General chemistry: principles and modern applications
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| Main Author: | |
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| Format: | Book |
| Language: | English |
| Published: |
New York
Macmillan [u.a.]
1985
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| Edition: | 4. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Erg. bildet: Wismer, Robert K.: Student study guide to accompany Petrucci's General chemistry, fourth edition |
| Physical Description: | Getr. Zählung Ill., graph. Darst. |
| ISBN: | 002394790X 0029465508 |
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| 245 | 1 | 0 | |a General chemistry |b principles and modern applications |c Ralph H. Petrucci |
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| 264 | 1 | |a New York |b Macmillan [u.a.] |c 1985 | |
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| 500 | |a Erg. bildet: Wismer, Robert K.: Student study guide to accompany Petrucci's General chemistry, fourth edition | ||
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Record in the Search Index
| _version_ | 1804126182437814272 |
|---|---|
| adam_text | General Chemistry
Principles and Modern Applications
Fourth Edition
Ralph H Petrucci
California State University, San Bernardino
Macmillan Publishing Company
New York
Collier Macmillan Publishers
London
Contents
Matter—Its Properties and Measurement
1-1 Properties of Matter 1
1-2 Classification of Matter 2
1-3 The Scientific Method 2
1-4 The Need for Measurement 3
1-5 The English and Metric Systems of Measurement 4
1-6 SI Units 6
1-7 Significant Figures 7
1-8 Density 9
1-9 Temperature 9
1-10 Problem Solving 10
Focus on Some Key Chemicals 17
Summary 18 Learning Objectives 19 Some New Terms 19
Suggestions for Further Study 20 Review Problems 20 Exercises 21
Additional Exercises 23 Self-Test Questions 24
Development of the Atomic Theory
2-1 Dalton s Atomic Theory 25
2-2 Cathode Rays 28
2-3 Canal Rays (Positive Rays) 30
2-4 X Rays 32
2-5 Radioactivity 32
2-6 The Nuclear Atom 33
2-7 Isotopes 34
2-8 Protons and Neutrons 35
2-9 Summary of the Properties of Fundamental Particles 35
2-10 Chemical Elements 36
2-11 Atomic Weights 39
2-12 Postscript: Do Atoms Exist? 40
Summary 41 Learning Objectives 41 Some New Terms 41
Suggestions for Further Study 42 Review Problems 42 Exercises 43
Additional Exercises 44 Self-Test Questions 45
ix
Stoichiometry I: Elements and Compounds
3-1 Avogadro s Number and the Concept of the Mole 46
3-2 Calculations Involving the Mole Concept 47
3-3 Chemical Compounds 49
3-4 Composition of Chemical Compounds 52
3-5 The Need to Name Chemical Compounds—Nomenclature 59
3-6 Metals and Nonmetals—An Introduction to the Periodic Table 60
3-7 Oxidation States 61
3-8 Systemic Nomenclature of Inorganic Compounds 62
Summary 68 Learning Objectives 68 Some New Terms 69
Suggestions for Further Study 69 Review Problems 69 Exercises 70
Additional Exercises 72 Self-Test Questions 73
Stoichiometry II: Chemical Reactions
4-1 The Chemical Equation 74
4-2 Types of Chemical Reactions 77
4-3 Quantitative Significance of the Chemical Equation 78
4-4 Chemical Reactions in Solutions 82
4-5 Some Additional Matters 85
Focus on Industrial Chemistry 93
Summary 95 Learning Objectives 95 Some New Terms 96
Suggestions for Further Study 96 Review Problems 96 Exercises 97
Additional Exercises 100 Self-Test Questions 101
Gases
5-1 Properties of a Gas 103
5-2_ Gas Pressure 103
5-3 THe~Simple Gas Laws 107
5-4 The Gas Laws and Development of the Atomic Theory 111
5-5 The Ideal Gas Equation 114
5-6 Molecular Weight Determination 116
5-7 Gas Densities 118
5-8 Gases in Chemical Reactions 118
5-9 Mixtures of Gases 120
5-10 Kinetic Molecular Theory of Gases 124
5-11 Nonideal Gases 129
5-12 Postscript: The Atmosphere 131
Summary 133 Learning Objectives 133 Some New Terms 134
Suggestions for Further Study 134 Review Problems 134
Exercises 135 Additional Exercises 137 Self-Test Questions 138
Thermochemistry
6-1 Thermodynamics: A Preview 140
6-2 Heat 141
6-3 Heat of Reaction 144
6-4 Enthalpy and Enthalpy Changes 147
6-5 Relations Involving AH 150
6-6 Standard Enthalpies of Formation 152
Focus on Sources and Uses of Energy 154
Summary 157 Learning Objectives 157
Suggestions for Further Study 158 Review
Exercises 159 Additional Exercises 162
Electrons in Atoms
7-1 Electromagnetic Radiation 164
7-2 Atomic Spectra 167
7-3 Quantum Theory 170
7-4 The Bohr Atom 172
7-5 Wave-Particle Duality 175
7-6 The Uncertainty Principle 176
7-7 Wave Mechanics 177
7-8 Electron Orbitals and Quantum Numbers 180
7-9 Electron Spin—A Fourth Quantum Number 182
7-10 Many-Electron Atoms 183
7-11 Electron Configurations 184
7-12 Electron Configurations of the Elements 185
Summary 188 Learning Objectives 188 Some New Terms 189
Suggestions for Further Study 189 Review Problems 190
Exercises 190 Additional Exercises 192 Self-Test Questions 193
Atomic Properties and the Periodic Table
8-1 On the Idea of Order 195
8-2 Periodic Law and the Periodic Table 195
8-3 A Modern Periodic Table—The Long Form 198
8-4 Electron Configurations and the Periodic Table 199
8-5 Metals and Nonmetals 201
8-6 Some Unresolved Issues Concerning the Periodic Table 203
8-7 Atomic Radius 204
8-8 Ionization Energy (Ionization Potential) 207
8-9 Electron Affinity 209
8-10 Electronegativity 210
8-11 Magnetic Properties 211
8-12 Using the Periodic Table to Compare Atomic Properties 212
Summary 213 Learning Objectives 214 Some New Terms 214
Suggestions for Further Study 215 Review Problems 215
Exercises 215 Additional Exercises 217 Self-Test Questions 218
Chemical Bonding I: Basic Concepts
9-1 Importance of Electrons in Chemical Bonding 219
9-2 Ionic Bonding 221
9-3 Covalent Bonding 223
Some New Terms 157
Problems 158
Self-Test Questions 163
9-4 Covalent Lewis Structures—Some Examples 224
9-5 Covalent Bonding in Polyatomic Ions 228
9-6 Resonance 229
9-7 Exceptions to the Octet Rule 230
9-8 Molecular Shapes 233
9-9 Bond Energies and Bond Distances 240
9-10 Partial Ionic Character of Covalent Bonds 242
Focus on Polymers 246
Summary 249 Learning Objectives 250 Some New Terms 250
Suggestions for Further Study 251 Review Problems 251
Exercises 252 Additional Exercises 254 Self-Test Questions 255
Chemical Bonding II: Additional Aspects
10-1 The Valence Bond Approach to Chemical Bonding 257
10-2 Hybridization of Atomic Orbitals 259
10-3 Multiple Covalent Bonds 264
10-4 Molecular Orbital Theory 267
10-5 Bonding in the Benzene Molecule 273
10-6 Other Structures with Delocalized Orbitals 275
10-7 Bonding in Metals 276
Focus on Semiconductors 278
Summary 280 Learning Objectives 280 Some New Terms 281
Suggestions for Further Study 281 Review Problems 281
Exercises 282 Additional Exercises 283 Self-Test Questions 284
Liquids, Solids, and Intermolecular Forces
11-1 Comparison of the States of Matter 285
I-1=2 Two Properties of Liquids 286
II-3 Vaporization 288
11-4 Some Calculations Involving Vapor Pressure and Related
Concepts 293
11-5 Transitions Involving Solids 296
11-6 Phase Diagrams 298
11-7 Evidence of Intermolecular Forces—Condensed States of the Noble
Gases 302
11-8 Van der Waals Forces 302
11-9 Hydrogen Bonds 305
11-10 Network Covalent Solids 307
11-11 The Ionic Bond as an Intermolecular Force 308
11-12 Calculation of Lattice Energy—The Born-Haber Cycle 309
11-13 Crystal Structures 310
11-14 Ionic Crystal Structures 316
11-15 Types of Solids: A Summary 318
Focus on Liquid Crystals 319
Summary 320 Learning Objectives 321 Some New Terms 321
Suggestions for Further Study 322 Review Problems 322
Exercises 323 Additional Exercises 326 Self-Test Questions 327
Solutions
12-1 Homogeneous and Heterogeneous Mixtures 328
12-2 Solution Concentration 331
12-3 Some Illustrative Examples Based on Solution Concentrations 333
12-4 Solubility Equilibrium 334
12-5 Colligative Properties 337
12-6 Theory of Electrolytic Dissociation 348
12-7 Interionic Attractions 350
12-8 Colloidal Mixtures 351
Focus on Obtaining Pure Materials 355
Summary 357 Learning Objectives 357 Some New Terms 358
Suggestions for Further Study 358 Review Problems 359
Exercises 359 Additional Exercises 362 Self-Test Questions 363
An Introduction to Descriptive Chemistry:
The First 20 Elements
13-1 Occurrence and Preparation of the Elements 364
13-2 Trends Among the First 20 Elements 365
13-3 Hydrogen 367
13-4 Helium, Neon, and Argon 369
13-5 Lithium, Sodium, and Potassium 370
13-6 Beryllium, Magnesium, and Calcium 374
13-7 Boron and Aluminum 377
13-8 Carbon 378
13-9 Silicon 381
13-10 Nitrogen 383
13-11 Phosphorus 388
13-12 Oxygen 390
13-13 Sulfur 393
13-14 Fluorine and Chlorine 397
-Summary 400 Learning Objectives 401 Some New Terms 401
Suggestions-for Further Study 401 Review Problems 402
Exercises 402 Additional Exercises 404 Self-Test Questions 405
Chemical Kinetics
14-1 The Rate of a Chemical Reaction 406
14-2 Experimental Determination of Reaction Rates 408
14-3 The Rate Law for Chemical Reactions 411
14-4 Zero-Order Reactions 413
14-5 First-Order Reactions 414
14-6 Second-Order Reactions 419
14-7 Theoretical Treatment of Rates of Chemical Reactions 421
14-8 The Effect of Temperature on Reaction Rates—The Arrhenius
Equation 424
14-9 Catalysis 426
14-10 Reaction Mechanisms 430
Focus on Sulfuric Acid 433
Summary 434 Learning Objectives 435 Some New Terms 435
Suggestions for Further Study 436 Review Problems 436
Exercises 437 Additional Exercises 441 Self-Test Questions 442
Principles of Chemical Equilibrium
15-1 The Condition of Chemical Equilibrium 443
15-2 Additional Relationships Involving Equilibrium Constants 446
15-3 Significance of the Magnitude of an Equilibrium Constant 450
15-4 Predicting the Direction and Extent of a Reaction 451
15-5 Altering Equilibrium Conditions—Le Chatelier s Principle 452
15-6 Equilibrium Calculations—Some Illustrative Examples 456
15-7 The Effect of Temperature on Equilibrium 460
15-8 Kinetic Basis of the Equilibrium Constant 462
Focus on The Synthesis of Ammonia and Other Nitrogen Compounds 464
Summary 466 Learning Objectives 467 Some New Terms 467
Suggestions for Further Study 467 Review Problems 468
Exercises 469 Additional Exercises 472 Self-Test Questions 473
Thermodynamics and Chemistry
16-1 The First Law of Thermodynamics 474
16-2 In Search of a Criterion for Spontaneous Change 478
16-3 Entropy and Disorder 480
16-4 Free Energy and Spontaneous Change 483
16-5 Standard Free Energy Change, AG° 485
16-6 Free Energy and Equilibrium 486
16s7 Relationship of AG to K 488
16-8 Tfie~Third Law of Thermodynamics 493
Focus on Heat Engines 495
Summary 497 Learning Objectives 497 Some New Terms 498
Suggestions for Further Study 498 Review Problems 499
Exercises 500 Additional Exercises 502 Self-Test Questions 503
Acids and Bases
17-1 Acid-Base Theories 504
17-2 Self-ionization (Autoionization) of Water 508
17-3 Strong Acids and Strong Bases 509
17-4 pH and pOH 511
17-5 Weak Acids and Weak Bases 513
17-6 Polyprotic Acids 517
17-7 Cations and Anions as Acids and Bases 520
17-8 Molecular Structure and Acid-Base Behavior 524
Summary 529 Learning Objectives 530 Some New Terms 530
Suggestions for Further Study 531 Review Problems 531
Exercises 532 Additional Exercises 534 Self-Test Questions 534
Contents xv
Additional Aspects of Acid-Base Equilibria 536
18-1 The Common Ion Effect in Acid-Base Equilibria 536
18-2 Buffer Solutions 539
18-3 Acid-Base Indicators 545
18-4 Neutralization Reactions and Titration Curves 546
18-5 The pH of Solutions of Salts of Polyprotic Acids 552
18-6 Acid-Base Equilibrium Calculations—A Summary 553
18-7 Postscript: Equivalent Weight and Normality 554
Summary 557 Learning Objectives 557 Some New Terms 558
Suggestions for Further Study 558 Review Problems 558
Exercises 559 Additional Exercises 561 Self-Test Questions 562
Solubility and Complex Ion Equilibria 564
19-1 The Solubility Product Constant, Ksp 564
19-2 Relationship Between Solubility and Ksp 566
19-3 Precipitation Reactions 570
19-4 Precipitation Reactions in Quantitative Analysis 573
19-5 Writing Net Ionic Equations 575
19-6 Solubility and pH 576
19-7 Complex Ions and Coordination Compounds—An Introduction 579
19-8 Equilibria Involving Complex Ions 580
19-9 Qualitative Analysis 583
19-10 H2S Equilibria Revisited—Precipitation and Solubilities of Metal
Sulfides 585
Summary 588 Learning Objectives 588 Some New Terms 589
Suggestions for Further Study 589 Review Problems 589
Exercises 590 Additional Exercises 593 Self-Test Questions 594
Oxidation-Reduction and Electrochemistry 595
20-1 Oxidation-Reduction: Some Definitions 595
20-2 More on Balancing Oxidation-Reduction Equations 596
20-3 Measurement of Oxidation and Reduction Tendencies 600
20-4 Electrical Work and Free Energy Change 608
20-5 £cell as a Function of Concentrations 611
20-6 Production of Electric Energy by Chemical Change 615
20-7 Electrochemical Mechanism of Corrosion 618
20-8 Electrolysis and Nonspontaneous Chemical Change 620
20-9 Postscript: Equivalent Weight and Normality in Oxidation-Reduction
Reactions 623
Focus on The Chlor-Alkali Process 624
Summary 626 Learning Objectives 627 Some New Terms 627
Suggestions for Further Study 628 Review Problems 628
Exercises 629 Additional Exercises 632 Self-Test Questions 633
Chemistry of the Representative Elements I:
Nonmetals
21-1 Group VIIA—The Halogen Elements 634
21-2 The Group VIA Elements 642
21-3 The Group VA Elements 649
21-4 The Group IVA Elements 659
21-5 Boron 661
21-6 Group 0—The Noble Gases 663
Summary 665 Learning Objectives 665 Some New Terms 666
Suggestions for Further Study 666 Review Problems 667
Exercises 667 Additional Exercises 669 Self-Test Questions 670
Chemistry of the Representative Elements II:
Metals
22-1 Group IA—The Alkali Metals 672
22-2 Group IIA—The Alkaline Earth Metals 678
22-3 The Group IIIA Metals 685
22-4 Extractive Metallurgy 690
22-5 Tin and Lead 693
22-6 The Group IIB Metals 696
Focus on Toxic Metals 700
Summary 702 Learning Objectives 702 Some New Terms 703
Suggestions for Further Study 703 Review Problems 704
Exercises 704 Additional Exercises 706 Self-Test Questions 707
Chemistry of the Transition Elements
- 23J^ General Properties of the Transition Elements 708
23-2 Scandium 711
23-3 Titanium 712
23-4 Vanadium 713
23-5 Chromium 715
23-6 Manganese 717
23-7 The Iron Triad—Fe, Co, and Ni 720
23-8 Metallurgy of Iron and Steel 723
23-9 The Coinage Metals—Cu, Ag, and Au 727
23-10 The Lanthanoid Elements 731
23-11 Qualitative Analysis of Some Transition Metal Ions 732
Summary 734 Learning Objectives 735 Some New Terms 735
Suggestions for Further Study 735 Review Problems 736
Exercises 736 Additional Exercises 738 Self-Test Questions 739
Complex Ions and Coordination Compounds
24-1 Early Theories of Coordination Compounds 740
24-2 Coordination Number and Structures of Complexes 742
Contents xvii
24-3 Ligands 742
24-4 Nomenclature 744
24-5 Isomerism 746
24-6 Bonding in Complex Ions—Valence Bond Theory 750
24-7 Inner and Outer Orbital Complexes 751
24-8 Bonding in Complex Ions—Crystal Field Theory 751
24-9 Color of Complex Ions 754
24-10 Additional Aspects of Complex Ion Equilibria 755
24-11 Acid-Base Reactions of Complex Ions 757
24-12 Some Kinetic Considerations 758
24-13 Applications of Coordination Chemistry 759
Summary 762 Learning Objectives 762 Some New Terms 763
Suggestions for Further Study 763 Review Problems 763
Exercises 764 Additional Exercises 766 Self-Test Questions 766
25-1 The Phenomenon of Radioactivity 768
25-2 Naturally Occurring Radioactive Nuclides 770
25-3 Nuclear Reactions and Artificially Induced Radioactivity 772
25-4 Transuranium Elements 772
25-5 Rate of Radioactive Decay 774
25-6 Energetics of Nuclear Reactions 777
25-7 Nuclear Stability 780
25-8 Nuclear Fission 782
25-9 Nuclear Fusion 785
25-10 Effect of Radiation on Matter 786
25-11 Applications of Radioisotopes 789
Summary 791 Learning Objectives 792 Some New Terms 792
Suggestions for Further Study 793 Review Problems 793
Exercises 794 Additional Exercises 795 Self-Test Questions 796
26-1 The Nature of Organic Compounds and Structures 797
26-2 Alkanes 803
26-3 Alkenes and Alkynes 807
26-4 Aromatic Hydrocarbons 811
26-5 Alcohols, Phenols, and Ethers 814
26-6 Aldehydes and Ketones 817
26-7 Carboxylic Acids and Their Derivatives 818
26-8 Amines 821
26-9 Heterocyclic Compounds 822
26-10 Synthesis of Organic Compounds 822
26-11 Raw Materials for the Organic Chemical Industry 823
Focus on Polymerization Reactions 827
Summary 830 Learning Objectives 831 Some New Terms 831
Suggestions for Further Study 832 Review Problems 833
Exercises 834 Additional Exercises 837 Self-Test Questions 837
Nuclear Chemistry 768
Organic Chemistry 797
xviii Contents
27 Chemistry of the Living State 839
27-1 Structure and Composition of the Cell 839
27-2 Principal Constituents of the Cell 839
27-3 Biochemical Reactivity 858
27-4 The Nucleic Acids 864
Summary 869 Learning Objectives 870 Some New Terms 870
Suggestions for Further Study 871 Review Problems 871
Exercises 872 Additional Exercises 873 Self-Test Questions 874
Appendix A Mathematical Operations A1
A-l Exponential Arithmetic A1
A-2 Logarithms A2
A-3 Algebraic Operations A6
A-4 Graphs A7
Appendix B Some Basic Physical Concepts A9
B-l Velocity and Acceleration
B-2 Force and Work A9
B-3 Energy A10
B-4 Magnetism A10
B-5 Static Electricity A10
B-6 Current Electricity A12
B-7 Electromagnetism A12
A9
Appendix C SI Units— A13
C-l SI Base Units A13
C-2 SI Prefixes A13
C-3 Derived SI Units A14
C-4 Units to Be Discouraged or Abandoned
C-5 Fundamental Constants A15
A14
Appendix D Thermodynamic Properties of Substances
Appendix E Electron Configurations of the Elements
Answers to Selected Exercises
Index
A16
A18
A21
II
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| genre | 1\p (DE-588)4151278-9 Einführung gnd-content 2\p (DE-588)4143389-0 Aufgabensammlung gnd-content |
| genre_facet | Einführung Aufgabensammlung |
| id | DE-604.BV011648406 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:13:23Z |
| institution | BVB |
| isbn | 002394790X 0029465508 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007851114 |
| oclc_num | 10949611 |
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| owner | DE-19 DE-BY-UBM |
| owner_facet | DE-19 DE-BY-UBM |
| physical | Getr. Zählung Ill., graph. Darst. |
| publishDate | 1985 |
| publishDateSearch | 1985 |
| publishDateSort | 1985 |
| publisher | Macmillan [u.a.] |
| record_format | marc |
| spelling | Petrucci, Ralph H. Verfasser aut General chemistry principles and modern applications Ralph H. Petrucci 4. ed. New York Macmillan [u.a.] 1985 Getr. Zählung Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Erg. bildet: Wismer, Robert K.: Student study guide to accompany Petrucci's General chemistry, fourth edition Chemistry Chimie Chemie Chemie (DE-588)4009816-3 gnd rswk-swf 1\p (DE-588)4151278-9 Einführung gnd-content 2\p (DE-588)4143389-0 Aufgabensammlung gnd-content Chemie (DE-588)4009816-3 s 3\p DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007851114&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Petrucci, Ralph H. General chemistry principles and modern applications Chemistry Chimie Chemie Chemie (DE-588)4009816-3 gnd |
| subject_GND | (DE-588)4009816-3 (DE-588)4151278-9 (DE-588)4143389-0 |
| title | General chemistry principles and modern applications |
| title_auth | General chemistry principles and modern applications |
| title_exact_search | General chemistry principles and modern applications |
| title_full | General chemistry principles and modern applications Ralph H. Petrucci |
| title_fullStr | General chemistry principles and modern applications Ralph H. Petrucci |
| title_full_unstemmed | General chemistry principles and modern applications Ralph H. Petrucci |
| title_short | General chemistry |
| title_sort | general chemistry principles and modern applications |
| title_sub | principles and modern applications |
| topic | Chemistry Chimie Chemie Chemie (DE-588)4009816-3 gnd |
| topic_facet | Chemistry Chimie Chemie Einführung Aufgabensammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007851114&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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