The infra-red spectra of complex molecules: 2 Advances in infrared group frequencies
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Chapman and Hall
1980
|
| Edition: | 2. ed. |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 299 S. |
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MARC
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| 003 | DE-604 | ||
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| 035 | |a (OCoLC)310765626 | ||
| 035 | |a (DE-599)BVBBV011441457 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-19 | ||
| 100 | 1 | |a Bellamy, Lionel John |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The infra-red spectra of complex molecules |n 2 |p Advances in infrared group frequencies |c Lionel John Bellamy* |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a London |b Chapman and Hall |c 1980 | |
| 300 | |a XI, 299 S. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 773 | 0 | 8 | |w (DE-604)BV005687483 |g 2 |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007695294&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-007695294 | ||
Record in the Search Index
| _version_ | 1804125958415843328 |
|---|---|
| adam_text | Titel: Bd. 2. The infra-red spectra of complex molecules. Advances in infrared group frequencies
Autor: Bellamy, Lionel John
Jahr: 1980
Contents
Preface
page
v
1
Alkanes
1
1.1.
Introduction
1
1.2.
CH
3
stretching
frequencies
2
1.3.
CH
2
stretching
frequencies
11
1.4.
The
symmetric
methyl
deformation
frequency
13
1.5.
The
CH
2
deformation
frequency
17
1.6.
Skeletal
vibrations
18
1.6.1.
CH
2
wagging,
twisting
and
rocking
modes
18
1.6.2.
Other
skeletal
modes
20
Bibliography
21
2
Alkenes
and
Vibrations
of
C=N
and
N=N
Links
24
2.1.
The
C=C
stretching
frequency
24
2.1.1.
Bond-angle
effects
25
2.1.2.
Fluorinated
hydrocarbons
(rings)
29
2.1.3.
Oxygenated
ring
systems
30
2.1.4.
Conjugation
effects
in
rings
31
2.1.5.
Fused
ring
systems
32
2.2.
C=C
Frequencies
in
open
chains
33
2.2.1.
The
effects
of
attachment
to
elements
other
than
carbon
35
2.2.2.
Fluorine
substitution
in
open
chains
36
2.2.3.
Conjugation
effects
on
double
bonds
in
open
chains
37
2.2.4.
The
effects
of
n
cloud
interactions
38
2.2.5.
Deuterium
substitution
39
2.3.
CH
stretching
vibrations
of
olefines
39
2.3.1.
In-plane
CH
deformations
in
alkenes
41
2.3.2.
CH
out-of-plane
deformation
vibrations
43
viii
Contents
2.3.3.
CH
out-of-plane
twisting
vibrations
45
2.3.4.
The
CH
2
=
wagging
mode
48
2.4.
The
C=N
stretching
frequency
52
2.5.
The
N=N
stretching
frequency
55
Bibliography
56
3
X=Y=Z
Systems
and
Triple
Bonds
59
3.1.
Introduction,
multiple
bond
systems
59
3.2.
Isothiocyanates
60
3.3.
Thiocyanates
64
3.4.
Isocyanates
64
3.5.
Azides
65
3.6.
Carbodi-imides
66
3.7.
Diazo
compounds
66
3.8.
Aliénés
67
3.8.1.
The
C=C=C
stretching
vibration
(as)
67
3.8.2.
The
CH
2
deformation
of
aliénés
and
its
overtone
band
68
3.9.
Factors
controlling
the
stretching
frequencies
of
triple
bonds
68
3.9.1.
Nitriles
73
3.10.
Isonitriles
77
3.11.
Alkynes
78
3.11.1
CH
stretching
frequencies
in
monosubstituted
alkynes
78
3.11.2.
vC=C
stretching
frequencies
79
3.11.3.
The
(5CH=
deformation
frequency
81
Bibliography
81
4
Unassociated
XH
Vibrations
85
4.1.
Introduction
85
4.2.
Changes
in
XH
stretching
frequencies
following
alterations
in
the
X
Element
87
4.3.
Changes
in
XH
stretching
frequencies
with
alterations
in
the
Substituents
at
X
90
4.4.
vOH
stretching
frequencies
95
4.4.1.
OH
attached
to
carbon
102
4.4.2.
OH
attached
to
nitrogen
105
4.4.3.
vOH
with
oxygen
attached
to
other
elements
106
4.5.
vNH
stretching
frequencies
107
4.5.1.
Primary
amines
and
amides
111
4.5.2.
Secondary
amines
and
amides
115
4.6.
Silicon
and
germanium
hydrides
118
4.6.1.
Silicon
hydrogen
stretching
frequencies
118
4.6.2.
Germanium
hydrogen
stretching
frequencies
119
4.7.
Hydrides
of
other
elements
120
4.7.1.
PH
stretching
frequencies
120
Contents
?*
4.7.2.
SH
and
SeH
stretching
frequencies
121
4.7.3.
BH
stretching
frequencies
122
4.7.4.
Metal-hydrogen
stretching
frequencies
122
Bibliography
123
5
Carbonyl
Frequencies
128
5.1.
Introduction
128
5.2.
Mass
effects
129
5.3.
Frequency
interaction
effects
131
5.3.1.
Interactions
through
Fermi
resonance
132
5.3.2.
Frequency
interactions
between
two
carbonyl
groups
133
5.3.3.
1,4-Dicarbonyl
compounds
136
5.3.4.
1,2-Dicarbonyl
compounds
137
5.4.
The
effects
of
changes
in
bond
angles,
and
in
the
strengths
of
the
adjacent
bonds
138
5.5.
Chemical
effects
141
5.5.1.
Inductive
and
resonance
effects
142
5.6.
Field
effects
in
carbonyl
compounds
147
5.6.1.
a-Halogen
interactions
148
5.6.2.
Field
effects
with
other
atoms
or
groups
in
the
a-position
152
5.6.3.
Interactions
with
polar
groups
not
at
the
a-position
153
5.7.
The
effects
of
changes
of
phase
or
of
Association
154
5.7.1.
Solvent
effects
on
vCO
155
5.7.2.
Interactions
of
the
carbonyl
group
with
hydrogen
donors
157
5.7.3.
Carbonyl
complexes
with
Lewis
acids
158
5.8.
Carbonyl
frequencies
in
specific
classes
of
compound
159
5.8.1.
Alkyl,
aryl
and
conjugated
ketones
162
5.8.2.
Aldehydes
171
5.8.3.
Esters
and
lactones
171
5.8.4.
Acid
halides
173
5.8.5.
Chloroformâtes
and
related
compounds
173
5.8.6.
Anhydrides
and
peroxides
174
5.8.7.
Carbonates,
thiolcarbonates
and
dithiolcarbonates
175
5.8.8.
Thiolesters
175
5.8.9.
Carboxylic
acids
176
5.8.10.
Amides
179
5.8.11.
Imides
183
5.8.12.
Carbamates
and
thiocarbamates
184
5.8.13.
Ureas
184
5.8.14.
Amides
with
an
element
other
than
carbon
attached
to
the
nitorgen
atom
185
5.8.15.
Silyl
esters
185
X
Contents
5.9.
The
carbonyl
deformation
frequency
186
Bibliography
186
6
X=Y
Bonds
Other
than
Carbonyl.
vS=0,
N=0,
P=0,
P=S,
C=S
and
C=Se
Vibrations
195
6.1.
The
sulphoxide
group
195
6.1.1.
Characteristic
frequencies
of
the
SO
link
195
6.1.2.
The
variations
of
vSO
with
changes
in
the
substituents
198
6.1.3.
Sulphoxides
as
donors;
solvent
effects
199
6.2.
The
XN=0
bond
201
6.2.1.
Bond
characteristics
201
6.2.2.
Group
frequencies
202
6.3.
The
P=0
stretching
frequency
204
6.3.1.
P=0
frequencies
in
compounds
other
than
acids
or
amides
205
6.3.2.
Group
frequencies
of
phosphorus
acids
and
amides
207
6.3.3.
The
systematics
of
the
P=0
frequencies
in
relation
to
the
substitution
pattern
209
6.3.4.
Basicity
studies
on
phosphoryl
compounds
210
6.4.
The
P=S
vibration
212
6.5.
The
P=Se
vibration
213
6.6.
The
C=S
vibration
214
6.7.
The
C=Se
vibration
216
Bibliography
217
7
Stretching
Vibrations
of
X0
2
Systems,
RS0
2
,
RN0
2
,
RC0
2
_
221
7.1.
The
S0
2
stretching
vibrations
221
7.1.1.
Group
frequencies
of
the
SOj
link
222
7.1.2.
Factors
affecting
the
positions
of
the
S0
2
stretching
bands
226
7.1.3.
Basic
properties
of
the
S0
2
group
228
7.2.
The
X—NO
z
stretching
vibrations
228
7.2.1.
The
C—N0
2
group
229
7.2.2.
Covalent
nitrates
232
7.2.3.
XN0
2
stretching
bands
when
X
is
an
element
other
than
carbon
or
oxygen
233
7.2.4.
The
Systematics
of
the
changes
in
v
as
and
v
t
in
XNO
z
compounds
233
7.2.5.
Other
characteristic
frequencies
of
the
nitro
group
234
7.3.
The
ionized
carboxyl
group
CO
2
”
235
Bibliography
237
8
Associated
XH
Frequencies,
The
Hydrogen
Bond
240
8.1.
Introduction
240
Contents
xi
8.2.
OH...X
systems
248
8.2.1.
OH
interactions
with
n
clouds
248
8.2.2.
OH...halogen
interactions
250
8.2.3.
OH...O
hydrogen
bonds
251
8.2.4.
OH...N
systems
268
8.2.5.
Very
strong
hydrogen
bonds
271
8.2.6.
OH
deformation
vibrations
273
8.3.
NH...X
hydrogen
bonds
274
8.3.1.
Hydrogen
bonding
in
alkyl
and
aryl
amines
274
8.3.2.
Hydrogen
bonding
by
heterocyclic
amines
276
8.3.3.
Hydrogen
bonding
in
amides
278
8.4.
Hydrogen
bonding
in
thiols
281
8.5.
CH...X
hydrogen
bonds
282
8.5.1.
Hydrogen
bonding
by
haloforms
282
8.5.2.
Hydrogen
bonds
with
acetylenic
and
other
acidic
CH
bonds
283
8.6.
Hydrogen
bonds
of
inorganic
acids
284
Bibliography
285
Subject
Index
293
|
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| id | DE-604.BV011441457 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T18:09:50Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007695294 |
| oclc_num | 310765626 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM |
| owner_facet | DE-19 DE-BY-UBM |
| physical | XI, 299 S. |
| publishDate | 1980 |
| publishDateSearch | 1980 |
| publishDateSort | 1980 |
| publisher | Chapman and Hall |
| record_format | marc |
| spelling | Bellamy, Lionel John Verfasser aut The infra-red spectra of complex molecules 2 Advances in infrared group frequencies Lionel John Bellamy* 2. ed. London Chapman and Hall 1980 XI, 299 S. txt rdacontent n rdamedia nc rdacarrier (DE-604)BV005687483 2 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007695294&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Bellamy, Lionel John The infra-red spectra of complex molecules |
| title | The infra-red spectra of complex molecules |
| title_auth | The infra-red spectra of complex molecules |
| title_exact_search | The infra-red spectra of complex molecules |
| title_full | The infra-red spectra of complex molecules 2 Advances in infrared group frequencies Lionel John Bellamy* |
| title_fullStr | The infra-red spectra of complex molecules 2 Advances in infrared group frequencies Lionel John Bellamy* |
| title_full_unstemmed | The infra-red spectra of complex molecules 2 Advances in infrared group frequencies Lionel John Bellamy* |
| title_short | The infra-red spectra of complex molecules |
| title_sort | the infra red spectra of complex molecules advances in infrared group frequencies |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007695294&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV005687483 |
| work_keys_str_mv | AT bellamylioneljohn theinfraredspectraofcomplexmolecules2 |