Polymorphism and polytypism in crystals:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New York [u.a.]
Wiley
1966
|
| Series: | Wiley monographs in crystallography
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIX, 341 S. Ill., graph. Darst. |
Staff View
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Record in the Search Index
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| adam_text |
IN CRYSTAIS AJIT RAM VERMA PROFESSOR AND HEAD OF THE DEPARTMENT OF
PHYSICS BANARAS HINDU UNIVERSITY, VARANASI, INDIA DIRECTOR, NATIONAL
PHYSICAL LAEBORATORY, NEW DELHI, INDIA P* KRISHNA LECTURER IN PHYSICS
BANARAS HINDU UNIVERSITY, VARANASI, INDIA *' . : * * *:, * 1 JOHN
WILEY & SONS, INC. NEW YORK * LONDON * SYDNEY CONTENTS CHAPTER 1.
INTRODUCTION 1 POLYMORPHISM AND POLYTYPISM 1 CHAPTER 2. POLYMORPHISM*THE
PHASE ASPECT 7 DESCRIPTION OF POLYMORPHISM 8 DEFINITION 8 POLYMORPHIE
TRANSITIONS 10 SOME EXAMPLES OF POLYMORPHIE TRANSITIONS . 11 THE EFFECT
OF PRESSURE ON POLYMORPHIE TRANSITIONS 12 PHASE DIAGRAMS 13 COMPARISON
WITH CHANGES OF STATE 15 THERMODYNAMIC ASPECTS OF POLYMORPHISM 16
RELATIVE STABILITY OF POLYMORPHS 18 VAPOR-PRESSURE CURVES 19 APPEARANEE
OF METASTABLE STATES 21 PHASE TRANSFORMATION THEORY 22 POLYMORPHIE
TRANSITIONS AT ORDINARY PRESSURES 22 POLYMORPHIE TRANSITIONS UNDER HIGH
PRESSURE 25 SECOND-ORDER PHASE TRANSFORMATIONS 28 SUMMARY AND CONCLUSION
30 REFERENEES 30 CHAPTER 3. POLYMORPHISM*THE STRUCTURAL ASPECT 33
RELATION OF THERMODYNAMICS TO STRUETURE 34 BUERGER AND BLOOM'S
INTERPRETATION 34 HIGH-PRESSURE TRANSITIONS 37 EFFECT OF TEMPERATURE ON
SYMMETRY AND COORDINATION 37 ABSENCE OF CRITICAL POINT 38 THE VELOEITY
OF POLYMORPHIE TRANSITION 39 METASTABLE PHASES*OSTWALD RULE*ENANTIOTROPY
AND MONOTROPY . . . 43 BUERGER'S STRUCTURAL CLASSIFICATION OF
POLYMORPHIE TRANSFORMATIONS. 45 TRANSFORMATIONS OF FIRST COORDINATION
46 DILATATIONAL TRANSFORMATIONS 47 RECONSTRUCTIVE TRANSFORMATIONS 48
TRANSFORMATIONS OF SECONDARY COORDINATION 50 RECONSTRUCTIVE
TRANSFORMATIONS 50 DISPLACIVE TRANSFORMATIONS 53 XV XVI CONTENTS
TRANSFORMATIONS OF DISORDER 54 ROTATIONAL TRANSFORMATION 55
SUBSTITUTIONAL TRANSFORMATION 55 TRANSFORMATIONS OF BOND TYPE 55
CONCLUSION 58 REFERENCES 58 CHAPTER 4. POIYTYPISM AND THE DESCRIPTION OF
POLYTYPIC STRUCTURES . 61 POIYTYPISM AND POLYMORPHISM 62 DESCRIPTION OF
POLYTYPIC STRUCTURES 64 THE CLOSE PACKINGS OF SPHERES 64 POSSIBLE
CONFIGURATIONS 66 AXIAL RATIO AND LATTICE CONSTANTS 68 VOIDS IN CLOSE
PACKINGS 69 SIZE AND COORDINATION OF THE VOIDS 71 EFFECT OF THE RADIUS
RATIO 73 STRUCTURE OF POLYTYPIC SUBSTANCES 73 ZINC SULFIDE 74 CADMIUM
IODIDE 77 SILICON CARBIDE 81 NOTATIONS TO DESCRIBE POLYTYPES 83 THE
RAMSDELL NOTATION 83 THE CLASSICAL ABC NOTATION 84 OTT'S INTERVAL
SEQUENCE 85 HAEGG'S NOTATION 85 NABARRO-FRANK OPERATORS 86 THE ZHDANOV
SYMBOL 86 RAMSDELL'S ZIGZAG SEQUENCE 87 NOTATION USCD BY PAULING,
WYCKOFF, AND JAGODZINSKI 88 CONVERTING FROM ONE NOTATION TO ANOTHER 88
REFERENCES - 89 CHAPTER 5. SILICON CARBIDE AND OTHER POLYTYPIC
SUBSTANCES . . . 92 SILICON CARBIDE 92 DISCOVERY AND OCCURRENCE 92
MANUFACTURE AND GROWTH 93 PREPARATION OF PURE SINGLE CRYSTALS OF SILICON
CARBIDE 95 THE METHOD OF GASEOUS CRACKING 95 THE METHOD OF SUBLIMATION
96 THE METHOD OF CRYSTALLIZATION FROM SOLUTION 97 PROPERTIES AND USES OF
SILICON CARBIDE 97 PHYSICAL PROPERTIES 97 THERMAL STABILITY 98 CHEMICAL
PROPERTIES 99 SEMICONDUCTING PROPERTIES 99 THE SILICON-CARBON BOND 102
IONIC OR ELECTROVALENT BINDING 102 NEUTRAL OR COVALENT BINDING 102
CONTENTS XVII THE STRUCTURAL CRYSTALLOGRAPHY OF SILICON CARBIDE 103 THE
TRANSFORMATION FROM SS SI C TO A SIC 111 OTHER POLYTYPIC SUBSTANCES 113
ZINC SULFIDE 113 CADMIUM IODIDE 115 CADMIUM BROMIDE 116 LEAD IODIDE 117
MOLYBDENITE (MOS 2 ) 118 NIOBIUM AND TANTALUM SELENIDES 118 GRAPHITE 118
POTASSIUM COBALTICYANIDE, K 3 CO(CN) 6 119 CLAY AND OTHER MINERAL LAYER
STRUCTURES 120 LONG-CHAIN ORGANIC COMPOUNDS 123 CONCLUSION 123
REFERENCES 123 CHAPTER 6. STRUCTURE DETERMINATION OF POLYTYPES 136 X-RAY
DIFFRACTION FROM POLYTYPES 137 NOMENCLATURE 137 THE RECIPROCAL LATTICE
FOR POLYTYPIC STRUCTURES 142 INTERPRETATION OF X-RAY DIFFRACTION
PHOTOGRAPHS 143 STRUCTURAL EXTINCTIONS 148 RHOMBOHEDRAL POLYTYPES 149
LONG-PERIOD POLYTYPES 150 DISORDERED POLYTYPES 152 EXPERIMENTAL
DETAILS 153 THE SYMMETRY AND SPACE GROUP OF POLYTYPIC CRYSTALS 154
CENTER OF SYMMETRY 157 CENTER OF SYMMETRY AT THE CENTER OF A SPHERE 157
CENTER OF SYMMETRY IN THE CENTER OF AN OCTAHEDRAL VOID 157 SYMMETRY
PLANE PERPENDICULAR TO [00-1] 158 HEXAGONAL SYMMETRY 158 POSSIBLE SPACE
GROUPS 159 CONDITIONS FOR A RHOMBOHEDRAL LATTICE 160 SPACE GROUP AND
ZHDANOV SYMBOL 161 ZHDANOV SYMBOL (4)3(2)3 161 ZHDANOV SYMBOL 3422 161
ZHDANOV SYMBOL 22(1)22(1) 162 EXPERIMENTAL DETERMINATION OF THE SPACE
GROUP 162 DETERMINATION OF THE UNIT CELL OF A POLYTYPE 164 THE
POSTULATION OF PROBABLE STRUCTURES 166 SILICON CARBIDE 166 POLYTYPE 10H.
SPACE GROUP P6 S MC 168 POLYTYPE 57SS. SPACE GROUP R3M 168 POLYTYPE 90AE.
SPACE GROUP WIM 168 CADMIUM IODIDE 169 CALCULATION OF INTENSITIES 170
THE STRUCTURE FACTOR 170 STRUCTURAL EXTINCTIONS 170 SPECIAL EXTINCTIONS
IN SOME HEXAGONAL POLYTYPES 171 XVIII CONTENTS INTENSITY OF THE 10-1
REFLECTIONS 171 CORRECTION FACTORS FOR INTENSITY 174 COMPARISON WITH
OBSERVED INTENSITIES 175 UNUSUAL STRUCTURE DETERMINATIONS 176 SILICON
CARBIDE TYPE 36FF 176 CALCULATION OF INTENSITIES 183 ATOMIC COORDINATES
183 CADMIUM IODIDE TYPE 2QH E 184 CONCLUSION 189 REFERENCES 190 CHAPTER
7. DISLOCATIONS AND THE SPIRAL GROWTH OF CRYSTALS . . . . 192 EARLIER
THEORIES OF CRYSTAL GROWTH 192 ATOMIC THEORY OF THE GROWTH OF A PERFECT
CRYSTAL 193 CONCENTRATION OF KINKS IN A STEP 195 MIGRATION OF ADSORBED
MOLECULES ON A CRYSTAL SURFACE 196 RATE OF ADVANCE OF A STRAIGHT STEP
197 SURFACE NUCLEATION 198 REAL CRYSTALS 200 DISLOCATIONS IN CRYSTALS
201 EDGE DISLOCATIONS 202 SCREW DISLOCATIONS 204 ROLE OF SCREW
DISLOCATIONS IN CRYSTAL GROWTH: GROWTH SPIRALS 207 GROWTH SPIRALS AND
THE EXPERIMENTAL EVIDENCE OF DISLOCATIONS 209 OBSERVATIONAL EXAMPLES OF
GROWTH SPIRALS 211 TYPES OF GROWTH SPIRALS 211 SHAPE OF SPIRALS 211
INTERACTION OF GROWTH PATTERNS FROM TWO DISLOCATIONS 214 GROWTH PATTERN
FROM THREE AND MORE DILOCATIONS: DISLOCATION DENSITY . 218 SPIRALS WITH
LARGE STEP HEIGHTS 220 STEP HEIGHTS AND CONCLUSION 221 DIRECT
OBSERVATION OF DISLOCATIONS 221 REFERENCES 227 CHAPTER 8. THEORIES OF
POLYTYPISM 233 EARLIER EXPLANATIONS OF POLYTYPISM 234 CORRELATION OF THE
STRUCTURE TYPE WITH THE IMPURITY CONTENT AND COLOR IN SILICON CARBIDE
234 CORRELATION BETWEEN THE STRUCTURE TYPE AND THE RATE OF
CRYSTALLIZATION FROM SOLUTION IN CADMIUM IODIDE 235 THE CONTROL OF
TEMPERATURE 235 THE POLYMER THEORY OF POLYTYPISM IN SILICON CARBIDE 237
THE DISLOCATION THEORY OF POLYTYPISM 239 FRANK'S THEORY 240 THE ORIGIN
OF STRUCTURE SERIES 241 MODIFICATION OF MITCHELL'S ASSUMPTIONS AND THE
GROWTH OF RHOMBOHEDRAL STRUCTURES 24S THE GROWTH OF RHOMBOHEDRAL
STRUCTURES 249 THE DEDUCTION OF POLYTYPIC STRUCTURES 250 POLYTYPES BASED
ON THE 6H PHASE 250 CONTENTS XIX POLYTYPES BASED ON THE 4FF PHASE 252
POLYTYPES BASED ON THE 15AE PHASE 252 THE ORIGIN OF SOREW DISLOCATIONS
253 EXPERIMENTAL EVIDENCE IN SUPPORT OF THE DISLOCATION THEORY OF
POLYTYPISM. 255 JAGODZINSKI'S DISORDER THEORY OF POLYTYPISM 259 REMOVAL
OF THE THERMODYNAMIC ANOMALY 261 THE ROLE OF THE VIBRATION ENTROPY IN
ONE-DIMENSIONAL DISORDER . . . . 262 CONCLUSIONS 265 THE
LAYER-TRANSPOSITION MECHANISM 266 EXPERIMENTAL EVIDENCE IN FAVOR OF THE
VIBRATION-ENTROPY THEORY . 267 LIMITATIONS OF THE DISORDER THEORY OF
POLYTYPISM 269 POLYTYPISM AS A SECOND-ORDER TRANSFORMATION 269
INTERACTION ENERGY OF THE ASSEMBLY 273 LONG-RANGE INTERACTIONS 276
ENTROPY 279 THE PHASE TRANSFORMATION RELATING POLYTYPES 279 CONCLUSIONS
281 EXPERIMENTAL EVIDENCE 281 POLYTYPISM AND THERMAL VIBRATIONS IN THE
STRUCTURE 283 TIME FUNCTIONALITY 286 SCREW DISLOCATIONS 286 DISCUSSION
287 CONCLUSION/ 287 REFERENCES 288 CHAPTER 9. RECENT OBSERVATIONS ON
POLYTYPISM AND PRESENT POSITION 295 SPIRAL STEP HEIGHT ON CADMIUM IODIDE
296 ANOMALOUS POLYTYPIC STRUCTURCS 298 ANOMALIES IN SILICON CARBIDE
POLYTYPES 298 POLYTYPES 57AE AND IHR 299 POLYTYPES 36FF, 54TF, 66TF, AND
126AE 300 90SS POLYTYPE 302 DISORDERED STRUCTURES -. 303 ANOMALIES IN
CADMIUM IODIDE POLYTYPES 305 OBSERVATIONS OF THE GROWTH PROCESS 312
PRESENT POSITION AND SUMMARY 316 CONCLUSION 322 REFERENCES 323 NAME
INDEX 327 SUBJECT INDEX 333 |
| any_adam_object | 1 |
| author | Verma, Ajit R. Krishna, Padmanabhan |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
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| id | DE-604.BV007098391 |
| illustrated | Illustrated |
| indexdate | 2024-07-20T07:50:53Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-004517295 |
| oclc_num | 610923947 |
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| owner_facet | DE-355 DE-BY-UBR DE-29 DE-29T DE-19 DE-BY-UBM DE-11 DE-188 DE-B16 |
| physical | XIX, 341 S. Ill., graph. Darst. |
| publishDate | 1966 |
| publishDateSearch | 1966 |
| publishDateSort | 1966 |
| publisher | Wiley |
| record_format | marc |
| series2 | Wiley monographs in crystallography |
| spelling | Verma, Ajit R. Verfasser aut Polymorphism and polytypism in crystals Ajit Ram Verma ; P. Krishna New York [u.a.] Wiley 1966 XIX, 341 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wiley monographs in crystallography Cristallographie Polymorphisme Polymorphism (Crystallography) Kristall (DE-588)4033209-3 gnd rswk-swf Polymorphie (DE-588)4175258-2 gnd rswk-swf Polytypie (DE-588)4123966-0 gnd rswk-swf Kristall (DE-588)4033209-3 s Polytypie (DE-588)4123966-0 s DE-604 Polymorphie (DE-588)4175258-2 s Krishna, Padmanabhan Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004517295&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Verma, Ajit R. Krishna, Padmanabhan Polymorphism and polytypism in crystals Cristallographie Polymorphisme Polymorphism (Crystallography) Kristall (DE-588)4033209-3 gnd Polymorphie (DE-588)4175258-2 gnd Polytypie (DE-588)4123966-0 gnd |
| subject_GND | (DE-588)4033209-3 (DE-588)4175258-2 (DE-588)4123966-0 |
| title | Polymorphism and polytypism in crystals |
| title_auth | Polymorphism and polytypism in crystals |
| title_exact_search | Polymorphism and polytypism in crystals |
| title_full | Polymorphism and polytypism in crystals Ajit Ram Verma ; P. Krishna |
| title_fullStr | Polymorphism and polytypism in crystals Ajit Ram Verma ; P. Krishna |
| title_full_unstemmed | Polymorphism and polytypism in crystals Ajit Ram Verma ; P. Krishna |
| title_short | Polymorphism and polytypism in crystals |
| title_sort | polymorphism and polytypism in crystals |
| topic | Cristallographie Polymorphisme Polymorphism (Crystallography) Kristall (DE-588)4033209-3 gnd Polymorphie (DE-588)4175258-2 gnd Polytypie (DE-588)4123966-0 gnd |
| topic_facet | Cristallographie Polymorphisme Polymorphism (Crystallography) Kristall Polymorphie Polytypie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004517295&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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