The chemistry of the fullerenes:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | German |
| Published: |
Stuttgart u.a.
Thieme
1994
|
| Series: | Thieme organic chemistry monograph series
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 203 S. graph. Darst. |
| ISBN: | 3131368012 |
Staff View
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Record in the Search Index
| _version_ | 1804124016968990720 |
|---|---|
| adam_text | THE CHEMISTRY OF THE FUUERENES ANDREAS HIRSCH UNIVERSITY OF TUEBINGEN
GEORG THIEME VERLAG STUTTGART * NEW YORK 1994 CONTENTS CHAPTER 1 THE
PARENT FULLERENES 1 1.1 THE FULLERENES: MOLECULAR AETIOTROPES OF CARBON 2
1.2 THE DISCOVERY OF THE FULLERENES 5 1.3 FULLERENE PRODUCTION 7 1.3.1
FULLERENE GENERATION BY VAPORIZATION OF GRAPHITE 7 1.3.1.1 RESITIVE
HEATING OF GRAPHITE ...7 13.1.2 ARE HEATING OF GRAPHITE 10 13.1.3 SOLAR
GENERATORS 10 13.1.4 INDUCTIVE HEATING OF GRAPHITE 11 1.3.2 FULLERENE
SYNTHESIS IN COMBUSTION 11 1.3.3 FORMATION OF FULLERENES BY PYROLYSIS OF
NAPHTHALENE 12 1.3.4 ENDOHEDRALS 12 1.3.5 THE FORMATION PROCESS 15 1.4
SEPARATION AND PURIFICATION 21 1.5 PROPERTIES 25 1.5.1 STRUCTURES 25
1.5.2 PHYSICAL AND SPECTROSCOPIC PROPERTIES 29 REFERENCES 33 CHAPTER 2
REDUCTION 37 2.1 INTRODUCTION 38 2.2 FUELLENDE ANIONS 38 2.3 REDUCTIVE
ELECTROSYNTHESIS 42 2.3.1 ELECTROCRYSTALLIZATION 42 2.3.2 ELECTROPHILIC
ADDITIONS TO FUELLENDE ANIONS 43 2.4 REDUCTION WITH METALS 44 2.4.1
ALKALI METAL FUELLENDES 44 2.4.1.1 GENERATION IN SOLUTION AND QUENCHING
EXPERIMENTS 44 2.4.1.2 SYNTHESIS AND PROPERTIES OF ALKALI METAL FUELLENDE
SOLIDS 45 2.4.2 ALKALINE EARTH METAL FULLERIDES 50 2.4.3 REDUCTION WITH
MERCURY 51 2.5 REDUCTION WITH ORGANIC DONOR MOLECULES 51 REFERENCES 53
CHAPTER 3 NUCLEOPHILIC ADDITIONS 56 3.1 INTRODUCTION 57 3.2 ADDITION OF
CARBON NUCLEOPHILES 57 3.2.1 HYDROALKYLATION AND HYDROARYLATION OF CG 0
AND C70 57 3.2.2 LANGMUIR - BLODGETT FILMS OF C 60 HF-BU 63 X CONTENTS
3.2.3 ADDITION OF MACROMOLECULAR CARBANIONS - FUUERENE POLYMERS 64 3.2.4
CYCLOPROPANATION OF C^N AND C70 66 3.3 ADDITION OF AMINES 73 3.4
ADDITION OF HYDROXIDE 76 REFERENCES 77 CHAPTER4 CYCLOADDITIONS 79 4.1
INTRODUCTION 80 4.2 [4+2] CYCLOADDITIONS 80 4.3 [3+2] CYCLOADDITIONS 87
4.3.1 ADDITION OF DIAZOMETHANES, DIAZOACETATES AND DIAZOAMIDES 87 4.3.2
ADDITION OF AZIDES 99 4.3.3 ADDITION OFTRIMETHYLENEMETHANES 99 4.3.4
ADDITION OF AZOMETHINE YLIDES 103 4.3.5 ADDITION OFNITRILE OXIDES 105
4.3.6 ADDITION OF SULFINIMIDES 106 4.3.7 ADDITION OF DISILIRANES 106 4.4
[2+2] CYCLOADDITIONS 10 7 4.4.1 ADDITION OF BENZYNE 107 4.4.2 ADDITION
OF ENONES 107 4.4.3 ADDITION OF QUADRICYCLANE 108 4.4.4 ADDITION OF
ELECTRON RIEH ALKYNES ? 109 4.4.5 PHOTOPOLYMERIZATION OF COEO 110 4.5
[2+1] CYCLOADDITIONS 111 4.5.1 ADDITION OF CARBENES 111 4.5.2 ADDITION
OF SILYLENES 111 REFERENCES 112 CHAPTERS HYDROGENATION 115 5.1
INTRODUCTION 116 5.2 OLIGOHYDROFULLERENES C5OH 2N AND C7OH 2N (N = 1 -
6) 116 5.2.1 HYDROGENATION VIA HYDROBORATION, HYDROZIRCONATION AND
ZINC/ACID REDUCTION 117 5.2.2 THEORETICAL INVESTIGATIONS 119 5.3
POLYHYDROFULLERENES C^TYN AND C 70 H 2N (N = 7 - 70) 125 5.3.1 BIRCH -
HUECKEL REDUCTION 125 5.3.2 TRANSFER HYDROGENATION OF CGQ AND C70 127
5.3.3 CATALYTIC HYDROGENATION 129 5.3.4 THEORETICAL INVESTIGATIONS 129
REFERENCES 134 CHAPTER 6 RADICAL ADDITIONS 136 6.1 INTRODUCTION 137 6.2
ESR INVESTIGATIONS OF RADICAL ADDITIONS 137 CONTENTS XI 6.2.1 ADDITION
OF SINGLE RADICALS 137 6.2.2 MULTIPLE RADICAL ADDITIONS 143 6.3
METALATION OF C^O WITH PENTACARBONYLRHENIUM RADICALS 146 6.4
HYDROSTANNYLATION OF CGG 147 6.5 ADDITION OF
BIS(TRIFLUOROMETHYL)NITROXIDE 147 6.6 RADICAL COPOLYMERIZATION OF CGO
AND PARACYCLOPHANE 147 REFERENCES 148 CHAPTER 7 TRANSITION METAL COMPLEX
FORMATION 150 7.1 INTRODUCTION 151 7.2 (TI 2 -COEO) TRANSITION METAL
COMPLEXES 151 7.3 HYDROMETALATION REACTIONS 159 7.4 ORGANOPALLADIUM
POLYMERS OF CGO 160 REFERENCES 160 CHAPTER 8 OXIDATION AND REACTIONS
WITH ELECTROPHILES 162 8.1 INTRODUCTION 163 8.2 ELECTROCHEMICAL
OXIDATION OF CGO AND C70 163 8.3 OXYGENATION 163 8.4 OSMYLATION 166 8.5
HALOGENATION 172 8.5.1 FLUORINATION 172 8.5.2 CHLORINATION 175 8.5.3
BROMINATION 177 8.5.4 REACTION WITH IODINE 180 8.6 REACTIONS WITH STRONG
OXIDIZING REAGENTS AND ACIDS 180 8.7 REACTION WITH LEWIS ACIDS AND
FULLERENATION OF AROMATICS 182 REFERENCES 183 CHAPTER 9 PRINCIPLES AND
PERSPECTIVES OF FULLERENE CHEMISTRY 185 9.1 INTRODUCTION 186 9.2
REACTIVITY 186 9.3 REGIOCHEMISTRY OF ADDITION REACTIONS 190 9.4 THE
FUTUREOF FULLERENE CHEMISTRY 195 9.4.1 MULTIPLE ADDITION PRODUCTS WITH A
DEFINED THREE-DIMENSIONAL STRUCTURE 195 9.4.2 HETEROFULLERENES 196 9.4.3
RING-OPENING AND DEGRADATION REACTIONS - SYNTHESIS OF ENDOHEDRALS 196
9.4.4 CHEMISTRY WITH HIGHER FULLERENES 197 9.5 PERSPECTIVES FOR
PRACTICAL APPLICATIONS 197 9.6 CONCLUDING REMARKS 199 REFERENCES 200
INDEX 202
|
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| author | Hirsch, Andreas 1960- |
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| dewey-ones | 546 - Inorganic chemistry |
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| discipline | Chemie / Pharmazie Physik Chemie |
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| id | DE-604.BV009671449 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:38:58Z |
| institution | BVB |
| isbn | 3131368012 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006396586 |
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| physical | 203 S. graph. Darst. |
| publishDate | 1994 |
| publishDateSearch | 1994 |
| publishDateSort | 1994 |
| publisher | Thieme |
| record_format | marc |
| series2 | Thieme organic chemistry monograph series |
| spelling | Hirsch, Andreas 1960- Verfasser (DE-588)123898269 aut The chemistry of the fullerenes Andreas Hirsch Stuttgart u.a. Thieme 1994 203 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Thieme organic chemistry monograph series Fullerenes Fullerene (DE-588)4305238-1 gnd rswk-swf Fullerene (DE-588)4305238-1 s DE-604 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006396586&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hirsch, Andreas 1960- The chemistry of the fullerenes Fullerenes Fullerene (DE-588)4305238-1 gnd |
| subject_GND | (DE-588)4305238-1 |
| title | The chemistry of the fullerenes |
| title_auth | The chemistry of the fullerenes |
| title_exact_search | The chemistry of the fullerenes |
| title_full | The chemistry of the fullerenes Andreas Hirsch |
| title_fullStr | The chemistry of the fullerenes Andreas Hirsch |
| title_full_unstemmed | The chemistry of the fullerenes Andreas Hirsch |
| title_short | The chemistry of the fullerenes |
| title_sort | the chemistry of the fullerenes |
| topic | Fullerenes Fullerene (DE-588)4305238-1 gnd |
| topic_facet | Fullerenes Fullerene |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006396586&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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