Corrosion and electrochemistry of zinc:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Plenum Press
1996
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XXI, 474 S. Ill., graph. Darst. |
| ISBN: | 0306453347 |
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| 100 | 1 | |a Zhang, Xiaoge Gregory |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Corrosion and electrochemistry of zinc |c Xiaoge Gregory Zhang |
| 264 | 1 | |a New York [u.a.] |b Plenum Press |c 1996 | |
| 300 | |a XXI, 474 S. |b Ill., graph. Darst. | ||
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| 650 | 4 | |a Zinc |x Corrosion | |
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| adam_text | IMAGE 1
CONTENTS
LIST OF SYMBOLS XIX
CHAPTER 1. PROPERTIES, PRODUCTS, AND PROCESSES
1.1. INTRODUCTION 1
1.2. BASIC PROPERTIES 1
1.2.1. PHYSICAL PROPERTIES 1
1.2.2. MECHANICAL PROPERTIES 2
1.2.3. ALLOYING PROPERTIES 3
1.3. MAIN PRODUCTS AND APPLICATIONS 3
1.3.1. ZINC COATINGS 3
1.3.2. CAST PRODUCTS 7
1.3.3. ROLLED ZINC 7
1.3.4. ZINC DUST AND POWDER 7
1.4. COATING PROCESSES 7
1.4.1. HOT-DIP GALVANIZING 7
1.4.2. ELECTROPLATING 13
1.3. PHOSPHATING 15
1.4. CHROMATING 16
CHAPTER 2. ELECTROCHEMICAL THERMODYNAMICS AND KINETICS
2.1. INTRODUCTION 19
2.2. THERMODYNAMIC STABILITY 19
2.3. IONIC PROPERTIES 25
2.4. DOUBLE-LAYER PROPERTIES 27
2.5. KINETICS OF ELEMENTAL REACTIONS 29
2.5.1. DISSOLUTION 29
2.5.2. DEPOSITION 36
2.5.3. HYDROGEN EVOLUTION 39
2.5.4. OXYGEN REDUCTION 48
IMAGE 2
2.6. CORROSION PROCESSES 54
2.6.1. GENERAL CONSIDERATIONS 54
2.6.2. IMPEDANCE OF CORRODING ELECTRODES 54
CHAPTER 3. PASSIVATION AND SURFACE FILM FORMATION
3.1. INTRODUCTION 65
3.2. CHARACTERISTICS AND CONDITIONS 65
3.3. ALKALINE SOLUTIONS 68
3.3.1. I-V CURVES 68
3.3.2. PASSIVATION TIME 70
3.3.3. CHARACTERISTICS 73
3.3.4. MECHANISMS OF FORMATION OF PASSIVE FILMS 75
3.4. OTHER SOLUTIONS 77
3.4.1. SLIGHTLY ALKALINE AND CARBONATE SOLUTIONS 77
3.4.2. PHOSPHATE SOLUTIONS 80
3.4.3. MISCELLANEOUS SOLUTIONS 84
3.5. ANODIZATION 85
3.6. STABILITY OF PASSIVATION 87
3.6.1. TYPE OF PASSIVATION 87
3.6.2. PASSIVATION BREAKDOWN 89
CHAPTER 4. ELECTROCHEMISTRY OF ZINC OXIDE
4.1. INTRODUCTION 93
4.2. BASIC PROPERTIES 93
4.2.1. PHYSICAL PROPERTIES 93
4.2.2. ELECTRONIC PROPERTIES 95
4.3. SEMICONDUCTOR ELECTROCHEMICAL BEHAVIOR 97
4.3.1. BASIC THEORIES 97
4.3.2. FLATBAND POTENTIAL 100
4.3.3. BAND STRUCTURE 103
4.3.4. ELECTRODE KINETICS IN THE DARK 105
4.3.5. PHOTOELECTROCHEMICAL KINETICS 109
4.3.6. ELECTROLUMINESCENCE 114
4.4. THIN ZNO FILMS 115
4.5. STABILITY 119
4.5.1. CONDITIONS OF STABILITY AND DECOMPOSITION REACTIONS 119
4.5.2. RATE OF DECOMPOSITION 121
CHAPTER 5. CORROSION POTENTIAL AND CORROSION CURRENT
5.1. INTRODUCTION 125
5.2. RELATION BETWEEN CORROSION POTENTIAL AND CORROSION CURRENT 125
5.2.1. POLARIZATION RESISTANCE AND CORROSION CURRENT 127
5.2.2. CONVERSION FACTORS 129
IMAGE 3
5.3. CORROSION POTENTIAL AND REACTION KINETICS 130
5.4. E CORR AND I CORR UNDER VARIOUS CONDITIONS . 133
5.4.1. EFFECT OF ZINC IONS 133
5.4.2. EFFECT OF ANIONS AND CATIONS 135
5.4.3. EFFECT OF PH 137
5.4.4. EFFECT OF TEMPERATURE 140
5.4.5. EFFECT OF AERATION AND CONVECTION 141
5.4.6. EFFECT OF SURFACE CONDITION 143
5.5. ZINC ALLOYS 144
5.6. EFFECT OF TIME 149
5.7. CORRELATION BETWEEN CORROSION CURRENT AND WEIGHT LOSS RATE 153
CHAPTER 6. CORROSION PRODUCTS
6.1. INTRODUCTION 157
6.2. IN ATMOSPHERIC ENVIRONMENTS 158
6.2.1. COMPOSITION AND STRUCTURE 158
6.2.2. QUANTITY AND MORPHOLOGY 163
6.2.3. FORMATION PROCESSES 165
6.3. IN WATERS 168
6.3.1. FRESH WATERS 168
6.3.2. SEAWATER 170
6.4. IN SOLUTIONS 171
6.4.1. EFFECT OF PH 171
6.4.2. FORMATION PROCESSES 173
6.4.3. ZINC ALLOYS 176
6.5. IN OTHER ENVIRONMENTS 176
6.6. EFFECT OF CORROSION PRODUCTS ON ZINC CORROSION 178
CHAPTER 7. CORROSION FORMS
7.1. INTRODUCTION 183
7.2. GALVANIC CORROSION 183
7.2.1. INTRODUCTION 183
7.2.2. THEORETICAL ASPECTS 185
7.2.3. PRACTICAL FACTORS 196
7.2.4. POLARITY REVERSAL 203
7.2.5. GALVANIC CORROSION IN NATURAL ENVIRONMENTS 208
7.2.6. GALVANIC PROTECTION OF STEEL BY ZINC 213
7.3. PITTING CORROSION 217
7.3.1. INTRODUCTION 217
7.3.2. OCCURRENCE OF PITTING 217
7.3.3. PITTING POTENTIAL 221
7.3.4. MORPHOLOGY 224
7.3.5. MECHANISMS 225
IMAGE 4
7.4. INTERGRANULAR CORROSION 227
7.4.1. INTRODUCTION 227
7.4.2. OCCURRENCE 227
7.4.3. METALLURGICAL EFFECTS 229
7.4.4. EFFECT OF ENVIRONMENTAL FACTORS 232
7.4.5. EFFECT ON MECHANICAL PROPERTIES 234
7.4.6. MECHANISMS 235
7.5. WET STORAGE STAIN 236
7.6. HYDROGEN EMBRITTLEMENT AND CORROSION CRACKING 238
CHAPTER 8. ATMOSPHERIC CORROSION
8.1. INTRODUCTION 241
8.2. ATMOSPHERIC FACTORS 241
8.2.1. TYPE OF WETTING 241
8.2.2. AIR POLLUTANTS 243
8.3. CORROSION IN OUTDOOR ENVIRONMENTS 245
8.3.1. TYPICAL CORROSION RATES 245
8.3.2. EFFECT OF TIME OF WETNESS 248
8.3.3. EFFECT OF POLLUTANTS . 249
8.3.4. EFFECT OF ELEVATION AND DISTANCE FROM SEAWATER 252
8.3.5. EFFECT OF INITIAL WEATHER CONDITIONS 252
8.3.6. EFFECT OF CLIMATE 254
8.3.7. EFFECT OF SAMPLE CONFIGURATION 254
8.3.8. EFFECT OF SHELTERING 255
8.3.9. GALVANIZED STEEL 256
8.3.10. EFFECT OF ALLOYING 258
8.3.11. EFFECT OF SURFACE TREATMENT 260
8.3.12. EFFECT OF CORROSION PRODUCTS 261
8.3.13. FORMS OF CORROSION 261
8.3.14. HIGHWAY ENVIRONMENT 262
8.4. CORROSION IN INDOOR ENVIRONMENTS 264
8.5. CORROSION IN SIMULATED ENVIRONMENTS 266
8.5.1. HUMIDITY CHAMBER EXPOSURE 267
8.5.2. WATER AND SALT SPRAY 270
8.5.3. CYCLIC TEST 272
8.5.4. THIN-LAYER ELECTROLYTES 274
8.6. CORROSION MECHANISMS 278
CHAPTER 9. CORROSION IN WATERS AND AQUEOUS SOLUTIONS
9.1. INTRODUCTION 283
9.2. CHARACTERISTICS OF WATERS 283
9.2.1. FRESH WATERS 283
9.2.2. SEAWATER 284
9.3. CORROSION IN PURE WATER 286
9.4. CORROSION IN NATURAL WATERS 288
IMAGE 5
9.4.1. COLD FRESH WATER 288
9.4.2. HOT FRESH WATER 289
9.4.3. SEAWATER 291
9.5. CORROSION IN AQUEOUS SOLUTIONS 296
9.5.1. EFFECT OF DISSOLVED SPECIES 296
9.5.2. EFFECT OF PH 298
9.5.3. EFFECT OF IMMERSION CONDITIONS 301
9.5.4. EFFECT OF SURFACE TREATMENTS 302
9.5.5. EFFECT OF METALLURGICAL FACTORS 302
CHAPTER 10. CORROSION IN SOIL
10.1. INTRODUCTION 305
10.2. CHARACTERISTICS OF SOIL 305
10.3. CORROSION RATES 308
10.3.1. EFFECT OF SOIL FACTORS 308
10.3.2. GALVANIC CORROSION 312
10.4. ELECTROCHEMICAL MEASUREMENTS 312
CHAPTER 11. UNDER-PAINT CORROSION
11.1. INTRODUCTION 315
11.2. BASIC CHARACTERISTICS OF PAINT 315
11.2.1. COMPONENTS IN PAINT 316
11.2.2. BARRIER PROPERTIES OF PAINT 316
11.3. CORROSION TESTS 317
11.4. CORROSION BEHAVIOR 319
11.4.1. CHARACTERIZATION OF CORROSION 319
11.4.2. EFFECT OF COATING TYPE 321
11.4.3. EFFECT OF TEST CONDITIONS 325
11.4.4. EFFECT OF PAINT SYSTEM 328
11.4.5. GALVANIC ACTION 332
11.5. CORROSION MECHANISMS 333
CHAPTER 12. ZINC-RICH COATINGS
12.1. INTRODUCTION 337
12.2. COATING CHARACTERISTICS 337
12.3. PROTECTION MECHANISM 339
12.4. PERFORMANCE 341
12.4.1. EFFECT OF ZINC CONTENT 341
12.4.2. EFFECT OF ZINC PARTICLE SIZE 343
12.4.3. EFFECT OF BINDERS 344
12.4.4. EFFECT OF COATING THICKNESS 345
12.4.5. EFFECT OF ADDITIVES 345
12.4.6. EFFECT OF SURFACE CONDITION 347
12.4.7. OTHER FACTORS 348
IMAGE 6
CHAPTER 13. CORROSION IN CONCRETE
13.1. INTRODUCTION 351
13.2. CONCRETE ENVIRONMENT 352
13.2.1. FORMATION OF CONCRETE 352
13.2.2. CHARACTERISTICS 353
13.3. CORROSION OF STEEL REINFORCEMENT IN CONCRETE 358
13.3.1. EFFECT OF CORROSION 358
13.3.2. PROTECTION METHODS 359
13.3.3. GALVANIZED COATINGS 359
13.4. CORROSION OF GALVANIZED STEEL IN CONCRETE 360
13.4.1. TESTING METHODS 360
13.4.2. FIELD TEST RESULTS 360
13.4.3. RESULTS FROM SIMULATED TESTS 365
CHAPTER 14. CORROSION IN BATTERIES
14.1. INTRODUCTION 373
14.2. ZINC CELLS AND BATTERIES 373
14.2.1. LECLANCHE CELL 373
14.2.2. ZINC CHLORIDE CELL 375
14.2.3. ZINC ALKALINE CELL 375
14.2.4. ZINC-AIR BATTERY 376
14.2.5. ZINC-NICKEL BATTERY 377
14.3. CORROSION 377
14.3.1. EFFECT OF TESTING TIME 379
14.3.2. EFFECT OF ELECTROLYTE 379
14.3.3. EFFECT OF CHEMICAL AGENTS 382
14.3.4. ZINC ELECTRODE 385
14.3.5. OPERATING CONDITIONS 390
CHAPTER 15. CORROSION IN OTHER ENVIRONMENTS
15.1. INTRODUCTION 393
15.2. ORGANIC SOLVENTS 393
15.2.1. CLASSIFICATION 393
15.2.2. CORROSION 395
15.3. GASEOUS ENVIRONMENTS 399
15.4. ZINC ANODES 403
15.4.1. SACRIFICIAL ANODES 403
15.4.2. ANODES FOR IMPRESSED CURRENT CATHODIC PROTECTION 407
REFERENCES 409
INDEX 463
|
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| id | DE-604.BV011072894 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T18:03:33Z |
| institution | BVB |
| isbn | 0306453347 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007417173 |
| oclc_num | 247097047 |
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| owner_facet | DE-29T DE-91G DE-BY-TUM DE-703 DE-355 DE-BY-UBR |
| physical | XXI, 474 S. Ill., graph. Darst. |
| publishDate | 1996 |
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| publisher | Plenum Press |
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| spelling | Zhang, Xiaoge Gregory Verfasser aut Corrosion and electrochemistry of zinc Xiaoge Gregory Zhang New York [u.a.] Plenum Press 1996 XXI, 474 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Electrochemistry Zinc Corrosion Elektrochemie (DE-588)4014241-3 gnd rswk-swf Korrosion (DE-588)4032518-0 gnd rswk-swf Zink (DE-588)4137453-8 gnd rswk-swf Zink (DE-588)4137453-8 s Elektrochemie (DE-588)4014241-3 s DE-604 Korrosion (DE-588)4032518-0 s OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007417173&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Zhang, Xiaoge Gregory Corrosion and electrochemistry of zinc Electrochemistry Zinc Corrosion Elektrochemie (DE-588)4014241-3 gnd Korrosion (DE-588)4032518-0 gnd Zink (DE-588)4137453-8 gnd |
| subject_GND | (DE-588)4014241-3 (DE-588)4032518-0 (DE-588)4137453-8 |
| title | Corrosion and electrochemistry of zinc |
| title_auth | Corrosion and electrochemistry of zinc |
| title_exact_search | Corrosion and electrochemistry of zinc |
| title_full | Corrosion and electrochemistry of zinc Xiaoge Gregory Zhang |
| title_fullStr | Corrosion and electrochemistry of zinc Xiaoge Gregory Zhang |
| title_full_unstemmed | Corrosion and electrochemistry of zinc Xiaoge Gregory Zhang |
| title_short | Corrosion and electrochemistry of zinc |
| title_sort | corrosion and electrochemistry of zinc |
| topic | Electrochemistry Zinc Corrosion Elektrochemie (DE-588)4014241-3 gnd Korrosion (DE-588)4032518-0 gnd Zink (DE-588)4137453-8 gnd |
| topic_facet | Electrochemistry Zinc Corrosion Elektrochemie Korrosion Zink |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007417173&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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