Concepts in bioenergetics:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Englewood, Cliffs, NJ
Prentice-Hall
1974
|
| Schriftenreihe: | Concepts of modern biology series.
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI,305 S.m.Abb. |
| ISBN: | 0131662643 |
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Datensatz im Suchindex
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|---|---|
| adam_text | IMAGE 1
CONTENTS
PREFACE XIII
1 ENERGY, THERMODYNAMICS, AND LIVING PROCESSES 1
1-1. ENERGETIC NATURE OF BIOLOGICAL PROCESSES 1 1-2. WHAT THERMODYNAMICS
IS ABOUT 1 1-3. THE PRACTICAL USES OF THERMODYNAMICS IN BIOLOGY 2 1-4.
BIRD S EYE VIEW OF THE BASIC ENERGETIC PROCESSES OF THE
BIOSPHERE 3 1-5. THE DYNAMIC DESIGN OF PLANTS AND ANIMALS 7 1-6. HOW
BIOLOGICAL SYSTEMS UTILIZE THEIR ENERGY 10 1-7. LEVELS OF BIOLOGICAL
ORGANIZATION 10 1-8. THE LARGE LEVELS OF ENERGY UTILIZATION AND
ORGANIZATION:
ECOSYSTEMS 15
2 THE FIRST LAW OF THERMODYNAMICS 19
2-1. THERMODYNAMIC SYSTEMS 19 2-2. EXAMPLES 21 2-3. EQUILIBRIUM 22 2-4.
INTENSIVE VS. EXTENSIVE VARIABLES 23 2-5. NOT ALL VARIABLES ARE NEEDED
TO SPECIFY THE EQUILIBRIUM
STATES UNIQUELY 24 2-6. FUNCTIONS OF STATE 25 2-7. IS THERE ANYTHING
SPECIAL ABOUT FUNCTIONS OF STATE? 25 2-8. CYCLIC PROCESSES 26
IMAGE 2
VI CONTENTS
2-9. SOME FUNCTIONS OF STATE ARE DEFINED IN TERMS OF COMBINATIONS OF
OTHER QUANTITIES WHICH ARE NOT THEMSELVES FUNCTIONS OF STATE 27 2-10.
ENERGY IS A FUNCTION OF STATE 27 2-11. WORK 28 2-12. HOW WORK IS
CALCULATED IN SPECIFIC CASES 29 2-13. WORK CAN BE CONVERTED INTO KINETIC
ENERGY 33 2-14. IS HEAT A FLUID? 35 2-15. METABOLIC HEAT AND ENERGY
CONSERVATION 35 2-16. THE MECHANICAL EQUIVALENT OF HEAT 36 2-17. ENERGY
IS A FUNCTION OF STATE 37
3 THE DIRECTION OF NATURAL PROCESSES: ENTROPY AND FREE ENERGY 41
3-1. THE SECOND LAW OF THERMODYNAMICS 42 3-2. REVERSIBLE VS.
IRREVERSIBLE PROCESSES 42 3-3. ENTROPY 43 3-4. ENTROPY CHANGES DURING
IRREVERSIBLE PROCESSES 46
3-5. ENTROPY IS A FUNCTION OF STATE! 47 3-6. ENTROPY CHANGES AND WORK 48
3-7. THE FIRST AND SECOND LAWS COMBINED 49 3-8. FREE ENERGY: THE
BIOLOGICAL FUNCTION OF STATE 49 3-9. THE USEFUL WORK AND AG 51 3-10. THE
EXPLICIT EXPRESSION FOR THE FREE-ENERGY CHANGE 52 3-11. EXAMPLE 53 3-12.
CAN MASS EVER MOVE FROM A LOW POTENTIAL TO A HIGH
POTENTIAL? 56 3-13. EXPLICIT FORM OF THE CHEMICAL POTENTIAL 56 3-14.
COMPLETE FORM OF THE CHEMICAL POTENTIAL 59 3-15. IONS AND THE
ELECTROCHEMICAL POTENTIAL: 60 3-16. THE ELECTROCHEMICAL POTENTIAL 62
4 MICROSCOPIC INTERPRETATION OF THERMODYNAMIC QUANTITIES 65
4-1. BUT WHAT IS ENTROPY? 65 4-2. IDEALITY AND MOLECULAR COHESION 66
4-3. IDEAL GAS KINETICS 67 4-4. THE PROBABILISTIC NATURE OF ENTROPY 70
4-5. ENTROPY, PROBABILITY, ORDER, AND DISORDER 72
IMAGE 3
CONTENTS VII
4-6. RELATIONSHIP BETWEEN MICROSCOPIC ENERGY AND
MICROSCOPIC ENTROPY 73 4-7. ENERGY, TEMPERATURE, AND PRESSURE OF THE
IDEAL GAS 76 4-8. THE SECOND LAW AND THE QUALITY OF ENERGY 79
5 FREE ENERGY IN MOLECULAR BIOLOGY AND BIOENERGETICS 81
5-1. RELATIONSHIP BETWEEN STANDARD FREE-ENERGY CHANGES AND EQUILIBRIUM
CONSTANTS 81 5-2. DIFFERENCE BETWEEN DIRECTION AND RATE 84 5-3. COVALENT
VS. WEAK BONDING: MOLECULAR BIOLOGY AS THE
CHEMISTRY OF MOLECULAR RECOGNITION 86 5-4. WHAT IS THE PHYSICAL BASIS OF
WEAK INTERACTIONS? 89 5-5. IS THE HYDROGEN ATOM CHARGED? 91 5-6.
ACTIVATION ENERGIES OF WEAK BONDS 91
5-7. IF WEAK BONDS FORM AND BREAK SO FAST, ARE THERE A SUBSTANTIAL
NUMBER PRESENT AT EQUILIBRIUM? 92 5-8. THE IMPORTANCE OF
THREE-DIMENSIONAL FITNESS 92 5-9. THREE-DIMENSIONAL SHAPES OF
MACROMOLECULES ARE
CONFIGURATIONS OF MINIMUM FREE ENERGY 94 5-10. HOW BIOLOGICAL FREE
ENERGY IS OBTAINED AND PUT TO WORK: BIOENERGETICS 94 5-11. THE RECOVERY
OF CHEMICAL ENERGY 97
5-12. COUPLING CHEMICAL REACTIONS 98 5-13. OTHER FORMS OF BIOLOGICAL
WORK ALSO REQUIRE ATP HYDROLYSIS 102 5-14. CONSERVATION OF BIOLOGICAL
ENERGY: THE GENERATION OF
ATP 102
THE ELECTROCHEMICAL POTENTIAL AS A MEASURE OF BIOLOGICAL EQUILIBRIUM:
OSMOTIC PRESSURE, NERNST AND DONNAN POTENTIALS 107
6-1. WHEN IS THE ELECTROCHEMICAL POTENTIAL A MEASURE OF
EQUILIBRIUM? 107 6-2. BIOLOGICAL RESTING POTENTIALS 108 6-3.
QUANTITATIVE DERIVATION OF THE ELECTRICAL POTENTIAL: NERNST EQUATION 110
6-4. MICROSCOPIC SEPARATION OF CHARGE 112 6-5. ACTION POTENTIALS 114
6-6. WHAT CAME FIRST: POTENTIALS OR CONCENTRATION DIFFERENCES? 116
IMAGE 4
VIII CONTENTS
6-7. THE IMPORTANCE OF EQUILIBRIUM CALCULATIONS; ACTIVITY COEFFICIENTS
117 6-8. ARE ACTIVITIES ARBITRARY QUANTITIES? THE GLASS ELECTRODE 118
6-9. GIBBS-DONNAN EQUILIBRIUM 119 6-10. GIBBS-DONNAN EQUILIBRIUM IN THE
ERYTHROCYTE 121 6-11. CHEMICAL POTENTIAL AND OSMOTIC EQUILIBRIUM 122
6-12. PHYSICAL MEANING AND BIOLOGICAL IMPLICATIONS OF
OSMOTIC PRESSURE 123 6-13. TURGOR PRESSURE AND STOMATAL OPENING 125
6-14. OSMOSIS IS A VERY STRONG FORCE 129 6-15. COLLOID OSMOTIC PRESSURE
AND THE MOTION OF WATER IN
CAPILLARIES 130 6-16. REFLECTION COEFFICIENTS 131 6-17. A POSSIBLE WAY
TO MEASURE A 133 6-18. OSMOTIC PRESSURE IN THE PRESENCE OF SEVERAL
SOLUTES 134 6-19. OSMOTIC REGULATION AND HABITAT 134
7 CHEMICAL POTENTIAL IN ACTION: DIFFUSION 139
7-1. THE MEANING OF THE CHEMICAL POTENTIAL AWAY FROM EQUILIBRIUM 139
7-2. VISUALIZATION OF THE POTENTIAL 141 7-3. STEADY VELOCITY 141 7-4.
EXPLICIT EXPRESSION FOR STEADY FLOW 143 7-5. FICK SLAW 144 7-6. PHYSICAL
MEANING OF FICK S LAW 145 7-7. INTUITIVE MEANING OF DIFFUSION 146 7-8.
EINSTEIN S MOLECULAR VIEW OF DIFFUSION 147 7-9. EVOLUTIONARY PRESSURES
IMPOSED BY DIFFUSIONAL PROCESSES:
DIFFUSION AND THE SIZE OF ORGANISMS 150 7-10. WHY ARE CELLS SO LARGE?
153 7-11. THE PROBLEM OF FLUCTUATIONS 153 7-12. GAS DIFFUSION 156 7-13.
RESPIRATION IN VERTEBRATES AS AN EXAMPLE OF GAS
DIFFUSION 157 7-14. SOME UNRELATED TRANSPORT PROCESSES 159 7-15.
THENEPHRON 162 7-16. POISEULLE, OR BULK, FLOW: PORES IN MEMBRANES 164
7-17. APPLICATIONS TO BIOLOGICAL MEMBRANES 165 7-18. INTERACTION BETWEEN
OSMOTIC AND HYDROSTATIC
GRADIENTS 165
IMAGE 5
CONTENTS IX
7-19. IN DILUTE SOLUTIONS JU IS THE VELOCITY OF THE SOLVENT 167 7-20.
HYDROSTATIC PRESSURES PUSH SOLUTE MOLECULES 168 7-21. DIFFUSIONAL FLOW
IN THE PRESENCE OF HYDROSTATIC AND CONCENTRATION GRADIENTS 169
8 INFORMATION THEORY, CODES, AND MESSAGES 177
8-1. INFORMATION THEORY 177 8-2. THE PRIMITIVE TELEGRAPH 178 8-3. THE
GENETIC MESSAGE, A BIOLOGICAL EXAMPLE 1 78 8-4. EFFICIENT CODING 182
8-5. OPTIMUM MAN-MADE CODES; BINARY SYSTEM 182 8-6. PROBABILITY AND
INFORMATION CONTENT 186 8-7. ENCODING AND DECODING REDUNDANT MESSAGES
188 8-8. BIOLOGICAL MISTAKES 189 8-9. ERROR-CORRECTING CODES 190 8-10.
INFORMATION THEORY AND THERMODYNAMICS; MAXWELL S
DEMON 192 8-11. INFORMATION CONTENT AND ENTROPY 193 8-12. REVERSIBLE VS.
IRREVERSIBLE TRANSMITTERS 193 8-13. INFORMATION AND KNOWLEDGE 295
9 INFORMATION THEORY AND BIOLOGY 197
9-1. HOW MANY BITS CAN THE HUMAN BRAIN STORE? 197 9-2. IS BIOLOGICAL
MEMORY STORED IN INFORMATIONAL MACROMOLECULES? 198 9-3. DANCING BEES AND
CHEMICAL ANTS 200 9-4. THE INFORMATION CONTENT OF A BACTERIAL CELL 204
9-5. FUNCTIONAL NUMBER OF GENETIC MESSAGES 205 9-6. THE EMERGENCE OF
LIFE AS AN ACCIDENT 207 9-7. HOW DID LIFE BEGIN? 208 9-8. LIFE IN OTHER
WORLDS? 210 9-9. EVOLUTION OF PROTEINS 212 9-10. CAPACITY OF A CHANNEL:
CRAYFISH PHOTORECEPTOR 214 9-11. IS THIS CODING EFFICIENT? 22 7
10 THERMODYNAMIC EFFICIENCY, BIOLOGICAL AND MECHANICAL MACHINES 219
10-1. EFFICIENCY OF HEAT ENGINES 219 10-2. TWO OBVIOUS PROBLEMS 221
IMAGE 6
CONTENTS
10-3. THE WAY AROUND THE EQUILIBRIUM PROBLEM: LOCAL EQUILIBRIUM AND
STEADY STATE 222 10-4. ENERGY VS. POWER 224 10-5. TRANSDUCERS 225
10-6. BIOLOGICAL PROCESSES CONSIST OF MANY TRANSDUCERS ATTACHED TO ONE
ANOTHER 227 10-7. HOW CAN TRANSDUCERS BE DESCRIBED IN QUANTITATIVE
TERMS? 228 10-8. DYNAMIC EFFICIENCY AND ONSAGER (NONEQUILIBRIUM)
THERMODYNAMICS 228 10-9. SPONTANEOUS COUPLING OF TWO PROCESSES REQUIRES
POSITIVE ENTROPY PRODUCTION 230 10-10. HOW NONEQUILIBRIUM THERMODYNAMICS
CHANGES OUR
PERCEPTION OF SOME BIOLOGICAL PROBLEMS 230 10-11. COUPLING AND ASYMMETRY
231
11 THERMODYNAMIC EFFICIENCY AND ECOLOGY 235
11-1. EFFICIENCY OF ENERGY FLOW IN THE BIOSPHERE: IMPLICATIONS FROM THE
SECOND LAW OF THERMODYNAMICS 235 11-2. WHAT ARE THE RELATIVE
EFFICIENCIES OF PRODUCERS AND CONSUMERS? 239 11-3. POLLUTION AND THE
SMOGMOBILE 240 11-4. POLLUTION AND THERMODYNAMICS 241 11-5. SECOND LAW
AND POLLUTION 241 11-6. ON TECHNICAL, CONVERSION, AND APPLICATION
EFFICIENCIES 242 11-7. GAS VS. ELECTRIC HEAT 244 11-8. POWER VS.
EFFICIENCY 244 11-9. CAN POLLUTION BE COMPLETELY AVOIDED? 247 11-10. HOW
LOW CAN YOU GET? 250 11-11. THE PRINCIPLE OF MINIMUM ENTROPY
PRODUCTION 252
APPENDIX MATHEMATICAL CONCEPTS IN THERMOSTATICS AND NONEQUILIBRIUM
THERMODYNAMICS 255
A-L. REVERSIBLE WORK 255 A-2. EXACT DIFFERENTIALS AND FUNCTIONS OF STATE
256 A-3. FIRST AND SECOND LAWS OF THERMODYNAMICS 258 A-4. OTHER
ENERGYLIKE STATE FUNCTIONS 259 A-5. EXPLICIT FORM OF THE CHEMICAL
POTENTIAL 260
IMAGE 7
CONTENTS XI
A-6. DIFFERENTIAL DEFINITION OF THE CHEMICAL POTENTIAL 261 A-7. THE
ELECTROCHEMICAL POTENTIAL 261 A-8. CHEMICAL POTENTIALS IN EQUILIBRIUM
AND AWAY FROM
EQUILIBRIUM 262 A-9. EXTERNAL FORCES AND STEADY STATE 263 A-10. CHEMICAL
POTENTIAL OUTSIDE EQUILIBRIUM: FICK S LAW 264 A-LL. CHEMICAL REACTIONS
IN THE STEADY STATE 265 A-12. THE INTERNAL PRODUCTION OF ENTROPY 266
A-13. SETTING UP THE PROPER EQUATIONS 268 A-14. DIFFUSION OF A SOLUTE IN
WATER 268
A-15. PASSAGE OF SOLUTE AND WATER ACROSS A MEMBRANE 270
GLOSSARY 273
SOLUTIONS TO PROBLEMS 277
AUTHOR INDEX 299
SUBJECT INDEX 301
|
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| indexdate | 2024-07-09T16:59:15Z |
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| isbn | 0131662643 |
| language | English |
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| series2 | Concepts of modern biology series. |
| spelling | Peusner, Leonardo Verfasser aut Concepts in bioenergetics Englewood, Cliffs, NJ Prentice-Hall 1974 XI,305 S.m.Abb. txt rdacontent n rdamedia nc rdacarrier Concepts of modern biology series. Bioénergétique Bioenergetics Biophysics Thermodynamics Bioenergetik (DE-588)4112769-9 gnd rswk-swf Bioenergetik (DE-588)4112769-9 s DE-604 SWB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004683902&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Peusner, Leonardo Concepts in bioenergetics Bioénergétique Bioenergetics Biophysics Thermodynamics Bioenergetik (DE-588)4112769-9 gnd |
| subject_GND | (DE-588)4112769-9 |
| title | Concepts in bioenergetics |
| title_auth | Concepts in bioenergetics |
| title_exact_search | Concepts in bioenergetics |
| title_full | Concepts in bioenergetics |
| title_fullStr | Concepts in bioenergetics |
| title_full_unstemmed | Concepts in bioenergetics |
| title_short | Concepts in bioenergetics |
| title_sort | concepts in bioenergetics |
| topic | Bioénergétique Bioenergetics Biophysics Thermodynamics Bioenergetik (DE-588)4112769-9 gnd |
| topic_facet | Bioénergétique Bioenergetics Biophysics Thermodynamics Bioenergetik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004683902&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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