Applications of synchrotron radiation: high-resolution studies of molecules and molecular adsorbates on surfaces
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
1995
|
| Schriftenreihe: | Springer series in surface sciences
35 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 290 S. zahlr. graph. Darst. |
| ISBN: | 354058031X 038758031X |
Internformat
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| 245 | 1 | 0 | |a Applications of synchrotron radiation |b high-resolution studies of molecules and molecular adsorbates on surfaces |c W. Eberhardt (ed.). With contributions by A. M. Bradshaw ... |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 1995 | |
| 300 | |a XII, 290 S. |b zahlr. graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Springer series in surface sciences |v 35 | |
| 650 | 4 | |a Adsorption | |
| 650 | 4 | |a Molecular dynamics | |
| 650 | 4 | |a Surface chemistry | |
| 650 | 4 | |a Surfaces (Physics) | |
| 650 | 4 | |a Synchrotron radiation |x Industrial applications | |
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| 700 | 1 | |a Eberhardt, Wolfgang |e Sonstige |4 oth | |
| 700 | 1 | |a Bradshaw, A. M. |e Sonstige |4 oth | |
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Datensatz im Suchindex
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| adam_text |
CONTENTS
1.
INTRODUCTION
W.
EBERHARDT
.
1
REFERENCES
.
7
2.
BAND-STRUCTURE
DETERMINATION
OF
ADSORBATES
H.-J.
FREUND
AND
H.
KUHLENBECK
(WITH
42
FIGURES)
.
9
2.1
HISTORICAL
INTRODUCTION
.
9
2.2
CO
ADSORBATES
.
12
2.2.1
SYMMETRY
CONSIDERATIONS
AND
CO-SUBSTRATE
INTERACTIONS
.
12
2.2.2
ORDERED
OVERLAYERS
.
15
2.3
ETHYLENE
ADSORBATES
.
39
2.3.1
SYMMETRY
CONSIDERATION
AND
ETHYLENE-SUBSTRATE
INTERACTION
.
40
2.3.2
ORDERED
ETHYLENE
OVERLAYERS
.
43
2.4
BENZENE
ADSORBATES
.
47
2.5
CO-ADSORBATES
.
58
2.6
SYNOPSIS
.
60
REFERENCES
.
60
3.
HIGH-RESOLUTION
CORE-LEVEL
PHOTOELECTRON
SPECTROSCOPY
OF
SURFACES
AND
ADSORBATES
N.
MBRTENSSON
AND
A.
NILSSON
(WITH
39
FIGURES)
.
65
3.1
BACKGROUND
.
65
3.2
INSTRUMENTATION
.
71
3.3
CORE-LEVEL
SHIFTS
.
73
3.3.1
INITIAL
AND
FINAL
STATE
EFFECTS
.
73
3.3.2
EQUIVALENT
CORE
OR
Z
+
1
APPROXIMATION
.
75
3.4
ADSORBATE
CORE-LEVEL
SHIFTS
.
76
3.4.1
FINAL
STATE
EFFECTS
.
'LL
3.4.2
CHEMICAL
SHIFTS
BETWEEN
INEQUIVALENT
ATOMS
.
80
3.4.3
ADSORPTION
SITE-DEPENDENT
SHIFT
IN
CO
.
81
3.4.4
MOLECULAR
ORIENTATION
AND
SITE-DEPENDENT
SHIFTS
IN
NO
.
.
85
3.4.5
PHYSISORPTION-INDUCED
SHIFTS
IN
O
2
.
87
VIII
CONTENTS
3.5
SURFACE
CORE-LEVEL
SHIFTS
.
89
3.5.1
CLEAN
METALS
.
89
3.5.2
ADSORBATE-INDUCED
SHIFTS
.
92
3.6
CORE-LEVEL
LINE
SHAPES
.
96
3.7
VIBRATIONAL
EFFECTS
.
98
3.7.1
THE
FRANCK-CONDON
PRINCIPLE
.
99
3.7.2
VIBRATIONAL
BROADENING
IN
ADSORBATES
.
100
3.8
SHAKE-UP
SATELLITES
.
107
3.8.1
GENERAL
ASPECTS
.
108
3.8.2
SUBSTRATE
EXCITATIONS
FOR
ADSORBED
ARGON
.
110
3.8.3
LOCAL
EXCITATIONS
IN
STRONGLY
CHEMISORBED
ATOMS
.
113
3.8.4
CHEMISORPTION-INDUCED
EXCITATIONS
IN
ADSORBED
CO
AND
N
2
.
116
REFERENCES
.
122
4.
STRUCTURE
DETERMINATION
OF
MOLECULAR
ADSORBATES
USING
PHOTOELECTRON
DIFFRACTION
A.M.
BRADSHAW
AND
D.P.
WOODRUFF
(WITH
26
FIGURES)
.
127
4.1
INTRODUCTORY
COMMENTS
.
127
4.2
BASIS
OF
THE
TECHNIQUE
AND
ITS
POTENTIAL
.
131
4.3
EXAMPLES
.
140
,
4.3.1
FORWARD-SCATTERING
PHOTOELECTRON
DIFFRACTION
(XPD):
CO
ON
NI
(110)
.
140
4.3.2
EXPERIMENTAL
METHODOLOGY
AND
QUALITATIVE
SITE
SENSITIVITY
IN
PHD
.
143
4.3.3
QUANTITATIVE
STRUCTURAL
ANALYSIS
WITH
PHD
.
150
4.3.4
CHEMICAL-SHIFT
PHOTOELECTRON
DIFFRACTION
.
159
4.4
CONCLUDING
REMARKS
.
165
REFERENCES
.
167
5.
NEAR
EDGE
X-RAY
ABSORPTION
AND
DECAY
DYNAMICS
OF
ADSORBED
MOLECULES
W.
WURTH
AND
D.
MENZEL
(WITH
16
FIGURES)
.
171
5.1
BACKGROUND
.
171
5.2
X-RAY
ABSORPTION
.
173
5.2.1
PHYSISORBED
MOLECULES
.
173
5.2.2
CHEMISORBED
MOLECULES
.
181
5.3
DECAY
DYNAMICS
.
187
5.3.1
PHYSISORBED
MOLECULES
.
188
5.3.2
CHEMISORBED
MOLECULES
.
192
5.4
DESORPTION
AND
DISSOCIATION
.
195
5.5
CONCLUSIONS
.
198
REFERENCES
.
198
CONTENTS
IX
6.
SPECTROSCOPY
AND
DYNAMICS
OF
THE
ELECTRONIC
DECAY
OF
CORE
ELECTRON
EXCITATIONS
IN
ISOLATED
AND
CHEMISORBED
MOLECULES
W.
EBERHARDT
(WITH
29
FIGURES)
.
203
6.1
DEEXCITATION
ELECTRON
SPECTROSCOPY
.
204
6.1.1
HISTORICAL
DEVELOPMENT
.
204
6.1.2
DEVELOPMENT
OF
AN
EMPIRICAL
ASSIGNMENT
.
207
6.1.3
RELATIONSHIP
BETWEEN
PHOTOEMISSION
AND
DES
.
210
6.2
PROBING
THE
LOCAL
ELECTRONIC
STRUCTURE
AND
RESPONSE
.
213
6.2.1
DEEXCITATION
.
213
6.2.2
BASIC
PARAMETERS
OF
THE
SPECTATOR
SHIFT
.
219
6.3
A
DETAILED
PROBE
OF
ELECTRON
CORRELATION
.
221
6.3.1
THE
DIFFERENCE
BETWEEN
N*
AND
RYDBERG
EXCITATIONS
IN
N
2
.
221
6.3.2
THRESHOLD
BEHAVIOUR
IN
CO
2
:
'
THERE
IS
NO
THRESHOLD
AT
THE
XPS-THRESHOLD
'
.
227
6.3.3
IDENTIFICATION
OF
THE
PRIMARY
EXCITATION
THROUGH
THE
DECAY
SPECTRA
(O
2
)
.
233
6.4
DYNAMICS
OF
CORE-ELECTRON-EXCITED
STATES
.
239
6.4.1
COHERENCE
AND
INTERFERENCE
.
239
6.4.2
THEORETICAL
DESCRIPTION
OF
THE
INTERFERENCE
PROFILES
.
240
6.4.3
VIBRATIONAL
RESOLUTION
IN
EXCITATION
AND
DECAY
(N
2
)
.
245
6.4.4
TIME
DEVELOPMENT
OF
THE
EIGENSTATES
ON
THE
FS
TIME
SCALE
(O
2
)
.
249
6.5
DIRECT
OBSERVATION
OF
CHARGE
TRANSFER
*
AND
SCREENING
PROCESSES
.
253
6.5.1
DEEXCITATION
OF
TRANSITION
METAL
CARBONYLS
AND
CO
CHEMISORBED
ON
SURFACES
.
253
6.6
SUMMARY
AND
OUTLOOK
.
258
REFERENCES
.
260
7.
SYNCHROTRON
RADIATION
IN
THE
FAR
INFRARED:
INFRARED
REFLECTION
ABSORPTION
SPECTROSCOPY
F.M.
HOFFMANN
AND
G.P.
WILLIAMS
(WITH
18
FIGURES)
.
263
7.1
IR
SPECTROSCOPY
AT
SURFACES
.
264
7.2
SYNCHROTRON
RADIATION
IN
THE
FAR
INFRARED
.
267
7.3
EXAMPLES
.
272
7.3.1
RESONANT
ADSORBATE-SUBSTRATE
INTERACTIONS
FOR
CO
ADSORBED
ON
CU(100)
.
272
7.3.2
POTASSIUM
-
OXYGEN
BOND
FORMATION
.
279
7.4
CONCLUSION
-
OUTLOOK
.
283
REFERENCES
.
284
INDEX
OF
MOLECULES
AND
ADSORBATE
SYSTEMS
.
287
SUBJECT
INDEX
.
289 |
| any_adam_object | 1 |
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| id | DE-604.BV009758944 |
| illustrated | Illustrated |
| indexdate | 2024-08-14T01:21:16Z |
| institution | BVB |
| isbn | 354058031X 038758031X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006455543 |
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| owner | DE-355 DE-BY-UBR DE-703 DE-384 DE-12 DE-29T DE-91G DE-BY-TUM DE-526 DE-634 DE-83 DE-188 |
| owner_facet | DE-355 DE-BY-UBR DE-703 DE-384 DE-12 DE-29T DE-91G DE-BY-TUM DE-526 DE-634 DE-83 DE-188 |
| physical | XII, 290 S. zahlr. graph. Darst. |
| publishDate | 1995 |
| publishDateSearch | 1995 |
| publishDateSort | 1995 |
| publisher | Springer |
| record_format | marc |
| series | Springer series in surface sciences |
| series2 | Springer series in surface sciences |
| spelling | Applications of synchrotron radiation high-resolution studies of molecules and molecular adsorbates on surfaces W. Eberhardt (ed.). With contributions by A. M. Bradshaw ... Berlin [u.a.] Springer 1995 XII, 290 S. zahlr. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in surface sciences 35 Adsorption Molecular dynamics Surface chemistry Surfaces (Physics) Synchrotron radiation Industrial applications Festkörperoberfläche (DE-588)4127823-9 gnd rswk-swf Synchrotronstrahlung (DE-588)4184235-2 gnd rswk-swf Molekülspektroskopie (DE-588)4128850-6 gnd rswk-swf Adsorbat (DE-588)4141453-6 gnd rswk-swf Festkörperoberfläche (DE-588)4127823-9 s Adsorbat (DE-588)4141453-6 s Synchrotronstrahlung (DE-588)4184235-2 s DE-604 Molekülspektroskopie (DE-588)4128850-6 s Eberhardt, Wolfgang Sonstige oth Bradshaw, A. M. Sonstige oth Springer series in surface sciences 35 (DE-604)BV000600785 35 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006455543&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Applications of synchrotron radiation high-resolution studies of molecules and molecular adsorbates on surfaces Springer series in surface sciences Adsorption Molecular dynamics Surface chemistry Surfaces (Physics) Synchrotron radiation Industrial applications Festkörperoberfläche (DE-588)4127823-9 gnd Synchrotronstrahlung (DE-588)4184235-2 gnd Molekülspektroskopie (DE-588)4128850-6 gnd Adsorbat (DE-588)4141453-6 gnd |
| subject_GND | (DE-588)4127823-9 (DE-588)4184235-2 (DE-588)4128850-6 (DE-588)4141453-6 |
| title | Applications of synchrotron radiation high-resolution studies of molecules and molecular adsorbates on surfaces |
| title_auth | Applications of synchrotron radiation high-resolution studies of molecules and molecular adsorbates on surfaces |
| title_exact_search | Applications of synchrotron radiation high-resolution studies of molecules and molecular adsorbates on surfaces |
| title_full | Applications of synchrotron radiation high-resolution studies of molecules and molecular adsorbates on surfaces W. Eberhardt (ed.). With contributions by A. M. Bradshaw ... |
| title_fullStr | Applications of synchrotron radiation high-resolution studies of molecules and molecular adsorbates on surfaces W. Eberhardt (ed.). With contributions by A. M. Bradshaw ... |
| title_full_unstemmed | Applications of synchrotron radiation high-resolution studies of molecules and molecular adsorbates on surfaces W. Eberhardt (ed.). With contributions by A. M. Bradshaw ... |
| title_short | Applications of synchrotron radiation |
| title_sort | applications of synchrotron radiation high resolution studies of molecules and molecular adsorbates on surfaces |
| title_sub | high-resolution studies of molecules and molecular adsorbates on surfaces |
| topic | Adsorption Molecular dynamics Surface chemistry Surfaces (Physics) Synchrotron radiation Industrial applications Festkörperoberfläche (DE-588)4127823-9 gnd Synchrotronstrahlung (DE-588)4184235-2 gnd Molekülspektroskopie (DE-588)4128850-6 gnd Adsorbat (DE-588)4141453-6 gnd |
| topic_facet | Adsorption Molecular dynamics Surface chemistry Surfaces (Physics) Synchrotron radiation Industrial applications Festkörperoberfläche Synchrotronstrahlung Molekülspektroskopie Adsorbat |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006455543&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000600785 |
| work_keys_str_mv | AT eberhardtwolfgang applicationsofsynchrotronradiationhighresolutionstudiesofmoleculesandmolecularadsorbatesonsurfaces AT bradshawam applicationsofsynchrotronradiationhighresolutionstudiesofmoleculesandmolecularadsorbatesonsurfaces |