Chemistry and physics of polycarbonates:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New York [u.a.]
Interscience Publ.
1964
|
| Series: | Polymer reviews
9 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 225 S. Ill., graph. Darst. |
Staff View
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Record in the Search Index
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|---|---|
| adam_text | CHEMISTRY AND PHYSICS
OF POLYCARBONATES
By HERMANN SCHNELL
Farbenfabriken Bayer AG, Werk I erdingen
Krefeld- Verdingen,
Germany
GMEUN-INSIiTUT
fiir ar org^nsc e Che ii e un1 G sn?gebiete
oer ME;-: • P - n:* • f e » sci: ft ?UR
hor truiig tier Wis e sch en
Frankfurt/Main
— Bibliothek- •
//y 7 9/77^ 2
INTERSCIENCE PUBLISHERS
A DIVISION OF JOHN WILEY amp; SO MS
NEW YORK • LONDON • SYDNKY
CONTENTS
I Introduction 1
«
II Historical 3
III Chemistry of Polycarbonates 9
1 Aliphatic Polycarbonates 9
A Preparation of Aliphatic Polycarbonates 9
1 Preparation of Aliphatic Polycarbonates 1 y Phosgenation 9
2 Preparation of Aliphatic Polycarbonates by Reaction of Bis-
Chlorocarbonie Acid Esters of Aliphatic Dihydroxy Compounds
with Aliphatic Dihydroxy Compounds 13
3 Preparation of Aliphatic Polycarbonates l v Transesterfication of
Aliphatic Dihydroxy Compounds with Carbonic Acid Diesters 14
I) Preparation of Aliphatic Polycarbonates by Polycondensation of
Bisalkvl or Bisaryl Carbonates of Aliphatic Dihydroxy Com
pounds 18
5 Preparation of Aliphatic Polycarbonates by Polymerization of
Cyclic Carbonates 18
B Propertiec of Aliphatic Polycarbonates 20
2 Aliphatic-Aromatic Polycarbonates 24
3 Aromatic polycarbonates 27
A Preparation of Aromatic Polycarbonates 31
1 Preparation of Aromatic Polycarbonates by Phosgeriation of Aro
matic Dihydroxy Compounds in the Presence of Pyridine 31
g Preparation -of Aromatic Polycarbonates I y Interfacial Polycon
densation 33
3 Isolation of Aromatic Polycarbonates from Their Respective
Solutions 41
4 Preparation of Aromatic Polycarbonates l v Transesterification 44
5 Other Methods of Preparation of Aromatic Polycarbonates 51
6 Preparation of Polycarbonate -Copolymer-* and Mixed Polycon-
densates Containing Carbonate Groups 53
A Polycarbonate Copofymers 53
B Mixed Polyesters Containing Carbonic Acid Ester Groups as
Well as Carboxylio Acid Ester Groups 58
c Mixed Polyesters Containing Carbonic Acid Ester Groups as
Well as Urethane Groups 60
D Mixed Polyesters Containing Carbonic Acid Ester Groups as
Well as Inline Carbonate or Siloxane Groups 61
7 Crosslinking of Polycarbonates 61
ix
CONTENTS
A Influence of Radiation on Aromatic Polycarbonates and Poly
carbonate Copolymers 62
B Crosslinking of Aromatic Polycarbonates by Heating in the •
Presence of Air 63
c Crosslinking of Polycarbonates and ] olyearbonate Copolymers
t Containing Tri- or Pqlyfunctional Groups 64
D Crosslinking of Polycarbonates by ihe Addition of Reactive
Polyfunctional Compounds 70
S Compilation of the Most Important Polycarbonates and Polycar
bonate Copolymers Prepared to Date 70
IV The Production of the Most Important Raw Materials and Intermediates
for Aromatic Polycarbonates 77
1 Derivatives of 4,4 -Dihydroxy-Diarvl Methane 77
A Production of Dihydroxv-Diaryl Methane (Derivatives from Aromatic
Hydroxy Compounds and Aldehydes or Ketones 78
1 Reaction of Aromatic Hydroxy Compounds with Carbonyl Com
pounds in the Presence of Acidic Condensing Agents 78
2 Reaction of Aromatic Hydroxy Compounds with Oxo Compounds
in the Presence of Alkaline Condensing Agents 83
B Other Methods for the Preparation of 4,4 -] ihydroxy-Diphenyl Meth
ane Derivatives 84
C Summary of the Most Important 4,4 -Dihydroxy-Diphenyl Methane
Derivatives Produced to Date 85
2 Diphenyl Carbonate 91
V Structure and Properties of Aromatic Polycarbonates 99
J
1 Solubility of Aromatic Polycarbonates (1-5) 99
2 Melting Range and Second-Order Transition Temperature of Aromatic
Polycarbonates (1^4) 101
3 Determination of the Molecular Data of Polycarbonates in Solution 110
A Fractionation of Bisphenol A Polycarbonaie 110
B Diffusion and Sedimentation Measurements on Bisphenol A Polycar
bonate Solutions 114
C Light-Scattering Measurements on Bisphenol A Polycarbonate Solu
tions 115
D Determination of Molecular Weights and Second Osmotic Virial
Coefficients of Bisphenol A Polycarbonates in Dilute Solution by
Osmometric Methods 117
E Solution Viscosities of Bisphenol A Polycarbonates 119
F Molecular Dimensions of Bisphenol A Polycarbonate in Solution as
Determined by Sedimentation, Diffusion, and Viscosity Measure
ments 121
4 Melt Viscosity of Bisphenol A Polycarbonate 124
5 Crystal Structure and Morphology of Bisphenol A Polycarbonate in the
Nonstretched and Stretched States 127
u
CONTENTS Xi
6 Mechanical and Thermal Properties and Properties under Dynamic
Conditions of Bisphenol A Polycarbonate 139
4 7 Electrical Properties of Aromatic Polycarbonates 157
8 Refractive Index and Light Transmittance of Aromatic Polycarbonates 165
9 Water Absorption, Water Vapor Permeability, and Gas Permeability of
Aromatic Polycarbonates 175
10 Aging and Chemical Resistance of Bisphenol A Polycarbonate 180
11 Physiological Properties of Bisphenol A Polycarbonate 184
12 Identification of Polycarbonates 185
VI The Manufacture and Use of Bisphenol A Polycarbonate Parts 189
1 Film and Fibers 190
2 Injection-Molded Parts, Extruded Tubes and Sliapes, and Blow-Molded
Articles 194
A Injection Molding 194
B Extrusion 199
C Compression Molding 201
D Machining 202
E Cold Forming 202
F Cementing, Welding, and Printing 203
G Foaming 203
3 Aromatic Polycarbonate Paints and Coatings 204
Author Index , 209
Subject Index 217
|
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| discipline | Chemie / Pharmazie Physik |
| format | Book |
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| id | DE-604.BV007206992 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:57:39Z |
| institution | BVB |
| language | English |
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| oclc_num | 2008221 |
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| owner_facet | DE-83 DE-188 |
| physical | XI, 225 S. Ill., graph. Darst. |
| psigel | TUB-nvmb |
| publishDate | 1964 |
| publishDateSearch | 1964 |
| publishDateSort | 1964 |
| publisher | Interscience Publ. |
| record_format | marc |
| series | Polymer reviews |
| series2 | Polymer reviews |
| spelling | Schnell, Hermann Verfasser aut Chemistry and physics of polycarbonates by Hermann Schnell New York [u.a.] Interscience Publ. 1964 XI, 225 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymer reviews 9 Polycarbonates Polycarbonate (DE-588)4175128-0 gnd rswk-swf Polycarbonate (DE-588)4175128-0 s DE-604 Polymer reviews 9 (DE-604)BV001890082 9 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004613670&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Schnell, Hermann Chemistry and physics of polycarbonates Polymer reviews Polycarbonates Polycarbonate (DE-588)4175128-0 gnd |
| subject_GND | (DE-588)4175128-0 |
| title | Chemistry and physics of polycarbonates |
| title_auth | Chemistry and physics of polycarbonates |
| title_exact_search | Chemistry and physics of polycarbonates |
| title_full | Chemistry and physics of polycarbonates by Hermann Schnell |
| title_fullStr | Chemistry and physics of polycarbonates by Hermann Schnell |
| title_full_unstemmed | Chemistry and physics of polycarbonates by Hermann Schnell |
| title_short | Chemistry and physics of polycarbonates |
| title_sort | chemistry and physics of polycarbonates |
| topic | Polycarbonates Polycarbonate (DE-588)4175128-0 gnd |
| topic_facet | Polycarbonates Polycarbonate |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004613670&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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