Ferrocenes: homogeneous catalysis, organic synthesis, materials science
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim u.a.
VCH
1995
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIX, 540 S. Ill. |
| ISBN: | 3527290486 |
Internformat
MARC
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| 245 | 1 | 0 | |a Ferrocenes |b homogeneous catalysis, organic synthesis, materials science |c ed. by Antonio Togni ... |
| 264 | 1 | |a Weinheim u.a. |b VCH |c 1995 | |
| 300 | |a XIX, 540 S. |b Ill. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Catalyse homogène |2 ram | |
| 650 | 7 | |a Compostos organometalicos (quimica organica) |2 larpcal | |
| 650 | 7 | |a Ferrocenen |2 gtt | |
| 650 | 7 | |a Ferrocène |2 ram | |
| 650 | 7 | |a Synthèse asymétrique |2 ram | |
| 650 | 4 | |a Ferrocene | |
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| 689 | 0 | 0 | |a Ferrocenderivate |0 (DE-588)4154117-0 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Togni, Antonio |e Sonstige |4 oth | |
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Datensatz im Suchindex
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| adam_text |
CONTENTS
PREFACE
.
V
LIST
OF
CONTRIBUTORS
.
XV
LIST
OF
ABBREVIATIONS
.
XVII
PART
1
HOMOGENEOUS
CATALYSIS
1
L,L'-BIS(DIPHENYLPHOSPHINO)FERROCENE
-
COORDINATION
CHEMISTRY,
ORGANIC
SYNTHESES,
AND
CATALYSIS
K.-S.
GAN
AND
T.
S.
A.
HOR
1.1
INTRODUCTION
.
3
1.2
PREPARATION
AND
COMPLEXATION
.
3
1.3
STRUCTURAL
PROPERTIES
.
18
1.3.1
MODES
OF
COORDINATION
.
18
1.3.2
GEOMETRICAL
DISTORTIONS
.
33
1.4
SPECTROSCOPIC
CHARACTERISTICS
.
35
1.4.1
TECHNIQUES
.
35
1.4.1.1
31
P
NMR
SPECTROSCOPY
.
35
1.4.1.2
X
H
NMR
SPECTROSCOPY
.
37
1.4.1.3
MBSSBAUER
SPECTROSCOPY
.
39
1.4.2
NMR
FLUXIONALITY
.
41
1.5
CATALYSIS
.
47
1.5.1
CROSS
COUPLING
.
;
.
47
1.5.1.1
ORGANIC
ELECTROPHILE
AND
ORGANOMETALLIC
COUPLING
.
47
1.5.1.2
ARYLATION
AND
VINYLATION
OF
ALKENES
.
65
1.5.1.3
CARBONYLATION
AND
CARBONYLATIVE
COUPLING
.
67
1.5.1.4
NUCLEOPHILIC
SUBSTITUTION
.
75
1.5.1.5
POLYCONDENSATION
AND
POLYMERIZATION
.
78
1.5.2
OLEFIN
FUNCTIONALIZATION
.
80
1.5.2.1
HYDROFORMYLATION
.
80
1.5.2.2
HYDROGENATION
AND
REDUCTION
.
83
VIII
CONTENTS
1.5.2.3
HYDROBORATION
AND
HYDROSILYLATION
.
86
1.5.2.4
ISOMERIZATION
.
88
1.6
CLUSTER
COMPLEXES
.
89
1.7
ELECTROCHEMISTRY
.
93
1.8
BIOMEDICAL
APPLICATIONS
.
94
1.9
SUMMARY
.
95
REFERENCES
.
96
2
ASYMMETRIC
CATALYSIS
WITH
CHIRAL
FERROCENYLPHOSPHINE
LIGANDS
T.
HAYASHI
2.1
INTRODUCTION
.
105
2.2
PREPARATION
OF
CHIRAL
FERROCENYLPHOSPHINES
.
106
2.3
STRUCTURE
OF
CHIRAL
FERROCENYLPHOSPHINES
AND
THEIR
TRANSITION-METAL
COMPLEXES
.
ILL
2.4
CATALYTIC
ASYMMETRIC
REACTIONS
WITH
CHIRAL
FERROCENYLPHOSPHINE
LIGANDS
.
113
2.4.1
CROSS-COUPLING
OF
ORGANOMETALLICS
WITH
HALIDES
.
113
2.4.2
ALLYLIC
SUBSTITUTION
REACTIONS
VIA
N-ALLYL
COMPLEXES
.
119
2.4.3
HYDROGENATION
OF
OLEFINS
AND
KETONES
.
128
2.4.4
HYDROSILYLATION
OF
OLEFINS
AND
KETONES
.
130
2.4.5
ALDOL
REACTION
OF
A-ISOCYANOCARBOXYLATES
.
132
2.4.6
OTHERS
.
138
REFERENCES
.
139
3
ENANTIOSELECTIVE
ADDITION
OF
DIALKYLZINC
TO
ALDEHYDES
CATALYZED
BY
CHIRAL
FERROCENYL
AMINOALCOHOLS
K
BUTSUGAN,
S.
ARAKI
AND
M.
WATANABE
3.1
INTRODUCTION
.
143
3.2
CHIRAL
FERROCENYLZINCS
BEARING
AN
AMINOETHANOL
AUXILIARY
.
144
3.2.1
SYNTHESIS
OF
THE
CATALYSTS
.
144
3.2.2
ADDITION
OF
DIETHYLZINC
TO
BENZALDEHYDE
.
145
3.3
V-(L-FERROCENYLALKYL)
V-ALKYLNOREPHEDRINES
.
148
3.3.1
SYNTHESIS
OF
THE
CATALYSTS
.
148
3.3.2
ADDITION
OF
DIETHYLZINC
TO
ALDEHYDES
.
149
3.4
CHIRAL
POLYMERS
BEARING
V-FERROCENYLMETHYLEPHEDRINE
.
151
3.4.1
SYNTHESIS
OF
THE
CATALYSTS
.
151
3.4.2
ADDITION
OF
DIETHYLZINC
TO
BENZALDEHYDE
.
152
3.5
CHIRAL
1,2-DISUBSTITUTED
FERROCENYL
AMINOALCOHOLS
.
153
3.5.1
SYNTHESIS
OF
THE
CATALYSTS
.
153
3.5.2
ADDITION
OF
DIETHYLZINC
TO
ALDEHYDES
.
155
CONTENTS
IX
3.5.3
ADDITION
OF
DIALKYLZINCS
TO
O-PHTHALALDEHYDE
:
A
FACILE
SYNTHESIS
OF
OPTICALLY
ACTIVE
3-ALKYLPHTHALIDES
.
162
3.5.4
ENANTIO
AND
DIASTEREOSELECTIVE
ADDITION
OF
DIETHYLZINC
TO
RACEMIC
A-THIO
AND
A-SELENOALDEHYDES
.
164
3.6
SUMMARY
.
167
REFERENCES
.
168
PART
2
ORGANIC
SYNTHESIS
-
SELECTED
ASPECTS
4
CHIRAL
FERROCENE
DERIVATIVES.
AN
INTRODUCTION
G.
WAGNER
AND
R.
HERRMANN
4.1
CENTRAL
AND
PLANAR
CHIRALITY
IN
METALLOCENES
.
173
4.2
OT-FERROCENYLALKYL
CARBOCATIONS
.
175
4.2.1
STRUCTURE
AND
STABILITY
.
175
4.2.2
STEREOCHEMISTRY
.
176
4.3
CENTRAL
CHIRAL
FERROCENE
DERIVATIVES
.
178
4.3.1
SYNTHESES
.
178
4.3.1.1
BY
RESOLUTION
.
178
4.3.1.2
BY
ASYMMETRIC
SYNTHESIS
.
181
4.3.1.3
FROM
THE
CHIRAL
POOL
.
182
4.3.2
ALKENES
.
188
4.3.3
AMINES
.
188
4.3.3.1
REACTIONS
AT
NITROGEN
.
190
4.3.3.2
REACTIONS
AT
CHIRAL
CARBON
.
190
4.3.3.3
STEREOSELECTIVE
METALLATION
.
193
4.4
PLANAR
CHIRAL
FERROCENE
DERIVATIVES
.
196
4.4.1
GENERAL
SYNTHETIC
METHODS
.
196
4.4.2
PHOSPHINES
.
200
4.4.3
SULFUR
AND
SELENIUM
COMPOUNDS
.
201
4.4.4
SILICON
AND
TIN
COMPOUNDS
.
203
4.4.5
OTHER
DERIVATIVES
.
204
4.5
APPLICATIONS
OF
CHIRAL
FERROCENE
DERIVATIVES
.
206
4.5.1
AS
CHIRAL
STARTING
MATERIALS
.
207
4.5.2
AS
CHIRAL
AUXILIARIES
.
208
4.5.2.1
FOUR
COMPONENT
CONDENSATIONS
.
208
4.5.2.2
OTHER
APPLICATIONS
.
210
4.5.3
AS
CHIRAL
CATALYSTS
.
212
4.5.3.1
C
-
C
COUPLING,
HYDROGENATION,
AND
HYDROSILYLATION
.
212
4.5.3.2
ALLYLATIONS
AND
ALDOL-TYPE
REACTIONS
.
214
4.5.4
OTHER
CATALYTIC
APPLICATIONS
.
214
REFERENCES
.
214
X
CONTENTS
5
FERROCENE
COMPOUNDS
CONTAINING
HETEROELEMENTS
M.
HERBERHOLD
5.1
INTRODUCTION
.
219
5.2
SYNTHESIS
OF
FERROCENE
DERIVATIVES
BEARING
HETEROELEMENT
SUBSTITUENTS
.
220
5.2.1
BORYLATION
.
220
5.2.2
METALLATION
.
221
5.3
SELECTED
FERROCENE
DERIVATIVES
WITH
REACTIVE
FUNCTIONAL
SUBSTITUENTS
.
225
5.3.1
AMINOFERROCENES
AND
RELATED
COMPOUNDS
.
225
5.3.2
HYDROXYFERROCENES
AND
RELATED
COMPOUNDS
.
229
5.3.3
MERCAPTOFERROCENES
AND
RELATED
COMPOUNDS
.
231
5.4
HOMOLEPTIC
FERROCENYL
DERIVATIVES
OF
THE
ELEMENTS
.
236
5.5
TRANSITION
METAL
COMPLEXES
WITH
FERROCENYL
AND
L,L'-FERROCENEDIYL
LIGANDS
.
240
5.6
COMPOUNDS
WITH
FERROCENYL
CHALCOGENATE
AND
1,1
'-FERROCENYLENE
DICHALCOGENATE
GROUPS
.
247
5.7
[3]FERROCENOPHANES
CONTAINING
CHALCOGENS
.
254
5.7.1
COMPOUNDS
WITH
ONE
L,3-DICHALCOGENA-[3]FERROCENOPHANE
RING
.
255
5.7.2
COMPOUNDS
WITH
TWO
OR
THREE
1,3-DICHALCOGENA
[3]FERROCENOPHANE
RINGS
.
261
5.8
OLIGO
AND
POLYNUCLEAR
FERROCENES
WITH
CHALCOGEN
AND
DICHALCOGEN
BRIDGES
.
264
5.9
CONCLUSIONS
.
267
REFERENCES
.
270
6
MACROCYCLES
AND
CRYPTANDS
CONTAINING
THE
FERROCENE
UNIT
C.
D.
HALL
6.1
INTRODUCTION
.
279
6.2
THE
FERROCENOPHANES
.
281
6.3
CRYPTANDS
CONTAINING
THE
FERROCENE
UNIT
.
291
6.4
MACROCYCLIC
CRYPTAND
AND
CAVITAND
DERIVATIVES
OF
FERROCENE
.
300
6.4.1
FERROCENE
BOUND
TO
MACROCYCLES
.
300
6.4.2
FERROCENE
BOUND
TO
CAVITAND
MOLECULES
.
308
6.5
SUMMARY
.
312
REFERENCES
.
313
CONTENTS
XI
7
ELECTROCHEMICAL
AND
X-RAY
STRUCTURAL
ASPECTS
OF
TRANSITION
METAL
COMPLEXES
CONTAINING
REDOX-ACTIVE
FERROCENE
LIGANDS
P.
ZANELLO
7.1
INTRODUCTION
.
317
7.2
FERROCENE
COMPLEXES
OF
HOMOMETALLIC
METAL
FRAGMENTS
.
318
7.2.1
GROUP
4
METAL
COMPLEXES
.
318
7.2.1.1
TITANIUM
COMPLEXES
.
318
7.24.2
ZIRCONIUM
COMPLEXES
.
321
7.2.1.3
HAFNIUM
COMPLEXES
.
322
7.2.2
GROUP
5
METAL
COMPLEXES:
VANADIUM
.
322
7.2.3
GROUP
6
METAL
COMPLEXES
.
323
7.2.3.1
CHROMIUM
COMPLEXES
.
323
7.2.3.2
MOLYBDENUM
COMPLEXES
.
330
7.2.3.3
TUNGSTEN
COMPLEXES
.
338
7.2.4
GROUP
7
METAL
COMPLEXES
.
341
7.2.4.1
MANGANESE
COMPLEXES
.
341
7.2.4.2
RHENIUM
COMPLEXES
.
342
7.2.5
GROUP
8
METAL
COMPLEXES
.
347
7.2.5.1
IRON
COMPLEXES
.
347
7.2.5.2
RUTHENIUM
COMPLEXES
.
351
7.2.5.3
OSMIUM
COMPLEXES
.
358
7.2.6
GROUP
9
METAL
COMPLEXES
.
359
7.2.6.1
COBALT
COMPLEXES
.
359
7.2.6.2
RHODIUM
COMPLEXES
.
377
7.2.6.3
IRIDIUM
COMPLEXES
.
383
7.2.7
GROUP
10
METAL
COMPLEXES
.
384
7.2.7.1
NICKEL
COMPLEXES
.
384
7.2.7.2
PALLADIUM
COMPLEXES
.
390
7.2.7.3
PLATINUM
COMPLEXES
.
401
7.2.8
GROUP
11
METAL
COMPLEXES
.
406
7.2.8.1
COPPER
COMPLEXES
.
406
7.2.8.2
SILVER
COMPLEXES
.
413
7.2.8.3
GOLD
COMPLEXES
.
416
7.2.9
GROUP
12
METAL
COMPLEXES
.
417
7.2.9.1
ZINC
COMPLEXES
.
417
7.2.9.2
CADMIUM
COMPLEXES
.
419
7.2.9.3
MERCURY
COMPLEXES
.
419
7.3
FERROCENE
COMPLEXES
OF
HETEROMETALLIC
FRAGMENTS
.
421
7.3.1
TRINUCLEAR
COMPLEXES
.
421
7.3.2
PENTANUCLEAR
COMPLEXES
.
422
7.4
CONCLUSIONS
.
423
REFERENCES
.
424
XII
CONTENTS
PART
3
MATERIALS
SCIENCE
8
FERROCENE-CONTAINING
CHARGE-TRANSFER
COMPLEXES.
CONDUCTING
AND
MAGNETIC
MATERIALS
A.
TOGNI
8.1
INTRODUCTION
.
433
8.2
CHEMICAL
AND
STRUCTURAL
REQUIREMENTS
.
435
8.3
CHARGE-TRANSFER
COMPLEXES
OF
POLYALKYLATED
FERROCENES
.
437
8.3.1
DECAMETHYLFERROCENE
.
440
8.3.1.1
WITH
ORGANIC
ACCEPTORS
.
440
8.3.1.2
WITH
INORGANIC
ACCEPTORS
.
449
8.3.2
OTHER
ALKYLFERROCENES
.
454
8.3.3
MISCELLANEOUS
FERROCENES
.
458
8.4
BIFERROCENES
.
459
8.5
CHARGE-TRANSFER
COMPLEXES
OF
FERROCENES
CONTAINING
CONJUGATED
HETEROATOM
SUBSTITUENTS
.
460
8.6
COMPARISON
WITH
OTHER
ORGANOMETALLIC
CHARGE-TRANSFER
COMPLEXES
.
464
8.7
CONCLUSIONS
AND
PERSPECTIVES
.
465
REFERENCES
.
466
9
FERROCENE-CONTAINING
THERMOTROPIC
LIQUID
CRYSTALS
R.
DESCHENAUX
AND
J.
W.
GOODBY
9.1
INTRODUCTION
.
471
9.2
MONOSUBSTITUTED
FERROCENE
DERIVATIVES
.
477
9.3
SYMMETRICALLY
DISUBSTITUTED
FERROCENE
DERIVATIVES
.
477
9.3.1
1,1
'-DISUBSTITUTED
FERROCENE
DERIVATIVES
.
477
9.3.2
1,3-DISUBSTITUTED
FERROCENE
DERIVATIVES
.
484
9.3.3
1,2-DISUBSTITUTED
FERROCENE
DERIVATIVES
.
488
9.4
UNSYMMETRICALLY
1,1
'-DISUBSTITUTED
FERROCENE
DERIVATIVES
.
489
9.5
FERROCENE-CONTAINING
LIQUID
CRYSTAL
POLYMERS
.
492
9.6
CONCLUDING
REMARKS
.
494
REFERENCES
.
494
CONTENTS
XIII
10
SYNTHESIS
AND
CHARACTERIZATION
OF
FERROCENE-CONTAINING
POLYMERS
K.
E.
GONSALVES
AND
X.
CHEN
10.1
INTRODUCTION
.
497
10.2
ADDITION
POLYMERS
.
499
10.3
CONDENSATION
POLYMERS
.
504
10.4
RING-OPENING
POLYMERIZATION
.
514
10.5
DERIVATIZATION
OF
PREFORMED
ORGANIC
POLYMERS
.
520
10.6
ELECTROPOLYMERIZATION
.
523
10.7
SUMMARY
.
527
REFERENCES
.
527
INDEX
.
531 |
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| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547/.056210459 |
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| id | DE-604.BV009888424 |
| illustrated | Illustrated |
| indexdate | 2024-08-16T01:32:32Z |
| institution | BVB |
| isbn | 3527290486 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006548013 |
| oclc_num | 31435230 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-29T DE-703 DE-19 DE-BY-UBM DE-83 DE-11 |
| owner_facet | DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-29T DE-703 DE-19 DE-BY-UBM DE-83 DE-11 |
| physical | XIX, 540 S. Ill. |
| publishDate | 1995 |
| publishDateSearch | 1995 |
| publishDateSort | 1995 |
| publisher | VCH |
| record_format | marc |
| spelling | Ferrocenes homogeneous catalysis, organic synthesis, materials science ed. by Antonio Togni ... Weinheim u.a. VCH 1995 XIX, 540 S. Ill. txt rdacontent n rdamedia nc rdacarrier Catalyse homogène ram Compostos organometalicos (quimica organica) larpcal Ferrocenen gtt Ferrocène ram Synthèse asymétrique ram Ferrocene Ferrocenderivate (DE-588)4154117-0 gnd rswk-swf Ferrocenderivate (DE-588)4154117-0 s DE-604 Togni, Antonio Sonstige oth DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006548013&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ferrocenes homogeneous catalysis, organic synthesis, materials science Catalyse homogène ram Compostos organometalicos (quimica organica) larpcal Ferrocenen gtt Ferrocène ram Synthèse asymétrique ram Ferrocene Ferrocenderivate (DE-588)4154117-0 gnd |
| subject_GND | (DE-588)4154117-0 |
| title | Ferrocenes homogeneous catalysis, organic synthesis, materials science |
| title_auth | Ferrocenes homogeneous catalysis, organic synthesis, materials science |
| title_exact_search | Ferrocenes homogeneous catalysis, organic synthesis, materials science |
| title_full | Ferrocenes homogeneous catalysis, organic synthesis, materials science ed. by Antonio Togni ... |
| title_fullStr | Ferrocenes homogeneous catalysis, organic synthesis, materials science ed. by Antonio Togni ... |
| title_full_unstemmed | Ferrocenes homogeneous catalysis, organic synthesis, materials science ed. by Antonio Togni ... |
| title_short | Ferrocenes |
| title_sort | ferrocenes homogeneous catalysis organic synthesis materials science |
| title_sub | homogeneous catalysis, organic synthesis, materials science |
| topic | Catalyse homogène ram Compostos organometalicos (quimica organica) larpcal Ferrocenen gtt Ferrocène ram Synthèse asymétrique ram Ferrocene Ferrocenderivate (DE-588)4154117-0 gnd |
| topic_facet | Catalyse homogène Compostos organometalicos (quimica organica) Ferrocenen Ferrocène Synthèse asymétrique Ferrocene Ferrocenderivate |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006548013&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT togniantonio ferroceneshomogeneouscatalysisorganicsynthesismaterialsscience |