Passivity and protection of metals against corrosion:
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New York
Plenum Pr.
1967
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | EST: Passivnost'i zaščita metallov ot korrozii <engl.> |
| Physical Description: | XV, 208 S. |
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MARC
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| 100 | 1 | |a Tomašov, Nikon D. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Passivity and protection of metals against corrosion |c Nikon D. Tomašov ; Galina P. Černova* |
| 264 | 1 | |a New York |b Plenum Pr. |c 1967 | |
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| 500 | |a EST: Passivnost'i zaščita metallov ot korrozii <engl.> | ||
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Record in the Search Index
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|---|---|
| adam_text | Passivity and Protection
of Metals Against Corrosion
Nikon D Tomashov
and Galina P Chernova
Institute of Physical Chemistry
Academy of Sciences of the USSR
Translated from Russian by
Boris H Tytell
Consulting Engineer
Greenwood, Massachusetts
i
Translation Editor
Herbert H Uhlig
Department of Metallurgy
Massachusetts Institute of Technology
Cambridge, Massachusetts
With a Foreword by
Edward C Greco
Research Department
United Gas Corporation
Shreveport, Louisiana
SP PLENUM PRESS • NEW YORK -3967
tJ
Contents
A Note on Soviet Alloy Designations xvi
Introduction 1
Chapter I
The Phenomenon of Passivity in Metals 9
Definition of Passivity 9
Mechanism and Theory of Passivity 12
Electrochemical Methods for Investigating Passivity 14
Anodic Potentiostatic Charge Curves 15
Anodic Galvanostatic Charge Curves 17
Cathodic Reduction Curves 18
Study of Potential Drop Curves 23
Measurement of the Double-Layer Capacity 25
Study of the Kinetics of Electrode Processes Under the Ac
tion of Alternating Currents 28
Investigation of the Nature and Structure of Passive Film s 32
Optical Method 32
Electron Diffraction 34
Microchemical Method for Determining Film Composit on 36
Kinetics of the Anodic Processes 38
Anodic Processes on a Passive Electrode 38
Method of Plotting Potentiostatic Curves 43
Chapter II
Passive Systems 55
Active State 55
Passive-Active State 56
Spontaneously Stable Passive State 58
Pitting Formation 60
xiii
xiv CONTENTS
The Transpassive State and Secondary Passivity 60
Construction of Corrosion Rate-Potential Curves 61
Chapter III
Basic Principles for Increasing the Corrosion Resistance of
Alloys by Increasing Their Passivity 67
Inhibiting the Anodic Process 67
Mechanism of Increasing Passivity by Alloying 67
Factors Determining Anodic Passivatioa of Alloys 68
Effect of the Anodic Process on Passivity of Alloys 79
Reduction of Corrosion in Passive Sysiems by Increasing
the Effectiveness of the Cathodic Process 81
Effect of the Cathodic Process on Passivity of Alloys 82
Mechanism of the Effect of Cathodic Alloying Elements 83
Significance of Anodic Passivation in Cathodic Alloying 86
Increase in Corrosion Resistance of Stainless Steels, Ti
tanium, Zirconium, and Chromium b^ Alloying with Ca
thodic Additives 91
Chapter IV
Anodic Protection 107
Anodic Protection of Stainless Steels 107
Effectiveness of Anodic Protection 107
Effect of Various Factors on the Parameters of Anodic »
Protection 110
Radius of Effective Anodic Protection 114
Anodic Protection and Intergranular Corrosion 117
Anodic Polarization and Corrosion Cracking 125
Effect of Halide Ions on Anodic Protect on 126
Anodic Protection of Carbon Steels 129
Anodic Protection of Titanium 135
Anodic Protection of Titanium in Sulfuric Acid 136
Anodic Protection of Titanium in Hydrochloric and Other
Acids 138
Practical Application of Anodic Protection 145
Prospects for the Development of Anodic Protection 149
Chapter V
Passivation of Metals by Contact with Cathodes 151
Use of Cathodic Protectors 151
Protection with Metallic Cathodes 152
Protection with Oxide Cathodes 156
CONTENTS xv
Protection Against Hydrogen Embrittlemcnt and Corrosion
Cracking 163
Cathodic Coatings 163
Introduction of Cations of Electropositive Metals into tie
Corrosive Medium 167
Chapter VI
Passivation of Metals by the Introduction of Oxidizers into tie
Corrosion Medium « 181
Mechanism of the Protective Effect of Oxidizing Inhibitors 181
Inhibitors Which Retard the Anodic Process 183
Oxidizers Which Increase the Effectiveness of the C i-
thodic Process ~ 185
Nature of the Oxidizing Inhibitor 189
Effect of the Metal and Aggressiveness of ilie Medium 195
References 199
Index 205
i
|
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| illustrated | Not Illustrated |
| indexdate | 2024-07-09T17:29:08Z |
| institution | BVB |
| language | English |
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| physical | XV, 208 S. |
| psigel | TUB-nveb |
| publishDate | 1967 |
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| publisher | Plenum Pr. |
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| spelling | Tomašov, Nikon D. Verfasser aut Passivity and protection of metals against corrosion Nikon D. Tomašov ; Galina P. Černova* New York Plenum Pr. 1967 XV, 208 S. txt rdacontent n rdamedia nc rdacarrier EST: Passivnost'i zaščita metallov ot korrozii <engl.> Korrosionsschutz (DE-588)4032522-2 gnd rswk-swf Korrosionsschutz (DE-588)4032522-2 s DE-604 Černova, Galina P. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005984016&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Tomašov, Nikon D. Černova, Galina P. Passivity and protection of metals against corrosion Korrosionsschutz (DE-588)4032522-2 gnd |
| subject_GND | (DE-588)4032522-2 |
| title | Passivity and protection of metals against corrosion |
| title_auth | Passivity and protection of metals against corrosion |
| title_exact_search | Passivity and protection of metals against corrosion |
| title_full | Passivity and protection of metals against corrosion Nikon D. Tomašov ; Galina P. Černova* |
| title_fullStr | Passivity and protection of metals against corrosion Nikon D. Tomašov ; Galina P. Černova* |
| title_full_unstemmed | Passivity and protection of metals against corrosion Nikon D. Tomašov ; Galina P. Černova* |
| title_short | Passivity and protection of metals against corrosion |
| title_sort | passivity and protection of metals against corrosion |
| topic | Korrosionsschutz (DE-588)4032522-2 gnd |
| topic_facet | Korrosionsschutz |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005984016&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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