Organoboron chemistry: 2 Boron-nitrogen and boron-phosphorus compounds
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York [u.a.]
Interscience Publ.
1966
|
| Ausgabe: | 1. publ. |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XX, 568 S. Ill. |
Internformat
MARC
| LEADER | 00000nam a2200000 cc4500 | ||
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| 001 | BV009379763 | ||
| 003 | DE-604 | ||
| 005 | 19990723 | ||
| 007 | t | ||
| 008 | 940401s1966 a||| |||| 00||| eng d | ||
| 035 | |a (OCoLC)310030170 | ||
| 035 | |a (DE-599)BVBBV009379763 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-29T |a DE-20 |a DE-188 | ||
| 100 | 1 | |a Steinberg, Howard |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Organoboron chemistry |n 2 |p Boron-nitrogen and boron-phosphorus compounds |c Howard Steinberg |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a New York [u.a.] |b Interscience Publ. |c 1966 | |
| 300 | |a XX, 568 S. |b Ill. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 773 | 0 | 8 | |w (DE-604)BV009379761 |g 2 |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006224787&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-006224787 | ||
Datensatz im Suchindex
| _version_ | 1804123787638079488 |
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| adam_text | Titel: Bd. 2. Organoboron chemistry. Boron-nitrogen and boron-phosphorus compounds
Autor: Steinberg, Howard
Jahr: 1966
CONTENTS
1.
Introduction
1
I.
General
Remarks
.......
1
II.
Nomenclature
.......
2
III.
Analyses
and
Spectra
......
2
IV.
References
........
3
2.
Tri(amino)boranes
........
4
I.
Introduction
........
4
II.
Historical
........
4
III.
Properties
........
5
IV.
Methods
of
Preparations
.....
10
A.
From
Boron
Halides
......
10
1.
Tri(alkylamino)-
and
tri(arylamino)boranes
10
a.
From
boron
trichloride
and
aminohaloboranes
10
b.
From
boron
trifluoride
....
11
2.
Tris(dialkylamino)
-
and
tris(diarylamino)boranes
12
a.
From
boron
trichloride
and
aminochloroboranes
.....
12
b.
From
boron
trifluoride
....
13
c.
From
boron
tribromide
....
13
B.
From
Boron-Oxygen
Compounds
14
C.
From
Boron-Sulfur
Compounds
.
15
D.
From
Boron
Hydrides
.....
16
E.
By
Transamination
Reactions
....
16
F.
By
Disproportionation
Reactions
19
G.
From
Diboron
Compounds
....
20
H.
Preparations
of
Complex
Tri(amino)boranes
21
V.
Reactions
........
24
A.
Thermal
Stability
......
1.
Symmetrical
tri(alkylamino)-
and
tri(aryl-
24
amino)boranes
......
2.
Symmetrical
tris(dialkylamino)-
and
tris(diaryl-
24
amino)boranes
......
24
3.
Unsymmetrical
tri(amino)boranes
.
25
B.
Hydrolysis
.......
26
C.
With
Alcohols
.......
27
D.
With
Mercaptans
......
28
vii
Contents
E.
With
Amines
and
Hydrazines
....
F.
With
Hydrogen
Halides
.....
G.
With
Isocyanates
and
Isothiocyanates
.
H.
With
Boron
Compounds
.
1.
Boron
halides
......
2.
Boron-carbon
compounds
....
3.
Boron-oxygen
compounds
....
4.
Boron-sulfur
compounds
....
5.
Boron
hydrides
......
I.
Grignard
Reactions
......
J.
Miscellaneous
Reactions
...
VI.
Physical
Constants
.......
A.
Symmetrical
Tri(amino)boranes
Derived
from
Pri¬
mary
Amines
.......
B.
Symmetrical
Tri(amino)boranes
Derived
from
Secon¬
dary
Amines
.......
C.
Tri(amino)boranes
Derived
from
Cyclic
Secondary
Amines
........
D.
Unsymmetrical
or
Mixed
Tri(amino)boranes
.
E.
Complex
Tri(amino)boranes
.
.
.
.
VII.
References
.
.
.
3.
Aminoboranes
.........
I.
Introduction
........
II.
Properties
........
III.
Preparations
........
A.
Mono(amino)boranes
.....
1.
Derived
from
primary
amines
.
.
.
.
2.
Derived
from
secondary
amines
a.
Pyrolyses
of
amine-boranes
b.
From
aminodiboranes
and
other
boron
hydrides
.......
c.
From
amine
hydrochlorides
d.
From
thioboranes
.....
e.
Miscellaneous
preparations
B.
Di(amino)boranes
......
1.
Derived
from
primary
amines
....
2.
Derived
from
both
primary
and
secondary
amines
3.
Derived
from
secondary
amines
IV.
Reactions
........
A.
Mono(amino)boranes
.....
1.
Thermal
stability
......
2.
Hydrolysis
.......
3.
With
amines
.......
4.
With
boron
hydrides
.....
28
29
31
31
31
32
32
33
34
34
35
36
36
38
39
40
41
42
45
45
45
48
48
48
49
49
51
53
53
54
55
55
57
57
60
60
60
61
61
61
Contents
ix
5.
With
other
boron
compounds
...
62
6.
Miscellaneous
reactions.....63
B.
Di(amino)boranes
......
64
V.
Physical
Constants
.......
66
A.
Mono(amino)boranes
.....
66
B.
Di(amino)boranes
......
67
VI.
References
........
69
4.
Aminohaloboranes
........
71
I.
Introduction
........
71
II.
Historical
........
72
III.
Properties
........
72
IV.
Methods
of
Preparation
......
77
A.
Aminodihaloboranes
......
77
1.
Primary
amine
derivatives
....
77
a.
By
aminolysis
reactions
....
77
b.
By
redistribution
reactions.
.
.
.78
c.
Miscellaneous
preparations
.
.
.78
d.
Preparations
of
hydrazinodihaloboranes
.
79
2.
Secondary
amine
derivatives
...
80
a.
Monomers
......
80
(1)
General
......
80
(2)
By
aminolysis
of
boron
trihalides
.
.
81
(3)
By
aminolysis
of
boron
trihalides
in
the
presence
of
tertiary
amines
...
82
(4)
By
redistribution
reactions
...
83
(5)
By
cleavage
of
silicon-nitrogen
compounds
85
(6)
Miscellaneous
preparations
^
86
b.
Dimers
.......
88
B.
Di(amino)haloboranes
.
.
.
.
.89
1.
Primary
amine
derivatives
....
89
2.
Secondary
amine
derivatives
...
90
a.
By
aminolysis
reactions
....
90
b.
By
redistribution
reactions
.
.
.91
c.
Miscellaneous
preparations
....
92
C.
Miscellaneous
Compounds
....
93
V.
Reactions
........
94
A.
Aminodihaloboranes
......
94
1.
Primary
amine
derivatives
.
.
...
94
2.
Secondary
amine
derivatives
....
95
a.
Thermal
stability
.....
95
b.
Dimerization
......
96
c.
Hydrolysis
......
97
d.
With
amines
......
97
e.
With
hydrogen
chloride
....
99
X
Contents
f.
With
organometallics
.
100
g.
With
metals
.
101
h.
With
metal
hydrides
.
102
i.
With
boron
compounds
.
102
j.
With
phosphorus
compounds
.
102
k.
With
inorganic
salts
.
103
B.
Di(amino)haloboranes
.
103
1.
Thermal
decomposition
.
.
103
2.
Hydrolysis
....
.
103
3.
With
amines
.
.
.
.
104
4.
With
organometallics
—
105
5.
With
metals
.
.
.
.
.
106
6.
With
metal
hydrides
.
107
7.
With
boron
compounds
.
.
107
8.
Miscellaneous
reactions
.
.
107
VI.
Physical
Constants
....
.
109
A.
Aminodihaloborane
Monomers
and
Derivatives
.
109
B.
Aminodihaloborane
Dimers
.
114
C.
Di(amino)haloboranes
.
116
VII.
References
.
.
.
.
.
119
5.
Alkoxyaminoboranes,
Aminothioboranes,
and
Related
Compounds
123
I.
Introduction
....
123
II.
Properties
....
123
III.
Dialkoxyaminoboranes
.
124
A.
Preparations
124
B.
Reactions....
125
IV.
Alkylenedioxyaminoboranes
and
Related
Compounds
126
A.
Preparations
126
B.
Reactions
130
V.
Alkoxydiaminoboranes
.
131
A.
Preparations
131
B.
Reactions
133
VI.
Alkoxyalkylenediazaboranes
134
VII.
Aminoboroxines
135
A.
Preparations
135
B.
Properties.
136
VIII.
Aminothioboranes
.
137
A.
Preparations
137
B.
Reactions....
139
IX.
Physical
Constants
.
140
A.
Alkoxyaminoboranes,
Aminothioboranes,
and
Re-
lated
Compounds
140
X.
References
....
146
Contents
6.
Aminoboranes
Containing
Two
Additional
Types
of
Substituent
Groups
..........
I.
Introduction
........
II.
Alkoxyaminohaloboranes
.....
III.
Alkoxyaminophosphinoboranes.
.
.
.
.
IV.
Aminohalohydridoboranes
.....
V.
Aminohalophosphinoboranes
and
Aminohydrido-
phosphinoboranes
.......
VI.
Aminohalothioboranes
......
VII.
Aminohydridothioboranes
.....
VIII.
Physical
Constants
.......
A.
Monomers.
.
.
.
B.
Dimers
........
IX.
References
.
.
.
.
.
.
7.
Pseudohalogen
Compounds
......
I.
Introduction
........
II.
Cyanoboranes.
.......
III.
Cyanato-
and
Isocyanatoboranes
....
IV.
Thiocyanato-
and
Isothiocyanatoboranes
.
V.
Azidoboranes
........
IV.
Physical
Constants
.......
VII.
References
........
8.
Borazines
..........
I.
Introduction
........
II.
Borazine
........
A.
Methods
of
Preparation
.....
1.
From
boron
hydrides
.....
a.
Diborane
and
its
derivatives
b.
Other
boron
hydrides
.
.
.
.
2.
From
metallic
borohydrides
....
3.
From
B-trihaloborazines
....
4.
By
reduction
of
amine-boron
trihalide
mixtures
5.
From
cyclotriborazanes
....
6.
Preparations
of
deuteroborazines
and
8
*
10
B-en-
riched
borazines
......
B.
Reactions
.......
1.
Thermal
stability
......
2.
Hydrolysis
.......
3.
With
alcohols
......
4.
With
amines
and
amine
salts
....
5.
With
hydrogen
halides
.
...
.
6.
Attempted
reductions
.
.
.
.
.
XI
148
148
148
149
149
151
152
153
156
156
157
157
159
159
159
161
163
165
172
173
175
175
177
177
177
177
178
178
179
180
181
181
182
182
184
184
185
185
185
Contents
7.
Alkylations
......
186
8.
With
halogens
......
186
9.
With
oxygen
......
187
10.
With
metallic
oxidizing
agents
.
.
.
187
11.
With
boron
trihalides
.....
188
12.
With
other
boron
compounds
.
.
.
188
13.
Deuterium
exchange
.....
188
14.
With
ethers
......
189
15.
Other
reactions
......
190
III.
JB-Trihaloborazines
......
^
190
A.
Preparations
.......
190
1.
jB-Trichloroborazine
.....
190
a.
General
.......
190
b.
From
boron
trichloride
and
ammonium
chloride
......
190
c.
From
other
borazines
....
192
d.
From
boron
trichloride
and
silylamines
.
193
e.
From
aminodihaloboranes.
.
.
.
193
2.
Ü-Trifluoroborazine
.....
193
3.
B-Tribromo-
and
B-Triiodoborazine
.
.
193
B.
Reactions
of
B-Trihaloborazines
.
.
.194
1.
Thermal
stability
.....
194
2.
Hydrolysis
......
195
3.
With
alcohols,
alkoxides,
and
mercaptans
.
195
4.
With
amines
and
hydrazines
....
196
5.
With
metals
......
197
6.
With
metallic
hydrides
....
198
7.
Alkylation
.......
198
a.
Grignard
......
198
b.
Other
alkylations
.....
199
8.
With
ethers
......
199
9.
With
inorganic
salts
.....
199
10.
With
organophosphorus
derivatives
.
.
200
11.
Miscellaneous
reactions
.
....
201
IV.
B-Trialkyl-
and
B-Triarylborazines
.
.
.
202
A.
Introduction
.......
202
B.
Preparations
.......
202
1.
General
.......
202
2.
Alkylations
of
borazine
and
B-trihaloborazines
203
a.
Grignard
......
203
b.
Other
alkylations
.....
203
3.
From
alkyl-
and
arylhaloboranes
.
.
.
204
4.
From
Alkyldialkylthioboranes
.
.
.
205
5.
From
boron
hydrides
.....
205
6.
From
di-
and
trialkylboranes....
206
Contents
xiii
C.
Reactions
.......
206
1.
Thermal
stability
.....
206
2.
Hydrolysis
......
207
3.
With
alcohols
and
phenols
....
207
4.
With
amines
......
208
5.
With
isocyanates
.....
208
6.
Miscellaneous
reactions
....
208
V.
B-Trialkoxyborazines
......
209
A.
Preparations
.......
209
B.
Reactions.
.
.
.
•
•
•
•
211
YI.
B-Tri(amino)borazines
.
.
.
.
.
.211
A.
Introduction
.
.
.
.
.
.
.211
B.
Preparations
.
.
.
.
.
.
.211
1.
From
B-trichloroborazine
.
.
.
.211
2.
From
other
B-tri(amino)borazines
.
.
213
3.
From
B-trialkylthioborazines
.
.
.213
4.
From
aminodihaloboranes
....
214
5.
Miscellaneous
preparations
....
215
C.
Reactions........
215
1.
Thermal
stability
.....
215
2.
Hydrolysis
.
.
.
.
.
.
215
3.
With
alcohols......216
4.
Transamination
......
216
5.
Miscellaneous
reactions
.
.
.
.216
VII.
Miscellaneous
Boron-substituted
N-H
Borazines.
.
217
A.
B-Trithioborazines
......
217
B.
B-Tris(dialkoxyphosphoryl)
borazines
.
.
.218
C.
B-Tricyanoborazines
and
Related
Compounds
.
219
D.
B-Triureidoborazines
.....
220
E.
B-Trisiloxyborazines
.
.
.
.
.221
VIII.
V-Trialkyl-
and
V-Triarylborazines
....
221
A.
Introduction
.......
221
B.
Preparations
.......
222
1.
From
amine
hydrochlorides
and
borohydrides
.
222
2.
From
amines,
boron
trifluoride
adducts,
and
borohydrides
......
222
3.
From
boron
hydrides
and
amines
.
.
.
222
4.
From
tertiary
amine-boranes
ahd
amines
or
amine
hydrochlorides
.....
224
5.
From
diborane
and
nitriles
....
225
6.
From
B-trihalo-V-trialkyl-
(or
-aryl-)
borazines
227
7.
From
cyclotriborazanes
....
227
8.
From
di(amino)boranes
derived
from
primary
amines
.......
228
9.
Miscellaneous
preparations
....
228
xiv
Contents
C.
Reactions
.......
228
1.
Thermal
stability.
.....
228
2.
Hydrolysis
......
228
3.
With
alcohols
......
229
4.
Alkylation
reactions
.....
229
5.
Exchange
reactions
.....
229
6.
Addition
reactions
.....
230
7.
Halogénation
reactions
....
230
IX.
B-Trihalo-A-trialkyl-
(or
-aryl-)
borazines
.
.
231
A.
Introduction
.......
231
B.
Preparations
.
.
.
.
.
.
.231
1.
B-
Trichloroborazines
.
.
.
.
.231
a.
From
primary
amines
and
boron
trichloride
231
b.
From
other
borazines
....
233
c.
From
aminoboranes
....
234
d.
Miscellaneous
preparations
.
.
.
234
2.
B-Trifiuoroborazines
.....
235
3.
B-Tribromoborazines
.
.
.
.
.
237
4.
B-Triiodoborazines
.....
237
C.
Reactions
.......
238
1.
Thermal
stability
.
,
.
•
.
.
.
238
2.
Hydrolysis
......
239
3.
With
alcohols,
phenols,
and
their
derivatives
.
239
4.
With
amines
......
240
5.
With
organometallics
.....
240
a.
Grignard
.
.
.
.
.
.
240
b.
Other
reagents
.....
241
6.
Reduction
.
.
.
.
.
.
.
242
7.
With
organic
sulfur
compounds
.
.
.
242
8.
With
organic
phosphorus
compounds
.
.
242
9.
With
inorganic
salts
.....
243
10.
Exchange
with
B-alkylborazines
.
.
.
244
11.
Miscellaneous
reactions
....
244
X.
B-Trialkyl-
(or
-aryl-)-A-trialkyl-
(or
-aryl-)
borazines
.
244
A.
Introduction
.......
244
B.
Preparations
.......
244
1.
From
B-Trihalo-A
-trialkyl-
(or
-aryl-)
borazines
244
a.
Grignard
reactions
.....
244
b.
Other
organometallic
reactions
.
.
.
247
2.
From
A-trialkyl-
and
A-triarylborazines
.
247
a.
Grignard
reactions
.....
247
b.
Other
organometallic
reactions
.
.
.
247
c.
Miscellaneous
preparations
.
.
.
248
3.
From
B-trihaloalkyl-A-trialkyl-
(or
-aryl-)
borazines
.......
249
Contents
xv
4.
From
difunctional
alkyl-
and
arylboranes
250
a.
General
.......
250
b.
From
dihaloboranes.....
250
c.
From
alkoxy(aryl)chloroboranes
d.
From
di(amino)alkyl-
and
di(amino)aryl-
251
boranes
.......
252
e.
From
alkoxy(amino)arylboranes
253
f.
From
aryldialkoxyboranes
254
5.
From
trialkylboranes
.
.
.
255
6.
From
unsaturated
borazines
....
255
7.
Miscellaneous
preparations
....
257
c.
Reactions
.......
257
1.
Thermal
stability
.....
257
2.
Hydrolysis
......
259
3.
With
alcohols
......
262
4.
With
amines
......
263
5.
With
hydrogen
chloride
....
263
6.
Oxidation
.......
263
7.
Exchange
reactions
.....
264
8.
Formation
of
n
complexes
....
264
9.
Miscellaneous
reactions
....
265
XI.
B-Trialkoxy-
(or
-aroxy-)-X-trialkyl-
(or
-aryl-)
borazines
........
266
A.
Preparations
.......
266
1.
From
-B-trihalo-A-trialkyl-
(or
-aryl-)
borazines
266
2.
From
B-tri(amino)-X-trialkylborazines
.
3.
From
B-trihydroxy-X-alkyl
(or
-aryl-)-
267
borazines
.......
268
4.
From
alkoxy(amino)boranes
....
268
5.
Polycyclic
borazines
268
B.
Reactions
.......
269
XII.
B-Trihydroxy-X-trialkyl-
(or
-aryl-
)borazines
.
269
XIII.
B-Tri(amino)-X-trialkyl-
(or
-aryl-)
borazines
271
A.
Preparations
.......
271
1.
From
other
borazines
.....
271
a.
From
B-trihalo-A-trialkyl-
(or
-aryl-)
bora¬
zines
.
.
.
.
.
.
271
b.
From
B-trialkylthio-X-trialkyl-
(or
-aryl-)
borazines
......
273
2.
From
tri(amino)boranes
.
273
3.
From
amino(dihalo)boranes
....
274
4.
From
trialkoxyboranes
....
275
5.
Polycyclic
tri(amino)borazines
276
6.
Miscellaneous
reactions
.
•
•
278
XVI
Contents
B.
Reactions
.......
278
1.
Thermal
stability
.....
278
2.
Hydrolysis
......
279
3.
With
alcohols
......
280
4.
With
amines
and
hydrazines
....
280
5.
With
phosphoryl
chloride
....
280
6.
With
isocyanates
.....
281
XIV.
Miscellaneous
Hexasubstituted
Borazines
.
.281
A.
B-Triisocyanato-
and
B-Tricyano-A-trialkyl-
(or
-aryl-)
borazines
and
Related
Compounds
.
.
281
B.
B-Trialkylthio-A
-trialkyl-
(or
-aryl-)
borazines
.~
283
C.
B-Trisiloxy-
and
B-Trisilyl-A-trialkyl
(or
-aryl-)
borazines
.......
284
D.
B-Triphosphoryl-A-trialkyl
(or
-aryl-)
borazines
.
285
E.
Hexachloroborazine
......
286
XV.
Unsaturated
Borazines
......
286
A.
Introduction
.......
286
B.
Preparations
.......
287
1.
B-Unsaturated
borazines
....
287
2.
A-Unsaturated
borazines
....
291
C.
Reactions........
292
XVI.
Unsymmetrical
Borazines
.....
295
A.
Introduction
.......
295
B.
B-Unsymmetrical
Borazines
....
295
1.
B-Haloborazines
.....
295
a.
Preparations
......
295
b.
Reactions
......
299
2.
B-Chloro-B-fluoroborazines
....
300
3.
B-Alkylborazines
.....
301
a.
Preparations
......
301
b.
Reactions
......
304
4.
B-Alkyl-B-haloborazines
....
304
a.
Preparations
......
304
b.
Reactions
......
307
5.
B-Alkyl-B-alkylborazines
....
308
6.
B-Alkyl-B-alkoxyborazines
.
.
.
309
7.
B-Alkyl-B-aminoborazines
....
310
8.
B-Alkyl-B-alkylthioborazines
.
.
.
312
9.
B-Alkoxy-B-haloborazines
....
313
10.
B-Alkoxy-B-aminoborazines
....
314
11.
Other
unsymmetrical
B-aminoborazines
.
.
315
12.
Miscellaneous
B-unsymmetrical
borazines
.
316
C.
A-Unsymmetrical
Borazines
....
317
D.
B-Unsymmetrical-A-unsymmetrical
Borazines
.
320
XVII.
Diborazines
and
Polyborazines
....
320
A.
Introduction
.......
320
Contents
xvii
B.
Diborazm.es
.......
1.
Bicyclic
.
.
.
2.
Directly-linked
diborazines
.
.
.
.
3.
Diborazines
linked
by
other
groups.
a.
Linked
through
oxygen
.
b.
Linked
through
nitrogen
.
.
.
.
c.
Linked
through
hydrocarbon
groups
.
C.
Polyborazines
.......
1.
Introduction
......
2.
Polycyclic
......
3.
Directly
linked
......
4.
Linked
through
substituent
groups
XVIII.
Cyclotriborazanes
.......
A.
Introduction
.......
B.
Cyclotriborazane
......
1.
Preparation
and
properties
.
.
.
.
2.
Reactions
.
.
.
.
C.
Boron-substituted
Cyclotriborazanes
D.
Nitrogen-substituted
Cyclotriborazanes
E.
Boron-
and
Nitrogen-substituted
Cyclotriborazanes
XIX.
Spectra
of
Borazines
and
Cyclotriborazanes
A.
Infrared
........
B.
Raman
........
C.
Ultraviolet
.......
D.
Nuclear
Magnetic
Resonance
....
XX.
Properties
and
Structure
of
Borazines
and
Cyclotribora¬
zanes
.........
A.
General
Properties
......
B.
Structure
.
.
.
.
.
.
.
.
XXI.
Physical
Constants
.......
A.
Vapor-pressure
Relationships
and
Related
Data
B.
Other
Physical
Constants
.....
1.
Borazine
(Section
II)
.
.
.
.
.
2.
jB-Trihaloborazines
(Section
III)
3.
-B-Trialkyl-
and
R-triarylborazines
(Section
IV)
4.
R-Trialkoxyborazines
(Section
V)
.
5.
-B-Triaminoborazines
(Section
VI)
6.
Miscellaneous
boron-substituted
N-H
borazines
(Section
VII)
......
7.
A-Trialkyl-
and
N
-triarylborazines
(Section
VIII)......
8.
B-Trihalo-A-trialkyl-
(or
-aryl-)
borazines
(Section
IX)
......
9.
-B-Trialkyl-
(or
-aryl-)-A-trialkyl-
(or
-aryl-)
borazines
(Section
X)
.
320
320
321
323
323
327
328
329
329
330
330
333
340
340
341
341
342
344
347
349
354
354
354
354
370
371
371
376
380
380
382
382
383
384
386
387
388
390
393
395
xviii
Contents
10.
.B-Trialkoxy-
(or
-aroxy-)
-
V-trialkyl-
(or
-aryl-)
borazines
(Section
XI)
....
399
11.
jS-Trihydroxy-JV -trialkyl-
(or
-aryl-)
borazines
(Section
XII)
......
401
12.
jB-Tri(amino)
-N
-trialkyl-
(or
-aryl-)
borazines
(Section
XIII)......402
13.
Miscellaneous
U-substituted-A-trialkyl-
(or
-aryl-)
borazines
(Section
XIY)
.
.
.
405
14.
Unsaturated
borazines
(Section
XY)
.
.
407
15.
Unsymmetrical
borazines
(Section
XVI)
.
.
409
16.
Diborazines
and
polyborazines
(Section
XVII)
415
17.
Cyclotriborazanes
(Section
XVIII)
.
.
420
XXII.
References
.......
*
421
9.
Miscellaneous
Heterocyclic
Boron-Nitrogen
Compounds
.
.
435
I.
Introduction
.
.
.
.
.
.
.
.
435
II.
Eight-membered
Ring
Compounds
(Borazocines)
.
435
III.
Four-membered
Ring
Compounds
(Diazaboretanes)
.
437
IV.
Other
Heterocyclic
Boron-Nitrogen
Systems
.
.
438
A.
General
........
438
B.
Ketotriazadiborinanes
.....
439
C.
Diketotriazaborinanes
.
.
.
.
.
439
D.
Cyclic
Borohydrazines
and
Related
Compounds
.
442
1.
Preparations
......
442
2.
Reactions
and
structure
....
444
V.
Physical
Constants
.......
446
A.
Borazocines
.
.
.
.
.
.
.
446
B.
Other
Heterocyclic
Boron-Nitrogen
Compounds
.
447
VI.
References
........
450
10.
Linear
Boron-Nitrogen
Polymers
......
452
I.
Introduction
........
452
II.
Preparations
from
Borazines
.....
452
III.
Preparations
from
Haloboranes
....
453
IV.
Preparations
from
Miscellaneous
Boron
Compounds
.
454
V.
Tetrahedral
Boron-Nitrogen
Polymers
.
.
.
455
VI.
References
.
.
.
.
.
.
•
•
456
11.
Tetrahedral
Boron-Nitrogen
Compounds
....
458
I.
Introduction
...
....
458
II.
Cationic
Compounds
......
458
III.
Anionic
Compounds
......
464
IV.
Internally
Compensated
Ions
.....
467
Contents
xix
V.
Physical
Constants
.......
472
VI.
References
.
.
.
.
.
.
.
.478
12.
Boron-Phosphorus,
Boron-Arsenic,
and
Boron-Antimony
Compounds
.........
479
I.
Boron-Phosphorus
Compounds.
....
479
A.
Introduction
.
.
.
.
.
.
.479
B.
History
........
480
C.
Monomers.
.......
480
1.
Properties,
structure,
and
bonding
.
.
.
480
2.
Preparations
......
482
a.
Aryl(phosphino)boranes
....
482
b.
Dialkyl(phosphino)boranes
and
alkyl(diphos-
phino)boranes
.....
483
c.
Aminophosphinoboranes
and
related
com¬
pounds
......
483
3.
Reactions
.......
484
D.
Dimers
.
.
.
.
.
.
.
.
487
E.
Trimers
........
489
1.
Introduction
......
489
2.
Properties
......
489
3.
Preparations
......
490
a.
From
boron
hydrides
....
490
b.
Reduction
of
phosphorus
compounds
with
borohydrides
.
.
.
.
.
.
492
c.
Reactions
of
phosphines
with
haloboranes
.
493
d.
From
cyclotriborophanes
and
cyclotetra-
borophanes
......
494
e.
Miscellaneous
preparations
.
.
.
497
4.
Reactions
.......
497
a.
Thermal
stability
.....
497
b.
Hydrolysis
......
498
c.
With
alcohols
.
.
.
.
.
.
499
d.
With
amines
......
499
e.
Miscellaneous
reactions
....
499
F.
Tetramers.
.......
500
1.
Introduction
......
500
2.
Preparations
......
500
3.
Reactions
.......
500
G.
Polymers
.......
501
H.
Polycyclic
borophanes
.....
504
II.
Boron-Antimony
Compounds
.....
505
III.
Boron-Arsenic
Compounds
.....
506
XX
Contents
IV.
Physical
Constants
.......
509
A.
Boron-Phosphorus
Monomers
....
509
B.
Boron-Phosphorus
Dimers
.....
510
C.
Boron-Phosphorus
Trimers
....
510
D.
Boron-Phosphorus
Tetramers
.
.
.
.512
E.
Polycyclic
Borophanes
.....
512
E.
Boron-Antimony
Compounds
....
513
G.
Boron-Arsenic
Compounds
.....
513
V.
References
........
514
.
517
Author
Index
Subject
Index
545
|
| any_adam_object | 1 |
| author | Steinberg, Howard |
| author_facet | Steinberg, Howard |
| author_role | aut |
| author_sort | Steinberg, Howard |
| author_variant | h s hs |
| building | Verbundindex |
| bvnumber | BV009379763 |
| ctrlnum | (OCoLC)310030170 (DE-599)BVBBV009379763 |
| edition | 1. publ. |
| format | Book |
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| id | DE-604.BV009379763 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:35:19Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-006224787 |
| oclc_num | 310030170 |
| open_access_boolean | |
| owner | DE-29T DE-20 DE-188 |
| owner_facet | DE-29T DE-20 DE-188 |
| physical | XX, 568 S. Ill. |
| publishDate | 1966 |
| publishDateSearch | 1966 |
| publishDateSort | 1966 |
| publisher | Interscience Publ. |
| record_format | marc |
| spelling | Steinberg, Howard Verfasser aut Organoboron chemistry 2 Boron-nitrogen and boron-phosphorus compounds Howard Steinberg 1. publ. New York [u.a.] Interscience Publ. 1966 XX, 568 S. Ill. txt rdacontent n rdamedia nc rdacarrier (DE-604)BV009379761 2 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006224787&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Steinberg, Howard Organoboron chemistry |
| title | Organoboron chemistry |
| title_auth | Organoboron chemistry |
| title_exact_search | Organoboron chemistry |
| title_full | Organoboron chemistry 2 Boron-nitrogen and boron-phosphorus compounds Howard Steinberg |
| title_fullStr | Organoboron chemistry 2 Boron-nitrogen and boron-phosphorus compounds Howard Steinberg |
| title_full_unstemmed | Organoboron chemistry 2 Boron-nitrogen and boron-phosphorus compounds Howard Steinberg |
| title_short | Organoboron chemistry |
| title_sort | organoboron chemistry boron nitrogen and boron phosphorus compounds |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006224787&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV009379761 |
| work_keys_str_mv | AT steinberghoward organoboronchemistry2 |