Phase equilibria among oxides in steelmaking:
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Reading, Mass.
Addison-Wesley
1965
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturverz. S. 205 - 224 |
| Physical Description: | XX, 236 S. graph. Darst. |
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| 100 | 1 | |a Muan, Arnulf |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Phase equilibria among oxides in steelmaking |c Arnulf Muan ; E. F. Osborn. Sponsored by American Iron and Steel Institute |
| 264 | 1 | |a Reading, Mass. |b Addison-Wesley |c 1965 | |
| 300 | |a XX, 236 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 500 | |a Literaturverz. S. 205 - 224 | ||
| 650 | 4 | |a Acier - Métallurgie - Procédés à l'oxygène | |
| 650 | 4 | |a Loi des phases et équilibre | |
| 650 | 4 | |a Oxydes | |
| 650 | 4 | |a Oxides | |
| 650 | 4 | |a Phase rule and equilibrium | |
| 650 | 4 | |a Steel |x Metallurgy |x Oxygen processes | |
| 700 | 1 | |a Osborn, Elburt F. |e Verfasser |4 aut | |
| 856 | 4 | 2 | |m HEBIS Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006115757&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
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Record in the Search Index
| _version_ | 1804123642587512832 |
|---|---|
| adam_text | PHASE EQUILIBRIA
AMONG OXIDES
IN STEELMAKING
ARNULFMUAN
Professor of Metallurgy
EFOSBORN
Professor of Geochemistry
and Vice President-Research
THEPENNSYLVANIASTATEUNIVERSITY
Sponsored by
AMERICANIRONANDSTEELINSTITUTE
•
VT
ADDISON-WES1;EYPUBLISHINGCOMPANY,INC
READJ NG, MASSACHUSETTS
CONTENTS
LIST OF FIGURES xi
GENERAL REFERENCES xvii
A THE PHASE RULE AN I ITS APPLICATION TO
VARIOUS CHEMICAL SYSTEMS xvii
B COMPILATIONS OF PHASE DIAGRAMS xviii
C GENERAL xviii
LEGENDS TO COMMON LINE SYMBOLS AND
PHASE NOTATIONS USED IN DIAGRAMS xix
A LINE SYMBOLS xix
B PHASE NOTATIONS XX
CHAPTER
1 INTRODUCTION
2 STABILITIES OF OXIDES
A STABILITIES RELATIVE TO THE ELEMENTS 3
B STABILITIES RELATIVE TO HYDROXIDES, CARBON-ATHS,
SULFIDES, NITRIDES, AND CARBIDES 5
C VAPORIZATION 14
D MELTING 16
3 ONE-COMPONENT SYSTEMS
A Si02 17
B Ca2Si04 20
C Fe203, AI2O3, JVL13O4, Zr02, TiO 2 1
4 TWO-COMPONENT SYSTEMS
A SYSTEMS IN WHU H A GAS PHASE PLAYS AN IMPOKTANT ROLE 24
1 C-0 24
2 Fe-0 25
3 H-0 31
4 Metal-Oxygen Systems Other Than Fe-0 31
Mn-0 33
Ti-0 33
V-0 33
Cr-0 33
CONTENTS
CHAPTER
B SYSTEMS IN WHICH A GAS PHASE PLAYS N O IMPORTANT ROLE
1 General Considerations 34
2 Systems with Si02 as a Component 35
Ca0-Si02 35
Al203-Si02 37
K20-Si02 38
Na20-3i02 39
Mg0-Si02 39
Cr203 Si02 39
Ti02-Si02 40
3 Systems without S1O2 as a Component 42
CaO-MgO 42
CaO-A^Os 42
CaO- l i02 42
CaO-P2Og 44
MgO-AbOs 46
Mg0-0r203 46
Mg0-Ti02 46
Al20 3-Cr203 46
Al20s-Ti02 46
5 THREE-COMPONENT SYSTEMS
A SYSTEMS IN WHICH A GAS PHASE PLAYS AN IMPORTANT ROLE
1 C-H-0 48
2 Fe-C-( • 49
3 Fe-Si- ) 53
a General considerations 53
b The liquidus surface 54
c Paths of equilibrium cystallization 58
d Composition sections through the system Fe0-Fe203-Si02 62
e The solidus surface 63
f Is thermal sections through the system Fe0-Fe203-Si02 65
4 Fe-H- ) 69
5 Metal i-Metals-Oxygen Systems Other Than Fe-Si-0 70
Mn-Si-0 71
Fe-Ti-0 73
Fe-Cr-0 75
Fe-Al-0 77
Fe-Mn-0 77
Fe-Mg 0 79
Ca-Fe-0 81
Ca-Cr-0 83
Mn-Al-0 83
Mn-Cr-0 85
Mn-Mg-0 85
Ca-Mn -0 87
Fe-Zr- ) 87
Fe-P-0 87
CONTENTS vii
CHAPTER
B SYSTEMS IN WHICH A GAS PHASE PLAYS NO IMPORTANT ROLE 88
1 General Considerations 88
2 Systems with Silica as a Component 90
K20-Al203-Si( 2 90
Na20-Al203-SiC 2 91
CaO-MgO-SiOn 92
Ca0-Al203-Si02 93
Mg0-Al203-Si02 96
Ca0-Ti02-Si0- 97
Mg0-Cr203-Si02 98
Al203-Cr203-^i02 99
Al203-Ti02-Si )2 100
3 Systems without Silica as a Component 101
CaO-MgO-A^1 3 101
Mg0-Al203-Ci 2O3 101
FOUR-COMPONENT SYSTEMS
A GENERAL CONSIDERATIONS 103
B SYSTEMS IN WHICH A GAS PHASE PLAYS AN IMPORTANT ROLE 104
1 The System M!50-Fe0-Pe203-Si02 104
a Liquidus relations 104
b Paths of equilibrium crystallization 105
c Composition sections through the system Mg0-Fe0-Fe203-Si02 111
2 Other Four-Component Systems Similar to Mg0-Fe0-Fe203-Si02 114 Other Four-Component Syste :ms Similar to Mg0-Fe0-Fe203-Si02
CaO-F e0-Fe20:-t-Si02 1 1 4
Fe0-Fe203-Al203-Si02 11 5
Fe0-Fe203-CrJ03-Si02 120
Fe0-Fe203-Ti( 2-Si02 120
Fe-Mn-Si-0 121
Ca0-Fe0-Fe203-P20s 122
Ca0-Cr203-Cr03-Si02 124
MgO-MnO-Mn 203-Si02 12 5
Ca0-Mn0-MnL, 03-Si02 126
Mn0-Mn203-Al203-Si02 127
C SYSTEMS IN WHICH A GAS PHASE PLAYS NO IMPORTANT ROLE 128
1 The System Ca0-Mg0-Al203-Si02 128
a Phase relal ions at liquidus temperatures 128
b Phase relal ions at solidus temperatures 137
c Isothermal sections 142
7 SYSTEMS WITH MORE THAN FOUR COMPONENTS
A GENERAL CONSIDERATIONS 143
B LIQUIDUS RELATIONS IN TWO SELECTED SYSTEMS 143
1 CaO-iron oxide-AI2O3-S1O2 in Contact with Metallic Iron 143
2 CaO-MgO-iron oxide-Si02 in Contact with Metallic Iron 146
viii CONTENTS
CHAPTER
8 SLAGS
A INTRODUCTION 148
B IRON BLAST FURNACE SLAGS 148
1 General Considerations 148
2 Phase Relations at Liquidus Temperatures in the System
CaO-M g0-Al203-Si02 149
3 Effect of Titanium Oxide on Liquidus Relations in the System
CaO-M -O-AMVSiOo 153
4 Phase Relations at Solidus Temperatures in the System
CaO-M ir0-Al203-Si02 157
C STEELMAKI TG SLAGS 158
1 Phosphate Slags 158
a Equilibria in the system CaO-iron oxide-P20,5 158
b Effects of various additions on equilibria in the system
Ca -iron oxide-P20s 160
2 Basic Open-Hearth and Basic Oxygen Converter Slags 165
3 Acid Slags 167
9 OXIDE INCLUSIONS
A INTRODUCTION 169
B INFERRED LIQUID IMMISCIHILITY RELATIONS BEARING
ON OXIDE INCLUSIONS 169
C BEHAVIOR OF OXIDE INCLUSIONS DURING HEATING
AND ROLLI NG OF STEEL 171
1 General Considerations 171
2 Equilibria When Only One Deoxidizing Element Is Used
in Plain Carbon Steel 171
Mn 171
A1 172
Si 172
Ti 172
Zr 173
Cr 173
B 173
3 Equilibria When Two Deoxidizing Elements Are Used 173
Mn-Si 173
Al-Si 174
4 Equilibria in Multicomponent Inclusion Systems 175
a General considerations 175
b Deoxidation with Ca alloys 175
c Deoxidation with Mn-Al-Si alloys 176
d Deoxidation with Fe-Si and AI in Mn-Cr steels 176
CONTENTS
CHAPTER
10 REFRACTORIES
A INTRODUCTION 177
B SILICA BRICK 178
1 General Considerations 178
2 Silica Briek as Manufactured 179
a Raw materials and their conversion 179
b Effect of AI2O3 on refractoriness of silica brick 1 80
c Effec tof Ti02 on refractoriness of silica brick 181
d Effect of Cr2C 3 on refractoriness of silica brick 181
3 Silica Brick in Service 183
a Reactions with iron oxides 183
b Fluxing by other oxide? 184
C ALTJMINA-SILICA REFRACTORIES 185
1 General ( onsiderations 185
2 Fluxing by Various Oxides 185
a Alkali oxides 185
b Iron oxide 185
c Reactions with other types of brick 186
d React ions with slags 1 87
3 Reactions with Ferro-Man;;anese Alloys 188
D CHROME REKRACTORIES 191
1 General ( onsiderations 191
2 Equilibria in a Simplified Chrome Ore:
The System Mg0-Cr203-Si02 192
3 Equilibria Among Other Constituents of Chrome Refractories 193
4 Solid Stai e Phase Changes in Chrome Refractories 1 93
5 Chrome-Magnesia Refractories 194
E MAGNESIA REFRACTORIES 195
1 Magnesite Refractories 195
a General considerations 195
b Read ions with iron oxides 195
c Inferred reactions with iron oxide and Cr203 197
d React ions with iron oxide and SiO2 198
e React ions with various silicate liquids 200
2 Dolomite Refractories 201
a General considerations 201
b Stabilization of dicalcium silicate 201
c React ions with iron oxide 201
3 Forsterite Refractories 202
REFERENCES 205
AUTHOR INDEX 225
SUBJECT INDEX 229
|
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| dewey-search | 669.101541363 |
| dewey-sort | 3669.101541363 |
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| discipline | Chemie / Pharmazie |
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| language | English |
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| physical | XX, 236 S. graph. Darst. |
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| spelling | Muan, Arnulf Verfasser aut Phase equilibria among oxides in steelmaking Arnulf Muan ; E. F. Osborn. Sponsored by American Iron and Steel Institute Reading, Mass. Addison-Wesley 1965 XX, 236 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturverz. S. 205 - 224 Acier - Métallurgie - Procédés à l'oxygène Loi des phases et équilibre Oxydes Oxides Phase rule and equilibrium Steel Metallurgy Oxygen processes Osborn, Elburt F. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006115757&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Muan, Arnulf Osborn, Elburt F. Phase equilibria among oxides in steelmaking Acier - Métallurgie - Procédés à l'oxygène Loi des phases et équilibre Oxydes Oxides Phase rule and equilibrium Steel Metallurgy Oxygen processes |
| title | Phase equilibria among oxides in steelmaking |
| title_auth | Phase equilibria among oxides in steelmaking |
| title_exact_search | Phase equilibria among oxides in steelmaking |
| title_full | Phase equilibria among oxides in steelmaking Arnulf Muan ; E. F. Osborn. Sponsored by American Iron and Steel Institute |
| title_fullStr | Phase equilibria among oxides in steelmaking Arnulf Muan ; E. F. Osborn. Sponsored by American Iron and Steel Institute |
| title_full_unstemmed | Phase equilibria among oxides in steelmaking Arnulf Muan ; E. F. Osborn. Sponsored by American Iron and Steel Institute |
| title_short | Phase equilibria among oxides in steelmaking |
| title_sort | phase equilibria among oxides in steelmaking |
| topic | Acier - Métallurgie - Procédés à l'oxygène Loi des phases et équilibre Oxydes Oxides Phase rule and equilibrium Steel Metallurgy Oxygen processes |
| topic_facet | Acier - Métallurgie - Procédés à l'oxygène Loi des phases et équilibre Oxydes Oxides Phase rule and equilibrium Steel Metallurgy Oxygen processes |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=006115757&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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