The analytical chemistry of silicones:
Saved in:
| Format: | Book |
|---|---|
| Language: | Undetermined |
| Published: |
New York u.a.
Wiley
1991
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| Series: | Chemical analysis
112. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XXII, 551 S. Ill., graph. Darst. |
| ISBN: | 0471516244 |
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MARC
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| 245 | 1 | 0 | |a The analytical chemistry of silicones |c ed. by A. Lee Smith |
| 264 | 1 | |a New York u.a. |b Wiley |c 1991 | |
| 300 | |a XXII, 551 S. |b Ill., graph. Darst. | ||
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| 490 | 1 | |a Chemical analysis |v 112. | |
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| adam_text | THE ANALYTICAL CHEMISTRY OF SILICONES EDITED BY A. LEE SMITH ANALYTICAL
RESEARCH DEPARTMENT DOW CORNING CORP. MIDLAND, MICHIGAN A
WILEY-INTERSCIENCE PUBLICATION JOHN WILEY & SONS, INC. NEW YORK /
CHICHESTER / BRISBANE / TORONTO / SINGAPORE CONTENTS PART 1.
INTRODUCTION 1 CHAPTER 1. INTRODUCTION TO SILICONES 3 A. LEE SMITH 1.
INTRODUCTION ., 3 2. NOMENCLATURE 4 3. PROPERTIES 8 4. CHEMISTRY OF THE
SILICONES 10 5. THE PHYSICAL CHEMISTRY OF ORGANOSILICON COMPOUNDS 13
REFERENCES 16 PART 2. THE PROBLEM-ORIENTED APPROACH 21 CHAPTER 2. THE
ANALYTICAL CHEMISTRY OF ORGANO- SILICON MATERIALS 23 A. LEE SMITH 1.
DEFINING THE PROBLEM 23 2. SAMPLING 27 3. ANALYSIS OF MONOMERS AND
OLIGOMERS 28 3.1. IDENTIFICATION 29 3.2. ANALYSIS OF PURE AND MIXED
MONOMERS 29 3.3. ANALYSIS OF OLIGOMERS 31 4. APPROACHES TO POLYMER
ANALYSIS 31 5. DETERMINATION OF MOLECULAR STRUCTURE 34 6. ANALYSIS FOR
TRANSIENT SPECIES 34 7. STRUCTURE-PROPERTY RELATIONSHIPS 35 8. QUALITY
IN THE ANALYTICAL LABORATORY 36 8.1. SAFETY HAZARDS AND PRACTICES 36
8.2. GOOD LABORATORY PRACTICES 36 IX X CONTENTS 8.2.1. SAMPLING 37
8.2.2. QUALITY VERIFICATION OF LABORATORY OPERATIONS 37 8.3. CLEANING
GLASSWARE AND OTHER MATERIALS 39 REFERENCES 42 CHAPTER 3. ANALYSIS OF
POLYMERS, MIXTURES, AND COMPOSITIONS 47 N. C. ANGELOTTI 1. INTRODUCTION
47 1.1. SCREENING TESTS 47 2. FLUIDS AND GUMS 48 2.1. PURE FLUIDS. . .
48 2.1.1. GENERAL 48 2.1.2. ANALYSIS 48 2.2. FLUIDS IN FORMULATIONS 51
2.2.1. IN SITU ANALYSIS 51 2.2.2. SEPARATION TECHNIQUES 51 2.3. HYBRID
FLUIDS 52 2.4. EMULSIONS 53 2.4.1. SEPARATION TECHNIQUES 53 2.4.2.
ANALYSIS 54 2.4.3. EMULSIFIER CHARACTERIZATION 56 2.5. GREASES 59 2.6.
PAPER, TEXTILE, AND LEATHER TREATMENTS 61 3. RESINS 61 3.1. GENERAL 61
3.2. RESIN CHARACTERIZATION 62 4. COUPLING AGENTS 63 5. SEALANTS 64 5.1.
GENERAL 64 5.2. ANALYSIS 64 6. ELASTOMERS 66 6.1. GENERAL 66 6.2.
ANALYSIS 66 REFERENCES 68 CONTENTS XI CHAPTER 4. TRACE ANALYSIS
INVOLVING SILICONES . . 71 A. LEE SMITH AND R. D. PARKER 1. INTRODUCTION
71 1.1. THE ANALYTICAL PROCEDURA 71 1.2. CONTAMINATION 72 1.3. LOSSES OF
SILICONES 74 2. ANALYSIS FOR SILICONES IN FOODS 75 2.1. THE ANALYTICAL
METHOD 75 2.2. TOTAL SILICON METHODS 76 2.3. SOLVENT EXTRACTION METHODS
77 2.4. MIGRATION FROM PACKAGING MATERIALS 78 3. SILICONES IN THE
ENVIRONMENT 80 3.1. SAMPLING AND ANALYSIS 80 3.1.1. ANALYSIS OF SOILS
AND SEDIMENTS 81 3.1.2. ANALYSIS OF WATER 81 3.1.3. ANALYSIS OF AIR 84
4. SILICONES IN PROCESS MATERIALS 85 5. SILICONES IN MEDICAL AND
BIOLOGICAL APPLICATIONS . . 86 5.1. MEDICAL USES OF SILICONES 86 5.2.
DEFINING THE PROBLEM 87 5.3. ANALYSIS OF PROCESSING AND SYNTHETIC AIDS
87 5.4. THERAPEUTIC AGENTS 88 5.5. MEDICAL DEVICES 88 5.6. SUMMARY 89
5.7. ANALYSIS OF SILICONE MATERIALS FOR TRACE CONTAMINANTS .... 89
REFERENCES 91 CHAPTER 5. ANALYSIS OF SURFACES 97 M. J. OWEN 1.
INTRODUCTION 97 1.1. DEFINING THE SURFACE 99 1.2. SAMPLE HANDLING 99 2.
INFORMATION PROVIDED BY KEY TECHNIQUES 100 2.1. STRUCTURAL INFORMATION
100 2.2. SURFACE PHYSICAL PROPERTIES 102 XLL CONTENTS 2.3. CHEMICAL
COMPOSITION 103 2.4. SUMMARY 107 3. COMMON SAMPLE TYPES ENCOUNTERED 108
3.1. CONTAMINATED SURFACES 108 3.2. SILANE COUPLING AGENTS AND PRIMERS
110 3.3. OTHER APPLIED COATINGS AND FILMS 110 3.4. POLYMER SURFACES 111
3.5. COPOLYMERS AND BLENDS 111 REFERENCES 112 CHAPTER 6. PERSONAL CARE
APPLICATIONS 117 HELEN M. KLIMISCH 1. INTRODUCTION 117 2. TYPES OF
SILICONES USED 118 2.1. DIMETHICONE 120 2.2. CYCLOMETHICONES 123 2.3.
DIMETHICONE COPOLYOL 123 2.4. AMINOFUNCTIONAL POLYMERS 124 3. SILICONES
IN FORMULATED PRODUCTS 124 3.1. SEPARATION TECHNIQUES 125 3.2.
IDENTIFICATION. 126 3.3. QUANTITATION 127 4. SILICONES ON SURFACES 127
4.1. TOTAL SI METHODS 128 4.2. SILOXANE SPECIFIC METHODS 129 REFERENCES
132 PART 3. THE BASIC TECHNIQUES 133 CHAPTER 7. PHYSICAL PROPERTIES AND
POLYMER STRUCTURE 135 O. L. FLANINGAM AND N. R. LANGLEY 1. INTRODUCTION
135 2. THE MEASUREMENT OF PHYSICAL PROPERTIES 135 2.1. REFRACTIVE INDEX
136 2.2. DENSITY AND SPECIFIC GRAVITY 138 CONTENTS X1H 2.3. FLASH POINT
140 2.4. VISCOSITY 140 2.4.1. MEASUREMENT OF VISCOSITY 141 2.4.2.
CLEANING VISCOMETERS 142 2.4.3. SILICONE FLUIDS AS STANDARDS 142 2.4.4.
FLOW BEHAVIOR OF SILICONE FLUIDS 143 2.5. MELTING POINT 144 2.6. VAPOR
PRESSURE, BOILING POINT, AND HEAT OF VAPORIZATION . . 144 2.6.1. VAPOR
PRESSURE 144 2.6.2. HEAT OF VAPORIZATION 145 2.7. VAPOR-LIQUID
EQUILIBRIUM 145 2.8. AUTOIGNITION TEMPERATURE 146 2.9. FLAMMABLE LIMITS
150 3. STRUCTURE AND PROPERTIES OF POLYMERS 150 3.1. MOLECULAR WEIGHT
150 3.1.1. SIGNIFICANCE 150 3.1.2. DESCRIPTION . . 151 3.1.3.
MEASUREMENT 152 3.1.4. EFFECTS OF MWD ON PROPERTIES 155 3.2. BRANCHING
156 3.2.1.1. SIGNIFICANCE 156 3.2.1.2. MEASUREMENT 157 3.3.
CROSS-LINKING 158 3.3.1.1. SIGNIFICANCE 158 3.3.1.2. MEASUREMENT 159
3.4. PHASE COMPOSITION 161 3.4.1.1. PHASES IN POLYMER SYSTEMS 161
3.4.1.2. METHODS OF PHASE DETECTION 161 3.5. THERMAL STABILITY OF THE
STRUCTURE . 163 REFERENCES 165 CHAPTER 8. CHEMICAL ANALYSIS 175 M. D.
GAUL AND N. C. ANGELOTTI 1. INTRODUCTION 175 2. ELEMENTAL ANALYSIS 175
XIV CONTENTS 2.1. SILICON 175 2.1.1. QUALITATIVE TESTS 176 2.1.2.
DECOMPOSITION PROCEDURES 177 2.1.3. QUANTITATIVE SILICON ANALYSIS
METHODS 180 2.1.4. UNSUBSTITUTED SILICON 183 2.2. CARBON, HYDROGEN AND
NITROGEN . 184 2.3. OXYGEN 186 2.4. HALOGENS 187 2.4.1. QUALITATIVE
TESTS FOR HALOGENS 187 2.4.2. QUALITATIVE ANALYSIS FOR HYDROLYZABLE
HALIDE 187 2.4.3. TOTAL HALIDE METHODS 187 2.5. SULFUR 188 3. FUNCTIONAL
GROUP ANALYSIS 188 3.1. HYDROXYL (SIOH) 188 3.1.1. TOTAL HYDROXYL
METHODS 189 3.1.2. SILANOL SPECIFIC MEASUREMENTS 196 3.1.3. WATER IN THE
PRESENCE OF SILANOL 196 3.2. SILANE HYDROGEN (SIH) 197 3.2.1. HYDROGEN
EVOLUTION METHODS 197 3.2.2. MERCURY(II) REDUCTION METHODS 199 3.2.3.
SILVER(I) REDUCTION METHODS 201 3.2.4. MISCELLANEOUS SIH REACTIONS 201
3.3. DISILANES (SISI) 202 3.4. VINYL (SIHC=CH 2 ) 202 3.4.1. ADDITION
REACTIONS 202 3.4.2. CLEAVAGE REACTIONS 203 3.5. ALKOXY (SIOR) . 204
3.5.1. ACETYLATION 204 3.5.2. ZEISEL 205 3.5.3. MISCELLANEOUS 205 3.6.
HYDROLYZABLE HALIDE (SIX) 205 3.7. ORGANIC SUBSTITUENTS ON SILICON 208
3.7.1. REACTIONS WITH ACIDS 208 3.7.2. REACTIONS WITH BASES 208 3.7.3.
SILICON SUBSTITUENT ANALYSIS 209 REFERENCES 211 CONTENTS XV CHAPTER 9.
MICROSCOPICAL CHARACTERIZATION ... 219 H. A. FREEMAN AND R. L. DURALL 1.
INTRODUCTION 219 2. CHOOSING AN APPROPRIATE TECHNIQUE 220 2.1. OPTICAL
MICROSCOPY 220 2.2. SCANNING ELECTRON MICROSCOPY 221 2.3. SCANNING
ELECTION MICROPROBE 223 2.4. TRANSMISSION ELECTRON MICROSCOPY 227 2.4.1.
USEFULNESS OF THE TECHNIQUE 227 2.4.2. REPLICATION TECHNIQUES 227 2.4.3.
POLYMER CHARACTERISTICS AND ARTIFACTS IN THE TEM . . . 228 2.4.4.
ELECTRON DIFFRACTION 230 2.4.5. SCANNING IMAGES IN THE TEM 232 2.5.
ANALYTICAL ELECTRON MICROSCOPE 233 2.6. IMAGE PROCESSING 234 3.
APPLICATION TO SILICONE MATERIALS 235 3.1. EMULSIONS AND POLYMERS 235
3.2. ELASTOMERS 237 3.2.1. FILIER CHARACTERIZATION 237 3.2.2. CURED
SILICONE ELASTOMERS 240 3.3. RESINS 241 3.4. SPECIAL APPLICATIONS OF
MICROSCOPY 242 3.4.1. COATINGS 242 3.4.2. ELECTRONIC MATERIALS 244
3.4.3. FIBERS AND COMPOSITES 244 3.4.4. BIOMATERIALS 249 REFERENCES 251
CHAPTER 10. CHROMATOGRAPHIC METHODS 255 R. D. STEINMEYER AND M. A.
BECKER 1. INTRODUCTION 255 2. BACKGROUND INFORMATION 256 2.1. SILANES
256 2.2. POLYSILOXANES 257 2.3. ORGANIC COMPOUNDS 260 3. SAMPLING 260
XVI CONTENTS 3.1. GENERAL COMMENTS 260 4. SAMPLE PREPARATION 261 4.1.
GENERAL COMMENTS 261 4.2. DERIVATIZATION SCHEINES 261 4.3. DECOMPOSTION
SCHEMES 262 4.4. EXTRACTION SCHEMES 262 5. GAS CHROMATOGRAPHY
INSTRUMENTATION 262 5.1. THE CHROMATOGRAPH 262 5.2. MATERIALS OF
CONSTRUCTION . . 263 5.3. INLET SYSTEMS 263 5.4. THE CARRIER GAS 263
5.5. SYSTEM CONDITIONING 264 5.6. SAMPLE INTRODUCTION 264 5.6.1.
SYRINGES 264 5.6.2. SAMPLING VALVES 265 5.6.3. HEADSPACE AND
PURGE-AND-TRAP DEVICES 265 5.6.4. PYROLYZERS 266 6. GAS CHROMATOGRAPHY
COLUMNS 266 6.1. THE SOLID SUPPORT 266 6.2. CHOOSING THE LIQUID PHASE
267 6.3. DESIGNING THE SEPARATION 268 6.4. PACKED COLUMNS FOR
CHLOROSILANES 271 6.5. PACKED COLUMNS FOR OTHER SILANES 272 6.6. PACKED
COLUMNS FOR SILOXANES 273 6.7. MISCELLANEOUS PACKED COLUMNS 273 6.8.
CAPILLARY COLUMNS 273 7. GAS CHROMATOGRAPHY DECTECTORS 281 7.1. GENERAL
COMMENTS 281 7.2. THE THERMAL CONDUCTIVITY DETECTOR 282 7.3. THE FLAME
IONIZATION DETECTOR 284 7.4. HYPHENATED METHODS 287 7.4.1. GC-MS 287
7.4.2. GC-FT IR 289 7.4.3. GC-AES 289 8. SUPERCRITICAL FLUID
CHROMATOGRAPHY 289 8.1. GENERAL COMMENTS 289 8.2. APPLICATIONS 290
CONTENTS XV11 9. GEL PERMEATION CHROMATOGRAPHY 294 9.1. GENERAL 294 9.2.
CALIBRATION 294 9.2.1. CALIBRATION USING NARROW MWD STANDARDS 294 9.2.2.
CALIBRATION USING BROAD MWD STANDARDS 295 9.2.3. CALIBRATION USING
MWD-SENSITIVE DETECTORS 295 9.3. CALCULATIONS 296 9.4. APPLICATION TO
SILICONE POLYMERS 296 9.5. SPECIAL PROBLEMS AND TECHNIQUES 298
REFERENCES 299 CHAPTER 11. INFRARED, RAMAN, NEAR-INFRARED, AND
ULTRAVIOLET SPECTROSCOPY 305 E. D. LIPP AND A. LEE SMITH 1. INTRODUCTION
305 1.1. PRINCIPLES 306 2. SAMPLING 313 2.1. GASES 313 2.2. LIQUIDS 314
2.3. SOLIDS 316 3. QUALITATIVE ANALYISIS 319 3.1. GROUP FREQUENCIES 319
3.1.1. THE INDUCTIVE EFFECT 322 3.1.2. MECHANICAL EFFECTS 323 3.1.3.
STERIC EFFECTS 323 3.2. INTERPRETATION 323 3.2.1. SI-METHYL 323 3.2.2.
SIH 324 3.2.3. SIOR 325 3.2.4. SIOH 325 3.2.5. SI-PHENYL 328 3.2.6.
SIOSI 328 3.3. ULTRAVIOLET 329 4. QUANTITATIVE ANALYSIS 330 4.1.
PRINCIPLES 330 4.2. TRACE ANALYSIS 331 XVU1 CONTENTS 4.3. NEAR-INFRARED
SPECTROSCOPY 331 4.4. ULTRAVIOLET 332 5. APPLICATIONS 332 5.1. POLYMER
ANALYSIS 332 5.2. SILICA AND GLASS 333 5.3. BIOLOGICAL 334 5.4. OTHER
APPLICATIONS 334 REFERENCES 337 CHAPTER 12. NUCLEAR MAGNETIC RESONANCE
SPEC- TROSCOPY 347 R. B. TAYLOR, B. PARBHOO, AND D. M. FILLMORE 1.
INTRODUCTION 347 2. PRACTICAL CONSIDERATIONS 348 3. PROTON NUCLEAR
MAGNETIC RESONANCE 353 3.1. EXPERIMENTAL 354 3.2. CHEMICAL SHIFTS AND
SPLITTING PATTERNS 355 3.3. APPLICATIONS 362 4. CARBON-13 NUCLEAR
MAGNETIC RESONANCE 362 4.1. CHEMICAL SHIFTS 363 4.1.1. SI-METHYL 363
4.1.2. OTHER SUBSTITUENTS 363 4.2. COUPLING CONSTANTS 364 4.3.
QUANTITATIVE ANALYSIS 365 4.4. APPLICATIONS 365 4.4.1. SILICONE-GLYCOLS
365 4.4.2. HEXENYL HYDROLYZATE ISOMERS 366 4.4.3. PC-PDMS BLOCK
COPOLYMERS 367 4.4.4. ALKYL-MODIFIED SOLUBLE SILICA 367 5. SILICON-29
NUCLEAR MAGNETIC RESONANCE 371 5.1. GENERAL 371 5.2. CHEMICAL SHIFTS 371
5.3. COUPLING CONSTANTS 376 5.4. QUANTITATIVE ANALYSIS 376 5.5.
STRUCTURAL APPLICATIONS 381 5.5.1. POLYMERS 381 5.5.2. COPOLYMERS 386
CONTENTS XIX 5.5.3. SILOXANE RANDORN COPOLYMERS 386 5.5.4. SILOXANE
ALTERNATING COPOLYMERS 394 5.5.5. INTERMEDIATE SITUATIONS 395 5.5.6.
TACTICITY IN SILOXANE POLYMERS 397 5.5.7 SILOXANE-ORGANIC BLOCK
COPOLYMERS 397 5.6. ANALYTICAL APPLICATIONS 399 6. TWO-DIMENSIONAL
FT-NMR 400 7. SOLID-STATE NMR 401 7.1. PRACTICAL CONSIDERATIONS 402 7.2.
QUANTITATION 404 7.3. APPLICATIONS 405 7.3.1. ORGANOSILANE MODIFIED
SILICA 405 7.3.2. CHARACTERIZATION OF POLY(DI-N-ALKYLSILANE) 408 7.3.3.
TOPOLOGY OF PSMS ELASTOMER NETWORKS 411 REFERENCES 414 CHAPTER 13. MASS
SPECTROMETRY 421 JOHN A. MOORE 1. INTRODUCTION 421 1.1. SILICON VERSUS
CARBON 421 1.2. SILICON-CONTAINING IONS AS BACKGROUND CONTAMINANTS ....
423 2. SAMPLE INTRODUCTION 423 2.1. GAS CHROMATOGRAPHY-MASS SPECTROSCOPY
425 2.2. SUPERCRITICAL FLUID CHROMATOGRAPHY-MASS SPECTROSCOPY. . . 426
2.3. LIQUID CHROMATOGRAPHY-MASS SPECTROSCOPY 426 2.4. PYROLYSIS-MASS
SPECTROSCOPY 427 2.5. DIRECT PROBES 427 3. IONIZATION METHODS 427 3.1.
ELECTRON IMPACT 427 3.2. CHEMICAL IONIZATION 429 3.3. FAST ATOM
BOMBARDMENT 432 3.4. FIELD DESORPTION 433 3.5. OTHER SECONDARY ION
TECHNIQUES 434 3.6. NEGATIVE IONS 434 4. INTERPRETATION 435 4.1. SILANES
435 XX CONTENTS 4.1.1. COMPOUNDS WITH SI-C OR SI-H BONDS 435 4.1.2.
HALOSILANES 440 4.1.3. SILANES WITH SI-OR BONDS 443 4.2. SILOXANES 451
4.2.1. POLY(DIMETHYLSILOXANES) 451 4.2.2. SILOXANE COPOLYMEFS 456 4.3.
SILAZANES 462 4.4. POLYSILANES 464 4.5. SILYL DERIVATIVES OF ORGANIC
COMPOUNDS 465 REFERENCES 467 CHAPTER 14. ATOMIC SPECTROSCOPY 471 NELSON
W. LYTLE 1. INTRODUCTION 471 2. ANALYTICAL CONSIDERATIONS 472 2.1.
APPLICABILITY 472 2.2. ACCURACY AND PRECISION 473 2.3. DETECTABILITY 473
2.4. INTERFERENCES 473 3. MAJOR METALS IN SILICONES 474 3.1.
DETERMINATION OF SILICON IN ORGANOSILICON COMPOUNDS BY DIRECT DILUTION
AND ATOMIC ABSORPTION SPECTROSCOPY 474 3.2. DETERMINATION OF SILICON BY
MATRIX DECOMPOSITION-ATOMIC ABSORPTION 475 4. TRACE METALS IN SILICONES
476 4.1. CHLOROSILANES 476 4.2. SILOXANES 477 4.2.1. SAMPLE PREPARATION
METHODS 477 4.2.2. DIRECT DETERMINATION BY ICP-AES 478 4.2.3.
ELECTROTHERMAL ATOMIZATION AAS 479 4.2.4. FLAME PHOTOMETRIE
DETERMINATION OF SODIUM AND POT- ASSIUM 479 5. TRACE SILICONES IN OTHER
MATERIALS 480 5.1. POLY(DIMETHYLSILOXANE) IN VEGETABLE COOKING OIL 481
REFERENCES 482 CONTENTS XXI CHAPTER 15. X-RAY METHODS 485 D. R.
PETERSON, R. D. PARKER, AND M. J. OWEN 1. INTRODUCTION 485 2. X-RAY
DIFFRACTION 487 2.1. NATURE OF DIFFRACTION 487 2.2. EXPERIMENTAL METHODS
488 2.3. APPLICATION TO SINGLE CRYSTALS 489 2.3.1. SAMPLE PREPARATION
489 2.3.2. DETERMINATION OF CRYSTAL PARAMETERS 489 2.3.3. IDENTIFICATION
489 2.3.4. CRYSTAL STRUCTURE DETERMINATION 489 2.4. APPLICATION TO
POLYCRYSTALLINE AGGREGATES 490 2.4.1. SAMPLE PREPARATION 490 2.4.2.
IDENTIFICATION 491 2.4.3. QUANTITATIVE ESTIMATION 492 2.4.4. OTHER
CHARACTERIZATION PROCEDURES 492 2.4.5. CRYSTAL STRUCTURE DETERMINATION
493 2.5. APPLICATION TO PARTLY CRYSTALLINE MATERIALS (POLYMERS) .... 493
2.6. APPLICATION TO NONCRYSTALLINE MATERIALS 493 2.7. RELATED AND
COMPLEMENTARY PROCEDURES 494 3. X-RAY FLUORESCENCE 495 3.1.
INSTRUMENTATION 495 3.2. SAMPLE HANDLING 496 3.3. DETECTION LIMITS 497
3.4. QUALITATIVE ANALYSIS 497 3.5. QUANTITATIVE ANALYSIS 498 3.6.
APPLICATIONS 498 3.6.1. TRACE METALS IN SILICONE FLUIDS 498 3.6.2.
SILICONE FLUIDS*PERCENT SILICON 500 3.6.3. EMULSIONS AND PARTICULATE
SUSPENSIONS 500 3.6.4. SILICONE ON SURFACES 501 3.6.5. OTHER SOLID
SAMPLES 502 4. X-RAY PHOTOELECTRON AND AUGER ELECTRON SPECTROSCOPY 503
4.1. INTRODUCTION 503 4.2. CAPABILITY AND LIMITATIONS 503 XXII CONTENTS
4.3. SAMPLE PREPARATION 504 4.4. X-RAY PHOTOELECTRON SPECTROSCOPY
ELEMENTAL ANALYSIS .... 505 4.5. OTHER ASPECTS OF X-RAY PHOTOELECTRON
SPECTROSCOPY ANALYSIS 508 4.5.1. CHEMICAL GROUP INFORMATION 508 4.5.2.
DEPTH PROFILING 510 4.6. SELECTED X-RAY PHOTOELECTRON SPECTROSCOPY AND
AUGER ELEC- TRON SPECTROSCOPY APPLICATIONS 511 5. REFERENCES 515
APPENDIX. PHYSICAL PROPERTIES OF ORGANOSILICON COMPOUNDS 523 ORA L.
FLANINGAM REFERENCES 537 INDEX. 543
|
| any_adam_object | 1 |
| author_GND | (DE-588)122192265 |
| building | Verbundindex |
| bvnumber | BV007687706 |
| classification_rvk | VK 7721 |
| ctrlnum | (OCoLC)246315417 (DE-599)BVBBV007687706 |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV007687706 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T17:07:39Z |
| institution | BVB |
| isbn | 0471516244 |
| language | Undetermined |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-005045063 |
| oclc_num | 246315417 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-703 DE-20 |
| owner_facet | DE-355 DE-BY-UBR DE-703 DE-20 |
| physical | XXII, 551 S. Ill., graph. Darst. |
| publishDate | 1991 |
| publishDateSearch | 1991 |
| publishDateSort | 1991 |
| publisher | Wiley |
| record_format | marc |
| series | Chemical analysis |
| series2 | Chemical analysis |
| spelling | The analytical chemistry of silicones ed. by A. Lee Smith New York u.a. Wiley 1991 XXII, 551 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Chemical analysis 112. Siliciumorganische Verbindungen (DE-588)4077449-1 gnd rswk-swf Analyse (DE-588)4122795-5 gnd rswk-swf Silicone (DE-588)4127342-4 gnd rswk-swf Siliciumorganische Verbindungen (DE-588)4077449-1 s Analyse (DE-588)4122795-5 s DE-604 Silicone (DE-588)4127342-4 s Smith, Albert Lee 1924- Sonstige (DE-588)122192265 oth Chemical analysis 112. (DE-604)BV000008780 112 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005045063&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | The analytical chemistry of silicones Chemical analysis Siliciumorganische Verbindungen (DE-588)4077449-1 gnd Analyse (DE-588)4122795-5 gnd Silicone (DE-588)4127342-4 gnd |
| subject_GND | (DE-588)4077449-1 (DE-588)4122795-5 (DE-588)4127342-4 |
| title | The analytical chemistry of silicones |
| title_auth | The analytical chemistry of silicones |
| title_exact_search | The analytical chemistry of silicones |
| title_full | The analytical chemistry of silicones ed. by A. Lee Smith |
| title_fullStr | The analytical chemistry of silicones ed. by A. Lee Smith |
| title_full_unstemmed | The analytical chemistry of silicones ed. by A. Lee Smith |
| title_short | The analytical chemistry of silicones |
| title_sort | the analytical chemistry of silicones |
| topic | Siliciumorganische Verbindungen (DE-588)4077449-1 gnd Analyse (DE-588)4122795-5 gnd Silicone (DE-588)4127342-4 gnd |
| topic_facet | Siliciumorganische Verbindungen Analyse Silicone |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=005045063&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000008780 |
| work_keys_str_mv | AT smithalbertlee theanalyticalchemistryofsilicones |