Environmental sampling for trace analysis:
Gespeichert in:
Format: | Buch |
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Sprache: | English |
Veröffentlicht: |
Weinheim [u.a.]
VCH
1994
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XXX, 524 S. Ill., graph. Darst. |
ISBN: | 3527300511 |
Internformat
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245 | 1 | 0 | |a Environmental sampling for trace analysis |c ed. by Bernd Markert |
264 | 1 | |a Weinheim [u.a.] |b VCH |c 1994 | |
300 | |a XXX, 524 S. |b Ill., graph. Darst. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
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Datensatz im Suchindex
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adam_text | Contents
List of Contributors XXVII
Parti: Historical Aspects 1
1 History of Sampling Demonstrated on the Ore Mining In-
dustry — Empirical and Theoretical Approaches 3
G. Kraft
Part II: General Aspects 9
2 General Aspects of Environmental Sampling 11
P. Hoffmann
2.1 Introduction 11
2.2 Terms and Definitions 12
2.3 Aspects of Sampling 13
2.3.1 Location, Place, and Position of Sample Removal 13
2.3.2 Size, Quantity, and Volume of the Sample 14
2.3.3 Number of Samples to be Taken 14
2.3.4 Time, Duration, and Frequency of Sampling 15
2.3.5 Homogeneity of the Sample 16
2.3.6 Contamination of the Sample 17
2.3.7 Losses in the Sample 18
2.3.8 Sample Storage and Conservation 19
2.4 Guidelines and Norms 19
2.4.1 Quality Assurance 20
2.4.2 Environmental Protection 21
2.5 References 22
2.6 Appendix 23
3 Trace Elements Need Trace Analysis 73
/. Pais
3.1 Problems of Trace Element Analysis 73
3.1.1 Introduction 73
3.1.2 Problems of Biological Analysis 74
3.1.3 Indicator Organs in Biological Evaluation 76
3.2 The Importance of Trace Elements 77
3.2.1 Introduction 77
3.2.2 Criteria of Essentiality and Beneficiality 80
XIV Contents
3.2.3 Criteria of Toxicity 81
3.2.4 Changes in Element Concentrations 83
3.2.5 The Importance of Trace Elements in the Environment 84
3.2.6 Interactions between Different Elements 86
3.2.7 The Importance of Interdisciplinary Trace Element
Research 88
3.3 References 89
4 Error Estimation in Environmental Sampling and Analysis 93
M. H. Ramsey
4.1 Introduction 93
4.2 Basic Concepts and Terminology 93
4.3 Sampling Error in Context 95
4.4 Methods for Estimating Quality of Measurements 96
4.4.1 Measuring Analytical Precision 96
4.4.2 Measuring Sampling Precision 99
4.4.3 Targets for Acceptable Levels of Precision in Sampling and
Analysis 102
4.4.4 Measuring Analytical Bias 103
4.4.5 Estimating Sampling Bias 105
4.5 Targets for Acceptable Levels of Bias in Sampling and Analy-
sis 106
4.6 Conclusions 107
4.7 References 107
5 Estimation with Varying Detection Limits 109
W. G. Warren
5.1 Introduction 109
5.2 Methodology 110
5.2.1 The One-Dimensional Case 110
5.2.2 The Bivariate Case 112
5.3 Examples 113
5.4 Discussion 118
5.5 References 118
5.6 Appendix 118
Part III: Examples for Sampling 123
A. Air 123
6 Particle and Gas Measurements on Filters 125
J. G. Watson, J. C. Chow
6.1 Introduction 125
6.2 Filter Analysis Methods 126
Outline XV
6.2.1 Mass 126
6.2.2 Elements 129
6.2.3 Water Soluble Ions 130
6.2.4 Organic and Elemental Carbon 132
6.3 Filter Media 134
6.4 Aerosol Sampling Systems 140
6.4.1 Size-Selective Inlets 142
6.4.2 Sampling Surfaces 146
6.4.3 Filter Holders 146
6.4.4 Pumps and Flow Controllers 147
6.4.5 Sampler Configurations 148
6.5 Sampling and Analysis Procedures 150
6.6 Summary 152
6.7 References 153
7 Organic Gas Sampling 163
B. Zielinska, E. Fujita
7.1 Introduction 163
7.2 Whole-Air Sampling 163
7.2.1 Sampling Media Selection and Preparation 164
7.2.2 Sampling 165
7.2.3 Storage and Transport 167
7.3 Preconcentration Methods 168
7.3.1 Preconcentration on Nonselective Solid Adsorbents 168
7.3.1.1 Sampling Media Selection and Preparation 168
7.3.1.2 Sampling 172
7.3.1.3 Storage and Transport 172
7.3.2 Selective Methods of Compound Preconcentration 172
7.3.2.1 Sampling Media Selection and Preparation 173
7.3.2.2 Sampling 175
7.3.2.3 Storage and Transport 175
7.4 Semi-Volatile Organic Compounds 175
7.5 Passive Sampling Techniques 177
7.6 Summary 178
7.7 References 181
B. Water 185
8 Sampling of Freshwaters for Estimation of all Detectable
Elements 187
U. M. Cowgill
8.1 Introduction 187
8.2 Problems Associated with Sampling 187
XVI Outline
8.2.1. Contamination from Sampling Devices and Laboratory Equip-
ment 188
8.2.2 Sorption and Leaching of Pollutants by Sampling Tool Mate-
rials 189
8.2.3 Replication 190
8.2.4 Frequency of Sampling 192
8.2.5 Equipment, Field, and Sampling Blanks 193
8.3 Sample Fractions and Sample Preservation 194
8.3.1 Preservation of Samples 194
8.3.2 Pretreatment, Storage, and General Precautions 194
8.4 Sampling of Lakes, Rivers, and Groundwater 196
8.4.1 Stratified Bodies of Water 196
8.4.2 Unstratified Bodies of Water 196
8.5 Sampling on Ice, Snow, Rain, Dew, and Fog 198
8.6 References 201
9 Guidelines for Sampling Freshwater for Eutrophication Ma-
nagement Programs 203
H. Klapper, W. Rast, D. Uhlmann
9.1 Introduction 203
9.2 What to Sample 203
9.3 Necessary Temporal and Spatial Resolution for Data 206
9.3.1 Where to Sample 206
9.3.2 When to Sample 209
9.3.3 Sampling Strategies in Waterbodies with Longitudinal Water
Quality Gradients 210
9.4 Calculating the Costs of Sample Collection 213
9.5 Compilation and Presentation of Data 218
9.6 References 220
10 The Sampling Strategy in the River Elbe — Experiences 223
H. Guhr, E. Weber
10.1 Characteristics of the River Elbe 223
10.1.1 Types of Use 223
10.1.2 Pollution Loads 223
10.1.2.1 Municipal Sewage Discharges 226
10.1.2.2 Discharges from Agriculture 227
10.1.3 Characteristics of Water Quality 227
10.2 Development of a Monitoring Strategy for the River Elbe —
Objectives 228
10.2.1 Selection of Sampling Points 229
10.2.2 Range of Measured Variables 230
10.2.3 Measuring Frequency 231
Outline XVII
10.2.4 Use of Automatic Monitoring Stations 231
10.2.5 Data Flow, Data Processing, and Evaluation 232
10.2.6 Special Investigations 233
10.3 Experience Made in Implementing the Sampling Strategy —
Representativeness of Sampling Points 234
10.3.1 Frequency of Measurements 235
10.3.2 Data Collection 237
10.3.2.1 Sampling 237
10.3.2.2 Preparation and Preservation of Samples 240
10.3.2.3 Chemical Analysis 240
10.3.2.4 Measuring Errors 241
10.3.3 Consideration of Sewage Discharges 243
10.3.4 Data Processing and Evaluation 245
10.4 Conclusions 247
10.5 References 247
11 Sampling Treated Wastewaters and Receiving Streams 249
J. E. Norris
11.1 Introduction 249
11.2 Sediment Sampling 249
11.3 Fish Sampling 250
11.4 Sampling of Industrial Wastewater Discharges 251
11.5 Sampling of Surface Waters: Receiving Streams 253
11.6 References 254
12 Water and Wastewater Sampling for Environmental Analy-
sis 255
E. M. Dick
12.1 Introduction 255
12.2 Why Sample Water? 255
12.3 Elements of the Sampling Plan 256
12.3.1 Sampling Objective 256
12.3.2 Sampling Location 257
12.3.3 Sample Types and Collection Techniques 257
12.3.4 Sampling Equipment 257
12.3.5 Sample Containers and Sample Preservation 258
12.3.6 Sample Labeling and Shipping 258
12.3.7 Types of Analyses 258
12.3.8 Chain-of-Custody Documentation 258
12.3.9 Quality Assurance and Quality Control 259
12.4 Types of Samples 259
12.5 Sampling Programs 261
12.6 Sampling Equipment 262
XVIII Outline
12.6.1 Power Source 264
12.6.2 Electronic Controller 264
12.6.3 Sample Intake 265
12.6.4 Sample Transport Line 265
12.6.5 Sample Storage 266
12.6.6 Sample Delivery System 268
12.7 Pumps and Representative Samples
12.7.1 Peristaltic Pumps 269
12.7.2 Vacuum Pumps 270
12.7.3 Bladder Pumps 271
12.8 Advancements in Sampling 272
12.8.1 Volatile Organic Sampling 272
12.8.2 Sample Volume Accuracy 272
12.8.3 Refrigeration 273
12.9 Preserving Sample Integrity 274
12.9.1 Sampling Equipment 274
12.9.2 Sampling Containers 275
12.9.3 Sample Handling 275
12.9.4 Sample Preservation 275
12.9.5 Sample Holding Time 275
12.9.6 On-Site Analysis 276
12.10 Conclusion 278
269
13 Sampling of Groundwater for General Quality
Monitoring 279
V. Schenk
13.1 Introduction 279
13.2 Sampling of Groundwater 279
13.2.1 Requirements for Sampling Sites 279
13.2.2 Sampling Equipment for Groundwater 281
13.3 Activities at the Sampling Site 282
13.3.1 Determinations and Preservations 282
13.3.2 Transport and Storage 283
13.4 Sampling Programs and Contents of Analyses 283
13.5 Interpretation 285
13.6 Conclusions 285
14 Groundwater Sampling for Metals 287
R. W. Puls
14.1 Introduction 287
14.2 Sampling Objectives 287
14.3 Sampling Point Design 288
14.4 Monitoring Well Development 289
Outline XIX
14.5 Colloidal Transport 290
14.6 Well Turbidity 291
14.7 Sampling Preparation 293
14.8 Purging and Sampling 294
14.8.1 Low Flow Purging 294
14.8.2 Isolation of the Sampling Zone 295
14.8.3 Water Quality Indicator Parameters 296
14.8.4 Sampling Materials 298
14.9 Filtration and Analysis 298
14.10 Summary 299
14.11 References 300
C. Soils and Sediments 303
15 Representative Soil Sampling 305
O. Franzle
15.1 Selection of Representative Soil Samples 305
15.1.1 Methodology of Statistical Design 305
15.1.2 Small-Scale Variability of European Soils in the Light of
Frequency Statistics 306
15.1.2.1 Determination of Regionally Representative Soils in Germany
by Means of Crosstabulation and Neighborhood Analysis 306
15.1.2.2 Selection of Representative European Soils for Sorption-
Testing Purposes 309
15.1.3 Large-Scale Soil Variability in the Light of Variogram Analy-
sis 310
15.1.3.1 Variogram Analysis 311
15.1.3.2 Model Applications of Variogram Analysis 315
15.2 Conclusions 319
15.3 Summary 319
15.4 References 320
16 Problems and Results in the Development of International
Standards for Sampling and Pretreatment of Soils 321
A. Paetz, B. Crofimann
16.1 Introduction 321
16.2 What is Soil? 322
16.3 Soil Sampling Objectives 323
16.4 Requirements on Sampling 323
16.5 Preliminary Investigation 325
16.6 Selection of Sampling Patterns 325
16.7 Sampling Depth 327
16.8 Sample Quantity 328
XX Outline
16.9 Single Sample or Composite Samples 328
16.10 Preservation of Soil Samples 329
16.11 Use of Appropriate Sampling Tools and Containers 329
16.12 Sampling Report 330
16.13 Quality Control 330
16.14 Pretreatment of Soil Samples 331
16.15 Summary 333
16.16 References 333
17 Fixed and Hypothesis-Guided Soil Sampling Methods —
Principles, Strategies, and Examples 335
R. W. Scholz, N. Nothbaum, T. W. May
17.1 Introduction 335
17.2 Fixed Sampling Plans/Grid Plans 338
17.3 Soil Sampling Plans Guided by Hypotheses 342
17.4 The IHEARU Schema 343
17.5 Conclusions 344
17.6 References 345
18 Sampling for Trace Analysis of Lake Sediments 347
U. M. Cowgill
18.1 Introduction 347
18.2 Sampling Devices 348
18.2.1 Grab Samplers 349
18.2.2 Corers 352
18.2.3 Sampling Devices for the Collection of Suspended Sedi-
ments 355
18.2.4 Mud-Water Interface Samplers 355
18.2.5 Sediment Pore Water Sampling 356
18.3 Subsampling of Sediment Grabs and Cores 358
18.4 Quality Control 359
18.5 Statistical Considerations 361
18.6 References 362
19 Sampling Design for Studying the Relationships between Heavy
Metals in Soils. Sediments, and Discharged Wastewaters 365
Zueng-Sang Chen
19.1 Introduction 365
19.2 Case I: Studies of Rice-Growing Soils near Chemical
Plants 365
19.2.1 Principles of Sampling Design 365
19.2.2 Sampling Methods 367
19.2.2.1 Soil Sampling 367
19.2.2.2 Sampling Design for Water and Sediments 368
Outline XXI
19.2.3 Analytical Methods 368
19.2.4 The Distribution of Heavy Metals in Soils, Discharged Water,
and Sediments 368
19.2.5 The Relationship between Heavy Metals in Soils, Discharged
Water, and Sediments 371
19.3 Case II: Studies of Rice-Growing Soils near an Industrial
Park 372
19.3.1 Principles of Sampling Design 372
19.3.2 Sampling Methods 373
19.3.2.1 Soil Sampling 373
19.3.2.2 Sampling Design of Water and Sediments 373
19.3.3 Analytical Methods 373
19.3.4 The Distribution of Heavy Metals in Soils, Discharged Water,
and Sediments 374
19.3.5 The Relationship between Heavy Metals in Soils, Discharged
Water, and Sediments 376
19.4 Conclusions 377
19.5 References 377
D. Plants and Animals 379
20 Sampling of Plants for Environmental Trace Analysis in
Terrestrial, Semiterrestrial and Aquatic Environments 381
W. H. O. Ernst
20.1 Introduction 381
20.2 What Do we Want to Know? 381
20.3 Are Trace Elements Relevant Objectives? 382
20.4 The Exploration of Environmental Compartments 384
20.4.1 The Hygro- and Hydrophytes 384
20.4.2 The Epiphytes 385
20.4.3 Soil Exploring Plants 386
20.5 Plant Parts and Life History 388
20.6 Conclusion 390
20.7 References 391
21 On the Sampling of Vascular Plants for Monitoring of Heavy
Metal Pollution 395
R. Djingova, I. Kuleff
21.1 Introduction 395
21.2 Concentration Differences at Biological Levels 396
21.3 Seasonal Variations in the Heavy Metal Content of
Plants 401
XXII Outline
403
21.4 Sample Pretreatment
21.5 Discussion 410
21.6 References 412
22 Sampling of Terricolous Lichen and Moss Species for Trace
Element Analysis, with Special Reference to Bioindication of
Air Pollution 415
Z. Tuba, Z. Csintalan, Z. Nagy, K. Szente, Z. Takdcs
22.1 Introduction 415
22.2 Materials and Methods 417
22.2.1 The Species of Investigation 417
22.2.2 The Original Habitat 417
22.2.3 The Cryptogam Transplantation Technique 417
22.2.4 Exposition 418
22.2.5 Sampling 418
22.2.6 Preparation of the Samples for Measuring Trace Element
Contents 419
22.2.7 Element Analysis 419
22.2.8 Data Analysis 419
22.3 Results and Discussion 419
22.3.1 Vertical Distribution of Trace Elements within the Various
Lichen and Moss Parts 419
22.3.2 Horizontal Distribution of Trace Elements within the Thalli
of C. furcata and the Cushions of T. ruralis 423
22.3.3 Distribution of Trace Element Contents in Parts of the Lichen
Thalli and Moss Cushions Compared to Whole Thalli and
Cushions, Respectively 424
22.3.4 Variability of the Trace Element Contents in the Lichen Thalli
and Moss Cushions 426
22.3.5 Trace Element Contents in the Soil Substrate of the Lichen
Thalli and Moss Cushions 426
22.3.6 The Influence of Sample Washing on Trace Element Con-
tents 429
22.4 Summary 431
22.5 References 433
23 Comparative Investigation of the Distribution of Chemical
Elements in an Aceri tatarico-Quercetum Plant Community
and in Stands of Cultivated Plants 435
M. Kovacs, K. Penksza, G. Turcsanyi, L. Kaszab, S. Toth, P.
Szoke
23.1 Introduction 435
23.2 Material and Methods 435
23.3 Results and Discussion
23.4 Summary 442
23.5 References 442
Outline XXIII
436
24 Sampling of Tropical Terrestrial Plants with Particular Refe-
rence to the Determination of Trace Elements 443
R. Jayasekera
24.1 Introduction 443
24.2 Statistical Aspects 444
24.3 Plant Sampling 444
24.4 Concluding Remarks 447
24.5 References 447
25 Sampling in the Stemflow and Throughfall Areas of Fo-
rests 449
G. Turcsdnyi, K. Penksza, I. Siller, E. Fiihrer, S. Toth, M.
Kovacs, S. Biittner
25.1 Introduction 449
25.2 Literature Data 449
25.2.1 The Amount of Stemflow and Throughfall in Stands of
Different Tree Species 449
25.2.2 Chemical Composition of Stemflow and Throughfall 451
25.2.3 Physical Changes in Soils Due to Stemflow 452
25.2.4 Chemical Changes in Soils Due to Stemflow 452
25.2.5 Living Organisms Influenced by Stemflow 453
25.2.5.1 Microorganisms 453
25.2.5.2 Fungi 453
25.2.5.3 Mosses and Lichens 454
25.2.5.4 Other Plants 454
25.2.6 Impact of Stemflow on the Roots of Trees 454
25.2.7 Impact of Stemflow on Animals 454
25.2.8 Some Contradictions 455
25.3 Material and Methods 455
25.4 Results and Discussion 456
25.5 Conclusions 459
25.6 References 460
26 Sampling of Different Social Categories of Red Wood Ants
(Formica s. str.) for Biomonitoring 465
V. Maavara, A.-J. Martin, A. Oja, P. Nuorteva
26.1 The Role of Ants in Nature 465
26.2 Pollutant Accumulation in Ants 466
26.3 Definition of the Red Wood Ants 468
XXIV Outline
26.4 Structure of the Nests and Territories 469
26.4.1 The Nest Mound 469
26.4.2 The Base of the Nest 470
26.4.3 The Underground Part of the Nest 470
26.4.4 The Foraging Territory 471
26.4.5 Super- and Substructures 471
26.5 Social Structure of Ant Colonies 472
26.5.1 Sexuals 472
26.5.2 Workers 473
26.5.2.1 Reserve Workers 473
26.5.2.2 Nurses 474
26.5.2.3 Inside Workers 474
26.5.2.4 Outside Workers 475
26.6 Sampling 475
26.6.1 What Kind of Nest Mounds is Suitable for Sampling? 475
26.6.2 Sample Taking 476
26.6.3 Sampling Objects 477
26.6.3.1 Foragers Leaving the Nest 477
26.6.3.2 Foragers Traveling to the Nest 477
26.6.3.3 Surface Workers from the Top of the Nest 477
26.6.3.4 Workers and Brood from the Brood Chamber 478
26.6.3.5 Reserve Ants 478
26.6.3.6 Nest Material 478
26.6.4 Collection of Background Data and the Order of Samp-
ling 479
26.6.4.1 Traffic Density of Foragers on Ant Roads 479
26.6.4.2 Ant Activity on the Nest Surface 479
26.6.4.3 Temperature of the Nest 479
26.6.4.4 Sample Taking from Ant Roads 479
26.6.4.5 Measuring the Size of the Nest Mound 480
26.6.4.6 Sampling from the Nest 480
26.7 Feeding Experiments 480
26.7.1 Honey as a Feeding Substrate 480
26.7.2 Fish as a Feeding Substrate 481
26.8 Description of some Pilot Studies already Performed 481
26.8.1 Natural Cd Levels in Different Castes and Worker
Groups 481
26.8.2 Cd Transfer to Ant Colonies under Pollution
Stress 483
26.8.3 Artificial Cadmium Feeding Experiments 483
26.8.4 Effects of Metal Pollution on the Enzyme Balance 486
26.9 References 486
Outline XXV
Part IV: Literature Survey 491
27 Overview of References for Sampling and Related Topics 493
S. Hannappet
27.1 Introduction 493
27.2 Literature 493
27.2.1 General Aspects 493
27.2.2 Statistical Methodology 495
27.2.3 Air 498
27.2.4 Water 499
27.2.5 Soils, Sediments, Sludges, Rocks and Mining 503
27.2.6 Biota 504
27.2.7 Waste, Sewage, Sludge 507
27.3 Norms by the International Organization of Standardization
in Geneva 507
27.3.1 Air 507
27.3.2 Water 508
27.3.3 Soil and Mining 508
27.3.4 Biota 509
Index 511
|
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discipline | Chemie / Pharmazie Allgemeines Biologie Chemie Bauingenieurwesen Umwelt |
format | Book |
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id | DE-604.BV009671447 |
illustrated | Illustrated |
indexdate | 2024-07-09T17:38:58Z |
institution | BVB |
isbn | 3527300511 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006396585 |
oclc_num | 844309619 |
open_access_boolean | |
owner | DE-M347 DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-M49 DE-BY-TUM DE-703 DE-634 DE-83 |
owner_facet | DE-M347 DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-M49 DE-BY-TUM DE-703 DE-634 DE-83 |
physical | XXX, 524 S. Ill., graph. Darst. |
publishDate | 1994 |
publishDateSearch | 1994 |
publishDateSort | 1994 |
publisher | VCH |
record_format | marc |
spelling | Environmental sampling for trace analysis ed. by Bernd Markert Weinheim [u.a.] VCH 1994 XXX, 524 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Umweltanalytik (DE-588)4282985-9 gnd rswk-swf Probenahme (DE-588)4047319-3 gnd rswk-swf Spurenanalyse (DE-588)4056593-2 gnd rswk-swf Spurenanalyse (DE-588)4056593-2 s Umweltanalytik (DE-588)4282985-9 s Probenahme (DE-588)4047319-3 s DE-604 Markert, Bernd 1958- Sonstige (DE-588)115493077 oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006396585&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Environmental sampling for trace analysis Umweltanalytik (DE-588)4282985-9 gnd Probenahme (DE-588)4047319-3 gnd Spurenanalyse (DE-588)4056593-2 gnd |
subject_GND | (DE-588)4282985-9 (DE-588)4047319-3 (DE-588)4056593-2 |
title | Environmental sampling for trace analysis |
title_auth | Environmental sampling for trace analysis |
title_exact_search | Environmental sampling for trace analysis |
title_full | Environmental sampling for trace analysis ed. by Bernd Markert |
title_fullStr | Environmental sampling for trace analysis ed. by Bernd Markert |
title_full_unstemmed | Environmental sampling for trace analysis ed. by Bernd Markert |
title_short | Environmental sampling for trace analysis |
title_sort | environmental sampling for trace analysis |
topic | Umweltanalytik (DE-588)4282985-9 gnd Probenahme (DE-588)4047319-3 gnd Spurenanalyse (DE-588)4056593-2 gnd |
topic_facet | Umweltanalytik Probenahme Spurenanalyse |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006396585&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT markertbernd environmentalsamplingfortraceanalysis |