Disperse systems:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Weinheim [u.a.]
Wiley-VCH
1999
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 317 S. graph. Darst. |
| ISBN: | 3527294589 |
Staff View
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Record in the Search Index
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| adam_text | MAKOTO TAKEO DISPERSE SYSTEMS WILEY-VCH WEINHEIM * NEW YORK *
CHICHESTER BRISBANE * SINGAPORE * TORONTO CONTENTS 1 DISPERSE SYSTEMS,
COLLOIDAL SYSTEMS, AND THEIR CLASSIFICATION . . 1 1.1 COMMON FEATURE OF
DISPERSIONS 1 1.2 PARTICLE SIZE AND CHEMICAL BONDING 2 1.3
CLASSIFICATION OF TWO-PHASE DISPERSE SYSTEMS 5 EXERCISES 7 REFERENCES 7
2 THERMODYNAMICS OF INTERFACES 9 2.1 TWO-PHASE SYSTEMS 9 2.1.1
THERMODYNAMIC APPROACH 9 2.1.2 COMPUTER SIMULATION OF INTERFACES 17 2.2
MONOLAYERS AND BILAYERS 20 2.2.1 GIBBS MONOLAYER 20 2.2.2 INSOLUBLE
MONOLAYERS 22 EXERCISES 27 REFERENCES 29 3 HOMOGENEOUS NUCLEATION 32 3.1
IMPORTANCE OF HOMOGENEOUS NUCLEATION 32 3.2 CLASSICAL NUCLEATION THEORY
32 3.3 NEW APPROACHES TO NUCLEATION THEORY 37 3.4 ATOMISTIC MODEL OF
NUCLEATION THEORY 40 EXERCISES 41 REFERENCES 42 4 PHYSICAL BEHAVIOR OF
COLLOIDAL PARTICLES 43 4.1 BROWNIAN MOTION 43 4.1.1 TRANSLATIONAL
BROWNIAN MOTION 43 4.1.2 ROTATIONAL BROWNIAN MOTION 52 4.1.3 BROWNIAN
MOTION IN CONCENTRATED SUSPENSION 60 4.2 RESPONSE TO A STATIC ELECTRIC
FIELD 65 VIII CONTENTS 4.3 RESPONSE TO A TIME-DEPENDENT ELECTRIC FIELD
67 4.4 RESPONSE TO MECHANICAL STRESS 69 EXERCISES 73 REFERENCES 74 5
FRACTAL AND BROWNIAN MOTION 76 5.1 FRACTAL 76 5.2 FRACTAL AND DIMENSION
78 5.3 BROWNIAN FRACTAL DIMENSION 80 5.4 POWER LAW (SCALING INVARIANCE)
81 EXERCISES 83 REFERENCES 84 6 DETERMINATION OF PRACTICAL SIZE 85 6.1
MICROSCOPIC OBSERVATION 85 6.1.1 OPTICAL MICROSCOPES 85 6.1.2
TRANSMISSION ELECTRON MICROSCOPE 86 6.1.3 SCANNING MICROSCOPE 86 6.2
LIGHT SCATTERING FOR PARTICLE SIZING 88 6.2.1 CLASSICAL LIGHT SCATTERING
88 6.2.1.1 RAYLEIGH AND RAYLEIGH-GANS-DEBYE SCATTERING 89 6.2.1.2 MIE
SCATTERING 95 6.2.2 FREQUENCY BROADENING AND PHOTON CORRELATION 95
6.2.2.1 BROWNIAN MOTION AND FREQUENCY BROADENING 95 6.2.2.2
AUTOCORRELATION FUNCTION AND LINE SHAPE FOR A SYMMETRIC TOP (DILUTE
MONODISPERSE SYSTEMS) 98 6.2.2.3 PHOTON CORRELATION IN SLIGHTLY DENSE
MONODISPERSE SYSTEMS 104 6.2.2.4 HIGHER-ORDER CORRELATION FUNCTIONS 105
6.3 SMALL-ANGLE X-RAY SCATTERING 108 6.4 SMALL-ANGLE NEUTRON SCATTERING
114 6.5 SEDIMENTATION METHODS 119 6.6 THE COULTER COUNTER 121 6.7
HYDRODYNAMIC CHROMATOGRAPHY (HDC) 122 EXERCISES 123 REFERENCES 125 7
PARTICLE SIZE DISTRIBUTION AND MONODISPERSE SOLS 128 7.1 PARTICLE SIZE
DISTRIBUTION 128 7.2 MONODISPERSE SYSTEMS 132 EXERCISES 140 REFERENCES
141 CONTENTS IX 8 DISPERSION FORCES 142 8.1 THE WORK OF ADHESION AND
COHESION AND DISPERSION FORCES 142 8.1.1 THE WORK OF ADHESION AND
COHESION 142 8.1.2 VAN DER WAALS FORCES 143 8.1.3 EFFECTS OF
ELECTROLYTES ON DISPERSION FORCES 156 8.2 NUMERICAL EVALUATIONS OF
LIFSHITZ THEORY AND EXPERIMENTS ON DISPERSION FORCES 157 8.2.1
NUMERICAL EVALUATIONS OF S(IV) 157 8.2.2 EXPERIMENTS ON VAN DER WAALS
FORCES 159 EXERCISES 160 REFERENCES 163 9 MICELLES, VESICLES, AND
BILAYERS 164 9.1 THERMODYNAMICS OF SELF-ASSEMBLY 164 9.2 THE CRITICAL
MICELLE (OR MICELHZATION) CONCENTRATION (CMC) 169 9.3 BILAYERS AND
VESICLES 171 9.4 GEOMETRIC PACKING OR SIZE OF A HYDROCARBON CHAIN IN A
MICELLE . . 171 9.5 SPECTROSCOPIC TECHNIQUE FOR INVESTIGATING MICELLES
172 9.5.1 METHODS FOR DETERMINING THE CMC 173 9.5.2 METHODS FOR
DETERMINING THE AGGREGATION NUMBER 173 9.5.2.1 SCATTERING METHOD 173
9.5.2.2 FLUORESCENCE METHOD 173 9.5.2.3 TIME-RESOLVED FLUORESCENCE
METHOD 174 9.5.2.4 OTHER METHODS FOR SIZING 174 9.6 MICELLAR DYNAMICS
175 9.6.1 FAST RELAXATION TIME, X X 175 9.6.2 SLOW RELAXATION TIME, * 2
177 9.6.3 RESIDENCE TIME OF MICELLES 178 EXERCISES 179 REFERENCES 179 10
ELECTROSTATIC AND ELECTROKINETIC PHENOMENA 181 10.1 THE ELECTRIC STRESS
TENSOR IN A COMPRESSIBLE FLUID 181 10.2 IONS IN LIQUID DIELECTRIC AND
ELECTRIC DOUBLE LAYER 184 10.2.1 THE POISSON-BOLTZMANN EQUATION AND THE
DEBYE-HIICKEL APPROXIMATION 184 10.2.2 THE ELECTRIC DOUBLE LAYER 186
10.2.3 STERN LAYER OR THE COMPACT LAYER 188 10.2.4 ELECTROCAPILLAROMETER
191 10.2.5 TEST OF THE POISSON-BOLTZMANN EQUATION 192 10.3 INTERACTING
PLANER DOUBLE LAYERS 193 10.3.1 SYMMETRIC CASE 193 10.3.2 FLAT PARTICLES
WITH DISSIMILAR DOUBLE LAYERS 196 X CONTENTS 10.4 INTERACTION BETWEEN
CHARGED SPHERES 197 10.4.1 FOR LARGE VALUES OF ** (~2.5) 197 10.4.2 FOR
SMALL VALUES OF ** 202 10.5 ELECTROKINETIC PHENOMENA 203 10.5.1
C(ZETA)-POTENTIAL 204 10.5.2 ELECTRO-OSMOSIS AND STREAMING POTENTIAL 204
10.5.3 ELECTROPHORESIS 206 10.6 MEASUREMENT OF C-POTENTIALS 210 10.7
ELECTRICAL CONDUCTIVITY OF DILUTE DISPERSIONS 213 EXERCISES 214
REFERENCES 217 11 STABILITY OF DISPERSIONS 219 11.1 DLVO THEORY 219 11.2
KINETICS OF COAGULATIONS 222 11.2.1 HOMOCOAGULATION 222 11.2.2
HETEROCOAGULATION 225 11.3 POLYMER OR STERIC STABILIZATION OF
DISPERSIONS 226 11.4 STABILITY OF LIQUID DROPLETS IN LIQUID (EMULSION)
232 11.5 STABILITY OF AEROSOLS 236 11.6 STABILITY OF BUBBLES AND FOAMS
236 EXERCISES 239 REFERENCES 241 12 EMULSIONS AND MICROEMULSIONS 244
12.1 INVERSION 244 12.2 THE HYDROPHILE-LIPOPHILE BALANCE (HLB), FACTORS
DETERMINING TYPES OF EMULSIONS 246 12.3 ELECTRICAL CONDUCTIVITY OF AN
EMULSION 247 12.4 DROPLET SIZE DISTRIBUTION AND EMULSION PREPARATION 248
12.4.1 CONDENSATION UNDER MECHANICAL AGITATION 248 12.4.2 EMULSION
POLYMERIZATION 249 12.4.3 PHASE-INVERSION TEMPERATURE METHOD 249 12.5
CREAMING OR SEDIMENTATION 250 12.6 MICROEMULSION 253 EXERCISES 255
REFERENCES 256 13 GELS 257 13.1 STRUCTURE OF GELS 257 13.2 GROWTH OF
AGGREGATES 258 13.3 SOL-GEL TRANSITION (GELATION) 261 13.3.1 THE KINETIC
THEORY 261 CONTENTS XI 13.3.2 PERCOLATION 264 13.4 MECHANICAL PROPERTIES
OF GELS 267 13.5 CHEMICAL POTENTIAL OF SOLVENT IN GELS 271 13.6
RHEOLOGICAL PROPERTIES OF GELS 274 13.7 APPLICATIONS OF GELS 274
EXERCISES 275 REFERENCES 276 14 AEROSOLS 27 8 14.1 FORMATION OF AEROSOLS
278 14.1.1 HOMOGENEOUS NUCLEATION OF VAPOR AND NUCLEATION BY IONS 279
14.1.2 PARTICLE GROWTH RATE BY CONDENSATION 280 14.2 PARTICLE GROWTH BY
BROWNIAN COAGULATION 283 14.2.1 DETAILED CONDITIONS IN COAGULATION
PROCESSES 283 14.2.2 GROWTH DUE TO COAGULATION 286 14.3 COAGULATION IN
SHEAR FLOWS 287 14.4 EVAPORATION OF AEROSOLS 289 14.5 THERMOPHORESIS 290
14.6 DIFFUSIOPHORESIS 291 14.7 PARTICLE CAPTURE 292 14.7.1 CAPTURE
EFFICIENCY AND THE FILTER COEFFICIENT 292 14.7.2 CAPTURE BY A SPHERE 293
14.7.3 CAPTURE BY A CYLINDER (FIBROUS FILTER) 295 14.8 EFFECTS OF
INERTIA, INTERACTIONS, DIFFUSION ON CAPTURE EFFICIENCY . . . 297 14.8.1
INERTIA AND HYDRODYNAMICS AND INTERPARTICLE INTERACTIONS 297 14.8.2
CAPTURE OF BROWNIAN PARTICLES 300 14.9 SCAVENGING BY FALLING WATER DROPS
304 EXERCISES 306 REFERENCES 307 SUBJECT INDEX 309
|
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| indexdate | 2024-07-09T18:23:40Z |
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| isbn | 3527294589 |
| language | English |
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| spelling | Takeo, Makoto Verfasser aut Disperse systems Makoto Takeo Weinheim [u.a.] Wiley-VCH 1999 XI, 317 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Aérosols ram Colloïdes ram Dispersion (chimie) ram Colloids Dispersion Matter Properties Dispersion (DE-588)4012484-8 gnd rswk-swf Kolloidchemie (DE-588)4134420-0 gnd rswk-swf Dispersion (DE-588)4012484-8 s DE-604 Kolloidchemie (DE-588)4134420-0 s GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008275522&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Takeo, Makoto Disperse systems Aérosols ram Colloïdes ram Dispersion (chimie) ram Colloids Dispersion Matter Properties Dispersion (DE-588)4012484-8 gnd Kolloidchemie (DE-588)4134420-0 gnd |
| subject_GND | (DE-588)4012484-8 (DE-588)4134420-0 |
| title | Disperse systems |
| title_auth | Disperse systems |
| title_exact_search | Disperse systems |
| title_full | Disperse systems Makoto Takeo |
| title_fullStr | Disperse systems Makoto Takeo |
| title_full_unstemmed | Disperse systems Makoto Takeo |
| title_short | Disperse systems |
| title_sort | disperse systems |
| topic | Aérosols ram Colloïdes ram Dispersion (chimie) ram Colloids Dispersion Matter Properties Dispersion (DE-588)4012484-8 gnd Kolloidchemie (DE-588)4134420-0 gnd |
| topic_facet | Aérosols Colloïdes Dispersion (chimie) Colloids Dispersion Matter Properties Kolloidchemie |
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