Aqueous phase organometallic catalysis: concepts and applications
Saved in:
| Format: | Book |
|---|---|
| Language: | German |
| Published: |
Weinheim [u.a.]
Wiley
1998
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVI, 615 S. Ill. |
| ISBN: | 3527294783 |
Staff View
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Record in the Search Index
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| adam_text | AQUEOUS-PHASE
ORGANOMETAUIC CATALYSIS
CONCEPTS AND APPLICATIONS
EDITED BY
BOY CORNILS AND WOLFGANG A. HERRMANN
WILEY-VCH
WEINHEIM * NEW YORK * CHICHESTER
BRISBANE * SINGAPORE * TORONTO
CONTENTS
1 INTRODUCTION
(B. CORNILS, W. A. HERRMANN) 1
2 BASIC AQUEOUS CHEMISTRY 17
2.1 ORGANIC CHEMISTRY IN WATER (A. LUBINEAU, J. AUGE) 19
2.2 ORGANOMETALLIC CHEMISTRY OF WATER (W. A. HERRMANN) 35
2.3 CHARACTERIZATION OF ORGANOMETALLIC COMPOUNDS IN WATER
(G. LAURENCZY) 46
3 CATALYSTS FOR AN AQUEOUS CATALYSIS 57
3.1 VARIATION OF CENTRAL ATOMS (J. S. MEROLA) 59
3.2 VARIATION OF LIGANDS 71
3.2.1 MONOPHOSPHINES (H. STELZER) 71
3.2.2 DIPHOSPHINES AND OTHER PHOSPHINES
(M. SCHREUDER GOEDHEIJT, P. KAMER, P. VAN LEEUWEN) 90
3.2.3 LIGANDS OR COMPLEXES CONTAINING ANCILLARY FUNCTIONALITIES
(P. KALCK, M. DESSOUDEIX) 105
3.2.4 TENSIDE LIGANDS (G. PAPADOGIANAKIS, R. A. SHELDON) 123
3.2.5 CHIRAL LIGANDS (W.A. HERRMANN, R. W. ECKET) 134
3.2.6 ALTERNATIVE CATALYST CONCEPTS
(W. A. HERRMANN, C.-P. REISINGER) 144
4 CATALYSES IN WATER AS A SPECIAL UNIT OPERATION ... 149
4.1 FUNDAMENTALS OF BIPHASIC REACTIONS IN WATER
(P. CLAUS, M. BAERNS) 151
4.2 TECHNICAL SOLUTIONS (A. BEHR) 163
4.3 SIDE EFFECTS, SOLVENTS, AND CO-SOLVENTS (B. E. HANSON) 181
VIII
CONTENTS
4.4 MEMBRANE TECHNIQUES (H. BAHRMANN, B. CORNILS) 189
4.5 MICELLAR SYSTEMS (G. OEHME) 193
4.6 ON THE BORDERLINE OF AQUEOUS-PHASE CATALYSIS 207
4.6.1 PHASE-TRANSFER CATALYSIS (E. V. DEHMLOW) 207
4.6.2 COUNTER-PHASE TRANSFER CATALYSIS (T. OKANO) 221
4.6.3 THERMOREGULATED PHASE-TRANSFER CATALYSIS (Z. JIN, X. ZHENG) . 233
4.7 TRANSITIONS TO HETEROGENEOUS TECHNIQUES
(SAPC AND VARIATIONS) (M. E. DAVIS) 241
5 AQUEOUS CATALYSTS FOR ENVIRONMENT AND SAFETY .. 253
5.1 WATER-SOLUBLE ORGANOMETALLICS IN THE ENVIRONMENT
(W. A. HERRMANN) 255
5.2 ENVIRONMENTAL AND SAFETY ASPECTS (B. CORNILS, E. WIEBUS) . . . 259
6 TYPICAL REACTIONS 269
6.1 HYDROFORMYLATION 271
6.1.1 DEVELOPMENT OF COMMERCIAL BIPHASIC OXO SYNTHESIS
(B. CORNILS, E. G. KUNTZ) 271
6.1.2 KINETICS (R. V. CHAUDHARI, B. M. BHANAGE) 283
6.1.3 REACTION OF OLEFINS 294
6.1.3.1 LOWER OLEFINS (C. D. FROHNING, C. W. KOHLPAINTNER) 294
6.1.3.2 HIGHER OLEFINS (H. BAHRMANN, S. BOGDANOVIC) 306
6.1.4 CONVERSION OF FUNCTIONALIZED OLEFINS
(E. MONFLIER, A. MORTREUX) 321
6.1.5 RE-IMMOBILIZATION TECHNIQUES (H. BAHRMANN) 328
6.2 HYDROGENATION (F. JOB, A. KATHOE) 340
6.3 CARBONYLATION REACTIONS (M. BELLER, J. G. E. KRAUTER) 373
6.4 C-C COUPLING BY HECK-TYPE REACTIONS
(W. A. HERRMANN, C.-P. REISINGER) 383
6.5 HYDROCYANATION (H. E. BRYNDZA, J. A. HARRELSON, JR.) 393
6.6 ALLYLIC SUBSTITUTIONS (D. SINOU) 401
6.7 HYDRODIMERIZATION (N. YOSHIMURA) 408
CONTENTS IX
6.8 BIOLOGICAL CONVERSIONS (P. J. QUINN) 418
6.9 ASYMMETRIE SYNTHESIS (D. SINOU) 432
6.10 FINE CHEMICALS SYNTHESES (S. HABER) 440
6.11 POLYMERS (W. A. HERRMANN, W. C. SCHATTENMANN) 447
6.12 OLEOCHEMISTRY (A. BEHR) 455
6.13 OLEFIN METATHESIS (R. H. GRUBBS, D. M, LYNN) 466
6.14 HYDROGENATION AND HYDROGENOLYSIS OF THIOPHENIC MOLECULES
(C. BIANCHINI, A. MELI) 477
6.15 C0
2
CHEMISTRY (W. LEITNER, E. DINJUS, F. GASSNER) 486
6.16 HALOGEN CHEMISTRY (M. BRESSAN, A. MORVILLO) 499
6.17 OXIDATIONS (R. A. SHELDON, G. PAPADOGIANAKIS) 506
6.18 WACKER-TYPE OXIDATIONS (E. MONFLIER, A. MORTREUX) 513
6.19 LANTHANIDES IN AQUEOUS-PHASE CATALYSIS (S. KOBAYASHI) 519
6.20 METHYLTRIOXORHENIUM(VII) IN OXIDATION CATALYSIS
(W. A. HERRMANN, F. E. KUEHN, G. M. LOBMAIER) 529
7 OTHER BIPHASIC CONCEPTS 539
7.1 SHOP PROCESS (D. VOGT) 541
7.2 FLUOROUS PHASES (I. T. HORVAETH) 548
7.3 NONAQUEOUS IONIC LIQUIDS (NAILS) (H. OLIVIER) 555
7.4 THE AMPHIPHILIC APPROACH
(P. C. J. KAMER, P. W. N. M. VAN LEEUWEN) 564
7.5 WATER-SOLUBLE POLYMER-BOUND CATALYSTS
(M. BELLER, J. G. E. KRAUTER) 577
8 AQUEOUS-PHASE CATALYSIS:
WHAT SHOULD BE DONE IN THE FUTURE
(B. CORNILS, W. A. HERRMANN) 583
INDEX 597
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| spelling | Aqueous phase organometallic catalysis concepts and applications ed. by Boy Cornils ... Aqueous-phase organometallic catalysis Weinheim [u.a.] Wiley 1998 XVI, 615 S. Ill. txt rdacontent n rdamedia nc rdacarrier Catalise (fisico-quimica) larpcal Catalyseurs Compostos organometalicos (quimica organica) larpcal Composés organométalliques hydrosolubles Catalysis Catalysts Recycling Heterogeneous catalysis Metal catalysts Water-soluble organometallic compounds Katalyse (DE-588)4029921-1 gnd rswk-swf Wässrige Lösung (DE-588)4124928-8 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 s Katalyse (DE-588)4029921-1 s Wässrige Lösung (DE-588)4124928-8 s DE-604 Cornils, Boy Sonstige oth DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=008016067&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Aqueous phase organometallic catalysis concepts and applications Catalise (fisico-quimica) larpcal Catalyseurs Compostos organometalicos (quimica organica) larpcal Composés organométalliques hydrosolubles Catalysis Catalysts Recycling Heterogeneous catalysis Metal catalysts Water-soluble organometallic compounds Katalyse (DE-588)4029921-1 gnd Wässrige Lösung (DE-588)4124928-8 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4124928-8 (DE-588)4038906-6 |
| title | Aqueous phase organometallic catalysis concepts and applications |
| title_alt | Aqueous-phase organometallic catalysis |
| title_auth | Aqueous phase organometallic catalysis concepts and applications |
| title_exact_search | Aqueous phase organometallic catalysis concepts and applications |
| title_full | Aqueous phase organometallic catalysis concepts and applications ed. by Boy Cornils ... |
| title_fullStr | Aqueous phase organometallic catalysis concepts and applications ed. by Boy Cornils ... |
| title_full_unstemmed | Aqueous phase organometallic catalysis concepts and applications ed. by Boy Cornils ... |
| title_short | Aqueous phase organometallic catalysis |
| title_sort | aqueous phase organometallic catalysis concepts and applications |
| title_sub | concepts and applications |
| topic | Catalise (fisico-quimica) larpcal Catalyseurs Compostos organometalicos (quimica organica) larpcal Composés organométalliques hydrosolubles Catalysis Catalysts Recycling Heterogeneous catalysis Metal catalysts Water-soluble organometallic compounds Katalyse (DE-588)4029921-1 gnd Wässrige Lösung (DE-588)4124928-8 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd |
| topic_facet | Catalise (fisico-quimica) Catalyseurs Compostos organometalicos (quimica organica) Composés organométalliques hydrosolubles Catalysis Catalysts Recycling Heterogeneous catalysis Metal catalysts Water-soluble organometallic compounds Katalyse Wässrige Lösung Metallorganische Verbindungen |
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