The Mott metal insulator transition: models and methods
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
1997
|
| Series: | Springer tracts in modern physics
137 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIII, 317 S. graph. Darst. |
| ISBN: | 3540614818 |
Staff View
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Record in the Search Index
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|---|---|
| adam_text | FLORIAN GEBHARD
THE MOTT
METAL-INSULATOR
TRANSITION
MODELS AND METHODS
WITH 38 FIGURES
SPRINGER
CONTENTS
1. METAL*INSULATOR TRANSITIONS 1
1.1 CLASSIFICATION OF METALS AND INSULATORS 2
1.1.1 DEFINITION OF METAL AND INSULATOR 2
1.1.2 CLASSES OF INSULATORS 4
1.1.3 GAP CRITERION FOR THE INSULATOR 5
1.1.4 ELECTRICAL CONDUCTIVITY AT LOW TEMPERATURE 7
1.1.5 GAP AT FINITE TEMPERATURE 7
1.2 TYPES OF METAL-INSULATOR TRANSITIONS 9
1.2.1 QUANTUM PHASE TRANSITION 9
1.2.2 THERMODYNAMIC PHASE TRANSITION 11
1.3 BAND, PEIERLS, AND ANDERSON INSULATORS 13
1.3.1 BAND INSULATORS 13
1.3.2 PEIERLS INSULATORS 18
1.3.3 ANDERSON INSULATORS 22
1.4 MOTT INSULATORS: BASIC THEORETICAL CONCEPTS 27
1.4.1 ELECTRON-ELECTRON INTERACTION IN METALS 28
1.4.2 EXCHANGE AND CORRELATIONS 29
1.4.3 MAGNETIC MOMENTS 31
1.4.4 SLATER INSULATOR 33
1.4.5 MOTT INSULATOR 34
1.4.6 MOTT-HUBBARD INSULATOR 35
1.4.7 MOTT-HEISENBERG INSULATOR 37
1.5 MOTT INSULATORS: SOME EXPERIMENTAL OBSERVATIONS 38
1.5.1 WIGNER INSULATOR 38
1.5.2 VERWEY INSULATOR 40
1.5.3 MULTI-BAND MOTT INSULATOR 41
1.5.4 CHARGE-TRANSFER INSULATOR 46
1.5.5 WHITHER THEORY? 47
2. HUBBARD MODEL 49
2.1 ELECTRONIC MANY-PARTICLE PROBLEM 50
2.1.1 HAMILTON OPERATOR OF SOLID-STATE PHYSICS 50
2.1.2 HAMILTON OPERATOR OF THE ELECTRONIC PROBLEM 51
X
CONTENTS
2.2 BAND STRUCTURE CALCULATIONS 52
2.2.1 INDEPENDENT ELECTRONS 53
2.2.2 HARTREE THEORY 53
2.2.3 LOCAL DENSITY APPROXIMATION 54
2.2.4 IMPROVEMENTS TO THE LOCAL DENSITY APPROXIMATION ... 56
2.3 DERIVATION OF THE HUBBARD MODEL 58
2.3.1 SECOND QUANTIZATION 58
2.3.2 HUBBARD MODEL 60
2.4 HUBBARD MODEL AND REAL MATERIALS 61
2.4.1 POLYMERS 61
2.4.2 TRANSITION METALS AND THEIR OXIDES 63
2.4.3 FULLERENES 64
2.4.4 HIGH-TEMPERATURE SUPERCONDUCTORS 65
2.4.5 HEAVY FERMION MATERIALS 66
2.4.6 LIQUID HELIUM 67
2.4.7 RELEVANCE OF THE HUBBARD MODEL 68
2.5 MODEL PROPERTIES 68
2.5.1 MODEL PARAMETERS 68
2.5.2 MODEL VARIANTS 69
2.5.3 SYMMETRIES 70
2.5.4 BASIC PROPERTIES OF THE HUBBARD MODEL 72
2.5.5 MAGNETISM 76
3. APPROXIMATE METHODS 79
3.1 HARTREE-FOCK THEORY 80
3.1.1 METHOD AND EXACT STATEMENTS 80
3.1.2 SLATER S THEORY OF THE ANTIFERROMAGNET 81
3.1.3 STONER S THEORY OF THE FERROMAGNET 83
3.1.4 SIMPLIFIED HARTREE-FOCK PHASE DIAGRAM 84
3.1.5 ADVANTAGES AND PROBLEMS 86
3.1.6 IMPROVEMENTS 87
3.2 LOCAL DENSITY APPROXIMATION 89
3.2.1 SITE OCCUPATION FUNCTIONAL THEORY 90
3.2.2 SITE OCCUPATION LOCAL DENSITY APPROXIMATION 92
3.2.3 XQ LOCAL DENSITY APPROXIMATION 94
3.2.4 LSDA WITH SELF-INTERACTION CORRECTIONS 96
3.3 GREEN-FUNCTION DECOUPLING METHOD 98
3.3.1 ATOMIC LIMIT AND HUBBARD BANDS 98
3.3.2 HUBBARD-I APPROXIMATION 99
3.3.3 ADVANTAGES AND PROBLEMS 100
3.3.4 IMPROVEMENTS 102
3.3.5 ALLOY-ANALOGY APPROXIMATION 103
3.3.6 HUBBARD-III APPROXIMATION 106
3.3.7 ADVANTAGES AND PROBLEMS 107
3.3.8 IMPROVEMENTS 108
CONTENTS XI
3.4 VARIATIONAL WAVE FUNCTIONS 111
3.4.1 GUTZWILLER-CORRELATED WAVE FUNCTIONS 111
3.4.2 VARIATIONAL CHARACTERIZATION OF AN INSULATOR 113
3.4.3 EXACT STATEMENTS 114
3.4.4 GUTZWILLER WAVE FUNCTION IN ONE DIMENSION 115
3.4.5 VARIATIONAL WAVE FUNCTIONS IN INFINITE DIMENSIONS .... 116
3.4.6 BRINKMAN-RICE TRANSITION 118
3.4.7 EXPANSION AROUND THE LIMIT OF INFINITE DIMENSIONS . . . 120
3.4.8 VARIATIONAL PHASE DIAGRAM IN INFINITE DIMENSIONS .... 121
3.4.9 EXTENSIONS AND IMPROVEMENTS 122
3.4.10 ADVANTAGES AND PROBLEMS 124
3.5 SLAVE BOSON APPROACH 125
3.5.1 SLAVE BOSONS AND FUNCTIONAL INTEGRALS 125
3.5.2 KOTLIAR-RUCKENSTEIN SLAVE BOSONS 127
3.5.3 KOTLIAR-RUCKENSTEIN APPROXIMATION 128
3.5.4 ADVANTAGES AND PROBLEMS 129
3.5.5 BARNES-COLEMAN SLAVE BOSONS AND APPROXIMATION. . . . 131
3.5.6 ADVANTAGES AND PROBLEMS 132
4. ONE-DIMENSIONAL HUBBARD MODELS 135
4.1 HUBBARD MODEL WITH NEAREST-NEIGHBOR HOPPING 136
4.1.1 TWO-ELECTRON PROBLEM FOR TWO LATTICE SITES 136
4.1.2 GENERAL TWO-ELECTRON PROBLEM IN ONE DIMENSION .... 137
4.1.3 BETHE ANSATZ FOR THE IV-ELECTRON PROBLEM 139
4.1.4 GROUND-STATE ENERGY AT HALF BAND-FILLING 142
4.1.5 METAHNSULATOR TRANSITION AT HALF BAND-FILLING 144
4.1.6 DRUDE WEIGHT BELOW HALF BAND-FILLING 147
4.1.7 METAHNSULATOR TRANSITION APPROACHING HALF FILLING . . 150
4.2 HUBBARD MODEL WITH LONG-RANGE HOPPING 152
4.2.1 BASIC PROPERTIES 152
4.2.2 GENERAL TWO-ELECTRON PROBLEM IN ONE DIMENSION .... 155
4.2.3 EFFECTIVE HAMILTONIAN FOR THE JV-ELECTRON PROBLEM .... 157
4.2.4 GROUND-STATE ENERGY AND METAHNSULATOR TRANSITION . 160
4.2.5 THERMODYNAMIC PROPERTIES 163
4.3 HUBBARD MODEL WITH VARIABLE-RANGE HOPPING 168
4.3.1 BASIC PROPERTIES 169
4.3.2 GENERAL TWO-ELECTRON PROBLEM IN ONE DIMENSION .... 170
4.3.3 S MATRIX AND GENERALIZED LIEB-WU EQUATIONS 173
4.3.4 GROUND-STATE ENERGY AT HALF BAND-FILLING 174
4.3.5 METAHNSULATOR TRANSITION AT HALF BAND-FILLING 175
4.4 MOTT-HUBBARD TRANSITION IN ONE DIMENSION 176
4.4.1 GR-OLOGY HAMILTONIAN 177
4.4.2 PERFECT NESTING IN ONE DIMENSION 179
4.4.3 LONG-RANGE HOPPING 181
4.4.4 COMPARISON WITH BASIC THEORETICAL CONCEPTS 182
CONTENTS
HUBBARD MODEL IN INFINITE DIMENSIONS 185
5.1 LIMIT OF INFINITE DIMENSIONS 186
5.1.1 SPIN MODELS IN INFINITE DIMENSIONS 186
5.1.2 NON-INTERACTING ITINERANT ELECTRONS 189
5.2 GENERALIZED MEAN-FIELD APPROACHES 191
5.2.1 MEAN-FIELD SPIN MODELS 191
5.2.2 RANDOM DISPERSION APPROXIMATION 193
5.3 SIMPLIFICATIONS IN INFINITE DIMENSIONS 197
5.3.1 POSITION-SPACE COLLAPSE OF DIAGRAMS 197
5.3.2 IRRELEVANCE OF MOMENTUM CONSERVATION 200
5.3.3 EFFECTIVE MODELS WITH SINGLE-SITE INTERACTION 202
5.4 ANALYTICAL RESULTS IN INFINITE DIMENSIONS 206
5.4.1 PERTURBATION THEORY FOR SMALL INTERACTIONS 207
5.4.2 PERTURBATION THEORY FOR LARGE INTERACTIONS 210
5.4.3 VARIATIONAL WAVE FUNCTIONS 212
5.4.4 FALICOV-KIMBALL MODEL 213
5.4.5 SPINLESS FERMIONS 218
5.5 APPROXIMATE SOLUTIONS OF THE HUBBARD MODEL 219
5.5.1 MODEL SPECIFICATIONS 220
5.5.2 CONSTRAINTS ON APPROXIMATE TREATMENTS 220
5.5.3 QUANTUM MONTE-CARLO CALCULATIONS 222
5.5.4 EXACT DIAGONALIZATION STUDIES 223
5.5.5 ITERATED PERTURBATION THEORY 224
5.5.6 NON-CROSSING APPROXIMATION 225
5.5.7 LOCAL MOMENTS IN HUBBARD S APPROXIMATIONS 227
5.5.8 LOCAL-MOMENT APPROACH 228
5.6 METAL-INSULATOR TRANSITIONS 231
5.6.1 MOTT-HEISENBERG INSULATOR 231
5.6.2 CORRELATED METAL 233
5.6.3 MOTT-HUBBARD INSULATOR 235
5.6.4 MOTT-HUBBARD TRANSITION 236
5.6.5 COMPARISON WITH BASIC THEORETICAL CONCEPTS 240
FURTHER MODELS WITH HUBBARD INTERACTION 243
6.1 DEGENERATE AND EXTENDED HUBBARD MODELS 243
6.1.1 BAND-DEGENERATE HUBBARD MODEL IN ONE DIMENSION . . 244
6.1.2 EXTENDED HUBBARD MODEL 245
6.1.3 GENERALIZED HUBBARD MODELS 247
6.2 MODELS WITH CONSERVED DOUBLE OCCUPANCIES 248
6.2.1 BOND-CHARGE INTERACTIONS AND HARRIS-LANGE MODEL. . . 249
6.2.2 HARRIS-LANGE MODEL IN ONE DIMENSION 250
6.2.3 MONTORSI-RASETTI MODEL 252
6.2.4 SUPERSYMMETRIC HUBBARD MODEL 253
6.3 MODELS WITH COMMUTING OPERATORS 255
6.3.1 HUBBARD MODEL WITH INFINITE-RANGE HOPPING 256
CONTENTS XIII
6.3.2 STONER MODEL WITH LONG-RANGE HOPPING 257
6.3.3 LANDAU-HUBBARD MODEL 260
7. CONCLUSIONS 263
APPENDIX 267
A.L CALCULATIONS FOR HARTREE-FOCK THEORY 267
A.1.1 DIAGONALIZATION OF THE HARTREE-FOCK HAMILTONIAN 267
A.1.2 GROUND-STATE PROPERTIES FOR HALF BAND-FILLING 268
A.2 GREEN FUNCTIONS AND HUBBARD-I APPROXIMATION 270
A.2.1 GREEN FUNCTIONS 270
A.2.2 HUBBARD-I APPROXIMATION 272
A.3 GENERALIZED LIEB-WU INTEGRAL EQUATIONS 274
A.3.1 DERIVATION OF THE INTEGRAL EQUATIONS 274
A.3.2 SOLUTION FOR HALF-FILLED BANDS 276
A.3.3 QUASI-PARTICLE DISPERSIONS 277
A.3.4 LIMIT OF LONG-RANGE HOPPING 279
REFERENCES 281
INDEX 309
|
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| author | Gebhard, Florian 1962- |
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| id | DE-604.BV011129806 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:04:28Z |
| institution | BVB |
| isbn | 3540614818 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007458394 |
| oclc_num | 246679947 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-29T DE-384 DE-703 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-20 DE-634 DE-83 DE-11 DE-188 |
| owner_facet | DE-355 DE-BY-UBR DE-29T DE-384 DE-703 DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-20 DE-634 DE-83 DE-11 DE-188 |
| physical | XIII, 317 S. graph. Darst. |
| publishDate | 1997 |
| publishDateSearch | 1997 |
| publishDateSort | 1997 |
| publisher | Springer |
| record_format | marc |
| series | Springer tracts in modern physics |
| series2 | Springer tracts in modern physics |
| spelling | Gebhard, Florian 1962- Verfasser (DE-588)133082326 aut The Mott metal insulator transition models and methods Florian Gebhard The Mott metal-insulator transition Berlin [u.a.] Springer 1997 XIII, 317 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer tracts in modern physics 137 Hubbard-Modell - Metall-Isolator-Phasenumwandlung Mathematische Physik Condensed matter Electron-electron interactions Many-body problem Mathematical physics Metal-insulator transitions Metall-Halbleiter-Kontakt (DE-588)4169590-2 gnd rswk-swf Vielkörperproblem (DE-588)4078900-7 gnd rswk-swf Elektron-Elektron-Wechselwirkung (DE-588)4151859-7 gnd rswk-swf Metall-Isolator-Phasenumwandlung (DE-588)4169600-1 gnd rswk-swf Hubbard-Modell (DE-588)4160713-2 gnd rswk-swf Metall-Halbleiter-Kontakt (DE-588)4169590-2 s Elektron-Elektron-Wechselwirkung (DE-588)4151859-7 s Vielkörperproblem (DE-588)4078900-7 s DE-604 Metall-Isolator-Phasenumwandlung (DE-588)4169600-1 s Hubbard-Modell (DE-588)4160713-2 s Springer tracts in modern physics 137 (DE-604)BV000000153 137 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007458394&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gebhard, Florian 1962- The Mott metal insulator transition models and methods Springer tracts in modern physics Hubbard-Modell - Metall-Isolator-Phasenumwandlung Mathematische Physik Condensed matter Electron-electron interactions Many-body problem Mathematical physics Metal-insulator transitions Metall-Halbleiter-Kontakt (DE-588)4169590-2 gnd Vielkörperproblem (DE-588)4078900-7 gnd Elektron-Elektron-Wechselwirkung (DE-588)4151859-7 gnd Metall-Isolator-Phasenumwandlung (DE-588)4169600-1 gnd Hubbard-Modell (DE-588)4160713-2 gnd |
| subject_GND | (DE-588)4169590-2 (DE-588)4078900-7 (DE-588)4151859-7 (DE-588)4169600-1 (DE-588)4160713-2 |
| title | The Mott metal insulator transition models and methods |
| title_alt | The Mott metal-insulator transition |
| title_auth | The Mott metal insulator transition models and methods |
| title_exact_search | The Mott metal insulator transition models and methods |
| title_full | The Mott metal insulator transition models and methods Florian Gebhard |
| title_fullStr | The Mott metal insulator transition models and methods Florian Gebhard |
| title_full_unstemmed | The Mott metal insulator transition models and methods Florian Gebhard |
| title_short | The Mott metal insulator transition |
| title_sort | the mott metal insulator transition models and methods |
| title_sub | models and methods |
| topic | Hubbard-Modell - Metall-Isolator-Phasenumwandlung Mathematische Physik Condensed matter Electron-electron interactions Many-body problem Mathematical physics Metal-insulator transitions Metall-Halbleiter-Kontakt (DE-588)4169590-2 gnd Vielkörperproblem (DE-588)4078900-7 gnd Elektron-Elektron-Wechselwirkung (DE-588)4151859-7 gnd Metall-Isolator-Phasenumwandlung (DE-588)4169600-1 gnd Hubbard-Modell (DE-588)4160713-2 gnd |
| topic_facet | Hubbard-Modell - Metall-Isolator-Phasenumwandlung Mathematische Physik Condensed matter Electron-electron interactions Many-body problem Mathematical physics Metal-insulator transitions Metall-Halbleiter-Kontakt Vielkörperproblem Elektron-Elektron-Wechselwirkung Metall-Isolator-Phasenumwandlung Hubbard-Modell |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007458394&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000000153 |
| work_keys_str_mv | AT gebhardflorian themottmetalinsulatortransitionmodelsandmethods AT gebhardflorian themottmetalinsulatortransition |