Liquid crystalline and mesomorphic polymers:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
New York u.a.
Springer
1994
|
| Series: | Partially ordered systems
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturangaben |
| Physical Description: | XVI, 361 S. Ill., graph. Darst. |
| ISBN: | 3540940464 0387940464 |
Staff View
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Record in the Search Index
| _version_ | 1804124106899062784 |
|---|---|
| adam_text | VALERY P. SHIBAEV LUI LAM EDITORS LIQUID CRYSTALLINE AND MESOMORPHIC
POLYMERS WITH 199 ILLUSTRATIONS SPRINGER-VERLAG NEW YORK BERLIN
HEIDELBERG LONDON PARIS TOKYO HONG KONG BARCELONA BUDAPEST CONTENTS
PREFACE V CONTRIBUTORS XV 1 MOLECULAR THEORY OF CHOLESTERIC POLYMERS 1
M.A. OSIPOV 1.1 INTRODUCTION 1 1.2 ELEMENTARY MODELS FOR CHIRAL
MOLECULES 3 1.3 CHIRAL ANISOTROPIC INTERACTION BETWEEN MACROMOLECULES IN
THE SOLVENT 5 1.3.1 MODEL POTENTIALS 5 1.3.2 SOLVENT EFFECT ON THE
CHIRAL INTERMOLECULAR INTERACTION 7 1.4 STATISTICAL THEORY OF
CHOLESTERIC ORDERING 10 1.4.1 GENERAL THEORY 10 1.4.2 TEMPERATURE AND
SOLVENT EFFECT ON THE CHOLESTERIC PITCH IN POLYPEPTIDE SOLUTIONS 14
1.4.3 CHOLESTERIC ORDERING IN BIOPOLYMER SOLUTIONS 17 1.4.4 INFLUENCE OF
SOLVENT CHIRALITY ON THE CHOLESTERIC ORDERING 19 1.5 INFLUENCE OF
MOLECULAR FLEXIBILITY ON THE CHOLESTERIC ORDERING IN POLYMER SOLUTIONS
21 REFERENCES 23 2 STRUCTURE OF THERMOTROPIC MAIN-CHAIN POLYMERS 26 A.H.
WINDLE 2.1 INTRODUCTION 26 2.1.1 SCOPE 26 2.1.2 MAIN-CHAIN MESOGENIC
SYSTEMS 26 2.2 MOLECULAR ARCHITECTURE 30 X CONTENTS 2.2.1 THEORETICAL
BACKGROUND 30 2.2.2 ARCHITECTURE OF ISOLATED POLYMER MOLECULES 31 2.2.3
PERSISTENCE LENGTH AS A CRITICAL PARAMETER 34 2.2.4 KUHN CHAINS 38 2.2.5
CHANGE IN CHAIN PARAMETERS IN THE NEMATIC PHASE 40 2.2.6 MICROSTRUCTURAL
CONSIDERATIONS INVOLVING NEMATIC POLYMERS 41 2.3 LEVELS OF ORDER IN
MESOPHASES OF MAIN-CHAIN LIQUID POLYMERS 46 2.3.1 CLASSIFICATION FOR
POLYMERS 46 2.3.2 ASPECTS OF CHAIN STRUCTURE 47 2.3.3 BASIS FOR
CLASSIFICATION 50 2.3.4 MESOPHASES FORMED BY SUCCESSIVE SHEAR DISORDER
OF THE CRYSTAL 51 2.3.5 MESOPHASES FORMED BY PARACRYSTALLINE DISORDER IN
ONE LATERAL DIMENSION 57 2.3.6 MESOPHASES RESULTING FROM PARACRYSTALLINE
DISORDER IN THE TWO (LATERAL) DIMENSIONS, AND TRANSLATIONAL MELTING IN
TWO DIMENSIONS 65 2.3.7 AUDIT OF POSSIBLE COMBINATIONS 71 2.3.8
OCCURRENCE OF MESOPHASE STRUCTURES 71 2.3.9 DISRUPTION OF ORDER ALONG
THE CHAIN AXIS 73 REFERENCES 74 MOLECULAR ARCHITECTURE AND STRUCTURE OF
THERMOTROPIC LIQUID CRYSTAL POLYMERS WITH MESOGENIC SIDE GROUPS 77 V.P.
SHIBAEV, YA.S. FREIDZON, AND S.G. KOSTROMIN 3.1 INTRODUCTION 77 3.2
MOLECULAR ARCHITECTURE OF LIQUID CRYSTAL POLYMERS 79 3.3 SPECIFIC
FEATURES OF COMB-SHAPED POLYMERS ASSOCIATED WITH THEIR MACROMOLECULAR
NATURE 84 3.4 MESOPHASE TYPES OF COMB-SHAPED LIQUID CRYSTAL POLYMERS.
PROBLEMS OF CLASSIFICATION 91 3.5 EFFECT OF MESOPHASE TYPE ON THE
STRUCTURE OF POLYMERS ORIENTED BY UNIAXIAL DRAWING 98 3.5.1 NEMATIC
POLYMERS 100 3.5.2 SMECTIC POLYMERS 102 3.6 PLACEMENT OF THE MAIN-CHAIN
IN SMECTIC AND NEMATIC PHASES OF COMB-SHAPED LIQUID CRYSTAL POLYMERS 103
3.7 STRUCTURE OF CHOLESTERIC POLYMERS 108 3.7.1 STRUCTURE OF
CHOLESTEROL-CONTAINING HOMOPOLYMERS 108 3.7.2 STRUCTURE OF
CHOLESTEROL-CONTAINING COPOLYMERS 113 REFERENCES 115 CONTENTS XI 4 PHASE
BEHAVIOR OF HIGH- AND LOW-MOLAR-MASS LIQUID CRYSTAL MIXTURES 121 F.
HARDOUIN, G. SIGAUD, AND M.F. ACHARD 4.1 INTRODUCTION 121 4.2 BINARY
MIXTURES OF LOW-MOLAR-MASS MESOGENS 124 4.3 MIXTURES OF A LIQUID
CRYSTALLINE POLYMER WITH A LOW-MOLAR-MASS LIQUID CRYSTAL 129 4.3.1
MISCIBILITY PROPERTIES 130 4.3.2 OTHER NONIDEAL BEHAVIORS 140 4.4
CONCLUSIONS 142 REFERENCES 144 5 POLYMER-DISPERSED LIQUID CRYSTAL FILMS
149 G.P. MONTGOMERY, JR., G. W. SMITH, AND N.A. VAZ 5.1 INTRODUCTION 149
5.2 FILM STRUCTURE AND OPERATION 150 5.3 FILM FORMATION: GENERAL ASPECTS
153 5.3.1 EMULSIFICATION*NCAP FILMS 153 5.3.2 PHASE
SEPARATION*POLYMER-DISPERSED LIQUID CRYSTAL FILMS 153 5.4
POLYMER-DISPERSED LIQUID CRYSTAL FORMATION: POLYMER-INDUCED PHASE
SEPARATION SYSTEMS 155 5.4.1 FORMATION MODEL 155 5.4.2 EXPERIMENTAL
STUDIES OF POLYMER-DISPERSED LIQUID CRYSTAL FORMATION 157 5.4.3
CONCLUDING REMARKS REGARDING POLYMER- DISPERSED LIQUID CRYSTAL FORMATION
163 5.5 MATERIALS SELECTION 163 5.5.1 REFRACTIVE INDICES 163 5.5.2
SOLUBILITY OF LIQUID CRYSTAL IN MATRIX 167 5.5.3 OPERATING TEMPERATURE
RANGE 168 5.5.4 ENVIRONMENTAL STABILITY 168 5.6 FILM FABRICATION AND
MORPHOLOGY 169 5.6.1 ULTRAVIOLET-CURING CONDITIONS 169 5.6.2 DROPLET
SIZE DISTRIBUTION 171 5.6.3 COLOR 171 5.7 ELECTROOPTIC PROPERTIES 172
5.7.1 REFRACTIVE INDICES AND FILM TRANSMITTANCE 172 5.7.2 TRANSMITTANCE
VERSUS VOLTAGE 174 5.7.3 RESPONSE TIMES 177 5.7.4 SPECTRAL TRANSMITTANCE
CHARACTERISTICS 179 5.8 LIGHT SCATTERING 180 5.8.1 THEORETICAL
TREATMENTS 180 5.8.2 ANGLE-DEPENDENT LIGHT SCATTERING MEASUREMENTS 181
XII CONTENTS 5.8.3 TRANSMITTANCE MEASUREMENTS 183 5.8.4 DROPLET SIZE
EFFECTS 186 5.8.5 CONCLUDING REMARKS REGARDING LIGHT SCATTERING 186 5.9
FINAL COMMENTS 187 REFERENCES 188 6 NUCLEAR MAGNETIC RESONANCE
SPECTROSCOPY OF THERMOTROPIC LIQUID CRYSTALLINE POLYMERS 193 L.
STROGANOV 6.1 INTRODUCTION 193 6.2 THERMOTROPIC LIQUID CRYSTALLINE
POLYMERS WITH MESOGENIC GROUPS IN THE MAIN CHAIN 194 6.2.1 J H AND 2 H
NUCLEAR MAGNETIC RESONANCE IN FAST MOTION LIMIT 194 6.2.2 MULTIPULSE
DYNAMIC NUCLEAR MAGNETIC RESONANCE 197 6.2.3 MOLECULAR DYNAMICS 198
6.2.4 ORIENTATIONAL ORDERING 200 6.2.5 BIPHASE REGION 208 6.2.6
MACROSCOPIC ORDERING 212 6.3 LIQUID CRYSTALLINE POLYMERS WITH MESOGENIC
GROUPS IN THE SIDE CHAINS 215 6.3.1 MOLECULAR DYNAMICS AND ORDERING IN
THE GLASSY STATE 215 6.3.2 ORDERING AND DYNAMICS IN LIQUID CRYSTALLINE
PHASES ABOVE THE GLASS TRANSITION TEMPERATURE 219 6.3.3 BIPHASE REGION
222 6.3.4 MACROSCOPIC ORDERING 223 REFERENCES 228 7 MESOPHASE OF
GRAPHITIZABLE CARBONS 231 H. MARSH AND M.A. DIEZ 7.1 INTRODUCTION 231
7.2 DISCOTIC NEMATIC LIQUID CRYSTALS 233 7.3 FORMATION OF THE MESOPHASE
236 7.4 STRUCTURE IN THE MESOPHASE 239 7.5 GROWTH AND COALESCENCE 242
7.6 FORMATION OF ANISOTROPIC CARBONS 244 7.7 FACTORS INFLUENCING THE
FORMATION OF ANISOTROPIC CARBONS 247 7.7.1 CHEMICAL FACTORS 247 7.7.2
PHYSICAL FACTORS 250 7.8 GRAPHITIZATION 251 7.9 INDUSTRIAL RELEVANCE OF
MESOPHASE: DISCOTIC, AROMATIC, AND NEMATIC LIQUID CRYSTALS 252 7.9.1
DELAYED COKING 252 7.9.2 METALLURGICAL COKE 253 CONTENTS ** 7.9.3 CARBON
FIBERS 253 7.9.4 GRAPHITE PRODUCTION 253 7.9.5 CARBON BLACKS 254
REFERENCES 254 8 MESOPHASE STATE OF POLYORGANOPHOSPHAZENES 258 V.G.
KULICHIKHIN, E.M. ANTIPOV, E.K. BORISENKOVA, AND D.R. TUR 8.1
INTRODUCTION 258 8.2 THERMODYNAMICS AND STRUCTURE OF POLYORGANOPHOS
PHAZENES 259 8.3 RELAXATION TRANSITIONS OF POLY-BIS-TRIFLUOROETHOXY-
PHOSPHAZENES 267 8.4 PROPERTIES OF DILUTED SOLUTIONS OF
POLY-FEIS-FLUOROALKOXY- PHOSPHAZENES 270 8.5 RHEOLOGICAL PROPERTIES OF
CONCENTRATED POLY-FTIS- TRIFLUOROETHOXYPHOSPHAZENE SOLUTIONS 273 8.6
RHEOLOGICAL PROPERTIES OF POLY-BIS-FLUOROALKOXY- PHOSPHAZENES IN THE
MESOPHASE STATE 281 8.7 POLYMER BLENDS ON A BASE OF
POLY-BI S-TRIFLUOROETHOXY- PHOSPHAZENE 287 8.8 CONCLUSIONS 293
REFERENCES 294 9 CHIRAL NEMATIC MESOPHASES OF LYOTROPIC AND THERMOTROPIC
CELLULOSE DERIVATIVES 298 D.G. GRAY AND B.R. HARKNESS 9.1 MESOPHASE
FORMATION 298 9.2 MESOPHASES OF CELLULOSE DERIVATIVES 300 9.3 CHIRAL
NEMATIC PROPERTIES 302 9.3.1 THEORIES OF THE CHIRAL NEMATIC STATE 302
9.3.2 CHIRAL NEMATIC PROPERTIES OF CELLULOSE DERIVATIVES 305 9.3.3
REVERSAL OF HANDEDNESS OF CHIRAL NEMATIC CELLULOSICS 307 9.4 CIRCULAR
DICHROISM AND INDUCED CIRCULAR DICHROISM 310 9.5 CHIROPTICAL PROPERTIES
OF SPECIFICALLY SUBSTITUTED CELLULOSE DERIVATIVES 312 9.6 CONCLUDING
REMARKS 318 REFERENCES 320 10 BOWLICS 324 L. LAM 10.1 INTRODUCTION 324
10.2 THE FIRST PAPER 327 10.3 BOWLIC MONOMERS 331 10.3.1 THE MOLECULES
331 XIV CONTENTS 10.3.2 MESOPHASES AND PHASE TRANSITIONS 333 10.3.3
PHYSICAL PROPERTIES 335 10.3.4 BOWLIC NEMATICS IN ELECTRIC FIELDS 336
10.3.5 BOWLIC LANGMUIR FILMS 338 10.4 BOWLIC POLYMERS 340 10.4.1 THE
DISCRETE MODEL FOR DILUTE SOLUTIONS 340 10.4.2 THE WORM-LIKE MODEL FOR
BOWLIC NEMATIC POLYMERS 346 10.4.3 ULTRAHIGH T C BOWLIC SUPERCONDUCTORS
349 10.5 CONCLUSIONS 350 REFERENCES 351 INDEX 354
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| genre_facet | Aufsatzsammlung |
| id | DE-604.BV009759757 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:40:24Z |
| institution | BVB |
| isbn | 3540940464 0387940464 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006455950 |
| oclc_num | 246828114 |
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| owner | DE-355 DE-BY-UBR DE-384 DE-703 DE-83 DE-11 DE-188 |
| owner_facet | DE-355 DE-BY-UBR DE-384 DE-703 DE-83 DE-11 DE-188 |
| physical | XVI, 361 S. Ill., graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
| publishDateSort | 1994 |
| publisher | Springer |
| record_format | marc |
| series2 | Partially ordered systems |
| spelling | Liquid crystalline and mesomorphic polymers Valery P. Shibaev ... eds. New York u.a. Springer 1994 XVI, 361 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Partially ordered systems Literaturangaben Flüssigkristalline Polymere (DE-588)4221742-8 gnd rswk-swf Mesomorphe Phase (DE-588)4169474-0 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Flüssigkristalline Polymere (DE-588)4221742-8 s DE-604 Polymere (DE-588)4046699-1 s Mesomorphe Phase (DE-588)4169474-0 s Šibaev, Valerij Petrovič 1936- Sonstige (DE-588)1063381487 oth GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006455950&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Liquid crystalline and mesomorphic polymers Flüssigkristalline Polymere (DE-588)4221742-8 gnd Mesomorphe Phase (DE-588)4169474-0 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4221742-8 (DE-588)4169474-0 (DE-588)4046699-1 (DE-588)4143413-4 |
| title | Liquid crystalline and mesomorphic polymers |
| title_auth | Liquid crystalline and mesomorphic polymers |
| title_exact_search | Liquid crystalline and mesomorphic polymers |
| title_full | Liquid crystalline and mesomorphic polymers Valery P. Shibaev ... eds. |
| title_fullStr | Liquid crystalline and mesomorphic polymers Valery P. Shibaev ... eds. |
| title_full_unstemmed | Liquid crystalline and mesomorphic polymers Valery P. Shibaev ... eds. |
| title_short | Liquid crystalline and mesomorphic polymers |
| title_sort | liquid crystalline and mesomorphic polymers |
| topic | Flüssigkristalline Polymere (DE-588)4221742-8 gnd Mesomorphe Phase (DE-588)4169474-0 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Flüssigkristalline Polymere Mesomorphe Phase Polymere Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006455950&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT sibaevvalerijpetrovic liquidcrystallineandmesomorphicpolymers |