Organic colloids:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Amsterdam u.a.
Elsevier
1958
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 655 S. Ill., graph. Darst. |
Internformat
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| 100 | 1 | |a Jirgensons, Bruno |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Organic colloids |
| 264 | 1 | |a Amsterdam u.a. |b Elsevier |c 1958 | |
| 300 | |a XIV, 655 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 650 | 7 | |a Colloïdes |2 ram | |
| 650 | 7 | |a Composés organiques |2 ram | |
| 650 | 7 | |a Kolloid |2 swd | |
| 650 | 7 | |a Kolloidchemie |2 swd | |
| 650 | 7 | |a Organische Verbindungen |2 swd | |
| 650 | 4 | |a Chemistry, Organic | |
| 650 | 4 | |a Colloids | |
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Datensatz im Suchindex
| _version_ | 1804123654936592384 |
|---|---|
| adam_text | ORGANIC COLLOIDS
bJ
BRUNOJIRGENSONS
Biochemist, University of Texas M D Anderson
Hospital and Tumor Institute ; Associa/ ; Projessor,
University oj Texas Postgraduate S hool oj
Medicine and Baylor University School f Medicine,
Houston (Texas), U S A
Eigentum der
Chemischen Zentralbiicherei
Carl Bosch-Haus
Frankfur t /Main
ELSEVIERPUBLISHINGCOMPANY
AMSTERDAMLONDONNEWYORKPRINCETON
Contents
Preface v
Part One - METHODS OF PREPARATION; STUDY OF
ORGANIC COLLOIDS
Chapter Page
1 Introduction The scope of organic colloi d chemistry Bas
ic terms 3
Additional important nomenclature: Summary 8
2 Development of the modern organic colloid chemistry
Classification of organic colloids io
3 The properties of organic substances is depending on
chemical constitution and molecular weight 21
1 Various types of molecules, 21 — 2 The variety of isomers in
homologous series, 25 - 3 The polymer-homologous series, 27 -
4 Classification of high polymers, 29 - 5 Some characteristic
properties of high polymeric substances, 33
4 The formation of large molecules 35
1 Polymerization, 35-2 Poh-condensatioi , 40-3 The forma
tion of space polymers, 42 - 4 Ring formal 011 and ring scission
in polymerization and polycondensation, (4-5 Dependence
of the properties of polymers on chain lenfj tli, 45-6 Degrada
tion of large molecules, 46-7 Synthesis o graft and block co
polymers, 47
XCONTENTS
Chapter Page
5 Preparation of dispersions and micellar colloids 50
1 Mechanical dispersion metliods, 50-2 Preparation of dis
persions by change of solvent, 53 - 3 Colloi d stability factors, 54
- 4 Charge and solvation of colloidal pari icles, 58 - 5 Micelle
formation and size of the hydrophobic chai n, 60 — 6 Micelles in
non-polar liquids, 62 - 7 The formation of super-micelles, 63
6 Surface phenomena 65
1 Surface tension, 65 - 2 Surface-active 01 ganic substances, 69
-3 Wetting of surfaces, 71 -4 Adsorption phenomena, 72 - 5
Chromatographic analysis, 75 - 6 Adsorption and ion exchange,
78 - 7 Monomolecular films on the surfaceof liquids, 79
7 The size and shape of macromolecules ; 1 nd micelles 86
1 Ultrafiltration, dialysis, and other semiquantitative methods,
86 - 2 Sedimentation in the ultracentrifu ;e, 89 - 3 Molecular
size and diffusion, 95 — 4 Determination of molecular weight by
osmotic pressure measurement, 99 - 5 Molecular weight deter
mination by light scattering, 105 - 6 Th streaming birefrin
gence and particle shape, 111 - 7 Colloidal particles in electron
microscope, 115 - 8 Determination of molecular weight by
chemical methods, 118 - 9 The terms mol cule and molecular
weight , 120
8 Fractionation and molecular size distril ution 124
1 The various molecular weight averages, 1:24 - 2 The size dis
tribution curves and degree of polydispersity, 127 - 3 Frac
tionation of polymers, 129
9 The viscosity of organic colloids 133
1 Basic terms, 133 - 2 The flow through capillaries, 135 — 3
Reduced viscosity Intrinsic viscosity, ly i - Methods of meas
urement: 4 The capillary viscometer of V ilhelm Ostwald, 138
- 5 Rotating cylinder viscometers, 139 - 1 Other types of vis
cometers, 140 - The viscosity of spherocoll ids: 7 Viscosity and
concentration, 141 - 8 Viscosity and particle size, 143 - 9 The
influence of electrolytes on the viscosity, 1 14- Viscosity of linear
colloids: 10 Viscosity and concentration 1 f linear colloids, 146
-11 Dependence of the viscosity on molecular weight, 148 - 32
The viscosity of ionized linear colloids, 150- 13 Viscosity and
axial ratio of asymmetric, rigid particles 150 - 14 Flexible
linear macromolecules in different solvents 152- 15 Flexibility
and length of linear macromolecules, 154- Inomalous flow prop
erties of colloidal solutions: 16 Non-New tonian systems The
influence of the temperature, 156 — 17 ( elation phenomena
Thixotropy, 158
CONTENTS XI
Chapter Page
io Organic colloids in electrical field 161
i Classification of colloidal electrolytes, 161 - 2 Conductivity,
162 - 3 Electrophoretic phenomena, 167 - 4 Electrophoresis
on paper, 175 - 5 Electro-osmosis and related phenomena, [77
- 6 Orientation in an electrical field, 182
11 The structure of colloidal particles 185
1 Macromolecules and micelles, 185 - 2 Physical evidence
about the presence of macromoLecules, 186 - 3 Chemical reac
tions with macromolecules, 187 - 4 Structural studies by
means of X-ray analysis, 192 - 5 Atomic distances and bond
angles, 198 - 6 Infrared spectroscopy, 200 * 7 The optical ro
tation of natural macromolecules, 201
12 Swelling, solubility, solubilization 207
1 Swelling and dissolution of polymers, 207 - 2 The solubility
of inhomogeneous macromolecular compounds, 212-3 Swel
ling phenomena, 213 - 4 Degree of swelling and amount of
cross-linking, 216 - 5 Swelling of polyelectrolytes, 2 [6 - 6 The
modes of binding of a solvent, 217 - 7 The s lubilizing capacity
of micellar colloids, 218 - 8 Solubility and swelling from the
point of view of thermodynamics, 220 •
13 Flocculation and gelation phenomena 223
1 Flocculation in non-polar and in polar svsi 31ns, 223 - 2 Floc
culation of lyophobic colloids, 226 - 3 Floe dilation of electri
cally charged lyophilic colloids, 228 - 4 The ] yotropic series and
salting out effects, 230 - 5 Gelation of lyopliilic colloids, 232 -
6 Flocculation and gelation in systems com aining electrolytes
and non-electrolytes, 233 — 7 The nature 01 forces involved in
aggregation, 235 -8A simple treatment f salting out and
coacervation, 237
14 Interactions among colloids 240
1 The stabilizing effect of hydrophilic colloi l s, 240 — 2 Mutual
flocculation of electrically charged colloids, 42-3 The floccu
lation of polymeric acids by polymeric bases, 244 - 4 Reactions
between polyelectrolytes and proteins, 245 -5I nteractions of
micellar electrolytes with other colloids, 247 - 6 Compatibility
of polymers, 248
15 Gels and membranes 251
1 The formation of gels, 251 - 2 The struct;ire of gels, 252 - 3
Mechanical properties and structure of gels, 255 - 4 Syneresis
of gels, 257 - 5 Diffusion and chemical reat :ions in gels, 259 -
6 Membranes as gels, 260 - 7 Donnan s equilibrium, 262
XII CONTENTS
Chapter Page
16 Properties of highly consistent macronr ilecular substances 266
1 Mechanical behavior of macromolecuUr substances, 266 -
2 Thermal properties of polymers, 272- Chemical and other
properties of polymers, 275
Part Two-SELECTED GROUPS OF ORGANIC COLLOIDS
17 Macromolecular hydrocarbons 281
1 The polyethylene resins, 281 — 2 Poh vsobutylene, 285 - 3
Polystyrene, 287 - 4 Natural rubber, 293 • 5 Synthetic rubbers,
• 297-6 Other polymeric hydrocarbons and their derivatives, 300
18 Macromolecular vinyl derivatives 304
1 Polyvinyl chloride, 304 — 2 Polyvinyl icetate, 306 — 3 Poly
vinyl alcohol, 307 - 4 Polyacrylic acid ani its derivatives, 309 -
5 The polymethacrylates, 312-6 Orieniation polymerization
in the presence of polymethacrylate, 316 7 Polyvinyl pyrroli-
done, 318
19 Linear condensation polymers 323
1 Linear polyesters, 324 - 2 Linear poly, mides, 330 - 3 Poly-
condensation products related to polyarmdes, 336
20 Cross-linked space polymers 339
1 Theaminoplasts, 340-2 Thephenoplasi s, 343-3 The anilirio-
plasts, 347 — 4 Space polymers as ion exi hangers, 348 — 5 The
alkyd resins, 350 - 6 Space polymers in di ying oils, 351
21 Cellulose and similar polysaccharides 353
1 Cellulose and its accompanying macromolecular substances,
353 - 2 Lignin - a polymer accompanying cellulose, 355 - 3 The
macromolecules of cellulose, 356 - 4 The lerivati ves of cellulose,
361 - 5 The hemicelluloses, 369
22 Starch and other branched chain polysaccharides 373
1 Starch, 373 - 2 Glycogen and similar polysaccharides, 382-
3 Dextrans, 385
23 Pectic substances and mucilages of pLmts 389
1 Pectins, 389 - 2 Pectic araban and g;ilactan, 393 - 3 Agar
and other seaweed polysaccharides, 395 - 4 Alginic acid, 398 -
5 Gums and mucilages, 398
24 Animal polysaccharides with fibrous macromolecules 402
1 Chitin, 402-2 Chondroitin sulfuiic acH, 405 - 3 Hyaluronic
acid, 407-4 Heparin, 410-5 Blood grou ) polysaccharides, 411
CONTENTS XIII
Chapter Page
25 Poly-amino acids and semi-colloidal proteins 414
1 Colloid-chemical aspects of classification, 414 - 2 Basic
structural features, 415-3 Simple, semi-colloidal proteins, 421
- 4 Synthetic poly-amino acids, 426
26 Globular proteins 433
i Isolation and criteria of purity, 434 - 2 Sizo, shape, and hy
dration, 437 - 3 The structure and configuration of the sphero-
proteins, 441 — 4 Ionization and ionic interac tions of globular
proteins, 444 - 5 Examples of globular proti ins Serum albu
min, 446 - 6 Examples of globulins, 452 - 7 ilemoglobins and
other respiratory proteins, 453 — 8 Examples of enzvmes, 455
- 9 Protein hormones, 457 - 10 Denaturation of proteins, 459 -
11 Chemical modification of proteins, 466
27 Fibrous proteins 472
1 Silk, 473 - 2 Wool and other keratins, 471 - 3, Epidermin,
482 -4 Collagen and gelatin, 484 - 5 The ) near proteins of
muscle, 494 - 6 Fibrinogen, 499 - 7 Fibrous 11 apoproteins, 500
28 Nucleic acids, nucleoproteins, and viruses 504
1 Nucleic acids, 505 - 2 The histones, 513 - The nucleopro
teins, 515 - 4 Viruses and bacteriophages, 51
29 Colloid phenomena in cells and tissues 529
1 Biocolloids in a cell, 529 - 2 The ground substance and con
nective tissues, 534 - 3 Permeability problem- in living tissues,
•538 - 4 Some colloid-chemical aspects of muS ular contraction,
541 - 5 Submicroscopic structures and biocolloids of nerve tis
sue, 543 - 6 The colloid chemistry of tanning, 545
30 Blood as a complex colloidal system 548
1 Corpuscles and plasma, 548-2 Blood groups and agglutina
tion phenomena, 549 - 3 The immunochemical reactions, 552 -
4 The white cells, 556 - 5 The clotting of bloc d, 558
31 Colloid-chemical characterization of biocolL ids in disease 563
1 Plasma proteins in disease, 563 - 2 Abnormal hemoglobins,
570 - 3 The urinary Bence-Jones proteins, 52-4 Abnormal
tissue proteins in disease, 575-5 Colloidal c mponents resem
bling viruses in milk and tissues, 577
32 Milk as a colloid 581
1 The caseins of cow s milk, 582 - 2 The wh y proteins, 588 -
3 Homogenization and the stability of fat globules of cream,
590 - 4 Whipped cream and other complex disperse systems,
XIV CONTENTS
Chapter Page
33 Emulsions and micellar lipids 595
x Particle size and stability of emulsions, 596 - 2 Practical
applications of emulsions, 601-3 The resorption of fats, 603 -
4 Micellar phospholipids and similar colloids, 605 — 5 Proteo-
lipids and lipoproteins, 609
34 Micellar detergents, dyes, and pigmeni •; 612
1 Three types of detergents, 612 - 2 The ;olloid-chemical prin
ciples of detergency,-6i6 - 3 The colloidal behavior of dyes, 618
- 4 Colloidal organic pigments, 621 - 5 Colloidal pheno-
thiazines, 624
Author Index 629
Subject Index 645
|
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| institution | BVB |
| language | German |
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| spelling | Jirgensons, Bruno Verfasser aut Organic colloids Amsterdam u.a. Elsevier 1958 XIV, 655 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Colloïdes ram Composés organiques ram Kolloid swd Kolloidchemie swd Organische Verbindungen swd Chemistry, Organic Colloids HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006124357&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Jirgensons, Bruno Organic colloids Colloïdes ram Composés organiques ram Kolloid swd Kolloidchemie swd Organische Verbindungen swd Chemistry, Organic Colloids |
| title | Organic colloids |
| title_auth | Organic colloids |
| title_exact_search | Organic colloids |
| title_full | Organic colloids |
| title_fullStr | Organic colloids |
| title_full_unstemmed | Organic colloids |
| title_short | Organic colloids |
| title_sort | organic colloids |
| topic | Colloïdes ram Composés organiques ram Kolloid swd Kolloidchemie swd Organische Verbindungen swd Chemistry, Organic Colloids |
| topic_facet | Colloïdes Composés organiques Kolloid Kolloidchemie Organische Verbindungen Chemistry, Organic Colloids |
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