYDROGEN TRANSFER 322 14.4.2
PROTON TRANSFER AND CONFORMATIONAL DYNAMICS IN CARBOXYPEP- TIDASE A
CATALYSED PEPTIDE AND ESTER HYDROLYSIS 322 14.4.3 FLUCTUATIONAL PT
BARRIER PREPARATION IN CHYMOTRYPSIN CATALYSIS 323 14.4.4 ORGANIZED
PROTON TRANSFER: THE PROTON PUMPS 325 REFERENCES 328 XU CONTENTS 15
PERSPECTIVES AND OUTLOOK 333 15.1 FUNDAMENTALS OF CHARGE TRANSFER THEORY
333 15.1.1 FUNDAMENTALS OF MOLECULAR APPROACHES TO CHARGE TRANSFER IN
CONDENSED MEDIA 333 15.1.2 INTERFACIAL ELECTRON TRANSFER 334 15.1.3 NEW
AREAS IN THE MELTING POT: ET NEAR PHASE TRANSITIONS AND COHERENT
MULTI-ET 335 15.2 TECHNOLOGICAL PERSPECTIVES FOR CHARGE TRANSFER THEORY
335 15.2.1 FUNCTIONAL MOLECULAR MATERIALS 336 15.2.2 FUNCTIONAL
SUPRAMOLECULAR ORGANIZATION 336 15.2.3 MOLECULAR AND SUPRAMOLECULAR
FUNCTION 336 15.2.3.1 MOLECULAR ELECTRONIC RECTIFICATION AND
AMPLIFICATION 336 15.2.3.2 QUANTUM SIZE EFFECTS AND SINGLE-ELECTRON
TUNNELLING (SET) 337 15.2.3.3 A WORKING BIOLOGICAL MOLECULAR ELECTRONIC
DEVICE: BACTERIORHODOPSIN 338 REFERENCES 339 APPENDIX A 341 DERIVATION
OF THE QUANTUM MECHANICAL RATE CONSTANT, EQUATION (5.34) 341 APPENDIX B
343 DERIVATION OF EQUATION (8.24) 343 APPENDIX C 345 ANALYSIS OF
EQUATIONS (5.34) AND (8.51) 345 CL. STRONG ELECTRONIC-VIBRATIONAL
COUPLING 345 C2. WEAK ELECTRONIC-VIBRATIONAL COUPLING 346 APPENDIX D 349
THE MAXWELLIAN VELOCITY DISTRIBUTION AT HIGH FRICTION 349 REFERENCES 350
INDEX 351
|
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| author | Kuznecov, Aleksandr M. Ulstrup, Jens |
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| id | DE-604.BV012455263 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:27:52Z |
| institution | BVB |
| isbn | 0471967491 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-008451784 |
| oclc_num | 611605214 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-703 DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-29T DE-20 DE-11 DE-188 |
| owner_facet | DE-91G DE-BY-TUM DE-703 DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-29T DE-20 DE-11 DE-188 |
| physical | XVI, 357 S. graph. Darst. |
| publishDate | 1999 |
| publishDateSearch | 1999 |
| publishDateSort | 1999 |
| publisher | Wiley |
| record_format | marc |
| series2 | Wiley series in theoretical chemistry |
| spelling | Kuznecov, Aleksandr M. Verfasser aut Electron transfer in chemistry and biology an introduction to the theory Alexander M. Kuznetsov ; Jens Ulstrup Chichester [u.a.] Wiley 1999 XVI, 357 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wiley series in theoretical chemistry Biologie (DE-588)4006851-1 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf Elektronentransfer (DE-588)4151907-3 gnd rswk-swf Elektronentransfer (DE-588)4151907-3 s Chemie (DE-588)4009816-3 s DE-604 Biologie (DE-588)4006851-1 s Ulstrup, Jens Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008451784&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kuznecov, Aleksandr M. Ulstrup, Jens Electron transfer in chemistry and biology an introduction to the theory Biologie (DE-588)4006851-1 gnd Chemie (DE-588)4009816-3 gnd Elektronentransfer (DE-588)4151907-3 gnd |
| subject_GND | (DE-588)4006851-1 (DE-588)4009816-3 (DE-588)4151907-3 |
| title | Electron transfer in chemistry and biology an introduction to the theory |
| title_auth | Electron transfer in chemistry and biology an introduction to the theory |
| title_exact_search | Electron transfer in chemistry and biology an introduction to the theory |
| title_full | Electron transfer in chemistry and biology an introduction to the theory Alexander M. Kuznetsov ; Jens Ulstrup |
| title_fullStr | Electron transfer in chemistry and biology an introduction to the theory Alexander M. Kuznetsov ; Jens Ulstrup |
| title_full_unstemmed | Electron transfer in chemistry and biology an introduction to the theory Alexander M. Kuznetsov ; Jens Ulstrup |
| title_short | Electron transfer in chemistry and biology |
| title_sort | electron transfer in chemistry and biology an introduction to the theory |
| title_sub | an introduction to the theory |
| topic | Biologie (DE-588)4006851-1 gnd Chemie (DE-588)4009816-3 gnd Elektronentransfer (DE-588)4151907-3 gnd |
| topic_facet | Biologie Chemie Elektronentransfer |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008451784&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT kuznecovaleksandrm electrontransferinchemistryandbiologyanintroductiontothetheory AT ulstrupjens electrontransferinchemistryandbiologyanintroductiontothetheory |