Absorption spectroscopy in mineralogy:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Amsterdam u.a.
Elsevier
1990
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIX, 294 S. graph. Darst. |
| ISBN: | 0444887997 |
Staff View
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| 245 | 1 | 0 | |a Absorption spectroscopy in mineralogy |c ed. by Annibale Mottana ... |
| 264 | 1 | |a Amsterdam u.a. |b Elsevier |c 1990 | |
| 300 | |a XIX, 294 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Espectroscopia |2 larpcal | |
| 650 | 7 | |a Mineralogia |2 larpcal | |
| 650 | 4 | |a Atomic absorption spectroscopy | |
| 650 | 4 | |a Mineralogy, Determinative | |
| 650 | 4 | |a Spectrum analysis | |
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Record in the Search Index
| _version_ | 1804122519146332160 |
|---|---|
| adam_text | CONTENTS
Chapter
1. SOMK
CONTRIBUTIONS OF SPECTRAL STUDIES IN THE VISIBLE
(AND NEAR VISIBLE) LIGHT REGION TO KINERALOGY.
D. J. VAUGHAN
Abstract
.......................................................2
Introduction
...................................................3
Experimental
...................................................5
Theoretical Aspects
............................................6
Crystal field transitions
.................................7
Ligand-metal charge transfer transitions
.................11
Metal-aetal charge transfer transitions
..................12
Transitions involving energy bands
.......................13
Applications
..................................................17
Concluding Remarks
............................................29
Acknowledgements
..............................................30
References
....................................................31
Chapter
2.
CONTRIBUTION OF RAMAN MICROSPECTROHETRY
TO THE STUDY OF MINERALS.
J. H. MALEZIEUZ
Introduction
..................................................40
1.
Theoretical Principles of Raman Diffusion
..................41
2.
Information
................................................43
3.
Instruments and Methods
....................................43
3.a. The device
..........................................43
3.b. The methodology
.....................................44
4.
Applications to Mineral Study
..............................44
4.
a. Mineral identification
..............................44
4.b. Vibrational behaviour of solid solutions
............45
4.C.
P
-Т
studies
.........................................45
4.
c.l. Phase transitions
.............................45
4.C.2. Determination of thermodynamic parameters
___46
5.
Examples
...................................................48
S.a.
Identification of mineral species and
fluid inclusions
.............................48
S.a.l. Mineral species
..............................48
5.8.2.
Fluid
inclusione
.............................48
5.
b. Vibrational
behaviour of solid solutions: spinels
...50
5.C. Raman studies at various
P
and
T
....................53
S.c.l. Raman study of
СаСОЗ
(calcite
form)
..........53
5.
с.
2.
HT
and HP studies of Ca2 GeO4
(olivine
form)
...............................57
6.
Conclusions
.................................................58
Reference List
................................................58
Recommended Reading
...........................................59
Chapter
3.
NUCLEAR HfiGHETIC
RESOHÄHCE
SPECTROSCOPY
AND
Al Si ORDENING
IN MINERALS.
A. PUTOIS
Abstract
......................................................62
1.
Introduction
...............................................62
1.1
Magnetic resonance
..................................63
1.2
Chemical shift
......................................63
1.3
HMR of solids
.......................................64
1.4
Nuclear
quadrupede
resonance
........................65
1.5
Relaxation times
....................................66
1.6
Fourier transform techniques
........................67
1.7
High resolution solid state NHR
-
Magic angle spinning
.........................67
2.
29Si Magic Angle Spinning HMR
.............................69
2.1
29Si NMR spectra
....................................70
2.2
Peak areas and Si site populations
..................70
2.3
Empirical correlations of 29Si chemical shifts
......73
3.
29Si Site Assignments
.....................................75
3.1
Si site assignments in ordered cordierite
...........75
3.2
Al,Si
ordering in Mg-cordierite from
29Si NMR spectra
.............................79
3.3
Al-O-Al linkages in cordierite
......................82
3.4
Correlation of
N(Al-Al)
with X-ray
synchrotron data in cordierite
...............84
3.5
Correlation of NMR with
IR spectroscopy
of cordierite
................................86
3.6
29Si HMR spectroscopy of a new synthetic
BeMg-cordierite
..............................88
4.
KMR Spectra of Quadrupolar Nuclei
.........................89
4.1
27A1 MAS NMR spectra
................................90
4.2
Al(4)
/
A1<6V coordination
,.........................92
5.
NMR Studies of
Al,Si
Order in Tetragonal
Leucite
..........92
6.
Conclusions
...............................................96
7.
References
................................................98
Chapter
4.
DISTRIBUTION OF IONS IN PHYLLOSILICATES
BY NMR SPECTROSCOPY.
J. SANZ
Abstract
.....................................................104
Introduction
.................................................105
Preliminary Considerations
...................................106
NMR Applications
.............................................
Ill
1.
Tetrahedral polymerization
...........................
Ill
2.
Structural sites
.....................................113
3.
Coordination number
..................................117
4.
Tetrahedral cation distribution
......................119
5.
Octahedral cation distribution
.......................127
6.
Kaolin-Mullite transformation
........................137
Conclusions
..................................................140
References
...................................................141
Chapter
5.
PHASE TRANSFORMATIONS IN MINERALS STUDIED
BY 57Fe
MÖSSBAUER
SPECTROSCOPY.
F. SEIFERT
Abstract
.....................................................146
1.
Introduction
.............................................146
2.
Mössbauer
Parameters
.....................................147
2.1
Debye-Waller factor
.................................147
2.2
Line shape and line width
...........................148
2.3 Isomer
shift
........................................149
2.4
Quadxupole splitting
................................150
2.5
Nuclear
Zeeman
splitting
............................152
3.
Phase Transitions and
Mössbauer Spectroscopy
.............153
4.
Specific Examples
........................................154
4.1
Structural Phase Transitions
........................154
4.1.1
Changes in the first coordination shell
......15«
a. Reconstructive phase transitions
.........154
b. Dilatative phase transitions
.............155
4.1.2
Changes in the second coordination shell
.....156
a. Reconstructive phase transitions
.........156
b. Displacive phase transitions
.............157
4.1.3
Phase transitions involving order-disorder
...157
a. Substitutive
phase transitions
...........157
b. Distortive and rotative transitions
......160
4.2
Electronic Transitions
..............................163
4.2.1
Intervalence
charge-transfer transitions
.....163
4.2.2
Spin changes in iron complexes
...............163
4.3
Magnetic transitions
................................164
5.
Concluding Remarks
........................................165
References
...................................................166
Chapter
6.
APPLICATION
OF EXAFS IN MINERALOGY.
6.
CALAS,
A. MANCEAU,
Ј.-И.
COMBES and F. FARGES
Abstract
.....................................................172
Introduction
.................................................172
General Presentation of
XAS
..................................174
Experimental Techniques
......................................177
Some general properties of synchrotron radiation
........177
The spectrometer
........................................179
The monochromator
.......................................179
The detection
...........................................180
EXAFS
........................................................181
Outline of the EXAFS theory
.............................181
Extraction of the information
...........................185
Mineralogical Applications
...................................186
Intersite
distribution
..................................186
Determination of oxidation states
.......................189
Intracrystalline distribution
...........................191
Crystal chemistry of Fe-Hn oxide minerals and gels
......192
Structure of silicate glasses
...........................193
Nucleation processes in glasses
.........................197
Metamict minerals
.......................................198
Conclusions
..................................................198
Acknowledgements
.............................................199
References
...................................................200
Chapter
7.
PRINCIPLES AND RECENT DEVELOPMENTS
OF
XAHES SPECTROSCOPy.
I. DAVOLI and E. PARIS
Abstract
.....................................................206
Introduction
.................................................207
Experimental Requirements
....................................209
General considerations
..................................209
Detection method
........................................213
Theoretical Interpretation of
XAHES
..........................215
Experimental Verification
....................................219
Acknowledgements
.............................................223
References
........................
¿...è
......................224
XMH
Chapter
8.
HIGH PRESSURE SPECTROSCOPY
K.
LANGER
Abstract
.....................................................228
1.
Introduction
.............................................229
2.
Units
....................................................229
3.
Methods
..................................................230
4.
Some
Mineralogicei
Applications and Results
of High Pressure Spectroscopy
......................241
4.1
Vibrational spectroscopy
(IR,
Raman)
................241
4.2
High pressure
Mössbauer
spectra
.....................249
4.3
High pressure electronic spectra
....................257
5.
Outlook
..................................................274
Acknowledgements
.............................................276
Literature
...................................................276
SUBJECT
ВГОЕХ
................................................285
xix
|
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| genre | (DE-588)1071861417 Konferenzschrift 1988 Rom gnd-content |
| genre_facet | Konferenzschrift 1988 Rom |
| id | DE-604.BV008138553 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:15:10Z |
| institution | BVB |
| isbn | 0444887997 |
| language | English |
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| physical | XIX, 294 S. graph. Darst. |
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| spelling | Absorption spectroscopy in mineralogy ed. by Annibale Mottana ... Amsterdam u.a. Elsevier 1990 XIX, 294 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Espectroscopia larpcal Mineralogia larpcal Atomic absorption spectroscopy Mineralogy, Determinative Spectrum analysis Absorptionsspektroskopie (DE-588)4141129-8 gnd rswk-swf Mineralogie (DE-588)4039457-8 gnd rswk-swf (DE-588)1071861417 Konferenzschrift 1988 Rom gnd-content Mineralogie (DE-588)4039457-8 s Absorptionsspektroskopie (DE-588)4141129-8 s DE-604 Mottana, Annibale Sonstige oth Digitalisierung TU Muenchen application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005368037&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Absorption spectroscopy in mineralogy Espectroscopia larpcal Mineralogia larpcal Atomic absorption spectroscopy Mineralogy, Determinative Spectrum analysis Absorptionsspektroskopie (DE-588)4141129-8 gnd Mineralogie (DE-588)4039457-8 gnd |
| subject_GND | (DE-588)4141129-8 (DE-588)4039457-8 (DE-588)1071861417 |
| title | Absorption spectroscopy in mineralogy |
| title_auth | Absorption spectroscopy in mineralogy |
| title_exact_search | Absorption spectroscopy in mineralogy |
| title_full | Absorption spectroscopy in mineralogy ed. by Annibale Mottana ... |
| title_fullStr | Absorption spectroscopy in mineralogy ed. by Annibale Mottana ... |
| title_full_unstemmed | Absorption spectroscopy in mineralogy ed. by Annibale Mottana ... |
| title_short | Absorption spectroscopy in mineralogy |
| title_sort | absorption spectroscopy in mineralogy |
| topic | Espectroscopia larpcal Mineralogia larpcal Atomic absorption spectroscopy Mineralogy, Determinative Spectrum analysis Absorptionsspektroskopie (DE-588)4141129-8 gnd Mineralogie (DE-588)4039457-8 gnd |
| topic_facet | Espectroscopia Mineralogia Atomic absorption spectroscopy Mineralogy, Determinative Spectrum analysis Absorptionsspektroskopie Mineralogie Konferenzschrift 1988 Rom |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005368037&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mottanaannibale absorptionspectroscopyinmineralogy |