Charge transfer complexes in biological systems:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
New York [u.a.]
Dekker
1997
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVIII, 543 S. graph. Darst. |
| ISBN: | 0824799860 |
Staff View
MARC
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| 650 | 4 | |a Charge transfer in biology | |
| 650 | 4 | |a Electron donor-acceptor complexes |x Physiological effect | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-007861539 | ||
Record in the Search Index
| _version_ | 1804126197038186496 |
|---|---|
| adam_text | Contents
Foreword (Barry S. Thornton) v
Preface vii
Acknowledgements xi
Chapter 1
General Considerations
1.0 Introduction 1
1.1 Definitions and Nomenclature 1
1.2 Classification of Charge Transfer Complexes (CTCs) 2
1.3 Summary of the Main Features of the Charge Transfer 7
Complex
1.4 Biological Significance of CTCs 7
References 10
Chapter 2
The Energetics of Charge Transfer Complexes
2.0 Introduction 13
2.1 Interactions 13
2.2 Conductivities 16
2.3 Thermodynamic Parameters 18
2.4 Ionization Energies and Electron Affinities 21
2.5 Polarization Energies 24
2.6 Solvation 26
2.7 Strong and Weak Complexes 28
xiii
xiv Contents
2.8 Contact Complexes 30
2.9 Excited States 30
2.10 Solitons 37
2.11 Energy Transfer 39
2.12 Autocomplexes 40
2.13 Ternary Complexes 41
2.14 Proton Complexes 42
2.15 Surface Complexes 43
2.16 Micellar, Reverse Micellar and Colloidal CTCs 45
2.17 Hydrophobic Bonding 50
2.18 Metachromasia 51
2.19 Stochastic Processes 61
2.20 Reversibility 62
2.21 Transient Complexes 64
References 66
Chapter 3
Some Techniques for Identifying Charge Transfer Complexes
3.0 Introduction 75
3.1 Optical Absorption and Emission Spectroscopy 75
3.2 Resonance Spectroscopy 85
3.3 Electrical Methods for Determining CTCs 93
3.4 Dielectric Effects 116
References 132
Chapter 4
Fractals, Irreversible Thermodynamics, Chaos and Feedback Cycles
4.0 Introduction 141
4.1 Fractals 142
4.2 Irreversible Thermodynamics 143
4.3 Feedback 149
4.4 Instability 151
4.5 Nonlinear Dynamics 160
4.6 A Hypothetical Biological Feedback Cycle 172
References 175
Contents xv
Chapter 5
Purine, Pyrimidine, Nucleoside, Nucleotide, DNA and
RNA Complexes
5.0 Introduction 179
5.1 Purines and Pyrimidines 179
5.2 Nucleosides and Nucleotides 181
5.3 DNA and RNA 183
5.4 Examples of Intercalation Charge Transfer Complexes 193
5.5 Bifunctional Intercalation Complexes 195
5.6 Free Radical Complexes and DNA 197
5.7 Complexes of Mutagens and Carcinogens with DNA 198
5.8 Complexes of Antimutagens with DNA as 202
Chemopreventatives
5.9 Charge Transfer Complexes and Cancer 203
References 214
Chapter 6
Charge Transfer Complexes of Amino Acids, Proteins
and Porphyrins
6.0 Introduction 221
6.1 Structure of Amino Acids and Proteins 221
6.2 Bonding Forces 227
6.3 Charge Transfer in Proteins 232
6.4 Complexes of Proteins and Their Components 238
6.5 Complexes of Methylglyoxal, Cytochromes and Porphyrins 243
6.6 CTCs of Light Harvesting, Accessory Pigment 254
and Reaction Center Molecules
References 268
Chapter 7
Charge Transfer Complexes of Saccharide Systems
7.0 Introduction 277
7.1 Carbohydrate: Iodine Complexes 279
7.2 Amadori and Maillard Complexes 280
xvi Contents
7.3 Heparin Complexes 280
7.4 Charge Transfer Complexes of Ionic Solutes 287
7.5 Complexes of Aminoglycosides with |3 Lactams 289
7.6 Lysozyme Complexes 290
7.7 Nucleotide and Nucleoside Derivative Complexes 292
7.8 Complexes in Glycolysis 295
7.9 Glucose Transport Complexes 299
7.10 Further Considerations of CTC Formation Mediated 300
by Water
7.11 Lactose Permease Complexes 305
7.12 ComplexationofATPases 307
7.13 Cyclodextrin Complexes 310
References 311
Chapter 8
Charge Transfer Complexes of Lipids, Lipid Systems and Vitamins
8.0 Introduction 319
8.1 Vitamins 320
8.2 Complexes Involving the Blood Brain Barrier 342
8.3 Lipid Complexes 344
References 372
Chapter 9
Complexes of Neurotransmitters and Neuroleptics
9.0 Introduction 383
9.1 Complexes of Neurotransmitters with Biologicals 384
9.2 Complexes of Neurotransmitters with Neuroleptics 386
9.3 Complexation Patterns of Neurotransmitters 387
and Neuroleptics
9.4 Biphasic Behavior of Neurotransmitters and Neuroleptics 390
9.5 Sites of Charge Transfer Activity in Neuroleptics 3%
9.6 Conformation of Neuroleptic Complexes 398
9.7 Neurotransmitter Complexes: Proton and Anion Influences 402
9.8 Complexes of Acetylcholine with Acetylcholinesterases 405
9.9 Acetylcholine Complexes in Vesicles 407
9.10 Neurotransmitter Complexes and Exocytosis 407
Contents xvii
9.11 Charge Transfer Interactions of Neuroleptics 414
with Membranes
9.12 Complexes of Local Anesthetics with Membrane 419
Components
9.13 Charge Transfer Complexation and Transmembrane 422
Passage
9.14 Melanin Charge Transfer Complexes: Composition 425
and Location of Melanins
9.15 Amino Acid and Miscellaneous Neurotransmitter 428
Complexes
References 430
Chapter 10
Charge Transfer Complexes in Micro organisms
10.0 Introduction 443
10.1 Complexes of Phenothiazines 443
10.2 Complex Formation of Tricyclic Drugs 446
with Plasmid DNA
10.3 Complexes Involving Structural Elements of Bacteria 447
10.4 Complex Formation of Endotoxin in Gram negative 451
Bacteria
10.5 Complexes of Bacterial Surface Proteins with 454
Phenothiazines
10.6 Complex Formation Inhibits Motility of Bacteria 457
10.7 Loss of Extrachromosomal Genetic Elements Due 461
to Complex Formation with Phenothiazines
10.8 Binding Site Similarity of Beta Adrenergic like Receptors 466
in Bacteria
10.9 The Role of CTCs in the Antifungal Activity of Various 470
Phenothiazines
10.10 Antiviral Effects of Some Phenothiazines 475
10.11 CTCs in Antiproliferative Effects 476
10.12 Activation of Oncogenes by Carcinogens 478
10.13 Signal Transfer via Charge Transfer in Biological 479
Membranes
10.14 Effects in vivo 482
References 483
xviii Contents
Chapter 11
Therapy and Charge Transfer Complexes
11.0 Introduction 489
11.1 Antibiotic Charge Transfer Complexes 494
11.2 Anticonvulsant Complexes 495
11.3 Complexes of Drugs with Neuroleptics, Including 495
Tricyclic Antidepressants
11.4 Some Medicinal Complexes 497
11.5 Antimalarial Complexes 501
11.6 Drug mediated Enzyme Complexes 502
11.7 Thiazine Complexes of Microbes and Tumors 504
References 507
Chapter 12
Retrospect, Outlook and Speculations
12.1 Retrospect 511
12.2 Outlook and Speculations: Summary 512
References 516
Index 517
|
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| dewey-tens | 570 - Biology |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T18:13:37Z |
| institution | BVB |
| isbn | 0824799860 |
| language | English |
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| owner_facet | DE-12 DE-355 DE-BY-UBR DE-11 |
| physical | XVIII, 543 S. graph. Darst. |
| publishDate | 1997 |
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| spelling | Charge transfer complexes in biological systems F. Gutmann ... New York [u.a.] Dekker 1997 XVIII, 543 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Charge transfer in biology Electron donor-acceptor complexes Physiological effect Biologisches System (DE-588)4122930-7 gnd rswk-swf Charge-transfer-Komplexe (DE-588)4147587-2 gnd rswk-swf Biologisches System (DE-588)4122930-7 s Charge-transfer-Komplexe (DE-588)4147587-2 s DE-604 Gutmann, Felix Sonstige oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007861539&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Charge transfer complexes in biological systems Charge transfer in biology Electron donor-acceptor complexes Physiological effect Biologisches System (DE-588)4122930-7 gnd Charge-transfer-Komplexe (DE-588)4147587-2 gnd |
| subject_GND | (DE-588)4122930-7 (DE-588)4147587-2 |
| title | Charge transfer complexes in biological systems |
| title_auth | Charge transfer complexes in biological systems |
| title_exact_search | Charge transfer complexes in biological systems |
| title_full | Charge transfer complexes in biological systems F. Gutmann ... |
| title_fullStr | Charge transfer complexes in biological systems F. Gutmann ... |
| title_full_unstemmed | Charge transfer complexes in biological systems F. Gutmann ... |
| title_short | Charge transfer complexes in biological systems |
| title_sort | charge transfer complexes in biological systems |
| topic | Charge transfer in biology Electron donor-acceptor complexes Physiological effect Biologisches System (DE-588)4122930-7 gnd Charge-transfer-Komplexe (DE-588)4147587-2 gnd |
| topic_facet | Charge transfer in biology Electron donor-acceptor complexes Physiological effect Biologisches System Charge-transfer-Komplexe |
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