Photoinitiation, photopolymerization, and photocuring: fundamentals and applications
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
München [u.a.]
Hanser [u.a.]
1995
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 375 S. Ill., graph. Darst. |
| ISBN: | 3446170693 1569901465 |
Internformat
MARC
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Datensatz im Suchindex
| _version_ | 1804124365358366720 |
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| adam_text | JEAN-PIERRE FOUASSIER PHOTOINITIATION, PHOTOPOLYMERIZATION, AND
PHOTOCURING FUNDAMENTALS AND APPLICATIONS HANSER PUBLISHERS, MUNICH
VIENNA NEW YORK HANSER/GARDNER PUBLICATIONS, INC., CINCINNATI CONTENTS 1
INTRODUCTION 1 REFERENCES 7 2 BASIC PRINCIPLES IN PHOTOINITIATION
PROCESSES OF PHOTOINDUCED POLYMERIZATION REACTIONS 8 2-1
PHOTOPOLYMERIZATION REACTIONS 8 2-2 PHOTOINITIATORS AND PHOTOSENSITIZERS
11 2-3 PROPERTIES OF PHOTOINITIATORS 11 REFERENCES 15 3 CBEMISTRY,
EXCITED STATES, AND REACTIVITY OF RADICAL PHOTOINITIATORS 17 3-1
INTRODUCTION TO EXCITED-STATE PROCESSES 17 3-2 CLEAVABLE PHOTOINITIATORS
20 3-2-1 A-CLEAVAGE PROCESS 20 3-2-1-1 BENZOIN ETHERS [14-17] 23 3-2-1-2
HYDROXY ALKYL PHENYL ACETOPHENONES [18] 23 3-2-1-3 DIALKOXY
ACETOPHENONES [21] 24 3-2-1-4 PHOSPHINE OXIDE DERIVATIVES [23] 24
3-2-1-5 AMINO KETONES [26] 25 3-2-1 -6 LASER SPECTROSCOPY OF
PHOTOINITIATORS 28 3-2-2 SS-CLEAVAGE PROCESS 29 3-2-3 MISCELLANEOUS
PRIMARY-CLEAVAGE PROCESSES 29 3-3 PHOTOINITIATORS INVOLVING
H-ABSTRACTION OR ELECTRON TRANSFER REACTIONS 32 3-4 OTHER MECHANISMS OF
INITIATION 35 3-4-1 NORRISH II PHOTOSCISSION PROCESS 35 3-4-2 CHARGE
TRANSFER COMPLEXES 35 3-4-3 MISCELLANEOUS PHOTOINITIATORS 37 3-5
CLEAVAGE REACTIONS, ELECTRON TRANSFER, AND MONOMER QUENCHING .... 41
3-5-1 MONOMER QUENCHING 41 3-5-2 AMINE QUENCHING 45 3-5-3 COMPETITION
BETWEEN CLEAVAGE AND QUENCHING BY AMINES AND MONOMERS 48 3-5-4 SOLVENT
EFFECTS 50 3-6 STRUCTURE-PROPERTY RELATIONSHIPS 51 3-6-1 ROLE OF THE
SKELETON 51 3-6-2 ROLE OF THE SUBSTITUTION 51 3-6-3 ROLE OF THE AMINE 53
3-6-4 ROLE OF THE H DONOR 56 CONTENTS IX 3-6-5 ROLE OF THE INITIATING
RADICAL 57 3-6-6 ROLE OF THE ENVIRONMENT 58 3-6-7 PHOTOCHEMISTRY IN
UPPER EXCITED STATES 65 3-6-8 OTHER FACTORS 65 3-7 HOW TO DESIGN
PHOTOINITIATORS EXHIBITING SPECIFIC PROPERTIES 66 3-7-1 ENHANCED AND
REDSHIFTED ABSORPTION 66 3-7-2 WATER SOLUBILITY AND HYDROPHILICITY 68
3-7-3 ACID-RELEASING SYSTEMS 71 3-7-4 HYDROPHOBIE AND OLIGOMERIC OR
POLYMERIE PHOTOINITIATORS ... 71 3-7-5 COPOLYMERIZABLE PHOTOINITIATORS
73 3-8 PHOTOSENSITIZED DEEOMPOSITION OF RADICAL PHOTOINITIATORS 74 3-8-1
PROCESSES INVOLVED 74 3-8-2 PHOTOINDUCED BOND CLEAVAGE VIA ELECTRON
TRANSFER REACTION 77 3-8-3 SENSITIZED REACTIONS IN PHOTOINITIATING
SYSTEMS 78 3-8-4 PHOTOSENSITIZED CLEAVAGE AND PHOTOINDUCED ELECTRON
TRANSFER IN COMBINATIONS OF PHOTOINITIATORS 80 3-9 VISIBLE LIGHT
PHOTOSENSITIVE SYSTEMS 84 3-10 MULTICOMPONENT SYSTEMS 90 3-10-1
ONE-COMPONENT SYSTEMS (THE PHOTOINITIATOR) 90 3-10-2 TWO-COMPONENT
SYSTEMS 90 3-10-3 THREE-COMPONENT SYSTEMS 91 3-10-4 MECHANISM INVOLVED
IN THREE-COMPONENT SYSTEMS 92 REFERENCES 93 4 CHEMISTRY, EXCITED-STATE
PROCESSES, AND REACTIVITY OF CATIONIC PHOTOINITIATORS 102 4-1 DIAZONIUM
SALTS 102 4-2 ONIUM SALTS 103 4-2-1 CHEMISTRY OF ONIUM SALTS 103 4-2-1-1
IODONIUM AND SULFONIUM SALTS 103 4-2-1-2 OTHER ONIUM SALTS 109 4-2-1-3
RECENT DEVELOPMENTS 112 4-2-2 DIRECT PHOTOCHEMICAL DEEOMPOSITION OF
ONIUM SALTS 115 4-2-2-1 GENERAL MECHANISM OF DEEOMPOSITION 115 4-2-2-2
ROLE OF VARIOUS FACTORS 119 4-2-2-3 OTHER ONIUM SALTS 120 4-2-2-4 DIRECT
PHOTOINITIATION OF THE POLYMERIZATION 122 4-2-3 SENSITIZED DEEOMPOSITION
OF ONIUM SALTS 123 4-2-3-1 SENSITIZATION BY HYDROCARBONS 124 4-2-3-2
ELECTRON TRANSFER WITH DYES 127 4-2-3-3 ELECTRON TRANSFER WITH METAL
SALTS 127 4-2-3-4 ENERGY TRANSFER WITH KETONES 128 4-2-3-5 ELECTRON
TRANSFER WITH KETONES 129 4-2-3-6 ELECTRON TRANSFER WITH RADICALS 132 X
CONTENTS 4-2-3-7 CATIONIC PHOTOINITIATORS AS SOURCES OR QUENCHERS OF
RADICALS 134 4-2-3-8 PHOTOSENSITIZED INITIATION OF THE CATIONIC
POLYMERIZATION REACTION 135 4-3 ORGANOMETALLIC DERIVATIVES 138
REFERENCES 14 1 5 PHOTOINITIATED POLYMERIZATION REACTIONS 145 5-1
COMPONENTS OF A TYPICAL PHOTOPOLYMERIZABLE FILM 145 5-2 MONOMERS AND
OLIGOMERS FOR POLYMERIZATION REACTIONS 147 5-2-1 RADICAL MONOMERS AND
OLIGOMERS: MONO- AND MULTIFUNCTIONAL ACRYLATES 150 5-2-2 UNSATURATED
POLYESTER RESINS 151 5-2-3 THIOL-ENE SYSTEMS 152 5-2-4 CATIONIC MONOMERS
157 5-2-5 PARTICULAR PHOTOPOLYMERIZABLE SYSTEMS 160 5-2-5-1 EXPANDING
MONOMERS 160 5-2-5-2 LIQUID CRYSTALLINE MONOMERS 161 5-2-5-3
MISCELLANEOUS MONOMERS AND METHODS OF POLYMERIZATION 162 5-2-5-4 ANIONIC
PHOTOPOLYMERIZATION 162 5-3 MONITORING THE PHOTOPOLYMERIZATION REACTION
164 5-3-1 SPECTROSCOPIC METHODS 164 5-3-2 OTHER METHODS 167 5-3-3
METHODS FOR ANALYZING THE PHYSICAL AND MECHANICAL PROPERTIES 172 5-4
PARTICULAR FEATURES OF A RADICAL PHOTOPOLYMERIZATION REACTION 174 5-4-1
EFFECT OF THE PHOTOINITIATING SYSTEM 174 5-4-1-1 REACTIVITY 174 5-4-1-2
CONCENTRATION 177 5-4-1 -3 IMPROVEMENT OF SPECIFIC PROPERTIES 179 5-4-1
-4 EXCITED-STATE BEHAVIOR IN BULK MEDIA 179 5-4-1-5 OTHEREFFECTS 181
5-4-2 EFFECT OF FILM THICKNESS 185 5-4-3 EFFECT OF THE LIGHT SOURCE 187
5-4-4 POLYMERIZATION PROFILE AND CHARACTERISTICS 190 5-4-5 ROLE OF THE
MONOMER AND THE OLIGOMER 193 5-4-5-1 ROLE OF THE MONOMER IN THE
PHOTOPOLYMERIZATION OF POLYURETHANE ACRYLATES OR EPOXY ACRYLATES 194
5-4-5-2 SUPERFICIAL HARDNESS 196 5-4-5-3 SOLUBILITY 198 5-4-5-4 THERMAL
RESISTANCE 199 5-4-5-5 PHOTOCHEMICAL STABILITY 199 5-4-5-6 FORMATION OF
SEMI-INTERPENETRATING NETWORKS 199 5-4-6 PROBLEM OF OXYGEN 199 CONTENTS
XI 5-5 CURING OF PIGMENTED SYSTEMS 200 5-5-1 REDSHIFTED ABSORBING
MOLECULES 202 5-5-2 COMBINATION OF PHOTOINITIATORS 203 5-5-2-1 BASIC
SYSTEMS INVOLVING TWO COMPONENTS 204 5-5-2-2 MULTICOMPONENT SYSTEMS 211
5-5-2-3 PHOTOCHEMICAL EFFECTS OF THE PIGMENT 211 5-6 SYNERGISTIC EFFECTS
212 5-7 KINETIC ASPECTS OF THE CATIONIC PHOTOPOLYMERIZATION OF EPOXIDES
.... 213 5-8 CHARACTERISTICS OF THE LASER-INDUCED POLYMERIZATION
REACTION 215 5-8-1 MATCHING OF THE PHOTOINITIATING SYSTEM ABSORPTION 216
5-8-2 KINETICS 217 5-8-3 REACTIVITY OF LASER-SENSITIVE INITIATING
SYSTEMS 218 5-9 PHOTOSTABILIZATION OF CURED COATINGS 220 5-9-1 MECHANISM
OF PHOTOOXIDATION OF UV-CURED POLYMER NETWORKS 221 5-9-2 PHOTOAGING
TESTS 225 5 -9-3 PHOTOSTABILIZERS AND PHOTOSTABILIZATION MECHANISMS 227
5-9-3-1 MECHANISMS 227 5-9-3-2 PERFORMANCE OF LIGHT STABILIZERS 233
5-9-3-3 EFFECT ON THE PHOTOPOLYMERIZATION PROFILE 234 5-9-3-4
PHOTOINITIATOR * LIGHT STABILIZER INTERACTION IN FILM MATRIX 235
REFERENCES 237 6 SOME PRACTICAL ASPECTS IN PHOTOCURING 246 6-1 BENEFIT S
OF LIGHT-CURABLE COATINGS 246 6-2 EQUIPMENT IN LIGHT-CURING TECHNOLOGIES
247 6-2-1 LIGHT SOURCES 247 6-2-1-1 CONVENTIONAL LIGHT SOURCES 247
6-2-1-2 LASERS 251 6-2-1-3 OTHERSOURCES 253 6-2-2 EXAMPLE OF UV DRYING
EQUIPMENT FOR THE CURING OF COATINGS 255 6-3 CHEMISTRY IN UV CURING 259
6-3-1 ACYLATE-BASED FORMULATIONS 259 6-3-1-1 CHEMISTRY VS. CURED-FILM
PROPERTIES 259 6-3-1-2 CHEMISTRY VS. ADHESION 260 6-3-2 EPOXIDE-BASED
FORMULATIONS 272 6-3-3 WATER-BASED UV-CURABLE SYSTEMS 273 6-3-4 ACID
CURING OF THERMOSETTING COATINGS 274 6-3-5 THIOL-ENE COATINGS 276 6-3-6
CURING OF MODIFIED SILICONE MONOMERS 276 6-3-7 PRINCIPLES OF HYBRID AND
DUAL CURE 278 6-3-7-1 HYBRIDCURE 278 6-3-7-2 DUAL CURE 283 XII CONTENTS
6-3-8 CLEAR COATINGS 285 6-3-9 PIGMENTED COATINGS 285 6-3-9-1 DIFFERENT
CATEGORIES OF PIGMENTS 286 6-3-9-2 ROLE OF THE PIGMENT 286 6-3-9-3 SOME
LUUSTRATIONS OF THE EFFECTS OF PIGMENTS 289 6-4 APPLICATIONS 297 6-4-1
INKS, COATINGS, VARNISHES, PAINTS, AND ADHESIVES 297 6-4-2 PHOTOPOLYMER
PRINTING PLATES 309 6-4-3 MICROELECTRONICS 311 6-4-4 OPTICS 314 6-4-5
DENTAL AND MEDICAL APPLICATIONS 314 6-4-6 LASER-INDUCED POLYMERIZATION
318 6-4-6-1 IMAGING SCIENCE 318 6-4-6-2 THREE-DIMENSIONAL MODELING 326
6-4-7 COMPOSITES 328 6-4-8 MISCELLANEOUS 329 6-5 SAFETY AND MARKET 330
REFERENCES 343 7 LATEST DEVELOPMENTS AND TRENDS 350 REFERENCES 360 INDEX
367
|
| any_adam_object | 1 |
| author | Fouassier, Jean-Pierre |
| author_facet | Fouassier, Jean-Pierre |
| author_role | aut |
| author_sort | Fouassier, Jean-Pierre |
| author_variant | j p f jpf |
| building | Verbundindex |
| bvnumber | BV009990251 |
| classification_rvk | UV 9555 ZM 5250 |
| classification_tum | CHE 731f WER 659f |
| ctrlnum | (OCoLC)844984273 (DE-599)BVBBV009990251 |
| dewey-full | 660/.295 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660/.295 |
| dewey-search | 660/.295 |
| dewey-sort | 3660 3295 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Physik Chemie Werkstoffwissenschaften Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV009990251 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:44:30Z |
| institution | BVB |
| isbn | 3446170693 1569901465 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006621704 |
| oclc_num | 844984273 |
| open_access_boolean | |
| owner | DE-703 DE-12 DE-91G DE-BY-TUM DE-210 DE-92 DE-634 DE-83 |
| owner_facet | DE-703 DE-12 DE-91G DE-BY-TUM DE-210 DE-92 DE-634 DE-83 |
| physical | XII, 375 S. Ill., graph. Darst. |
| publishDate | 1995 |
| publishDateSearch | 1995 |
| publishDateSort | 1995 |
| publisher | Hanser [u.a.] |
| record_format | marc |
| spelling | Fouassier, Jean-Pierre Verfasser aut Photoinitiation, photopolymerization, and photocuring fundamentals and applications Jean-Pierre Fouassier München [u.a.] Hanser [u.a.] 1995 XII, 375 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Strahlenhärten (DE-588)4373773-0 gnd rswk-swf Härten (DE-588)4139793-9 gnd rswk-swf Fotochemische Reaktion (DE-588)4138378-3 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Photopolymerisation (DE-588)4174541-3 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Strahlenhärten (DE-588)4373773-0 s DE-604 Kunststoff (DE-588)4033676-1 s Härten (DE-588)4139793-9 s Polymere (DE-588)4046699-1 s Fotochemische Reaktion (DE-588)4138378-3 s Photopolymerisation (DE-588)4174541-3 s GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006621704&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Fouassier, Jean-Pierre Photoinitiation, photopolymerization, and photocuring fundamentals and applications Strahlenhärten (DE-588)4373773-0 gnd Härten (DE-588)4139793-9 gnd Fotochemische Reaktion (DE-588)4138378-3 gnd Kunststoff (DE-588)4033676-1 gnd Polymere (DE-588)4046699-1 gnd Photopolymerisation (DE-588)4174541-3 gnd |
| subject_GND | (DE-588)4373773-0 (DE-588)4139793-9 (DE-588)4138378-3 (DE-588)4033676-1 (DE-588)4046699-1 (DE-588)4174541-3 (DE-588)4143413-4 |
| title | Photoinitiation, photopolymerization, and photocuring fundamentals and applications |
| title_auth | Photoinitiation, photopolymerization, and photocuring fundamentals and applications |
| title_exact_search | Photoinitiation, photopolymerization, and photocuring fundamentals and applications |
| title_full | Photoinitiation, photopolymerization, and photocuring fundamentals and applications Jean-Pierre Fouassier |
| title_fullStr | Photoinitiation, photopolymerization, and photocuring fundamentals and applications Jean-Pierre Fouassier |
| title_full_unstemmed | Photoinitiation, photopolymerization, and photocuring fundamentals and applications Jean-Pierre Fouassier |
| title_short | Photoinitiation, photopolymerization, and photocuring |
| title_sort | photoinitiation photopolymerization and photocuring fundamentals and applications |
| title_sub | fundamentals and applications |
| topic | Strahlenhärten (DE-588)4373773-0 gnd Härten (DE-588)4139793-9 gnd Fotochemische Reaktion (DE-588)4138378-3 gnd Kunststoff (DE-588)4033676-1 gnd Polymere (DE-588)4046699-1 gnd Photopolymerisation (DE-588)4174541-3 gnd |
| topic_facet | Strahlenhärten Härten Fotochemische Reaktion Kunststoff Polymere Photopolymerisation Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006621704&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT fouassierjeanpierre photoinitiationphotopolymerizationandphotocuringfundamentalsandapplications |