Modern aspects of emulsion science:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Cambridge
Royal Soc. of Chemistry
1998
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII, 430 S. Ill., graph. Darst. |
| ISBN: | 0854044396 |
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Record in the Search Index
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| adam_text | MODERN ASPECTS OF EMULSION SCIENCE EDITED BY BERNARD P. BINKS DEPARTMENT
OF CHEMISTRY, UNIVERSITY OFHULL, UK THE ROYAL SOCIETY OF CHEMISTRY
INFORMATION SERVICES CONTENTS CHAPTER 1 EMULSIONS - RECENT ADVANCES IN
UNDERSTANDING BERNARD P BINKS 1.1 1.2 1.3 1.4 1.5 1.6 1.7 INTRODUCTION
EMULSION TYPE AND THE SYSTEM HYDROPHILE-LIPOPHILE BALANCE 1.2.1
EMULSIONS OF TWO LIQUID PHASES 1.2.2 EMULSIONS OF THREE LIQUID PHASES
PHASE INVERSION EMULSION STABILITY 1.4.1 CREAMING 1.4.2 FLOCCULATION
1.4.3 COALESCENCE 1.4.4 OSTWALD RIPENING GEL EMULSIONS FORCES BETWEEN
OIL-WATER INTERFACES 1.6.1 FORCES BETWEEN EMULSION DROPS 1.6.2 FORCES
BETWEEN A DROP AND A PLANAR OIL-WATER INTERFACE REFERENCES 1 2 2 8 10 13
13 17 26 33 38 42 42 44 48 CHAPTER 2 EMULSION FORMATION 56 PIETER
WALSTRA AND PAULINE E.A. SMULDERS 2. 1 INTRODUCTION 56 2.2 REGIMES 58
2.3 DROPLET BREAK-UP 60 2.3.1 LAMINAR FLOW 61 2.3.2 TURBULENT FLOW 66
.2.3.3 EFFECT OF DROPLET VISCOSITY 69 2.3.4 EFFECTS OF SCALE AND
CONTINUOUS PHASE VISCOSITY 73 2.4 ROLES OF THE SURFACTANT 74 2.4.1
SURFACTANT PROPERTIES 76 2.4.2 EFFECTIVE INTERFACIAL TENSION 79 2.4.3
EFFECT ON DROPLET DEFORMATION 83 2.4.4 PREVENTING RECOALESCENCE 88 2.4.5
SPONTANEOUS EMULSIFICATION 91 VLLL CONTENTS 2.5 FURTHER CONSIDERATIONS
92 2.5.1 EFFECTS OF VOLUME FRACTION 92 2.5.2 EMULSIFICATION EFFICIENCY
95 2.5.3 MEMBRANE EMULSIFICATION 97 2.6 CONCLUDING REMARKS 97 2.7
REFERENCES 98 CHAPTER 3 EMULSION FORMATION BY NUCLEATION AND GROWTH
MECHANISMS 100 BRIAN VINCENT, ZOLTAN KIRALY AND TIM M. OBEY 3.1
INTRODUCTION 100 3.2 PHYSICAL METHODS 105 3.3 CHEMICAL METHODS 110 3.4
REFERENCES 114 CHAPTER 4 EMULSION FLOCCULATION AND CREAMING 115 MARGARET
M. ROBINS AND DAVID J. HIBBERD 4.1 INTRODUCTION 115 4.1.1 INSTABILITY
PROCESSES 115 4.1.2 STRATEGIES FOR STABILITY 117 4.1.3 INTERACTION
POTENTIAL BETWEEN DROPLETS 118 4.1.4 FLOCCULATION DUE TO POLYMERS 120
4.2 EMULSION CREAMING 122 4.2.1 INTRODUCTION AND THEORETICAL PRINCIPLES
122 4.2.2 ULTRASONIC MONITORING OF CREAMING 124 4.2.3 CREAMINGOF
POLYDISPERSE EMULSIONS WITHOUT ADDED POLYMER 128 4.2.4 CREAMING OF
EMULSIONS WITH LOW CONCENTRATIONS OF NON-ADSORBING POLYMER 130 4.2.5
CREAMING OF EMULSIONS WITH HIGH CONCENTRATIONS OF NON-ADSORBING POLYMER
131 4.2.6 CREAMINGOF EMULSIONS WITH ADSORBING POLYMER 133 4.3
NON-INTRUSIVE DETERMINATION OF FLOCCULATION IN EMULSIONS 137 4.3.1
INTRODUCTION AND THE PRINCIPLE OF ULTRASONIC SCATTERING 137 4.3.2
ULTRASONIC SCATTERING FROM UNFLOCCULATED EMULSIONS 139 4.3.3 ULTRASONIC
SCATTERING FROM EMULSIONS DURING DEPLETION FLOCCULATION 141 4.4 SUMMARY
141 4.5 REFERENCES 143 CHAPTER 5 RHEOLOGY OF EMULSIONS - THE
RELATIONSHIP TO STRUCTURE AND STABILITY 145 ERIC DICKINSON 5.1
INTRODUCTION 145 5.2 THEORETICAL BACKGROUND 146 5.2.1 DILUTE DISPERSIONS
OF SPHERICAL PARTICLES 147 CONTENTS IX 5.2.2 CONCENTRATED DISPERSIONS OF
SPHERICAL PARTICLES 150 5.2.3 FLOCCULATED EMULSIONS 152 5.3 EXPERIMENTAL
INVESTIGATIONS 157 5.3.1 NON-FLOCCULATED EMULSIONS 157 5.3.2 FLOCCULATED
EMULSIONS 163 5.4 REFERENCES 171 CHAPTER 6 PHASE INVERSION AND DROP
FORMATION IN AGITATED LIQUID-LIQUID DISPERSIONS IN THE PRESENCE OF
NONIONIC SURFACTANTS 175 BRIAN W. BROOKS, HOWARD N. RICHMOND AND MOHAMED
ZERFA 6.1 INTRODUCTION 175 6.2 BASIC PRINCIPLES OF PHASE INVERSION 176
6.2.1 DISSOLUTION STATE OF NONIONIC SURFACTANTS 177 6.2.2 CHANGE OF
PHASE BEHAVIOUR WITH TEMPERATURE 178 6.2.3 FACTORS AFFECTING PHASE
INVERSION 179 6.3 DYNAMIC INVERSION MAPS 189 6.4 CATASTROPHIC INVERSION
191 6.5 TRANSITIONAL INVERSION 194 6.6 PARTITIONING OF SURFACTANT 197
6.6.1 BASIS OF PHASE SEPARATION MODEL 198 6.6.2 THEORY APPLIED TO
TRANSITIONAL INVERSION 198 6.6.3 LUMPING OF DISTRIBUTED SURFACTANT TERMS
200 6.7 CONCLUDING REMARKS 201 6.8 REFERENCES 202 CHAPTER 7 COALESCENCE
IN EMULSIONS 205 ALEXEY S. KABALNOV 7.1 INTRODUCTION 205 7.2
THERMODYNAMIC PROPERTIES OF SURFACTANT MONOLAYERS: PHASE BEHAVIOR,
MONOLAYER ELASTICITY AND INTERFACIAL TENSION 206 7.2.1 SURFACTANT
ADSORPTION AND MICELLIZATION 207 7.2.2 ELASTICITY OF MONOLAYERS 207
7.2.3 SPONTANEOUS CURVATURE 211 7.2.4 IMPLICATIONS FOR THE PHASE
BEHAVIOR 214 7.2.5 INTERFACIAL TENSION 216 7.3 EXPERIMENTAL TRENDS IN
MACROEMULSION STABILITY 218 7.3.1 SURFACTANT NATURE: ORIENTED WEDGE
TREND 218 7.3.2 BANCROFT S RULE 220 7.3.3 HLB SCALE 221 7.3.4 MOLECULAR
COMPLEXES 223 7.3.5 PIT CONCEPT 224 7.3.6 OPTIMAL SURFACTANT
FORMULATION 226 7.3.7 OTHER EMPIRICAL CORRELATIONS 227 7.3.8 MULTIPLE
EMULSIONS 229 X CONTENTS 7.3.9 SURFACTANT CONCENTRATION: TIGHT MONOLAYER
PACKING 229 7.3.10 CONCENTRATION FOR FORMATION OF BLACK FILMS, C BLACK
230 7.3.11 STABILIZATION BY A LAMELLAR PHASE 231 7.3.12 EFFECTOF VOLUME
FRACTIONOF DISPERSE PHASE AND DROPLET SIZE 232 7.4 THEORYOF EMULSION
COALESCENCE 232 7.4.1 RUPTURE OF SINGLE FILMS AND THE EMULSION LIFETIME
232 7.4.2 ACTIVATION ENERGY: DE VRIES THEORY 234 7.4.3 THE
KABALNOV-WENNERSTROEM THEORY 237 7.4.4 NUCLEATION PORE IN
MULTILAMELLAR-COVERED EMULSION FILMS 247 7.5 THE KABALNOV-WENNERSTROEM
THEORY VERSUS EXPERIMENT 248 7.5.1 EXPERIMENTAL MEASUREMENTS OF THE
ACTIVATION ENERGY AND THE PRE-EXPONENT 248 7.5.2 C 12 E 5
-N-OCTANE-WATER-NACL SYSTEM: OVERALL TREND 250 7.5.3 WINSOR III REGION
252 7.5.4 WINSOR II REGION 253 7.5.5 PRE-EXPONENT 254 7.5.6 SURFACTANT
CONCENTRATION 255 7.6 SUMMARY AND OUTLOOK 256 7.7 REFERENCES 257 CHAPTER
8 LIFETIME AND DESTRUCTION OF CONCENTRATED EMULSIONS UNDERGOING
COALESCENCE 261 BENEDICTE DEMINIERE, ANNIE COLIN, FERNANDO LEAL CALDERON
AND JEROEME BIBETTE 8.1 INTRODUCTION 261 8.2 THIN FILM METASTABILITY:
BACKGROUND 263 8.3 DESTRUCTION OF CONCENTRATED EMULSIONS UNDERGOING
COALESCENCE 266 8.4 DROPLET GROWTH IN DENSE EMULSIONS UNDERGOING
COALESCENCE 268 8.5 GROWTH MODEL FOR DENSE EMULSIONS 272 8.6
DETERMINATION OF A^R), CO 0 AND A 275 8.7 DISCUSSION 281 8.8
CONCLUSION 290 8.9 REFERENCES 290 CHAPTER 9 MOLECULAR DIFFUSION IN
EMULSIONS AND EMULSION MIXTURES 292 JEFFRY G. WEERS 9.1 OSTWALD RIPENING
292 9.1.1 THE KELVIN EQUATION 292 9.1.2 LIFSHITZ-SLEZOV-WAGNER (LSW)
THEORY 293 9.2 DEVIATIONS FROM LSW THEORY 297 9.2.1 EFFECT OFBROWNIAN
MOTION 297 9.2.2 EFFECT OF DISPERSE PHASE VOLUME FRACTION 298 9.2.3 ROLE
OF MICELLES IN FACILITATING MOLECULAR DIFFUSION 299 9.3 STABILIZATION
OFEMULSIONS WITHRESPECTTO OSTWALD RIPENING 303 CONTENTS XI 9.3.1 OSTWALD
RIPENING IN EMULSIONS CONTAINING TWO DISPERSE PHASE COMPONENTS - 303
9.3.2 EFFECT OF THE INTERFACIAL LAYER IN SLOWING OSTWALD RIPENING 305
9.3.3 OTHER WAYS OF SLOWING OSTWALD RIPENING 308 9.4 EFFECT OF OSTWALD
RIPENING ON INITIAL DROPLETSIZE 308 9.5 COMPOSITION RIPENING 310 9.6
PRAETICAL IMPORTANCEOF MOLECULAR DIFFUSION 314 9.6.1 OSTWALD RIPENING IN
FLUOROCARBON EMULSIONS 314 9.6.2 OSTWALD RIPENING IN TRIGLYCERIDE
EMULSIONS WITH ADDED ETHANOL 318 9.6.3 MINIEMULSION POLYMERIZATION 318
9.6.4 USE OF COMPOSITION RIPENING TO PRODUCE LARGE MONODISPERSE LATEX
PARTICLES 320 9.6.5 STABILIZATION OF GAS EMULSIONS 320 9.7 REFERENCES
325 CHAPTER 10 INTERACTIONS AND MACROSCOPIC PROPERTIES OF EMULSIONS AND
M ICROEMULSIONS 328 DIMITER N. PETSEV 10.1 INTRODUCTION 328 10.2 PAIR
ENERGY OF INTERACTION 329 10.2.1 VAN DER WAALS INTERACTION ENERGY 330
10.2.2 INTERACTIONS CALCULATED BY MEANS OF DERJUAGIN S APPROXIMATION 331
10.2.3 INTERACTION ENERGY CONTRIBUTIONS DUE TO THE INTERFACIAL
PROPERTIES OF THE INDIVIDUAL DROPLET-SURFACE AREA EXTENSION AND BENDING
ENERGIES 336 10.2.4 APPLICATIONS OF THE EXPRESSIONS FOR THE PAIR
INTERACTION ENERGY 339 10.2.5 ACCURACY OF THE MODEL SHAPE-ACTUAL
GEOMETRY OF TWO INTERACTING DEFORMABLE DROPLETS 349 10.3 DENSE SYSTEMS
351 10.3.1 NONIONIC EMULSIONS AND MICROEMULSIONS 352 10.3.2 IONIC
EMULSIONS AND MICROEMULSIONS 360 10.4 CONCLUDING REMARKS 363 10.5
REFERENCES 363 CHAPTER 11 GEL EMULSIONS - RELATIONSHIP BETWEEN PHASE
BEHAVIOUR AND FORMATION 367 CONXITA SOLANS, RAMON PONS ANDHIRONOBU
KUNIEDA 11.1 INTRODUCTION 367 11.2 GEL EMULSIONS: STRACTURAL ASPECTS AND
PROPERTIES 368 11.2.1 STRUCTURE 368 11.2.2 STABILITY 370 XII CONTENTS
11.2.3 RHEOLOGICAL PROPERTIES 374 11.2.4 DIFFUSION. 377 11.3 GEL
EMULSION FORMATION 381 11.3.1 PHASE BEHAVIOUR OF WATER/POLYOXYETHYLENE
NONIONIC SURFACTANT/OIL SYSTEMS 3 81 11.3.2 METHODS OF PREPARATION 383
11.4 RELATIONSHIP BETWEEN PHASE BEHAVIOUR AND SPONTANEOUS GEL EMULSION
FORMATION 385 11.4.1 WATER-IN-OIL (W/O) GEL EMULSIONS 385 11.4.2
OIL-IN-WATER (O/W) GEL EMULSIONS 390 11.5 REFERENCES 393 CHAPTER 12
APPLICATIONS OF EMULSIONS 395 THOMAS FOERSTER AND WOLFGANG VON RYBINSKI
12.1 INTRODUCTION 395 12.2 COSMETICS 396 12.2.1 SPREADING PROPERTIES AND
VISCOSITY 396 12.2.2 NEWTYPES OF EMULSIONS 399 12.2.3 MICROEMULSIONS 401
12.2.4 SKIN PENETRATION 404 12.3 METAL PROCESSING 407 12.3.1 ROLLING OIL
EMULSIONS 407 12.3.2 LUBRICANT EMULSIONS 408 12.4 TEXTILES 409 12.4.1
TEXTILE FIBER PREPARATIONS 409 12.4.2 TEXTILE FINISHING 410 12.5
OILFIELDS 411 12.6 WASHING AND CLEANING PROCESSES 412 12.6.1 DETERGENCY
MECHANISMS 412 12.6.2 DRY CLEANING 417 12.6.3 MICROEMULSION CLEANERS 418
12.7 SOIL REMEDIATION 420 12.8 REFERENCES 423 SUBJECT INDEX 427
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| indexdate | 2024-07-09T18:27:07Z |
| institution | BVB |
| isbn | 0854044396 |
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| spelling | Modern aspects of emulsion science ed. by Bernard P. Binks Cambridge Royal Soc. of Chemistry 1998 XII, 430 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Quimica coloidal larpcal Émulsions ram Emulsions Emulsion (DE-588)4014626-1 gnd rswk-swf Emulsion (DE-588)4014626-1 s DE-604 Binks, Bernard P. Sonstige oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008419890&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Modern aspects of emulsion science Quimica coloidal larpcal Émulsions ram Emulsions Emulsion (DE-588)4014626-1 gnd |
| subject_GND | (DE-588)4014626-1 |
| title | Modern aspects of emulsion science |
| title_auth | Modern aspects of emulsion science |
| title_exact_search | Modern aspects of emulsion science |
| title_full | Modern aspects of emulsion science ed. by Bernard P. Binks |
| title_fullStr | Modern aspects of emulsion science ed. by Bernard P. Binks |
| title_full_unstemmed | Modern aspects of emulsion science ed. by Bernard P. Binks |
| title_short | Modern aspects of emulsion science |
| title_sort | modern aspects of emulsion science |
| topic | Quimica coloidal larpcal Émulsions ram Emulsions Emulsion (DE-588)4014626-1 gnd |
| topic_facet | Quimica coloidal Émulsions Emulsions Emulsion |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008419890&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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