Photoelectron spectroscopy of metal clusters:
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| Main Author: | |
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| Format: | Book |
| Language: | English |
| Published: |
1994
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Köln, Univ., Diss., 1994 |
| Physical Description: | 68 S. graph. Darst. |
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| adam_text |
CONTENTS
1
CONTENTS
1 INTRODUCTION 3
1.1 THE ELECTRONIC STRUCTURE OF METAL CLUSTERS. 3
1.1.1 THE JELLIUM MODEL. 3
1.2 MOTIVATION OF THE EXPERIMENT . 4
1.2.1 MONOVALENT METAL CLUSTERS: CU, AG. 5
1.2.2 TRIVALENT METAL CLUSTERS: AL, GA. 6
1.3 OBJECTIVES OF OUR EXPERIMENTS. 8
2 METHODS OF CLUSTER SPECTROSCOPY 10
2.1 EXPERIMENTS WITH NEUTRAL CLUSTER BEAMS . 10
2.2 PES(A): PRINCIPLE. 10
2.3 PES(A): INSTRUMENTATION. 11
2.3.1 CW-PES(A) . 11
2.3.2 PULSED PES(A). 12
3 EXPERIMENTAL SETUP 16
3.1 GENERAL SETUP. 16
3.2 PACIS CLUSTER ANION SOURCE . 16
3.2.1. GEOMETRY. 16 *
3.2.2 OPERATION. 17
3.3 TOF ELECTRON SPECTROMETER. 18
3.3.1 GEOMETRY. 19
3.3.2 ENERGY RESOLUTION.22
4 THEORETICAL BACKGROUND OF PES(A) 23
4.1 PES(A) AS TRANSITION BETWEEN STATES .23
4.2 PES(A) IN THE SINGLE PARTICLE PICTURE.23
4.3 BEYOND THE SINGLE-PARTICLE MODEL .24
4.3.1 SHAKE-UP TRANSITIONS.24
4.3.2 MULTIPLET SPLITTING.25
5 PES(A) OF
CU~ AND AG~ 28
5.1 IDENTIFICATION THE S AND D EMISSION.28
5.2 SHELL MODEL INTERPRETATION OF CU~ SPECTRA.32
5.3 SHELL MODEL AND QUANTUM CHEMICAL CALCULATIONS.36
5.3.1 GEOMETRY OF AG^ TO AG*.37
5.3.2 MOLECULAR ORBITALS AND SHELL ORBITALS.37
5.3.3 AGI.38
5.3.4 AGA .40
5.4 CONCLUSIONS.43
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/943007437
2
CONTENTS
6 PES(A) OF
AL~ AND GA~ 44
6.1 IDENTIFICATION OF THE S AND P EMISSION.44
6.1.1 PARTIAL SP HYBRIDIZATION .44
6.2 QUANTUM CHEMICAL CALCULATIONS.48
6.2.1 ALJ/GAJ .48
6.2.2
ALI/GAJ .50
6.2.3 AL^/GA^ .52
6.3 STRUCTURAL TRANSITION.53
6.3.1 PLANAR CLUSTERS .54
6.3.2 ONSET OF 3D STRUCTURES.55
6.4 JELLIUM MODEL.58
6.4.1 PARTIAL P SHELL STRUCTURE .59
6.5 CONCLUSIONS.61
7 SUMMARY AND OUTLOOK 62
7.1 SUMMARY.62
7.2 FUTURE EXPERIMENTS.62 |
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| indexdate | 2024-10-09T16:18:47Z |
| institution | BVB |
| language | English |
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| physical | 68 S. graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
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| spelling | Zha, Jia-Yan Verfasser aut Photoelectron spectroscopy of metal clusters vorgelegt von Chia-Yen Cha 1994 68 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Köln, Univ., Diss., 1994 Metallcluster (DE-588)4128942-0 gnd rswk-swf Ultraviolett-Photoelektronenspektroskopie (DE-588)4264090-8 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Metallcluster (DE-588)4128942-0 s Ultraviolett-Photoelektronenspektroskopie (DE-588)4264090-8 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006614388&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Zha, Jia-Yan Photoelectron spectroscopy of metal clusters Metallcluster (DE-588)4128942-0 gnd Ultraviolett-Photoelektronenspektroskopie (DE-588)4264090-8 gnd |
| subject_GND | (DE-588)4128942-0 (DE-588)4264090-8 (DE-588)4113937-9 |
| title | Photoelectron spectroscopy of metal clusters |
| title_auth | Photoelectron spectroscopy of metal clusters |
| title_exact_search | Photoelectron spectroscopy of metal clusters |
| title_full | Photoelectron spectroscopy of metal clusters vorgelegt von Chia-Yen Cha |
| title_fullStr | Photoelectron spectroscopy of metal clusters vorgelegt von Chia-Yen Cha |
| title_full_unstemmed | Photoelectron spectroscopy of metal clusters vorgelegt von Chia-Yen Cha |
| title_short | Photoelectron spectroscopy of metal clusters |
| title_sort | photoelectron spectroscopy of metal clusters |
| topic | Metallcluster (DE-588)4128942-0 gnd Ultraviolett-Photoelektronenspektroskopie (DE-588)4264090-8 gnd |
| topic_facet | Metallcluster Ultraviolett-Photoelektronenspektroskopie Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006614388&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT zhajiayan photoelectronspectroscopyofmetalclusters |