Alkaloid chemistry: Transl. from the German ed. by I. Ralph C. Bick
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English German |
| Published: |
New York
Wiley
1981
|
| Series: | A Wiley-Interscience publication.
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | EST: Alkaloidchemie (engl.) |
| Physical Description: | XII, 231 S. graph. Darst. |
| ISBN: | 0471079731 |
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| 245 | 1 | 0 | |a Alkaloid chemistry |b Transl. from the German ed. by I. Ralph C. Bick |
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Record in the Search Index
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| adam_text | CONTENTS
1 INTRODUCTION
2 CONCEPT AND DEFINITION OF AN ALKALOID
2
3 NOMENCLATURE
6
4 ARTIFACTS
7
5 CLASSIFICATION OF ALKALOIDS
10
5.1 HETEROCYCLIC ALKALOIDS, 12
5.1.1 PYRROLIDINE ALKALOIDS, 13
5.1.2 INDOLE ALKALOIDS, 13
5.1.2.1 SIMPLE INDOLE BASES, 15, 5.1.2.2 ALKALOIDS WITH A
CARBAZOLE NUCLEUS, 16, 5.1.2.2.1 CARBAZOLE ALKALOIDS, 16,
5.1.2.2.2 ASPIDOSPERMINE AND BIOGENETICALLY RELATED BASES, 16,
5.1.2.2.3 ALKALOIDS OF THE CONDYLOCARPINE TYPE, 18, 5.1.2.2.4
STRYCHNOS ALKALOIDS AND RELATED BASES, 19, 5.1.2.2.5 ULEINE
ALKALOIDS, 20, 5.1.2.3 ALKALOIDS WITH A /3-CARBOLINE SKELETON,
20, 5.1.2.3.1 SIMPLE J3-CARBOLINE DERIVATIVES, 20, 5.1.2.3.2
ALKALOIDS OF THE CANTHINE TYPE, 20, 5.1.2.3.3 EBURNAMINE
ALKALOIDS, 21, 5.1.2.3.4 HETEROYOHIMBANE AND BIOGENETICALLY
RELATED BASES, 21, 5.1.2.3.5 YOHIMBANE ALKALOIDS, 24, 5.1.2.4
ALKALOIDS WITH A 7-CARBOLINE SKELETON, 25, 5.1.2.5 IBOGA ALKA
LOIDS, 25, 5.1.2.6 INDOLE ALKALOIDS WITH A PYRROLIDINOINDOLE
SKELETON, 26, 5.1.2.6.1 ESERINE-TYPE ALKALOIDS, 26, 5.1.2.6.2
ECHITAMINE-ERININE-TYPE ALKALOIDS, 26, 5.1.2.7 ERGOT ALKA
LOIDS, 27, 5.1.2.8 EVODIAMINE-TYPE ALKALOIDS, 28
IX
HTTP://D-NB.INFO/1008635383
X
CONTENTS
5.1.3 PIPERIDINE ALKALOIDS, 28
5.1.4 PYRIDINE ALKALOIDS, 29
5.1.5 TROPANE AND RELATED BASES, 30
5.1.6 HISTAMINE, IMIDAZOLE, AND GUANIDINE ALKALOIDS, 31
5.1.7 ISOQUINOLINE ALKALOIDS, 32
5.1.7.1 SIMPLE ISOQUINOLINE ALKALOIDS, 32, 5.1.7.2 BENZYL-
ISOQUINOLINE ALKALOIDS, 33, 5.1.7.3 PHENYLTETRAHYDROISOQUINO-
LINE ALKALOIDS, 34, 5.1.7.4 PHTHALIDEISOQUINOLINE ALKALOIDS, 34,
5.1.7.5 RHOEADINE AND PAPAVERRUBINE ALKALOIDS, 34, 5.1.7.6
IPECACUANHA ALKALOIDS, 34, 5.1.7.7 CRYPTAUSTOLINE-TYPE ALKA
LOIDS, 35, 5.1.7.8 APORPHINE AND HOMOAPORPHINE ALKALOIDS,36,
5.1.7.9 PROAPORPHINE AND HOMOPROAPORPHINE ALKALOIDS, 36,
5.1.7.10 CULARINE ALKALOIDS, 37, 5.1.7.11 BERBERINE ALKALOIDS,
37, 5.1.7.12 PROTOPINE ALKALOIDS, 38, 5.1.7.13 BENZOPHENAN-
THRIDINE ALKALOIDS, 39, 5.1.7.14 SPIROBENZYLISOQUINOLINE ALKA
LOIDS, 39, 5.1.7.15 PAVINE AND ISOPAVINE ALKALOIDS, 40, 5.1.7.16
MORPHINE ALKALOIDS, 40, 5.1.7.17 AMARYLLIDACEOUS ALKALOIDS,
41, 5.1.7.18 CHERYLLINE-TYPE ALKALOIDS, 42, 5.1.7.19 ERY-
THRINA ALKALOIDS, 42
5.1.8 QUINOLINE ALKALOIDS, 43
5.1.8.1 QUINOLONE-2 AND QUINOLONE-4 DERIVATIVES, 43, 5.1.8.2
FUROQUINOLINE ALKALOIDS, 45, 5.1.8.3 QUININE ALKALOIDS (CIN-
CHONA ALKALOIDS),45, 5.1.8.4MELODINUS ALKALOIDS, 45, 5.1.8.5
CAMTOTHECA BASES, 46
5.1.9 A CRIDINE A IKALOIDS, 4 6
5.1.10 QUINAZOLINE ALKALOIDS, 4 7
5.1.11 IZIDINE ALKALOIDS, 47
5.1.11.1 PYRROLIZIDINE ALKALOIDS (SENECIO ALKALOIDS), 48,
5.1.11.2 INDOLIZIDINE ALKALOIDS, 49, 5.1.11.3 QUINOLIZIDINE
ALKALOIDS, 50, 5.1.11.3.1 LUPIN ALKALOIDS, 50, 5.1.11.3.2
NUPHAR ALKALOIDS, 50, 5.1.11.3.3 LYTHRACEOUS ALKALOIDS, 51,
5.1.11.3.4 LYCOPODIUM ALKALOIDS, 51
5.2 ALKALOIDS WITH AN EXOCYCLIC NITROGEN, 52
5.3 PUTRESCINE, SPERMIDINE, AND SPERMINE ALKALOIDS, 53
5.4 PEPTIDE ALKALOIDS, 54
5.5 DITERPENE ALKALOIDS, 54
5.6 STEROIDAL ALKALOIDS, 56
CONTENTS
X
J
6 ASPECTS OF ALKALOID BIOGENESIS 59
6.1 BOTANICAL ORIGIN OF SOME IMPORTANT 1-BENZYLISOQUINOLINE
ALKALOIDS, 61
6.2 STATISTICS FOR 1-BENZYLISOQUINOLINE ALKALOIDS, 62
6.3 CHEMICAL REACTIONS INVOLVED IN THE TRANSFORMATION OF VARIOUS
SUB-GROUPS OF THE 1-BENZYLISOQUINOLINE ALKALOIDS, 70
6.4 BIOGENESIS OF ALKALOIDS OF PAPAVER SOMNIFERUM, 72
6.5 APORPHINE BIOGENESIS IN PAPAVER ORIENTATE, 19
1 ASPECTS OF CHEMOTAXONOMY 83
7.1 CHEMOTAXONOMY OF THE PLUMERANE ALKALOIDS, 85
7.2 CHEMOTAXONOMIC EVALUATION, 90
7.2.1 SKELETAL TYPES, 94
7.2.2 ABSOLUTE CONFIGURATION, 101
7.2.3 FURTHER STRUCTURAL OBSERVATIONS, 107
7.3 RESULTS, 110
8 STRUCTURAL ELUCIDATION BY MODERN METHODS:
VILLALSTONINE 112
8.1 OCCURRENCE, 112
8.2 PHYSICAL PROPERTIES, 113
8.3 SPECTRA AND FUNCTIONAL GROUPS, 114
8.4 ACID-CATALYZED CLEAVAGE REACTIONS OF VILLALSTONINE, 122
8.5 ELUCIDATION OF THE STRUCTURE OF THE FRAGMENT MACROLINE, 127
8.6 STRUCTURAL ELUCIDATION OF VILLAMINE AND VILLALSTONINE, 138
9 IMPORTANT DEGRADATION REACTIONS OF ALKALOIDS 144
9.1 HOFMANN DEGRADATION, 144
9.1.1 HOFMANN DEGRADATION WITH FORMATION OF EPOXIDES
(OXIRANE FORMATION), 148
9.1.2 HOFMANN DEGRADATION WITH ETHER FORMATION, 151
9.1.3 FURTHER REACTIONS UNDER HOFMANN
DEGRADATION CONDITIONS, 152
XLL
CONTENTS
9.2 EMDE DEGRADATION, 155
9.3 THE VON BRAUN REACTION (CYANOGEN BROMIDE DEGRADATION), 159
10 DIMERIC ALKALOIDS-B1SALKALOIDS 162
10.1 MANNICH REACTION, 163
10.2 MICHAEL CONDENSATION, 166
10.3 ALDEHYDE-AMINE REACTIONS, 166
10.4 COUPLING BY PHENOL OXIDATION, 168
10.5 LACTONIZATION, 172
10.6 COMBINED MECHANISMS, 172
11 EXAMPLES OF ALKALOID SYNTHESIS 175
11.1 SYNTHESIS,OF MESEMBRINE, 175
11.2 A BIOMIMETIC SYNTHESIS: PORANTHERINE, 178
11.3 SYNTHESIS OF THE MACROCYCLIC SPERMIDINE
ALKALOID ONCINOTINE, 185
11.4 STEREOSELECTIVE SYNTHESIS: VINCAMINE, 192
ABBREVIATIONS FOR PLANT FAMILIES 201
BIBLIOGRAPHY 203
INDEX
217
|
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| discipline | Chemie / Pharmazie |
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| indexdate | 2024-07-09T17:05:06Z |
| institution | BVB |
| isbn | 0471079731 |
| language | English German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-004948791 |
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| physical | XII, 231 S. graph. Darst. |
| publishDate | 1981 |
| publishDateSearch | 1981 |
| publishDateSort | 1981 |
| publisher | Wiley |
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| series2 | A Wiley-Interscience publication. |
| spelling | Hesse, Manfred Verfasser aut Alkaloid chemistry Transl. from the German ed. by I. Ralph C. Bick New York Wiley 1981 XII, 231 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier A Wiley-Interscience publication. EST: Alkaloidchemie (engl.) Alkaloids Alkaloide (DE-588)4068543-3 gnd rswk-swf Alkaloide (DE-588)4068543-3 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004948791&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hesse, Manfred Alkaloid chemistry Transl. from the German ed. by I. Ralph C. Bick Alkaloids Alkaloide (DE-588)4068543-3 gnd |
| subject_GND | (DE-588)4068543-3 |
| title | Alkaloid chemistry Transl. from the German ed. by I. Ralph C. Bick |
| title_auth | Alkaloid chemistry Transl. from the German ed. by I. Ralph C. Bick |
| title_exact_search | Alkaloid chemistry Transl. from the German ed. by I. Ralph C. Bick |
| title_full | Alkaloid chemistry Transl. from the German ed. by I. Ralph C. Bick |
| title_fullStr | Alkaloid chemistry Transl. from the German ed. by I. Ralph C. Bick |
| title_full_unstemmed | Alkaloid chemistry Transl. from the German ed. by I. Ralph C. Bick |
| title_short | Alkaloid chemistry |
| title_sort | alkaloid chemistry transl from the german ed by i ralph c bick |
| title_sub | Transl. from the German ed. by I. Ralph C. Bick |
| topic | Alkaloids Alkaloide (DE-588)4068543-3 gnd |
| topic_facet | Alkaloids Alkaloide |
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