Chemistry of precious metals:
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London [u.a.]
Blackie Acad. & Professional
1997
|
| Edition: | 1. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII, 374 S. graph. Darst. |
| ISBN: | 0751404136 |
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| 245 | 1 | 0 | |a Chemistry of precious metals |c S. A. Cotton |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a London [u.a.] |b Blackie Acad. & Professional |c 1997 | |
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| adam_text | Titel: Chemistry of precious metals
Autor: Cotton, Simon
Jahr: 1997
Contents
Preface
List of abbreviations
1 Ruthenium and osmium
1.1 Introduction
1.2 The elements and uses
1.2.1 Extraction
1.3 Halides
1.3.1 Ruthenium halides
1.3.2 Osmium halides
1.3.3 Oxyhalides
1.3.4 Halide complexes
1.3.5 Ruthenium blues
1.3.6 Oxyhalide complexes
1.4 Oxides and related anions
1.4.1 Anions
1.5 Other binary compounds
1.6 Aqua ions
1.7 Compounds of ruthenium(0)
1.8 Compounds of ruthenium(II) and (III)
1.8.1 Ammine complexes
1.8.2 Tertiary phosphine complexes
1.8.3 Carboxylate complexes
1.8.4 Sulphide and sulphoxide complexes
1.8.5 Nitrosyl complexes
1.8.6 Porphyrin complexes
1.8.7 EDTA complexes
1.8.8 Other complexes of ruthenium
1.9 Complexes of ruthenium(IV)
1.10 Complexes of osmium(O)
1.11 Osmium complexes in oxidation states (II-IV)
J.I 1.1 Ammine complexes
1. U .2 Tertiary phosphine complexes
1.11.3 Carboxylate complexes
1.11.4 Nitrosyl complexes
1.11.5 Other osmium complexes
1.12 Compounds in high oxidation states
1.12.1 Compounds of the MO|+ groups
1.12.2 Nitride complexes
1.12.3 Imides
1.13 Simple alkyls and aryls
2 Rhodium and iridium
2.1 Introduction
2.2 The elements and uses
2.2.1 Extraction
ix
xi
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vi
CONTENTS
2.3 Halides and halide complexes
2.3.1 Rhodium halides
2.3.2 Iridium halides
2.3.3 Halometallates
2.4 Oxides, hydrides and other binary compounds
2.5 Aqua ions and simple salts
2.6 Compounds of rhodium(O)
2.7 Compounds of rhodium(I)
2.7.1 Tertiary phosphine complexes
2.7.2 Carbonyl complexes
2.7.3 Alkene complexes
2.7.4 Isocyanide complexes
2.8 Rhodium(I I) complexes
2.8.1 Phosphine complexes
2.8.2 Dimers
2.8.3 Other complexes
2.9 Rhodium(III) complexes
2.9.1 Complexes of O-donors
2.9.2 Complexes of ammines
2.9.3 Complexes of other N-donors
2.9.4 Complexes of S-donors
2.9.5 Tertiary phosphine complexes
2.10 Iridium (I) complexes
2.10.1 Tertiary phosphine complexes
2.10.2 Vaska s compound
2.11 Dioxygen complexes
2.12 Iridium(ll) complexes
2.13 Iridium(lll) complexes
2.13.1 Complexes of ammines
2.13.2 Complexes of S-donors
2.13.3 Tertiary phosphine and arsine complexes
2.13.4 Hydride complexes
2.13.5 Case study of dimethylphenylphosphine complexes
2.14 Iridium(IV) complexes
2.15 Iridium(V) complexes
2.16 Nitrosyls of iridium and rhodium
2.17 Simple alkyls and aryls of iridium and rhodium
3 Palladium and platinum
3.1 Introduction
3.2 The elements and uses
3.2.1 Extraction
3.3 Halides
3.3.1 Palladium halides
3.3.2 Platinum halides
3.3.3 Halide complexes
3.4 Other binary complexes
3.5 Aqua ions
3.6 Palladium(O) and platinum(O) compounds
3.6.1 Tertiary phosphine complexes
3.6.2 Reactions of Pt(PPh3)„ and related species
3.6.3 Carbonyl complexes
3.6.4 Carbonyl clusters
3.6.5 Isocyanide complexes
3.7 Palladium(I) and platinum(I) compounds
3.7.1 Phosphine complexes
3.7.2 Isocyanide complexes
79
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CONTENTS
vii
3.8 Complexes of palladium(II) and platinum(II) 199
3.8.1 Complexes of O-donors 199
3.8.2 Complexes of N-donors 201
3.8.3 Tertiary phosphine complexes 209
3.8.4 Complexes of C-donors 219
3.8.5 Complexes of S-donors 225
3.8.6 Complexes of ambidentate ligands 228
3.8.7 Stability of cis- and fron-isomers 233
3.8.8 Five-coordinate compounds 235
3.8.9 The trans-effect 236
3.8.10 Structural evidence for //mr-influence 242
3.8.11 Spectroscopic evidence for f/mr-influence 245
3.9 PalIadium(III) and platinum(III) 248
3.10 Complexes of platinum(IV) 250
3.10.1 Complexes of N-donors 250
3.10.2 Tertiary phosphine complexes 254
3.10.3 Complexes of S-donors 256
3.10.4 Application of the trans-effect to synthesis of platinum(lV)
complexes 256
3.10.5 The trans-influence in some platinum(IV) compounds 258
3.11 Complexes of palladium(lV) 260
3.12 The a-bonded organometallics of palladium(IV) and platinum(IV) 261
3.12.1 Reductive elimination reactions 266
3.13 Anti-tumour activity of platinum complexes 267
3.14 Bond lengths in palladium and platinum analogues 272
Silver and gold 273
4.1 Introduction 273
4.2 The elements and uses 274
4.2.1 Extraction 275
4.2.2 Gold plating and other methods of gold deposition 276
4.3 Halides 276
4.3.1 Silver halides 276
4.3.2 Gold halides 279
4.4 Oxides and other binary compounds 282
4.5 Aqua ions 283
4.6 Silver(I) complexes 285
4.6.1 Complexes of O-donors 285
4.6.2 Complexes of N-donors 285
4.6.3 Tertiary phosphine and arsine complexes 286
4.6.4 Complexes of halogen-donors 287
4.6.5 Complexes of C-donors 288
4.6.6 Complexes of S-donors 288
4.7 Silver(II) complexes 290
4.8 Silver(III) complexes 291
4.9 Gold(-I) complexes 291
4.10 Gold(I) complexes 292
4.10.1 Complexes of O-donors 292
4.10.2 Complexes of N-donors 292
4.10.3 Tertiary phosphine and arsine complexes 292
4.10.4 Complexes of halogen-donors 295
4.10.5 Complexes of C-donors 296
4.10.6 Complexes of S-donors 296
4.10.7 MO schemes for 2-coordinate gold(I) complexes 298
4.11 Gold(II) complexes -.n,
4.12 Gold(III) complexes ^
4.12.1 Complexes of halogens ,
4.12.2 Complexes of N-donors
viii
CONTENTS
4.12.3 Tertiary phosphine and arsine complexes 303
4.12.4 Other complexes 304
4.12.5 Coordination numbers and gold(III) 305
4.12.6 The trans-tfleet and franr-influence 306
4.13 Gold(IV) complexes 307
4.14 Gold(V) complexes 307
4.15 Organometallic compounds of silver 307
4.15.1 Complexes of unsaturated hydrocarbons 308
4.16 Organometallic compounds of gold 310
4.16.1 Gold(I) complexes 310
4.16.2 Gold(III) complexes 313
4.17 Gold cluster complexes 319
4.18 Relativistic effects in gold chemistry 322
4.19 Aurophilicity 323
4.20 Silver and gold compounds in medicine 325
4.21 Mossbauer spectroscopy of gold compounds 327
References 328
Index 363
|
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| indexdate | 2024-07-09T18:11:14Z |
| institution | BVB |
| isbn | 0751404136 |
| language | English |
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| physical | XII, 374 S. graph. Darst. |
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| spelling | Cotton, Simon Verfasser aut Chemistry of precious metals S. A. Cotton 1. ed. London [u.a.] Blackie Acad. & Professional 1997 XII, 374 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Métaux précieux ram Precious metals Chemie (DE-588)4009816-3 gnd rswk-swf Edelmetallkomplexe (DE-588)4151042-2 gnd rswk-swf Edelmetall (DE-588)4013531-7 gnd rswk-swf Edelmetallkomplexe (DE-588)4151042-2 s DE-604 Edelmetall (DE-588)4013531-7 s Chemie (DE-588)4009816-3 s HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007756484&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Cotton, Simon Chemistry of precious metals Métaux précieux ram Precious metals Chemie (DE-588)4009816-3 gnd Edelmetallkomplexe (DE-588)4151042-2 gnd Edelmetall (DE-588)4013531-7 gnd |
| subject_GND | (DE-588)4009816-3 (DE-588)4151042-2 (DE-588)4013531-7 |
| title | Chemistry of precious metals |
| title_auth | Chemistry of precious metals |
| title_exact_search | Chemistry of precious metals |
| title_full | Chemistry of precious metals S. A. Cotton |
| title_fullStr | Chemistry of precious metals S. A. Cotton |
| title_full_unstemmed | Chemistry of precious metals S. A. Cotton |
| title_short | Chemistry of precious metals |
| title_sort | chemistry of precious metals |
| topic | Métaux précieux ram Precious metals Chemie (DE-588)4009816-3 gnd Edelmetallkomplexe (DE-588)4151042-2 gnd Edelmetall (DE-588)4013531-7 gnd |
| topic_facet | Métaux précieux Precious metals Chemie Edelmetallkomplexe Edelmetall |
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