Photoelectron spectroscopy: Chemical and analytical aspects
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Oxford [u.a.]
Pergamon Press
1972
|
| Edition: | 1. ed. |
| Series: | International series of monographs on analytical chemistry
53 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | X, 180 S. Ill., graph. Darst. |
| ISBN: | 0080169104 |
Staff View
MARC
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| 245 | 1 | 0 | |a Photoelectron spectroscopy |b Chemical and analytical aspects |c A. D. Baker and D. Betteridge |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Oxford [u.a.] |b Pergamon Press |c 1972 | |
| 300 | |a X, 180 S. |b Ill., graph. Darst. | ||
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Record in the Search Index
| _version_ | 1804123405479313408 |
|---|---|
| adam_text | CONTENTS
PREFACE ix
1. Basic Principles 1
2. Factors Underlying Instrumentation and Their Bearing on the
Interpretation of Results 7
Sources 7
(a) The different types of sources 7
(6) Source energies 10
(c) The width of photon emission lines 14
Sample Introduction 17
(a) UV-photoelectron spectrometers 17
(Jo) X-ray photoelectron spectrometers 19
Energy Analysis of the Ejected Electrons, and Related Factors
Affecting the Resolution 20
Electron Multipliers and Counting Equipment 25
References 26
3. Fundamental Factors Affecting the Appearance of a Spectrum 29
Factors Influencing the Shapes of Bands in the Spectra 29
General points 29
(a) Spin-orbit coupling 30
(A) Vibrational fine structure 31
(c) Dissociation 37
(d) The John-Teller effect 37
(e) Exchange splitting and multiplet splitting 39
Factors Influencing the Position of Bands in the Spectra 39
Examples of the Photoelectron Spectra of Simple Atoms and Molecules 41
(a) Rare gases 42
(b) Nitrogen 43
(c) Water 47
Complicating Factors 51
-4«yer Effect and Autoionization 51
References 53
Vi CONTENTS
4. Interpretation of UV-photoelectron Spectra 55
General Comments 55
Electronegativity and Inductive Effects 56
Mesomeric Effects 60
Lone-pair Non-bonding Orbitals and Interactions between them 61
Interactions between ir-systems and Lone-pair Orbitals 68
Haloacetylenes 70
Cis- and trans- ,3,-Dichloropropene 72
Vinyl Halides 74
Substituted Benzenes 75
Heterocyclic Compounds 80
Steric Effects 81
The Perfluoro Effect 83
Correlations 83
Future Developments and Other Studies 84
Review of Other Studies 85
References 96
5. Structural Effects on Core Electron Binding Energies and
X-ray Photoelectron Spectra 102
Chemical Shifts 102
(a) General comments 102
(b) Correlations of chemical shifts with other parameters 109
(i) Partial charges 111
(//) The principle of equivalent cores 114
(iij ) Correlation with Mossbauer shifts 117
References 117
6. Analytical Applications 118
Introduction 118
Analysis by X-ray PES (ESCA) 119
{a) Sample 119
(b) Calibration 119
Qualitative Analysis 120
Quantitative Analysis 123
(c) Application to the study of surfaces and surface layers 128
( /) Applications in polymer chemistry 128
UV-PES 130
(c) Introduction of sample 130
(/) Calibration 131
(#) Qualitative identification 134
(A) Mixtures 139
Quantitative Aspects 141
References 144
CONTENTS
Vll
7. Other Forms of Electron Spectroscopy 145
Auger Electron Spectroscopy (AS) 145
Electron-impact Energy-loss Spectroscopy (E1S) 149
Ion Neutralization Spectroscopy (INS) 151
Angular Distributions of Photoelectrons 151
Other Photoelectron Techniques 153
References 154
appendix 1. Inner-Shell Orbital Ionization Potentials
for Atoms 157
appendix 2. First Ionization Potentials of Atoms, eV 161
appendix 3. Selected Approximate Orbital Ionization
Potentials of Some Small Molecules, eV 163
appendix 4. Selected Values of Inner-Shell Binding Energies
Measured by Photoelectron Spectroscopy 164
appendix 5. The Calculation of Partial Charges on Atoms
in Molecules
appendix 6. Probability of Auger Transition as a
Function of Atomic Number
169
174
INDEX
175
OTHER TITLES IN THE SERIES
179
|
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| id | DE-604.BV009049740 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:29:15Z |
| institution | BVB |
| isbn | 0080169104 |
| language | English |
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| physical | X, 180 S. Ill., graph. Darst. |
| publishDate | 1972 |
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| publisher | Pergamon Press |
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| series | International series of monographs on analytical chemistry |
| series2 | International series of monographs on analytical chemistry |
| spelling | Baker, Arthur D. Verfasser aut Photoelectron spectroscopy Chemical and analytical aspects A. D. Baker and D. Betteridge 1. ed. Oxford [u.a.] Pergamon Press 1972 X, 180 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier International series of monographs on analytical chemistry 53 Foto-elektronspectrometrie gtt Spectroscopie électronique Electron spectroscopy Elektronenspektroskopie (DE-588)4014332-6 gnd rswk-swf Photoelektronenspektroskopie (DE-588)4174491-3 gnd rswk-swf Elektronenspektroskopie (DE-588)4014332-6 s DE-604 Photoelektronenspektroskopie (DE-588)4174491-3 s 1\p DE-604 Betteridge, D. Verfasser aut International series of monographs on analytical chemistry 53 (DE-604)BV001889010 53 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005989686&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Baker, Arthur D. Betteridge, D. Photoelectron spectroscopy Chemical and analytical aspects International series of monographs on analytical chemistry Foto-elektronspectrometrie gtt Spectroscopie électronique Electron spectroscopy Elektronenspektroskopie (DE-588)4014332-6 gnd Photoelektronenspektroskopie (DE-588)4174491-3 gnd |
| subject_GND | (DE-588)4014332-6 (DE-588)4174491-3 |
| title | Photoelectron spectroscopy Chemical and analytical aspects |
| title_auth | Photoelectron spectroscopy Chemical and analytical aspects |
| title_exact_search | Photoelectron spectroscopy Chemical and analytical aspects |
| title_full | Photoelectron spectroscopy Chemical and analytical aspects A. D. Baker and D. Betteridge |
| title_fullStr | Photoelectron spectroscopy Chemical and analytical aspects A. D. Baker and D. Betteridge |
| title_full_unstemmed | Photoelectron spectroscopy Chemical and analytical aspects A. D. Baker and D. Betteridge |
| title_short | Photoelectron spectroscopy |
| title_sort | photoelectron spectroscopy chemical and analytical aspects |
| title_sub | Chemical and analytical aspects |
| topic | Foto-elektronspectrometrie gtt Spectroscopie électronique Electron spectroscopy Elektronenspektroskopie (DE-588)4014332-6 gnd Photoelektronenspektroskopie (DE-588)4174491-3 gnd |
| topic_facet | Foto-elektronspectrometrie Spectroscopie électronique Electron spectroscopy Elektronenspektroskopie Photoelektronenspektroskopie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005989686&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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