Heavy metals in soils:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
London [u.a.]
Blackie Academic & Professional
1995
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIV, 368 S. Ill., graph. Darst. |
| ISBN: | 0751401986 |
Staff View
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Record in the Search Index
| _version_ | 1804124996187979776 |
|---|---|
| adam_text | Heavy Metals in Soils
Second edition
edited by
B J Alloway
Professor of Soil Science
The University of Reading
Reading
UK
ES
BLACKIE ACADEMIC amp; PROFESSIONAL
An Imprint of Chapman amp; Hall
London ■ Glasgow • Weinheim • New York ■ Tokyo • Melbourne ■ Madras
Contents
Section 1—General Principles 1
1 Introduction 3
B J ALLOWAY
References 9
2 Soil processes and the behaviour of heavy metals 11
B J ALLOWAY
2 1 Introduction to the soil 11
2 2 Key soil properties 11
221 Soil pH 12
222 Soil organic matter 13
223 Clay minerals 15
224 Oxides of iron, manganese and aluminium 16
225 Oxidation and reduction in soils 17
2 3 The adsorption of metal ions by soils and their constituents 18
231 Cation exchange 19
232 Specific adsorption 20’
233 Co-precipitation 20
234 Insoluble precipitates of heavy metals in soils 21
235 Organic complexation 22
236 Selectivity of adsorbents for different metals 22
237 Quantitative description of metal ion adsorption 23
238 Adsorption as surface complexation 24
239 Biomethylation of heavy metals 24
2 4 Soil-plant relationships of heavy metals 25
241 The soil-plant system 25
242 Plant uptake of metals 25
243 Foliar absorption 28
244 Translocation of metals within plants 28
245 Interactions between metals and other elements 29
246 The biological essentiality of trace metals 30
247 Sensitivity of plants to micronutrient deficiencies 32
248 Heavy metal toxicity in plants 32
249 Effects of heavy metals on the soil microbial biomass 34
References 35
3 The origin of heavy metals in soils 38
B J ALLOWAY
3 1 Geochemical origins of heavy metals 38
3 2 Pedogenesis and the translocation of heavy metals in soils 40
321 Pedogenesis 41
3 3 Sources of heavy metal contaminants in soils 42
331 Metalliferous mining and smelting 42
X HEAVY METALS IN SOILS
332 Agricultural and horticultural materials 44
333 Sewage sludges 45
334 Fossil fuel combustion 48
335 Metallurgical industries 49
336 Electronics 49
337 Chemical and other industrial sources 50
338 Waste disposal 50
339 Sports shooting 51
3 3 10 Warfare and military training 51
3 4 Heavy metals from atmospheric deposition 52
3 5 Heavy metal concentrations in agricultural soils 54
References 56
4 Methods of analysis for heavy metals in soils 58
A M URE
4 1 Introduction: types of analysis 58
4 2 Field sampling 59
4 3 Sample drying, storage and subsampling 60
4 4 Contamination 61
4 5 Reference materials 62
4 6 Methods for total analysis of solid samples 62
461 X-ray fluorescence spectrometry (XRF) 62
462 Instrumental neutron activation analysis (INAA) 64
463 Direct-current arc atomic emission spectrometry (DCAAES) 66
464 Total analysis using slurry samples 68
4 7 Acid dissolution for total analysis of solution samples 68
4 8 Fusion methods for total analysis by techniques that use solution samples 70
4 9 Pseudo-total analysis: strong acid digestion procedures 71
4 10 Atomic spectrometric methods for the analysis of solutions 73
4 10 1 Atomic absorption spectrometry (AAS) 73
4 10 2 Atomic emission spectrometry (AES) 81
4 10 3 Atomic mass spectrometry 86
4 11 Special methods in atomic spectrometry 86
4 11 1 Hydride generation methods 86
4 11 2 Atom trapping atomic spectrometry (ATAAS) 87
4 11 3 Pre-concentration and separation techniques for atomic
spectrometry 88
4 11 4 Cold vapour atomic absorption spectrometry (CVAAS) 89
4 12 The analysis of soil extracts 89
4 12 1 Soil extraction procedures 89
4 13 Speciation 91
4 14 Recent applications of atomic spectrometry 93
4 15 Concluding comments 94
References 94
Section 2—Individual elements 103
5 Arsenic 105
p o neill
5 1 Introduction 105
5 2 Geochemical occurrence 105
5 3 Origin of arsenic in soils 106
531 Soil parent materials 106
532 Agricultural materials 107
533 Atmospheric deposition 108
CONTENTS XI
534 Sewage sludges 108
535 Other sources of arsenic 109
5 4 Chemical behaviour in the soil 110
5 5 Soil-plant relationships 115
5 6 Polluted soils 117
5 7 Concluding comments 119
References 119
6 Cadmium 122
B J ALLOWAY
6 1 Introduction 122
6 2 Geochemical occurrence 123
6 3 Origin of cadmium in soils 123
631 Soil parent materials 123
632 Agricultural materials 126
633 Atmospheric deposition of cadmium 128
634 Sewage sludges 129
635 Other sources of cadmium 131
636 Summary of cadmium inputs into soils 131
6 4 The chemical behaviour of cadmium in soils 131
641 Speciation of cadmium in the soil solution 131
642 The adsorption of cadmium in soils 132
6 5 Soil-plant relationships 135
651 Soil factors affecting the uptake of cadmium by plants 136
652 Plant factors affecting the uptake of cadmium from soil 139
6 6 Cadmium-polluted soils 140
661 Contamination from metalliferous mining and smelting 140
662 Soil contamination from heavy applications of sewage sludge 142
663 Amelioration and rehabilitation of cadmium-contaminated soils 144
6 7 Concluding comments 146
References 147
7 Chromium and nickel 152
S P McGRATH
7 1 Introduction 152
711 Usage 152
712 Biological requirements 153
7 2 Geochemical occurrence 155
7 3 Origin of chromium in soils and parent materials 156
731 Nickel and chromium in soils and parent materials 156
732 Agricultural materials 157
733 Atmospheric deposition 158
734 Sewage sludges 160
735 Other sources of chromium and nickel 162
7 4 Chemical behaviour in the soil 164
7 5 Soil-plant relationships 168
7 6 Polluted soils 171
7 7 Soil protection against chromium and nickel 172
References 174
8 Copper 179
D E BAKER and J P SENFT
8 1 Introduction 179
8 2 Geochemical occurrence of copper 180
xii HEAVY METALS IN SOILS
8 3 Origin of copper in soils 182
831 Soil parent materials 182
832 Agricultural materials 184
833 Atmospheric deposition 184
834 Sewage sludges 186
8 4 Chemical behaviour of copper in the soil 187
841 Solubility of Cufjl) minerals and soil copper 188
842 Copper adsorption by soils 189
8 5 Soil-plant relationships 191
851 Copper in crop nutrition 191
852 Absorption and translocation of copper 194
8 6 Polluted soils 195
8 7 Copper in soil-plant-animal relationships 197
8 8 The Baker soil test for soil diagnostics 199
8 9 Concluding comments 202
References 202
9 Lead 206
B E DAVIES
9 1 Introduction 206
9 2 Chemistry and geochemistry of lead 206
921 Applied chemistry 206
922 Lead contents of rocks and soils 207
9 3 Sources of lead in soils 207
931 Lead derived from vehicle exhausts 208
932 General atmospheric additions to soil and vegetation 209
933 Lead in urban soils 210
934 Contamination from mining and smelting 211
935 Lead derived from agricultural materials 212
9 4 Lead in soil profiles 213
9 5 The chemical behaviour oflead in soils 214
951 Fate of lead and lead compounds entering the soil 214
952 Lead in soil fractions 215
953 Lead in the soil solution 216
9 6 Soil-plant relationships 217
961 Uptake oflead from soil and translocation to shoots 217
962 The problem of airborne lead and foliar deposition 218
963 Soil factors controlling lead uptake 218
9 7 Leading and soil microorganisms 219
9 8 Concluding comments 219
References 220
10 Manganese and cobalt 224
K A SMITH and J E PATERSON
10 1 Introduction 224
10 2 Geochemical occurrence 226
10 3 Origin of manganese and cobalt in soils 228
10 4 Manganese and cobalt chemistry affecting plant availability 230
10 5 Estimates of plant availability 240
10 5 1 Manganese 240
10 5 2 Cobalt 240
10 5 3 Assessment using isotopic exchange 240
10 6 Concluding comments 242
References 242
CONTENTS xiii
11 Mercury 245
E STEINNES
11 1 Introduction 245
11 1 1 Cunent uses of mercury 24 5
11 1 2 Release of mercury to the environment 245
11 1 3 Harmful effects of mercury 246
11 2 Geochemical occurrence 247
11 3 Origin of mercury in soils 248
11 3 1 Soil parent materials 248
11 3 2 Atmospheric deposition 249
11 3 3 Agricultural materials 250
11 3 4 Sewage sludge 250
11 4 Chemical behaviour of mercury in soil 251
11 4 1 Occurrence and stability of inorganic mercury species in soil 251
11 4 2 Volatilisation of mercury from soil 252
11 4 3 Leaching of mercury from soil 252
11 4 4 Retention of mercury in soil material 253
11 4 5 Methylation of mercury in soil 253
11 4 6 Concentration and distribution of mercury in soils 253
11 5 Mercury in the soil-plant system 256
11 6 Investigations of mercury-polluted soils 256
11 7 Global budgets of mercury 257
References 257
12 Selenium 260
R H NEAL
12 1 Introduction 260
12 2 Geochemical occurrence 261
12 3 Origin of selenium in soils 262
12 3 1 Soil parent materials 262
12 3 2 Agricultural materials 263
12 3 3 Atmospheric deposition 264
12 3 4 Sewage sludges 264
12 4 Chemical behaviour in soils 264
12 4 1 Speciation: Inorganic ions 264
12 4 2 Speciation: Organic ions 267
12 4 3 Adsorption 268
12 4 4 Biological transformations 271
12 4 5 Selenium in ground waters 272
12 4 6 Contrasting behaviour in marine waters and sediments 272
12 5 Soil-plant relationships 273
12 6 Polluted soils: case histories 276
12 6 1 California 276
12 6 2 China 279
12 7 Concluding comments 279
References 280
13 Zinc 284
L KIEKENS
13 1 Introduction 284
13 2 Geochemical occurrence of zinc 285
13 3 Origin of zinc in soils 285
13 3 1 Soil parent materials 285
13 3 2 Atmospheric fall-out 285
xiv HEAVY METALS IN SOILS
13 3 3 Agricultural use of sewage sludge
13 3 4 Agrochemicals
13 4 Chemical behaviour of zinc in soils
13 4 1 Zinc fractions in soils
13 4 2 Solubility of zinc in soils
13 4 3 Adsorption and desorption of zinc in soils
13 4 4 Influence of soil organic matter on the behaviour of zinc in soils
13 5 Soil-plant relationships
13 5 1 Factors affecting the availability of zinc in soils
13 5 2 Evaluation of zinc availability in soils
13 5 3 Plant factors affecting the uptake of zinc from soil
13 6 Zn polluted soils
13 6 1 Contamination from metalliferous mining and smelting
13 6 2 Soil pollution from heavy applications of sewage sludge
13 7 Concluding remarks
References
14 Other less abundant elements of potential environment
significance
N W LEPP, R EDWARDS and K C JONES
14 1 Antimony
References: Antimony
14 2 Gold
References: Gold
14 3 Molybdenum
References: Molybdenum
14 4 Silver
References: Silver
14 5 Thallium
References: Thallium
14 6 Tin
References: Tin
14 7 Uranium
References: Uranium
14:8 Vanadium
References: Vanadium
Appendices
Appendix 1: Chemical properties of the heavy metals
Appendix 2: Concentrations of heavy metals in soils and plants
Appendix 3: Maximum metal concentrations allowed in soils treated with
sewage sludge in different countries
Appendix 4: US Environmental Protection Agency Part 503 Regulations for sewage
sludge applied to land
Appendix 5: UK Department of the Environment ICRCL ‘trigger’ concentrations
for metals in contaminated land which is to be redeveloped for the uses specified
Appendix 6: Guide values and quality standards used in the Netherlands for assessing
soil contamination
Appendix 7: Comparison between the US Soil Taxonomy and the FAO/UNESCO
soil classification schemes
Appendix 8: Common and botanical names of cultivated plants
Appendix 9: Element concentrations in selected certified reference materials
Index
|
| any_adam_object | 1 |
| author_GND | (DE-588)171948807 |
| building | Verbundindex |
| bvnumber | BV010528425 |
| callnumber-first | S - Agriculture |
| callnumber-label | S592 |
| callnumber-raw | S592.6.H43 |
| callnumber-search | S592.6.H43 |
| callnumber-sort | S 3592.6 H43 |
| callnumber-subject | S - General Agriculture |
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| classification_tum | UMW 175f UMW 194f LAN 117f |
| ctrlnum | (OCoLC)33280157 (DE-599)BVBBV010528425 |
| dewey-full | 631.4/16 363.7396 |
| dewey-hundreds | 600 - Technology (Applied sciences) 300 - Social sciences |
| dewey-ones | 631 - Techniques, equipment & materials 363 - Other social problems and services |
| dewey-raw | 631.4/16 363.7396 |
| dewey-search | 631.4/16 363.7396 |
| dewey-sort | 3631.4 216 |
| dewey-tens | 630 - Agriculture and related technologies 360 - Social problems and services; associations |
| discipline | Allgemeines Agrarwissenschaft Soziologie Agrar-/Forst-/Ernährungs-/Haushaltswissenschaft / Gartenbau Umwelt Pflanzenbau Geographie |
| edition | 2. ed. |
| format | Book |
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| indexdate | 2024-07-09T17:54:32Z |
| institution | BVB |
| isbn | 0751401986 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-007017566 |
| oclc_num | 33280157 |
| open_access_boolean | |
| owner | DE-703 DE-19 DE-BY-UBM DE-M49 DE-BY-TUM DE-11 |
| owner_facet | DE-703 DE-19 DE-BY-UBM DE-M49 DE-BY-TUM DE-11 |
| physical | XIV, 368 S. Ill., graph. Darst. |
| publishDate | 1995 |
| publishDateSearch | 1995 |
| publishDateSort | 1995 |
| publisher | Blackie Academic & Professional |
| record_format | marc |
| spelling | Heavy metals in soils ed. by B. J. Alloway 2. ed. London [u.a.] Blackie Academic & Professional 1995 XIV, 368 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Bodemverontreiniging gtt Zware metalen gtt Umwelt Heavy metals Environmental aspects Plant-soil relationships Soil pollution Soils Heavy metal content Boden (DE-588)4007348-8 gnd rswk-swf Pflanzen (DE-588)4045539-7 gnd rswk-swf Bodenverschmutzung (DE-588)4206275-5 gnd rswk-swf Nachschlagewerk (DE-588)4041070-5 gnd rswk-swf Schwermetall (DE-588)4053963-5 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Schwermetall (DE-588)4053963-5 s Boden (DE-588)4007348-8 s Bodenverschmutzung (DE-588)4206275-5 s Nachschlagewerk (DE-588)4041070-5 s 1\p DE-604 Pflanzen (DE-588)4045539-7 s 2\p DE-604 Alloway, Brian J. 1944- Sonstige (DE-588)171948807 oth HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007017566&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Heavy metals in soils Bodemverontreiniging gtt Zware metalen gtt Umwelt Heavy metals Environmental aspects Plant-soil relationships Soil pollution Soils Heavy metal content Boden (DE-588)4007348-8 gnd Pflanzen (DE-588)4045539-7 gnd Bodenverschmutzung (DE-588)4206275-5 gnd Nachschlagewerk (DE-588)4041070-5 gnd Schwermetall (DE-588)4053963-5 gnd |
| subject_GND | (DE-588)4007348-8 (DE-588)4045539-7 (DE-588)4206275-5 (DE-588)4041070-5 (DE-588)4053963-5 (DE-588)4143413-4 |
| title | Heavy metals in soils |
| title_auth | Heavy metals in soils |
| title_exact_search | Heavy metals in soils |
| title_full | Heavy metals in soils ed. by B. J. Alloway |
| title_fullStr | Heavy metals in soils ed. by B. J. Alloway |
| title_full_unstemmed | Heavy metals in soils ed. by B. J. Alloway |
| title_short | Heavy metals in soils |
| title_sort | heavy metals in soils |
| topic | Bodemverontreiniging gtt Zware metalen gtt Umwelt Heavy metals Environmental aspects Plant-soil relationships Soil pollution Soils Heavy metal content Boden (DE-588)4007348-8 gnd Pflanzen (DE-588)4045539-7 gnd Bodenverschmutzung (DE-588)4206275-5 gnd Nachschlagewerk (DE-588)4041070-5 gnd Schwermetall (DE-588)4053963-5 gnd |
| topic_facet | Bodemverontreiniging Zware metalen Umwelt Heavy metals Environmental aspects Plant-soil relationships Soil pollution Soils Heavy metal content Boden Pflanzen Bodenverschmutzung Nachschlagewerk Schwermetall Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=007017566&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT allowaybrianj heavymetalsinsoils |