An introduction to polymer science:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Weinheim [u.a.]
VCH
1997
|
| Edition: | 1. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XXII, 470 S. graph. Darst. |
| ISBN: | 3527287906 |
Staff View
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV011117252 | ||
| 003 | DE-604 | ||
| 005 | 20100423 | ||
| 007 | t | ||
| 008 | 961209s1997 gw d||| |||| 00||| eng d | ||
| 016 | 7 | |a 948942738 |2 DE-101 | |
| 020 | |a 3527287906 |9 3-527-28790-6 | ||
| 035 | |a (OCoLC)845317586 | ||
| 035 | |a (DE-599)BVBBV011117252 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 044 | |a gw |c DE | ||
| 049 | |a DE-384 |a DE-703 |a DE-29T |a DE-19 |a DE-91G |a DE-898 |a DE-1051 |a DE-634 |a DE-83 |a DE-11 |a DE-525 |a DE-188 | ||
| 050 | 0 | |a QD381 | |
| 082 | 0 | |a 547.7 |2 21 | |
| 084 | |a VE 8000 |0 (DE-625)147145:253 |2 rvk | ||
| 084 | |a VK 8000 |0 (DE-625)147532:253 |2 rvk | ||
| 084 | |a CHE 700f |2 stub | ||
| 084 | |a WER 550f |2 stub | ||
| 100 | 1 | |a Elias, Hans-Georg |d 1928- |e Verfasser |0 (DE-588)128433426 |4 aut | |
| 245 | 1 | 0 | |a An introduction to polymer science |c Hans-Georg Elias |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Weinheim [u.a.] |b VCH |c 1997 | |
| 300 | |a XXII, 470 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Biopolymeren |2 gtt | |
| 650 | 7 | |a Copolymeren |2 gtt | |
| 650 | 7 | |a Fysische eigenschappen |2 gtt | |
| 650 | 7 | |a Polimeros (quimica) |2 larpcal | |
| 650 | 7 | |a Polymeren |2 gtt | |
| 650 | 4 | |a Polymères | |
| 650 | 7 | |a Thermodynamica |2 gtt | |
| 650 | 7 | |a Vloeibare kristallen |2 gtt | |
| 650 | 4 | |a Polymers | |
| 650 | 0 | 7 | |a Polymere |0 (DE-588)4046699-1 |2 gnd |9 rswk-swf |
| 655 | 7 | |8 1\p |0 (DE-588)4123623-3 |a Lehrbuch |2 gnd-content | |
| 689 | 0 | 0 | |a Polymere |0 (DE-588)4046699-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007449782&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 883 | 1 | |8 1\p |a cgwrk |d 20201028 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-007449782 | |
Record in the Search Index
| _version_ | 1809768402230706176 |
|---|---|
| adam_text |
CONTENTS
PREFACE
.
LIST
OF
SYMBOLS
FOR
PHYSICAL
QUANTITIES
.
CONTENTS
.
1.
INTRODUCTION
.
1
1.1.
FUNDAMENTAL
TERMS
.
1
1.2.
HISTORY
.
4
CHEMISTRY
2.
CHEMICAL
STRUCTURE
.
10
2.1.
CONSTITUTION.
10
2.1.1.
NOMENCLATURE
.
10
2.1.2.
MONOMERS
FOR
POLYMERS
.
12
2.1.3.
PROCESS-BASED
TERMS
.
12
2.1.4.
STRUCTURE-BASED
TERMS
.
14
2.1.5.
ONE-,
TWO-AND
THREE-DIMENSIONAL
MACROMOLECULES
.
16
2.1.6.
BRANCHED
MACROMOLECULES
.
20
2.2.
MOLAR
MASS
AND
MOLAR
MASS
DISTRIBUTION
.
23
2.2.1.
DEGREE
OF
POLYMERIZATION
.
23
2.2.2.
MOLECULAR
MASS,
MOLECULAR
WEIGHT,
MOLAR
MASS
.
24
2.2.3.
DISTRIBUTION
FUNCTIONS
.
27
2.2.4.
EXPERIMENTAL
METHODS
.
31
MASS
SPECTROMETRY
.
31
SIZE-EXCLUSION
CHROMATOGRAPHY
.
32
2.3.
CONFIGURATION
.
34
2.3.1.
STEREOISOMERS
.
34
2.3.2.
IDEAL
TACTICITY
.
35
2.3.3.
REAL
TACTICITY
.
40
2.3.4.
EXPERIMENTAL
METHODS
.
41
2.4.
CONFORMATION
.
43
2.4.1.
MICROCONFORMATION
.
43
2.4.2.
MACROCONFORMATION
IN
CRYSTALS
.
45
2.4.3.
MACROCONFORMATION
IN
MELTS
AND
SOLUTIONS
.
46
3.
CHAIN-GROWTH
POLYMERIZATIONS
.
50
3.1.
OVERVIEW
OF
POLYMERIZATIONS
.
50
CONTENTS
XIII
3.1.1.
CLASSES
OF
POLYMERIZATIONS
.
;
.
50
3.1.2.
EXAMPLES
OF
POLYMERIZATIONS
.
52
3.1.3.
FUNCTIONALITY
.
53
3.1.4.
EXPERIMENTAL
INVESTIGATIONS
.
53
3.1.5.
KINETICS
AND
STATISTICS
.
54
3.2.
THERMODYNAMICS
OF
POLYMERIZATIONS
.
54
3.2.1.
POLYMERIZATION
EQUILIBRIA
.
54
3.2.2.
CRITICAL
POLYMERIZATION
TEMPERATURES
.
55
3.2.3.
CEILING
AND
FLOOR
TEMPERATURES
.
56
3.2.4.
POLYMERIZATION
ENTHALPIES
AND
ENTROPIES
.
57
3.2.5.
CHAIN
AND
RING
FORMATION
.
58
3.3.
STATISTICS
OF
CHAIN
POLYMERIZATIONS
.
59
3.4.
ANIONIC
POLYMERIZATIONS
.
63
3.4.1.
ION
EQUILIBRIA
.
63
3.4.2.
MONOMERS
.
64
3.4.3.
INITIATORS
.
65
3.4.4.
LIVING
POLYMERIZATIONS
.
66
3.4.5.
TERMINATION
AND
CHAIN
TRANSFER
.
68
3.4.6.
STEREOCONTROL
.
70
3.5.
CATIONIC
POLYMERIZATIONS
.
71
3.5.1.
MONOMERS
.
71
3.5.2.
INITIATORS
.
72
3.5.3.
PROPAGATION
.
74
3.5.4.
TERMINATION
AND
CHAIN
TRANSFER
.
75
3.6.
INSERTION
POLYMERIZATIONS
.
77
3.6.1.
INTRODUCTION
.
77
3.6.2.
ZIEGLER-NATTA
POLYMERIZATIONS
.
78
HETEROGENEOUS
ZIEGLER
CATALYSTS
.
79
HOMOGENEOUS
ZIEGLER
CATALYSTS
.
81
KINETICS
.
82
3.6.3.
METATHESIS
POLYMERIZATIONS
.
83
METATHESES
.
83
POLYELIMINATION
OF
ALIPHATIC
OLEFINS
.
84
RING-OPENING
POLYMERIZATION
OF
CYCLOOLEFINS
.
84
3.6.4.
GROUP
TRANSFER
POLYMERIZATIONS
.
85
3.7.
FREE-RADICAL
POLYMERIZATIONS
.
86
3.7.1.
INTRODUCTION
.
86
3.7.2.
FORMATION
OF
FREE
RADICALS
.
86
SELF-INITIATED
POLYMERIZATIONS
.
86
THERMAL
INITIATORS
.
88
REDOX
INITIATORS
.
90
PHOTO
INITIATORS
.
90
XIV
CONTENTS
3.7.3.
INITIATION,
PROPAGATION
AND
TERMINATION
.
90
3.7.4.
STEADY
STATE
.
92
3.7.5.
IDEAL
KINETICS
.
93
3.7.6.
ALLYL
POLYMERIZATIONS
.
96
3.7.7.
KINETIC
CHAIN
TRANSFER
.
96
3.7.8.
NON-IDEAL
KINETICS
.
100
3.7.9.
INDUSTRIAL
POLYMERIZATIONS
.
102
REACTORS
.
102
POLYMERIZATION
IN
BULK
.
103
POLYMERIZATION
IN
SOLUTION
AND
BY
PRECIPITATION
.
104
POLYMERIZATION
IN
SUSPENSION
.
104
POLYMERIZATION
IN
EMULSION
.
105
3.8.
COPOLYMERIZATIONS
.
107
3.8.1.
INTRODUCTION
.
107
3.8.2.
COPOLYMERIZATION
EQUATION
.
107
3.8.3.
SEQUENCE
STATISTICS
.
110
3.8.4.
KINETICS
OF
RADICAL
COPOLYMERIZATIONS
.
ILL
3.8.5.
2,E-SCHEME
.
112
3.8.6.
IONIC
COPOLYMERIZATIONS
.
114
APPENDIX
TO
CHAPTER
3
.
115
A
3-1:
EQUILIBRIA
.
115
A
3-2:
POISSON
DISTRIBUTION
.
116
A
3-3
STATIONARY
STATE
.116
A
3-4:
SCHULZ-FLORY
DISTRIBUTION
.
117
4.
STEP-GROWTH
POLYMERIZATIONS
AND
POLYMER
REACTIONS
.
120
4.1.
POLYCONDENSATIONS
AND
POLYADDITIONS
.
120
4.1.1.
INTRODUCTION
.
120
4.1.2.
CHEMISTRY
OF
BIFUNCTIONAL
POLYCONDENSATIONS
.
121
4.1.3.
EQUILIBRIA
OF
BIFUNCTIONAL
POLYCONDENSATIONS
.
124
EQUILIBRIUM
CONSTANTS
.
124
NUMBER-AVERAGE
DEGREES
OF
POLYMERIZATION
.
124
DISTRIBUTIONS
OF
DEGREES
OF
POLYMERIZATION
.
126
4.1.4.
KINETICS
OF
BIFUNCTIONAL
REACTIONS
.
127
4.1.5.
DIFFUSION-CONTROLLED
POLYCONDENSATIONS
.
129
4.1.6.
ACTIVATED
POLYCONDENSATIONS
.
130
4.1.7.
CYCLIZATIONS
.
131
INTRAMOLECULAR
CYCLIZATIONS
.
131
INTRAMERAR
CYCLIZATIONS
.
132
4.1.8.
POLYADDITIONS
.
135
POLYURETHANES
PUR
.
135
EPOXY
RESINS
EP
.
137
4.1.9
BRANCHING
POLYCONDENSATIONS
.
138
CONTENTS
X
V
HYPERBRANCHED
POLYMERS
.
139
DENDRITIC
POLYMERS
.
139
GEL
POINT
.
139
ALKYD
RESINS
.
142
PHENOL-FORMALDEHYDE
RESINS
(PHENOLIC
RESINS)
PF
.
142
MELAMINE
RESINS
MF
AND
UREA
RESINS
UF
.
144
4.2.
BIOLOGICAL
POLYMERIZATIONS
.
145
4.2.1.
INTRODUCTION
.
145
4.2.2.
NUCLEIC
ACIDS
.
146
4.2.3.
PROTEINS
.
148
STRUCTURE
.
148
PROTEIN
SYNTHESES
.
150
ENZYMES
.
152
SILK
.
153
WOOL
.
153
COLLAGEN
AND
ELASTIN
.
154
4.2.4.
LIGNINS
.
155
4.2.5.
POLYSACCHARIDES
.
156
NOMENCLATURE
.
157
BIOSYNTHESES
.
157
CELLULOSES
.
158
AMYLOSE
AND
AMYLOPECTIN
.
159
OTHER
POLYSACCHARIDES
.
160
4.2.6.
POLYESTERS
.
161
4.2.7.
POLYPRENES
.
161
4.3.
REACTIONS
OF
MACROMOLECULES
.
.
.
162
4.3.1.
POLYMER
ANALOG
REACTIONS
.
162
4.3.2.
CHAIN
EXTENSIONS
.
163
BLOCK
FORMATION
.
163
GRAFTING
REACTIONS
.
164
4.3.3.
CROSS-LINKING
REACTIONS
.
165
4.3.4.
DEGRADATION
.
166
CHAIN
SCISSION
.
166
DEPOLYMERIZATION
.
167
PHYSICAL
CHEMISTRY
5
SIZE
AND
SHAPE
OF
MOLECULES
.170
5.1.
INTRODUCTION
.
170
5.2.
SCATTERING
METHODS
.
170
5.2.1.
STATIC
LIGHT
SCATTERING
.
171
INFINITE
DILUTION
.
171
CONCENTRATION
DEPENDENCE
.
173
XVI
CONTENTS
ANGULAR
DEPENDENCE
.
173
5.2.2.
SMALL
ANGLE
X-RAY
AND
NEUTRON
SCATTERING
.
175
5.3.
IDEAL
COIL
MOLECULES
.
176
5.3.1.
MACROCONFORMATIONS
.176
5.3.2.
RANDOM
COILS
.
179
5.3.3.
STERIC
FACTOR
AND
HINDRANCE
PARAMETER
.
181
5.3.4.
RADIUS
OF
GYRATION
.
183
5.3.5.
COIL
DENSITY
.184
5.4.
WORM-LIKE
CHAINS
.
185
5.5.
REAL
COIL
MOLECULES
.
186
5.5.1
EXCLUDED
VOLUME
.
186
5.5.2.
DEPENDENCE
ON
MOLAR
MASS
.
187
5.5.3.
BRANCHED
POLYMERS
.
189
5.5.4.
TETHERED
CHAINS
.
191
5.6.
EUCLIDIAN
BODIES
.
191
5.6.1.
SPHERES
AND
SPHEROIDS
.
191
5.6.2.
RODS
.
192
5.6.3.
EXCLUDED
VOLUME
.
193
5.7.
SCALING
.
195
5.7.1.
SELF-SIMILARITY
.
195
5.7.2.
OVERLAP
OF
COILS
.
196
5.7.3.
FRACTALS
.
198
5.8.
VISCOSIMETRIC
DIMENSIONS
.
200
5.8.1.
INTRODUCTION
.
200
5.8.2.
CONCENTRATION
DEPENDENCE
.201
5.8.3.
MOLAR
MASS
DEPENDENCE
.
203
5.8.4.
HYDRODYNAMIC
VOLUMES
.
205
5.9.
INTERPRETATION
OF
[RJ]
=F(M)
.
206
5.9.1.
UNPERTURBED
COILS
.
206
5.9.2.
FLORY
CONSTANT
OF
FLEXIBLE
MOLECULES
.
207
5.9.3.
PERTURBED
COILS
.
210
5.9.4.
RODS
.211
5.9.5.
BRANCHED
POLYMERS
.
211
APPENDIX
TO
CHAPTER
5
.
213
A
5-1:
END-TO-END
DISTANCES
OF
FREELY
ROTATING
CHAINS
.
213
A
5-2:
END-TO-END
DISTANCE
AND
RADIUS
OF
GYRATION
.
214
A
5-3:
CHAINS
WITH
PERSISTENCE
.
216
6
SOLUTION
THERMODYNAMICS
.
218
6.1.
PHENOMENA
.
218
CONTENTS
XVII
6.1.1.
INTRODUCTION
.
YY.
.
218
6.1.2.
CONCENTRATION
RANGES
.
219
6.1.3.
SOLUBILITY
PARAMETERS
.
220
6.2.
STATISTICAL
THERMODYNAMICS
.
223
6.2.1.
TYPES
OF
SOLUTIONS
.
223
6.2.2.
LATTICE
THEORY
.
224
ENTHALPY
OF
MIXING
.
225
ENTROPY
OF
MIXING
.
226
GIBBS
ENERGY
OF
MIXING
.
227
6.2.3.
PHASE
SEPARATION
.
227
SOLUTIONS
OF
AMORPHOUS
POLYMERS
.
227
POLYMER
BLENDS
.
230
CRITICAL
SOLUTION
TEMPERATURES
.231
SOLUTIONS
OF
CRYSTALLINE
POLYMERS
.
232
6.3.
OSMOTIC
PRESSURE
.
233
6.3.1.
FUNDAMENTALS
.
233
6.3.2.
MEMBRANE
OSMOMETRY
.
235
6.3.3.
VAPOR
PHASE
OSMOMETRY
.
236
6.3.4.
VIRIAL
COEFFICIENTS
.
237
6.3.5.
OVERLAP
CONCENTRATIONS
.
239
6.4.
ASSOCIATION
.
241
6.4.1.
OPEN
ASSOCIATIONS
.
242
6.4.2.
CLOSED
ASSOCIATIONS
.
243
6.4.3.
GELS
.
245
7.
POLYMER
HYDRODYNAMICS
.
247
7.1.
INTRODUCTION
.
247
7.2.
DIFFUSION
IN
SOLUTION
.
247
7.2.1.
MUTUAL
DIFFUSION
.
247
7.2.2.
FRICTIONAL
COEFFICIENTS
.
248
7.2.3.
SPRING-AND-BEAD
MODELS
.
250
7.3.
SEDIMENTATION
IN
SOLUTION
.
252
7.3.1.
FUNDAMENTALS
.
252
7.3.2.
SEDIMENTATION
RATE
.
253
7.3.3.
SEDIMENTATION
EQUILIBRIUM
.
255
7.4.
VISCOSITY
OF
SOLUTIONS
AND
MELTS
.
256
7.4.1.
INTRODUCTION
.
256
7.4.2.
VISCOMETRY
.
256
7.4.3.
NEWTONIAN
VISCOSITIES
.
259
7.4.4.
NON-NEWTONIAN
VISCOSITIES
.
261
7.4.5.
FLOW
CURVES
.
263
7.4.6.
EXTENSIONAL
VISCOSITIES
.
265
XVIII
CONTENTS
7.5.
MOLECULAR
DYNAMICS
OF
MELTS
.
266
7.5.1.
DIFFUSION
.
266
7.5.2.
VISCOSITY
.
267
APPENDIX
TO
CHAPTER
7
.271
A
7-1:
HYDRODYNAMICALLY
EFFECTIVE
VOLUME
.271
PHYSICS
8.
POLYMER
ASSEMBLIES
.
273
8.1.
INTRODUCTION
.
273
8.2.
MELTS
AND
AMORPHOUS
STATES
.
274
8.3.
CRYSTALLINE
POLYMERS
.
275
8.3.1.
INTRODUCTION
.
275
8.3.2.
X-RAY
DIFFRACTION
.
276
8.3.3.
CRYSTAL
STRUCTURES
.
279
8.3.4.
MACROCONFORMATION
AND
PACKING
.
281
8.3.5.
CHAIN
FOLDING
.
284
8.3.6.
MORPHOLOGY
.
286
8.3.7.
ORIENTATION
.
288
8.4.
LIQUID
CRYSTALS
.
290
8.4.1.
INTRODUCTION
.
290
8.4.2.
MESOGENS
AND
MESOPHASES
.
290
8.4.3.
THERMOTROPIC
LIQUID
CRYSTALS
.
292
8.4.4.
LYOTROPIC
LIQUID
CRYSTALS
.
293
8.5.
BLOCK
COPOLYMERS
.
294
8.6.
IONOMERS
.
297
9.
TRANSITIONS
AND
RELAXATIONS
.
299
9.1.
INTRODUCTION
.
299
9.2.
THERMAL
PROPERTIES
.
299
9.2.1.
STATES
AND
METHODS
.
299
9.2.2.
THERMAL
EXPANSION
.301
9.2.3.
HEAT
CAPACITIES
.
302
9.2.4.
HEAT
CONDUCTIVITY
.
303
9.3.
CRYSTALLIZATION
.
304
9.3.1.
NUCLEATION
.
304
9.3.2.
CRYSTALLIZATION
RATE
.
306
9.4.
MELTING
TEMPERATURE
.
309
9.4.1.
PHENOMENA
.
309
9.4.2.
EFFECT
OF
MOLAR
MASS
.
310
CONTENTS
XIX
9.4.3.
EFFECT
OF
CRYSTALLITE
SIZE
.
311
9.4.4.
EFFECT
OF
CONSTITUTION
.311
9.5.
THERMAL
TRANSITIONS
AND
RELAXATIONS
.
313
9.6.
GLASS
TEMPERATURES
.
315
9.6.1.
STATIC
GLASS
TEMPERATURE
.
315
9.6.2.
DYNAMIC
GLASS
TEMPERATURES
.
316
9.6.3.
EFFECTS
OF
CONSTITUTION
.
317
9.6.4.
PLASTICIZATION
.
319
9.7.
DIFFUSION
AND
PERMEATION
.321
9.7.1.
PERMEATION
OF
GASES
.
321
9.7.2.
PERMEATION
OF
LIQUIDS
.
322
10.
SOLID
STATE
PROPERTIES
.
325
10.1.
INTRODUCTION
.
325
10.2.
DEFORMATION
.
326
10.2.1.
INTRODUCTION
.
326
10.2.2.
TENSILE
TESTS
.
326
10.2.3.
TENSILE
BEHAVIOR
.
329
10.2.4.
MODULI
AND
POISSON
RATIOS
.
330
10.3.
ENERGY
ELASTICITY
.
333
10.3.1.
INTRODUCTION
.
333
10.3.2.
THEORETICAL
AND
EXPERIMENTAL
MODULI
.
333
10.4.
ENTROPY
ELASTICITY
.
336
10.4.1.
CHEMICAL
THERMODYNAMICS
.
336
10.4.2.
STRUCTURE
OF
NETWORKS
.
337
10.4.3.
STATISTICAL
THERMODYNAMICS
.
338
10.4.4.
MODELS
.
339
10.4.5.
UNIAXIAL
STRETCHING
.
340
10.4.6.
REAL
STRESS-STRAIN
BEHAVIOR
.
342
10.4.7.
SHEARING
.
342
10.5.
VISCOELASTICITY
.
344
10.5.1.
FUNDAMENTALS
.
344
10.5.2.
MODELS
.
344
10.5.3.
STRESS
RELAXATION
.
346
10.5.4.
CREEP
EXPERIMENT
.
348
10.5.5.
BOLTZMANN
SUPERPOSITION
PRINCIPLE
.
349
10.5.6.
DYNAMIC
MEASUREMENTS
.
351
10.5.7.
SHEAR
MODULI
OF
MELTS
.
354
10.6.
FAILURE
.
356
10.6.1.
FRACTURE
PHENOMENA
.
356
10.6.2.
THEORETICAL
FRACTURE
STRENGTHS
.
357
XX
CONTENTS
10.6.3.
FAILURE
STRENGTHS
.
358
10.6.4.
FRACTURE
STRENGTHS
OF
BRITTLE
MATERIALS
.
359
10.6.5.
FRACTURE
STRENGTH
OF
DUCTILE
POLYMERS
.
362
10.6.6.
IMPACT
STRENGTHS
.
363
10.6.7.
STRESS
CRAZING
.
365
10.7.
SURFACE
PROPERTIES
.
366
10.7.1.
SURFACE
TENSION
.
366
10.7.2.
HARDNESS
.
367
10.7.3.
FRICTION
.
367
10.7.4.
ABRASION
.
368
10.8.
ELECTRICAL
PROPERTIES
.
369
10.8.1.
INTRODUCTION
.
369
10.8.2.
RELATIVE
PERMITTIVITY
.
369
10.8.3.
RESISTIVITIES
.
370
10.8.4.
DISSIPATION
FACTORS
.
371
10.8.5.
ELECTROSTATIC
CHARGING .
373
10.8.6.
ELECTRICALLY
CONDUCTING
POLYMERS
.
373
10.9.
OPTICAL
PROPERTIES
.
375
10.9.1.
REFRACTIVE
INDEX
.
375
10.9.2.
LIGHT
TRANSMISSION
AND
GLOSS
.
376
TECHNOLOGY
11.
POLYMER
AUXILIARIES
.
379
11.1.
POLYMER
SYSTEMS
.
379
11.2.
FORMULATION
.
380
11.3.
STABILIZERS
.
381
11.3.1.
ANTIOXIDANTS
.
381
11.3.2.
LIGHT
STABILIZERS
.
383
11.3.3.
HEAT
STABILIZERS
.
384
11.3.4.
FLAME
RETARDANTS
.
384
11.4.
COLORANTS
.
385
11.5.
FILLERS
.
385
11.6.
EMIGRATION
OF
AUXILIARIES
.
386
12.
ELASTOMERS
.
388
12.1.
INTRODUCTION
.
388
12.2.
PROCESSING
.
388
12.3
RUBBER
TYPES
.
389
12.4.
VULCANIZATION
.
390
CONTENTS
XXI
12.5.
PROPERTIES
.
391
12.6.
RECLAIMING
.
392
13.
FIBERS
.
394
13.1.
INTRODUCTION
.
394
13.2.
PRODUCTION
.
395
13.3.
FIBER
SPINNING
.
396
13.4.
TEXTILE
FIBERS
.
399
13.5.
INDUSTRIAL
FIBERS
.
402
13.6.
RECYCLING
.
403
14.
PLASTICS
.
404
14.1.
INTRODUCTION
.
404
14.2.
PROCESSING
.
405
14.2.1.
OVERVIEW
.
405
14.2.2.
PROCESSING
STEPS
.
406
14.2.3.
PROCESSING
OF
VISCOUS
MATERIALS
.
408
14.2.4.
PROCESSING
OF
VISCOELASTIC
MATERIALS
.
409
14.3.
THERMOPLASTICS
.
411
14.4.
THERMOSETS
.
414
14.5.
FILLED
AND
REINFORCED
PLASTICS
.
417
14.5.1.
MIXING
RULES
.
418
14.5.2.
MODULI
.
418
14.5.3.
INTERLAYERS
.
420
14.5.4.
STRENGTHS
AND
ELONGATIONS
.421
14.5.5.
THERMAL
PROPERTIES
.
423
14.6.
POLYMER BLENDS
.
425
14.6.1.
MECHANICAL
MIXING
.
426
14.6.2.
IN-SITU
POLYMERIZATIONS
.
427
14.6.3.
RUBBER-MODIFIED
THERMOPLASTICS
.
428
14.7.
DISPOSAL
.
430
14.7.1.
LANDFILLS
.
431
14.7.2.
BIOLOGICAL
DEGRADATION
.
431
14.7.3.
RECYCLING
.
432
15.
APPENDIX
.
436
15.1.
PHYSICAL
QUANTITIES
AND
UNITS
.
436
TABLE
15-1
NAMES
AND
SYMBOLS
FOR
PHYSICAL
QUANTITIES
.
436
XXII
CONTENTS
TABLE
15-2
IMPORTANT
SI
DERIVED
UNITS
.
437
TABLE
15-3
SI
PREFIXES
.
437
TABLE
15-4
OLDER
NON-SI
UNITS
.
438
TABLE
15-5
FUNDAMENTAL
CONSTANTS
.
439
TABLE
15-6
CONVERSION
OF
OUT-DATED
AND
ANGLO-SAXON
UNITS
.
439
15.2.
CONCENTRATIONS
.
444
15.3.
RATIOS
OF
PHYSICAL
QUANTITIES
.
444
15.4.
ABBREVIATIONS
OF
PLASTICS,
FIBERS,
ELASTOMERS,
ETC
.
445
15.5.
GENERIC
AND
TRADE
NAMES
OF
FIBERS
AND
PLASTICS
.
447
16.
INDEX
.
449 |
| any_adam_object | 1 |
| author | Elias, Hans-Georg 1928- |
| author_GND | (DE-588)128433426 |
| author_facet | Elias, Hans-Georg 1928- |
| author_role | aut |
| author_sort | Elias, Hans-Georg 1928- |
| author_variant | h g e hge |
| building | Verbundindex |
| bvnumber | BV011117252 |
| callnumber-first | Q - Science |
| callnumber-label | QD381 |
| callnumber-raw | QD381 |
| callnumber-search | QD381 |
| callnumber-sort | QD 3381 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VE 8000 VK 8000 |
| classification_tum | CHE 700f WER 550f |
| ctrlnum | (OCoLC)845317586 (DE-599)BVBBV011117252 |
| dewey-full | 547.7 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.7 |
| dewey-search | 547.7 |
| dewey-sort | 3547.7 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie Werkstoffwissenschaften |
| edition | 1. ed. |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>00000nam a2200000 c 4500</leader><controlfield tag="001">BV011117252</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20100423</controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">961209s1997 gw d||| |||| 00||| eng d</controlfield><datafield tag="016" ind1="7" ind2=" "><subfield code="a">948942738</subfield><subfield code="2">DE-101</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">3527287906</subfield><subfield code="9">3-527-28790-6</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)845317586</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV011117252</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="044" ind1=" " ind2=" "><subfield code="a">gw</subfield><subfield code="c">DE</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-384</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-29T</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-91G</subfield><subfield code="a">DE-898</subfield><subfield code="a">DE-1051</subfield><subfield code="a">DE-634</subfield><subfield code="a">DE-83</subfield><subfield code="a">DE-11</subfield><subfield code="a">DE-525</subfield><subfield code="a">DE-188</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QD381</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">547.7</subfield><subfield code="2">21</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VE 8000</subfield><subfield code="0">(DE-625)147145:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VK 8000</subfield><subfield code="0">(DE-625)147532:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 700f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">WER 550f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Elias, Hans-Georg</subfield><subfield code="d">1928-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)128433426</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">An introduction to polymer science</subfield><subfield code="c">Hans-Georg Elias</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">1. ed.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Weinheim [u.a.]</subfield><subfield code="b">VCH</subfield><subfield code="c">1997</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XXII, 470 S.</subfield><subfield code="b">graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Biopolymeren</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Copolymeren</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Fysische eigenschappen</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Polimeros (quimica)</subfield><subfield code="2">larpcal</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Polymeren</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polymères</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Thermodynamica</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Vloeibare kristallen</subfield><subfield code="2">gtt</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polymers</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Polymere</subfield><subfield code="0">(DE-588)4046699-1</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="8">1\p</subfield><subfield code="0">(DE-588)4123623-3</subfield><subfield code="a">Lehrbuch</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Polymere</subfield><subfield code="0">(DE-588)4046699-1</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007449782&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="883" ind1="1" ind2=" "><subfield code="8">1\p</subfield><subfield code="a">cgwrk</subfield><subfield code="d">20201028</subfield><subfield code="q">DE-101</subfield><subfield code="u">https://d-nb.info/provenance/plan#cgwrk</subfield></datafield><datafield tag="943" ind1="1" ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-007449782</subfield></datafield></record></collection> |
| genre | 1\p (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV011117252 |
| illustrated | Illustrated |
| indexdate | 2024-09-10T00:54:03Z |
| institution | BVB |
| isbn | 3527287906 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007449782 |
| oclc_num | 845317586 |
| open_access_boolean | |
| owner | DE-384 DE-703 DE-29T DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-898 DE-BY-UBR DE-1051 DE-634 DE-83 DE-11 DE-525 DE-188 |
| owner_facet | DE-384 DE-703 DE-29T DE-19 DE-BY-UBM DE-91G DE-BY-TUM DE-898 DE-BY-UBR DE-1051 DE-634 DE-83 DE-11 DE-525 DE-188 |
| physical | XXII, 470 S. graph. Darst. |
| publishDate | 1997 |
| publishDateSearch | 1997 |
| publishDateSort | 1997 |
| publisher | VCH |
| record_format | marc |
| spelling | Elias, Hans-Georg 1928- Verfasser (DE-588)128433426 aut An introduction to polymer science Hans-Georg Elias 1. ed. Weinheim [u.a.] VCH 1997 XXII, 470 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Biopolymeren gtt Copolymeren gtt Fysische eigenschappen gtt Polimeros (quimica) larpcal Polymeren gtt Polymères Thermodynamica gtt Vloeibare kristallen gtt Polymers Polymere (DE-588)4046699-1 gnd rswk-swf 1\p (DE-588)4123623-3 Lehrbuch gnd-content Polymere (DE-588)4046699-1 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007449782&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Elias, Hans-Georg 1928- An introduction to polymer science Biopolymeren gtt Copolymeren gtt Fysische eigenschappen gtt Polimeros (quimica) larpcal Polymeren gtt Polymères Thermodynamica gtt Vloeibare kristallen gtt Polymers Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4123623-3 |
| title | An introduction to polymer science |
| title_auth | An introduction to polymer science |
| title_exact_search | An introduction to polymer science |
| title_full | An introduction to polymer science Hans-Georg Elias |
| title_fullStr | An introduction to polymer science Hans-Georg Elias |
| title_full_unstemmed | An introduction to polymer science Hans-Georg Elias |
| title_short | An introduction to polymer science |
| title_sort | an introduction to polymer science |
| topic | Biopolymeren gtt Copolymeren gtt Fysische eigenschappen gtt Polimeros (quimica) larpcal Polymeren gtt Polymères Thermodynamica gtt Vloeibare kristallen gtt Polymers Polymere (DE-588)4046699-1 gnd |
| topic_facet | Biopolymeren Copolymeren Fysische eigenschappen Polimeros (quimica) Polymeren Polymères Thermodynamica Vloeibare kristallen Polymers Polymere Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007449782&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT eliashansgeorg anintroductiontopolymerscience |