On the structure property relation of selected polysilylene homo- and copolymers:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | German |
| Veröffentlicht: |
1997
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | VII, 201 S. Ill., zahlr. graph. Darst. |
Internformat
MARC
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| 001 | BV011565383 | ||
| 003 | DE-604 | ||
| 005 | 19980120 | ||
| 007 | t | ||
| 008 | 970929s1997 gw ad|| m||| 00||| ger d | ||
| 016 | 7 | |a 951102354 |2 DE-101 | |
| 035 | |a (OCoLC)258612363 | ||
| 035 | |a (DE-599)BVBBV011565383 | ||
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| 041 | 0 | |a ger | |
| 044 | |a gw |c DE | ||
| 049 | |a DE-29T |a DE-355 |a DE-11 |a DE-188 | ||
| 100 | 1 | |a Schwegler, Leonore Alexandra |d 1968- |e Verfasser |0 (DE-588)115576878 |4 aut | |
| 245 | 1 | 0 | |a On the structure property relation of selected polysilylene homo- and copolymers |c vorgelegt von Leonore Alexandra Schwegler |
| 264 | 1 | |c 1997 | |
| 300 | |a VII, 201 S. |b Ill., zahlr. graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Ulm, Univ., Diss. | ||
| 650 | 0 | 7 | |a Polysilylene |0 (DE-588)4387928-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Copolymerisation |0 (DE-588)4070106-2 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Polysilylene |0 (DE-588)4387928-7 |D s |
| 689 | 0 | 1 | |a Copolymerisation |0 (DE-588)4070106-2 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007787866&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-007787866 | |
Datensatz im Suchindex
| _version_ | 1807229775411937280 |
|---|---|
| adam_text |
CONTENTS
1
INTRODUCTION
1
2
SYNTHESIS
AND
PROPERTIES
OF
POLYSILYLENES
2.1
HISTORICAL
5
2.2
SYNTHESIS
6
2.2.1
MONOMER
SYNTHESIS
7
DICHLOROSILANES
BY
GRIGNARD
REACTION
7
DICHLOROSILANES
BY
HYDROSILYLATION
7
2.2.2
POLYMERIZATION
8
MECHANISTIC
ASPECTS
OF
WURTZ-TYPE
POLYMERIZATION
9
SOLVENT
EFFECTS
10
2.2.3
ALTERNATIVE
POLYMERIZATION
PROCEDURES
11
2.3
OPTOELECTRONIC
PROPERTIES
12
UV
ABSORPTION
12
FLUORESCENCE
AND
PHOSPHORESCENCE
13
PHOTOCHEMICAL
PROPERTIES
14
ELECTRICAL
AND
PHOTOCONDUCTIVITY
14
2.4
PHASE
BEHAVIOR
AND
MESOMORPHIC
PROPERTIES
15
2.5
APPLICATION
POTENTIAL
AND
FUTURE
DEVELOPMENT
16
2.6
REFERENCES
18
I
FUNCTIONALIZATION
OF
POLYSILYLENES
3
SYNTHESIS
AND
CHARACTERIZATION
OF
A
SERIES
OF
ETHER
SUBSTITUTED
POLYSILYLENES
3.1
INTRODUCTION
25
3.2
EXPERIMENTAL
PART
26
3.4
RESULTS
AND
DISCUSSION
31
MONOMER
SYNTHESIS
31
POLYMER
SYNTHESIS
32
BULK
CHARACTER
34
3.4
SUMMARY
36
3.5
REFERENCES
36
4
CHARACTERIZATION
AND
PROPERTIES
OF
SYMMETRICALLY
AND
NONSYMMETRICALLY
ETHER
SUBSTITUTED
POLYSILYLENES
4.1
INTRODUCTION
39
4.2
EXPERIMENTAL
PART
39
4.3
RESULTS
AND
DISCUSSION
41
BULK
PROPERTIES
41
SOLUTION
PROPERTIES
46
AMPHIPHILIC
CHARACTER
47
4.4
SUMMARY
50
4.5
REFERENCES
50
5
POLY(DI-N-PENTYLSILYLENE)
COPOLYMERS
CONTAINING
DIETHYLEN
GLYCOL-DIETHYLETHER
SIDE
CHAINS
5.1
INTRODUCTION
51
5.2
EXPERIMENTAL
PART
52
5.3
RESULTS
AND
DISCUSSION
55
SOLUTION
PROPERTIES
58
BULK
PROPERTIES
60
5.4
CONCLUSIONS
64
5.5
REFERENCES
65
6
SYNTHESIS
OF
POLYETHYLENE
OXIDE
GRAFT
POLYSILYLENES
AND
WELL
DEFINED
NETWORKS
BASED
ON
POLY(DI-N-PENTYLSILYLENE/N-PENTYL
OCT-7-ENYL)-COPOLYMERS
6.1
INTRODUCTION
67
6.2
EXPERIMENTAL
PART
67
6.3
RESULTS
AND
DISCUSSION
72
SYNTHESIS
OF
THE
COPOLYMER
SERIES
72
THERMAL
BEHAVIOR
76
PEO-GRAFTED
POLY(
DIPENTYLSILYLENE)
80
THERMAL
CROSSLINKING
82
POLYMER
ANALOGOUS
HYDROSILYLATION
OF
THE
VINYL
FUNCTIONALITIES
85
CHEMICAL
CROSSLINKING
WITH
DI-N-PENTYLSILANE
85
CROSSLINKING
BY
HYDROLYSIS
OF
SI-CL
FUNCTIONALITIES
85
6.4
SUMMARY
86
6.5
REFERENCES
87
II
7
PREPARATION
OF
TELECHELIC
POLYSILYLENES:
A
GENERAL
METHOD
FOR
THE
SYNTHESIS
OF
POLYSILYLENE
BASED
TRIBLOCK
COPOLYMERS
7.1
INTRODUCTION
89
7.2
EXPERIMENTAL
PART
90
7.3
RESULTS
AND
DISCUSSION
91
PREPARATION
OF
OT,O DIBROMOPOLY(DI-N-HEXYLSILYLENE)
91
SYNTHESIS
OF
PS-PDHS-PS
TRIBLOCK
COPOLYMERS
93
THERMAL
ANALYSIS
95
MORPHOLOGY
STUDIES
96
7.4
CONCLUSIONS
98
7.5
REFERENCES
99
II
STRUCTURAL
ORGANIZATION
8
MESOPHASE
STABILITY
OF
POLY(DI-N-HEXYLSILYLENE)
IN
PRESENCE
OF
LOW
MOLECULAR
WEIGHT
ADDITIVES
8.1
INTRODUCTION
101
8.2
EXPERIMENTAL
PART
102
8.3
RESULTS
AND
DISCUSSION
103
8.4
CONCLUSIONS
113
8.5
REFERENCES
113
9
ORIENTED
POLY(DI-N-HEXYLSILYLENE)
FILMS
9.1
INTRODUCTION
115
9.2
EXPERIMENTAL
PART
116
9.3
RESULTS
AND
DISCUSSION
118
OPTICAL
AND
ATOMIC
FORCE
MICROSCOPY
118
POLARIZED
IR
SPECTROSCOPY
124
POLARIZED
UV
SPECTROSCOPY
126
X-RAY
INVESTIGATIONS
128
9.4
SUMMARY
131
9.5
REFERENCES
132
III
ILL
CHIRO-OPTICAL
PROPERTIES
AND
PHOTO
ABLATION
10
COMPARISON
OF
POLYDIPENTYLSIYLENES
AND
-SILOXANES
CONTAINING
CHIRAL
GROUPS
10.1
INTRODUCTION
135
10.2
EXPERIMENTAL
PART
136
10.3
RESULTS
AND
DISCUSSION
140
SILOXANE
MONOMER
SYNTHESIS
140
SILOXANE
POLYMERIZATION
143
POLYSILYLENE
SYNTHESIS
146
THERMAL
PROPERTIES
147
OPTICAL
PROPERTIES
149
10.4
CONCLUSIONS
151
10.5
REFERENCES
151
11
SEPARATION
OF
LINEAR
AND
CIRCULAR
DICHROISM
AND
MORPHOLOGY
STUDIES
OF
SPIN
CAST
FILMS
OF
POLY(BIS[(S)-(+)-2-METHYLBUTYL]
DIPENTYLSILYLENE)
COPOLYMERS
11.1
INTRODUCTION
153
11.2
EXPERIMENTALPART
154
11.3
RESULTS
AND
DISCUSSION
155
MORPHOLOGY
STUDIES
ON
SPIN
CASTED
POLYSILYLENE
FILMS
155
SOLID
STATE
CD
SPECTROSCOPY
PERFORMED
ON
SPIN
CAST
FILMS
OF
CHIRAL
POLYSILYLENES
157
THEORETICAL
BACKGROUND
FOR
THE
SEPARATION
OF
LINEAR
AND
CIRCULAR
DICHROISM
AND
BIREFRINGENCE
159
SEPARATION
OF
LINEAR
AND
CIRCULAR
EFFECTS
FOR
SPIN
CASTED
FILMS
OF
A
POLY(BIS[(S)-(+)-METHYLBUTYL]-DIPENTYL)SILYLENE
COPOLYMER
160
11.4
SUMMARY
165
11.5
REFERENCES
165
12
PHOTO
DEGRADATION
OF
POLYDIALKYLSILYLENES
12.1
INTRODUCTION
167
12.2
EXPERIMENTAL
PART
168
IV
12.3
RESULTS
AND
DISCUSSION
170
PHOTO
DEGRADATION
IN
SOLUTION
170
PHOTO
ABLATION
OF
SPIN
COATED
PDPS
FILMS
179
12.4
CONCLUSIONS
181
12.5
REFERENCES
181
APPENDIX
1
GRAZING
INCIDENCE
X-RAY
DIFFRACTION
183
APPENDIX
2
EMISSION
SPECTRUM
OF
A
HG/XE-LAMP
185
OPTICAL
FILTERS
SUMMARY
187
ZUSAMMENFASSUNG
193
DANKWORT
199
CURRICULUM
VITAE
201
V |
| any_adam_object | 1 |
| author | Schwegler, Leonore Alexandra 1968- |
| author_GND | (DE-588)115576878 |
| author_facet | Schwegler, Leonore Alexandra 1968- |
| author_role | aut |
| author_sort | Schwegler, Leonore Alexandra 1968- |
| author_variant | l a s la las |
| building | Verbundindex |
| bvnumber | BV011565383 |
| ctrlnum | (OCoLC)258612363 (DE-599)BVBBV011565383 |
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| genre_facet | Hochschulschrift |
| id | DE-604.BV011565383 |
| illustrated | Illustrated |
| indexdate | 2024-08-13T00:23:40Z |
| institution | BVB |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007787866 |
| oclc_num | 258612363 |
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| owner | DE-29T DE-355 DE-BY-UBR DE-11 DE-188 |
| owner_facet | DE-29T DE-355 DE-BY-UBR DE-11 DE-188 |
| physical | VII, 201 S. Ill., zahlr. graph. Darst. |
| publishDate | 1997 |
| publishDateSearch | 1997 |
| publishDateSort | 1997 |
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| spelling | Schwegler, Leonore Alexandra 1968- Verfasser (DE-588)115576878 aut On the structure property relation of selected polysilylene homo- and copolymers vorgelegt von Leonore Alexandra Schwegler 1997 VII, 201 S. Ill., zahlr. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Ulm, Univ., Diss. Polysilylene (DE-588)4387928-7 gnd rswk-swf Copolymerisation (DE-588)4070106-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Polysilylene (DE-588)4387928-7 s Copolymerisation (DE-588)4070106-2 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007787866&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Schwegler, Leonore Alexandra 1968- On the structure property relation of selected polysilylene homo- and copolymers Polysilylene (DE-588)4387928-7 gnd Copolymerisation (DE-588)4070106-2 gnd |
| subject_GND | (DE-588)4387928-7 (DE-588)4070106-2 (DE-588)4113937-9 |
| title | On the structure property relation of selected polysilylene homo- and copolymers |
| title_auth | On the structure property relation of selected polysilylene homo- and copolymers |
| title_exact_search | On the structure property relation of selected polysilylene homo- and copolymers |
| title_full | On the structure property relation of selected polysilylene homo- and copolymers vorgelegt von Leonore Alexandra Schwegler |
| title_fullStr | On the structure property relation of selected polysilylene homo- and copolymers vorgelegt von Leonore Alexandra Schwegler |
| title_full_unstemmed | On the structure property relation of selected polysilylene homo- and copolymers vorgelegt von Leonore Alexandra Schwegler |
| title_short | On the structure property relation of selected polysilylene homo- and copolymers |
| title_sort | on the structure property relation of selected polysilylene homo and copolymers |
| topic | Polysilylene (DE-588)4387928-7 gnd Copolymerisation (DE-588)4070106-2 gnd |
| topic_facet | Polysilylene Copolymerisation Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007787866&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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