Chemistry of aluminium, gallium, indium and thallium:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
London [u.a.]
Blackie Acad. & Professional
1993
|
| Ausgabe: | 1. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 526 S. Ill., graph. Darst. |
| ISBN: | 075140103X 9780751401035 |
Internformat
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| 245 | 1 | 0 | |a Chemistry of aluminium, gallium, indium and thallium |c ed. by A. J. Downs |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a London [u.a.] |b Blackie Acad. & Professional |c 1993 | |
| 300 | |a XI, 526 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 650 | 7 | |a Aluminium - Composés |2 ram | |
| 650 | 7 | |a Aluminium |2 ram | |
| 650 | 7 | |a Gallium - Composés |2 ram | |
| 650 | 7 | |a Gallium |2 ram | |
| 650 | 7 | |a Indium - Composés |2 ram | |
| 650 | 7 | |a Indium |2 ram | |
| 650 | 7 | |a Thallium - Composés |2 ram | |
| 650 | 7 | |a Thallium |2 ram | |
| 650 | 4 | |a Aluminum | |
| 650 | 4 | |a Gallium | |
| 650 | 4 | |a Indium | |
| 650 | 4 | |a Thallium | |
| 650 | 0 | 7 | |a Aluminium |0 (DE-588)4001573-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Thallium |0 (DE-588)4059684-9 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Gallium |0 (DE-588)4155859-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Indium |0 (DE-588)4161516-5 |2 gnd |9 rswk-swf |
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| 689 | 1 | |5 DE-604 | |
| 689 | 2 | 0 | |a Indium |0 (DE-588)4161516-5 |D s |
| 689 | 2 | |5 DE-604 | |
| 689 | 3 | 0 | |a Thallium |0 (DE-588)4059684-9 |D s |
| 689 | 3 | |5 DE-604 | |
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Datensatz im Suchindex
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| adam_text | IMAGE 1
CONTENTS
CHEMISTRY OF THE GROUP 13 METALS: SOME THEMES AND VARIATIONS 1 A.J.
DOWNS
1.1 INTRODUCTION: SOME CHARACTERISTICS OF THE GROUP 13 ELEMENTS 1
1.2 HISTORY AND OCCURRENCE 14
1.2.1 HISTORY 14
1.2.2 OCCURRENCE 16
1.3 PHYSICAL PROPERTIES OF METAL ATOMS 19
1.3.1 NUCLEAR PROPERTIES: ISOTOPES 19
1.3.2 PROPERTIES OF THE ATOMS 35
1.4 CHEMICAL PROPERTIES OF THE ELEMENTS AND THEIR COMPOUNDS 39
1.4.1 CHOICE OF OXIDATION STATE: + 1, + 2 OR + 3? 39
1.4.2 COORDINATION CHEMISTRY OF THE METALS 46
1.4.3 STRUCTURAL ASPECTS 49
1.4.4 COMPOUNDS WITH METAL-METAL BONDS 65
1.5 ORGANISATION OF SUBSEQUENT CHAPTERS 70
REFERENCES 72
THE ELEMENTS 81
I.J. POLMEAR
2.1 CHARACTERISTICS AND PHYSICAL PROPERTIES 81
2.2 EXTRACTION AND REFINING OF ALUMINIUM 83
2.2.1 BAYER PROCESS FOR ALUMINA PRODUCTION 84
2.2.2 ALTERNATIVE SOURCES OF ALUMINA 85
2.2.3 PRODUCTION OF ALUMINIUM BY THE HALL-HEROULT PROCESS 85
2.2.4 ALTERNATIVE METHODS FOR PRODUCING ALUMINIUM 87
2.3 PRODUCTION OF GALLIUM, INDIUM AND THALLIUM 88
2.3.1 PRODUCTION OF GALLIUM 88
2.3.2 PRODUCTION OF INDIUM 89
2.3.3 PRODUCTION OF THALLIUM 90
2.4 ALLOYING OF ALUMINIUM 91
2.4.1 ALLOYING ELEMENTS 91
2.4.2 CLASSIFICATION OF ALUMINIUM ALLOYS 92
2.4.3 NON-HEAT TREATABLE ALLOYS 93
2.4.4 HEAT TREATABLE ALLOYS 95
2.4.5 CORROSION BEHAVIOUR 98
2.4.6 NEW DEVELOPMENTS IN ALUMINIUM ALLOYS 100
2.5 USES OF THE ELEMENTS 103
2.5.1 ALUMINIUM AND ITS ALLOYS 103
2.5.2 USES OF GALLIUM 105
2.5.3 USES OF INDIUM 106
2.5.4 USES OF THALLIUM 108
REFERENCES 109
INORGANIC DERIVATIVES OF THE ELEMENTS 111
M.J. TAYLOR AND P.J. BROTHERS
3.1 INTRODUCTION 111
3.2 DERIVATIVES OF THE TRIVALENT STATE 118
3.2.1 HYDRIDES 118
IMAGE 2
3.2.2 BINARY HALIDES
3.2.3 DERIVATIVES WITH BONDS TO OXYGEN 138
3.2.4 DERIVATIVES WITH BONDS TO SULFUR, SELENIUM OR TELLURIUM 161
3.2.5 DERIVATIVES WITH BONDS TO GROUP 15 ATOMS 168
3.2.6 DERIVATIVES WITH BONDS TO BORON OR GROUP 14 ATOMS 181
3.2.7 PSEUDOHALIDE DERIVATIVES 190
3.3 DERIVATIVES OF THE LOWER VALENCE STATES 191
3.3.1 LOW OXIDATION STATES IN GROUP 13 191
3.3.2 LOW-VALENT HYDRIDES 195
3.3.3 LOW-VALENT HALIDES 198
3.3.4 LOW-VALENT OXIDES, HYDROXIDES, ALKOXIDES AND OXYANION SALTS 207
3.3.5 LOW-VALENT SULFIDES, SELENIDES AND TELLURIDES 211
3.3.6 LOW-VALENT CARBONYLS AND ORGANOMETALLIC DERIVATIVES 215
3.4 INTERMETALLIC DERIVATIVES 216
3.4.1 MOLECULAR SPECIES 216
3.4.2 INTERMETALLIC COMPOUNDS 217
3.4.3 GROUP 13 TRANSITION-METAL CARBONYL DERIVATIVES 226
REFERENCES 230
PROPERTIES AND USES OF OXIDES AND HYDROXIDES 248
K.A. EVANS
4.1 ALUMINIUM OXIDES AND HYDROXIDES 248
4.2 NOMENCLATURE 249
4.3 PHYSICAL PROPERTIES AND METHODS OF SYNTHESIS 249
4.3.1 ALUMINIUM HYDROXIDES 249
4.3.2 ALUMINIUM OXIDE HYDROXIDE 252
4.3.3 ALUMINIUM OXIDE 253
4.3.4 USES OF ALUMINIUM HYDROXIDES 257
4.3.5 USES OF ALUMINIUM OXIDE 266
4.4 ACTIVATED ALUMINA 280
4.4.1 INTRODUCTION 280
4.4.2 PRODUCTION OF ACTIVATED ALUMINA 281
4.4.3 USES OF ACTIVATED ALUMINA 282
4.5 OXIDES AND HYDROXIDES OF GALLIUM, INDIUM AND THALLIUM 284
4.5.1 GALLIUM OXIDES: FORMS, PREPARATION AND STRUCTURE 284
4.5.2 USES OF GALLIUM(III) OXIDE 285
4.5.3 GALLIUM HYDROXIDES: FORMS AND PREPARATION 285
4.5.4 INDIUM OXIDES 285
4.5.5 USES OF INDIUM OXIDES 286
4.5.6 INDIUM HYDROXIDE 286
4.5.7 THALLIUM OXIDES 286
4.5.8 THALLIUM HYDROXIDE 287
4.5.9 SUPERCONDUCTIVITY OF THALLIUM-CONTAINING COMPOUNDS 287
4.5.10 SUPERCONDUCTING COMPONENTS CONTAINING ALUMINIUM OR GALLIUM 288
REFERENCES 288
III-V COMPOUNDS 292
I.R. GRANT
5.1 INTRODUCTION 292
5.2 PROPERTIES OF THE COMPOUNDS 296
5.2.1 BONDING AND CRYSTAL STRUCTURE 296
5.2.2 PHASE EQUILIBRIA AND VAPOUR PRESSURE 299
5.3 BINARY COMPOUND SYNTHESIS 301
5.3.1 GAAS AND INAS
IMAGE 3
5.3.2 INP AND GAP 302
5.3.3 SINGLE CRYSTAL GROWTH 305
5.4 INFLUENCES ON ELECTRICAL PROPERTIES 306
5.4.1 IMPURITIES 306
5.4.2 DEFECTS 309
5.5 INTERMETALLIC ALLOYS 311
5.6 EPITAXIAL LAYER GROWTH 313
5.6.1 LIQUID PHASE EPITAXY 313
5.6.2 VAPOUR PHASE EPITAXY 314
5.6.3 MOLECULAR BEAM EPITAXY 316
5.7 CHEMICAL REACTIVITY 317
5.7.1 SURFACE OXIDES 317
5.7.2 WET CHEMICAL ETCHING 318
5.7.3 DRY ETCHING 319
5.8 CONCLUSION 319
REFERENCES 320
ORGANOMETALLIC COMPOUNDS: SYNTHESIS AND PROPERTIES 322
K.B. STAROWIEYSKI
6.1 INTRODUCTION AND BASIC LITERATURE 322
6.2 SYNTHESIS OF ORGANO DERIVATIVES 323
6.2.1 GENERAL CONSIDERATIONS 323
6.2.2 METHODS OF SYNTHESIS 324
6.3 METAL VAPOUR REACTIONS 328
6.4 PHYSICAL PROPERTIES AND STRUCTURES 332
6.5 COMPLEXES WITH NEUTRAL BASES AND THEIR REACTIVITY 342
6.5.1 SYNTHESIS AND STRUCTURE OF COMPLEXES 342
6.5.2 REACTIVITY OF COMPLEXES 349
6.6 ORGANO DERIVATIVES OF THE ELEMENTS IN LOWER OXIDATION STATES 351
6.7 MIXED METAL DERIVATIVES 356
6.7.1 COMPOUNDS WITH DIRECT M-M BONDS 357
6.7.2 COMPOUNDS WITH BRIDGED M * * * M UNITS 360
6.7.3 COMPOUNDS WITH DIFFERENT METALS CONNECTED THROUGH CHAINS OF MORE
THAN ONE HETEROATOM 363
6.7.4 SALT-LIKE COMPOUNDS 364
BIBLIOGRAPHY AND REVIEWS 365
REFERENCES 366
ORGANIC TRANSFORMATIONS MEDIATED BY GROUP 13 METAL COMPOUNDS 372 J.A.
MILLER
7.1 ORGANOALUMINIUM COMPOUNDS 372
7.1.1 INTRODUCTION 372
7.1.2 TRANSFORMATIONS OF ALKENES AND ALKYNES 373
7.1.3 SELECTIVE REDUCTION AND ALKYLATION OF CARBONYL COMPOUNDS 391
7.1.4 REARRANGEMENTS 395
7.1.5 ASYMMETRIC TRANSFORMATIONS 398
7.2 ORGANOGALLIUM AND -INDIUM COMPOUNDS 403
7.2.1 INTRODUCTION 403
7.2.2 REACTIONS WITH CARBONYL COMPOUNDS 404
7.2.3 OTHER CARBON-CARBON BOND FORMING REACTIONS 406
7.3 ORGANOTHALLIUM COMPOUNDS 408
7.3.1 INTRODUCTION 408
7.3.2 THALLATION AND FUNCTIONALISATION OF AROMATIC COMPOUNDS 409
7.3.3 OXYTHALLATION OF UNSATURATED ORGANIC COMPOUNDS 412
IMAGE 4
7.3.4 HETEROCYCLISATION REACTIONS 416
7.3.5 CARBON-CARBON BOND FORMING REACTIONS 419
REFERENCES 422
THE COORDINATION AND SOLUTION CHEMISTRY OF ALUMINIUM, GALLIUM, INDIUM
AND THALLIUM 430
D.G. TUCK
8.1 INTRODUCTION 430
8.2 HYDRIDE COMPLEXES 432
8.2.1 DERIVATIVES OF MH 3 432
8.2.2 BOROHYDRIDE DERIVATIVES 433
8.3 HALIDE COMPLEXES 433
8.3.1 INTRODUCTION 433
8.3.2 NEUTRAL COMPLEXES WITH MONODENTATE LIGANDS 434
8.3.3 NEUTRAL COMPLEXES WITH POLYDENTATE LIGANDS 439
8.3.4 THE STABILITY OF NEUTRAL ADDUCTS 441
8.3.5 ANIONIC COMPLEXES WITH HALIDE LIGANDS 443
8.3.6 THE STABILITIES OF ANIONIC COMPLEXES 447
8.3.7 ANIONIC MIXED HALIDE AND HALIDE/OTHER LIGAND COMPLEXES 449
8.4 COMPLEXES WITH GROUP 16 DONORS 450
8.4.1 OXYGEN DONOR COMPLEXES 450
8.4.2 COMPLEXES WITH GROUP 15 OXYANIONS 450
8.4.3 COMPLEXES WITH GROUP 16 OXYANIONS 451
8.4.4 GROUP 14 OXYANION COMPLEXES 452
8.4.5 HYDROXIDE AND ALKOXIDE COMPLEXES 453
8.4.6 COMPLEXES OF SS -KETOENOLATE, DIOLATE AND RELATED LIGANDS 454
8.4.7 SULFUR, THIOLATE AND SELENOLATE COMPLEXES 456
8.4.8 BIDENTATE SULFUR LIGAND DERIVATIVES 456
8.5 GROUP 15 DERIVATIVES 457
8.5.1 COMPLEXES OF NEUTRAL MONO- AND BIDENTATE NITROGEN DONORS 457
8.5.2 AMIDE AND IMIDE COMPLEXES 457
8.5.3 AZIDE, CYANATE, THIOCYANATE AND SELENOCYANATE DERIVATIVES 458
8.5.4 COMPLEXES WITH PHOSPHORUS, ARSENIC AND ANTIMONY DONORS 459
8.5.5 MIXED LIGAND COMPLEXES INCLUDING GROUP 15 DONORS 460
8.6 AQUO COMPLEXES AND SOLUTION SPECIES 460
8.6.1 AQUO AND OTHER CATIONIC COMPLEXES 460
8.6.2 HYDROLYSIS OF M 3+(AQ) IONS 462
8.6.3 STABILITY CONSTANT STUDIES 462
8.6.4 SOLUTION SPECIES OTHER THAN M 3+(AQ) 462
8.6.5 REDOX PROPERTIES 465
8.7 LOWER OXIDATION STATES 465
8.7.1 INDIUM(I) 466
8.7.2 THALLIUM(I) 467
8.7.3 GALLIUM(II) AND INDIUM(II) COMPLEXES 468
8.7.4 THALLIUM(II) 469
REFERENCES 470
THE ELEMENTS IN THE ENVIRONMENT 474
R.B. MARTIN
9.1 INTRODUCTION 474
9.2 GEOCHEMISTRY 475
9.2.1 ABUNDANCES 475
9.2.2 ALUMINIUM 476
IMAGE 5
9.2.3 GALLIUM
9.2.4 INDIUM
9.2.5 THALLIUM
9.3 ENVIRONMENTAL ASPECTS 9.3.1 AL 3+ HYDROLYSIS 9.3.2 PAL = - L O G [ A
L 3 + ]
9.4 BIOLOGICAL ASPECTS 9.4.1 PHOSPHATE BINDING 9.4.2 PLASMA CARRIERS OF
ALUMINIUM 9.5 TOXICOLOGY
9.5.1 ALUMINIUM 9.5.2 GALLIUM
9.5.3 INDIUM
9.5.4 THALLIUM
REFERENCES
10 ANALYTICAL METHODS H. ONISHI
10.1 ALUMINIUM 10.1.1 SEPARATIONS 10.1.2 METHODS OF DETERMINATION 10.1.3
ANALYSIS OF ALUMINIUM AND ALUMINIUM ALLOYS 10.2 GALLIUM
10.2.1 SEPARATIONS 10.2.2 METHODS OF DETERMINATION 10.2.3 ANALYSIS OF
GALLIUM AND GALLIUM ARSENIDE 10.3 INDIUM
10.3.1 SEPARATIONS 10.3.2 METHODS OF DETERMINATION 10.4 THALLIUM
10.4.1 SEPARATIONS 10.4.2 METHODS OF DETERMINATION REFERENCES
INDEX
477 477 477 478 479 481 483 483
484 485 485 487
487 488 488
491
491 491 492 496 496 496 497 499 499
500 500 502
503 503 507
511
|
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| dewey-ones | 546 - Inorganic chemistry |
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| dewey-search | 546/.67 |
| dewey-sort | 3546 267 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| edition | 1. ed. |
| format | Book |
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| id | DE-604.BV008184682 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:15:58Z |
| institution | BVB |
| isbn | 075140103X 9780751401035 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-005401737 |
| oclc_num | 27265357 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-703 DE-11 DE-188 |
| owner_facet | DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-703 DE-11 DE-188 |
| physical | XI, 526 S. Ill., graph. Darst. |
| publishDate | 1993 |
| publishDateSearch | 1993 |
| publishDateSort | 1993 |
| publisher | Blackie Acad. & Professional |
| record_format | marc |
| spelling | Chemistry of aluminium, gallium, indium and thallium ed. by A. J. Downs 1. ed. London [u.a.] Blackie Acad. & Professional 1993 XI, 526 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Aluminium - Composés ram Aluminium ram Gallium - Composés ram Gallium ram Indium - Composés ram Indium ram Thallium - Composés ram Thallium ram Aluminum Gallium Indium Thallium Aluminium (DE-588)4001573-7 gnd rswk-swf Thallium (DE-588)4059684-9 gnd rswk-swf Gallium (DE-588)4155859-5 gnd rswk-swf Indium (DE-588)4161516-5 gnd rswk-swf Aluminium (DE-588)4001573-7 s DE-604 Gallium (DE-588)4155859-5 s Indium (DE-588)4161516-5 s Thallium (DE-588)4059684-9 s Downs, Anthony J. Sonstige (DE-588)174099460 oth OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005401737&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Chemistry of aluminium, gallium, indium and thallium Aluminium - Composés ram Aluminium ram Gallium - Composés ram Gallium ram Indium - Composés ram Indium ram Thallium - Composés ram Thallium ram Aluminum Gallium Indium Thallium Aluminium (DE-588)4001573-7 gnd Thallium (DE-588)4059684-9 gnd Gallium (DE-588)4155859-5 gnd Indium (DE-588)4161516-5 gnd |
| subject_GND | (DE-588)4001573-7 (DE-588)4059684-9 (DE-588)4155859-5 (DE-588)4161516-5 |
| title | Chemistry of aluminium, gallium, indium and thallium |
| title_auth | Chemistry of aluminium, gallium, indium and thallium |
| title_exact_search | Chemistry of aluminium, gallium, indium and thallium |
| title_full | Chemistry of aluminium, gallium, indium and thallium ed. by A. J. Downs |
| title_fullStr | Chemistry of aluminium, gallium, indium and thallium ed. by A. J. Downs |
| title_full_unstemmed | Chemistry of aluminium, gallium, indium and thallium ed. by A. J. Downs |
| title_short | Chemistry of aluminium, gallium, indium and thallium |
| title_sort | chemistry of aluminium gallium indium and thallium |
| topic | Aluminium - Composés ram Aluminium ram Gallium - Composés ram Gallium ram Indium - Composés ram Indium ram Thallium - Composés ram Thallium ram Aluminum Gallium Indium Thallium Aluminium (DE-588)4001573-7 gnd Thallium (DE-588)4059684-9 gnd Gallium (DE-588)4155859-5 gnd Indium (DE-588)4161516-5 gnd |
| topic_facet | Aluminium - Composés Aluminium Gallium - Composés Gallium Indium - Composés Indium Thallium - Composés Thallium Aluminum |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005401737&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT downsanthonyj chemistryofaluminiumgalliumindiumandthallium |