Carbocyclic ring expansion reactions:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New York
Acad. Press
1968
|
| Series: | Advances in alicylic chemistry
Supplement ; 1 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 243 S. |
Staff View
MARC
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| 100 | 1 | |a Gutsche, Carl D. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Carbocyclic ring expansion reactions |c C. David Gutsche and Derek Redmore |
| 264 | 1 | |a New York |b Acad. Press |c 1968 | |
| 300 | |a 243 S. | ||
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Record in the Search Index
| _version_ | 1804121276515614720 |
|---|---|
| adam_text | Titel: Carbocyclic ring expansion reactions
Autor: Gutsche, C. D
Jahr: 1968
Contents
Preface
..............
v
Chapter
I
Introduction
Text
..............
1
Chapter
II
Wagner-Meerwein
Rearrangements
of
Cycloalkanecarbinyl
Systems
A.
General
Discussion
..........
3
B.
Cyclopropylcarbinyl
-
Cyclobutyl
........
9
C.
Cyclobutylcarbinyl
-
Cyclopentyl
........
16
D.
Cyclopentylcarbinyl
-»
Cyclohexyl
........
29
E.
Cyclohexylcarbinyl
-»
Cycloheptyl
........
45
F.
Cycloheptylcarbinyl
and
Larger
Rings
-
Cyclooctyl
and
Larger
Rings
.
.
57
Chapter
III
Pinacol-Type
Rearrangements
of
Cycloalkanecarbinyl
Systems
A.
General
Discussion
..........
61
B.
Cyclopropylcarbinyl
-»
Cyclobutyl
........
63
C.
Cyclobutylcarbinyl
-?
Cyclopentyl
........
64
D.
Cyclopentylcarbinyl
-
Cyclohexyl
........
64
E.
Cyclohexylcarbinyl
-
Cycloheptyl
........
73
F.
Cycloheptylcarbinyl
and
Larger
Rings
-»
Cyclooctyl
and
Larger
Rings
.
.
79
Chapter
IV
Diazoalkane
Ring
Expansions
of
Cycloalkanones
A.
General
Discussion
.
.
.
.
.
.
.
.
.
.81
B.
Cyclopropanone
- •
Cyclobutanone
........
83
C.
Cyclobutanone
-
Cyclopentanone
........
84
D.
Cyclopentanone
-
Cyclohexanone
........
84
E.
Cyclohexanone
-»
Cycloheptanone
........
86
F.
Cycloheptanone
and
Larger
Cycloalkanones
-
Cyclooctanone
and
Larger
Cycloalkanones
...........
95
vii
viii
Contents
Chapter
V
Ring
Expansions
via
Anionic
Intermediates
A.
Zinc-Induced
Rearrangement
of
1,1-Bisbromomethylcycloalkanes
.
99
B.
Base-Induced
Rearrangements
of
Bromomethylenecycloalkanes
.
.
.
100
C.
Base-Induced
Rearrangements
of
1,2-Glycol
Monotosylates
.
.
.101
D.
Base-Induced
Rearrangement
of
a-Ketols
.
.
.
.
.
.
.104
E.
Rearrangements
of
a-Aminoketones
and
a-Hydroxyimines
.
.
.
.106
F.
Miscellaneous
Rearrangements
.
.
.
.
.
.
.108
Chapter
VI
Ring
Expansions
via
Carbene
or
Radical
Intermediates
Text..............Ill
Chapter
VII
Photochemically
Induced
Ring
Expansions
Text..............119
Chapter
VIII
Ring
Expansion
Sequences
via
Bicyclo[/i.l.0]alkane
Intermediates
A.
General
Discussion
.
.
.
.
.
.
.
.127
B.
Cyclopropyl
-
Cyclobutyl
.........
131
C.
Cyclobutyl
-
Cyclopentyl
.
.
.
.
.
.
.132
D.
Cyclopentyl-*
Cyclohexyl
.
.
.
.
.
.
.
.132
E.
Cyclohexyl
-
Cycloheptyl
.
.
.
.
.
.137
F.
Cycloheptyl
and
Larger
Rings
-
Cyclooctyl
and
Larger
Rings
.
.
.155
Chapter
IX
Ring
Expansion
by
Two
Carbon
Atoms
A.
Sequential
One-Carbon
Transformations
.
.
.
.
.161
B.
Vinylcyclopropane
Rearrangement
........
163
C.
Cope
Rearrangement
.
.
.
.
.
.
.
.
.170
D.
Ring
Expansion
Sequences
Involving
Bicyclo[n.2.0]alkane
Intermediates
.
173
E.
Ring
Annulation-Scission
Methods
.
.
.
.
.
.
.181
F.
Miscellaneous
Methods
.
.
.
.
.187
Chapter
X
Ring
Expansion
by
Three
or
More
Carbon
Atoms
A.
Ring
Annulation-Scission
Methods
........
191
B.
Cope
Rearrangement
.
.
.
.
.195
C.
Miscellaneous
Methods
..........
197
Author
Index
.........
199
Subject
Index
.........
213
Starting
Compound
and
Product
Index
......
224
|
| any_adam_object | 1 |
| author | Gutsche, Carl D. Redmore, Derek |
| author_facet | Gutsche, Carl D. Redmore, Derek |
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| discipline | Chemie / Pharmazie |
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| id | DE-604.BV007093867 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T16:55:25Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-004513425 |
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| physical | 243 S. |
| psigel | TUB-nvmb |
| publishDate | 1968 |
| publishDateSearch | 1968 |
| publishDateSort | 1968 |
| publisher | Acad. Press |
| record_format | marc |
| series | Advances in alicylic chemistry |
| series2 | Advances in alicylic chemistry : Supplement |
| spelling | Gutsche, Carl D. Verfasser aut Carbocyclic ring expansion reactions C. David Gutsche and Derek Redmore New York Acad. Press 1968 243 S. txt rdacontent n rdamedia nc rdacarrier Advances in alicylic chemistry : Supplement 1 Carbone - Composés Chimie - Réactions Organic cyclic compounds Ring formation (Chemistry) Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Umlagerung (DE-588)4061594-7 gnd rswk-swf Carbocyclen (DE-588)4131204-1 gnd rswk-swf Ringerweiterung Chemie (DE-588)4115769-2 gnd rswk-swf Carbocyclen (DE-588)4131204-1 s Umlagerung (DE-588)4061594-7 s DE-604 Ringerweiterung Chemie (DE-588)4115769-2 s Organische Verbindungen (DE-588)4043816-8 s Redmore, Derek Verfasser aut Advances in alicylic chemistry Supplement ; 1 (DE-604)BV006649978 1 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004513425&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gutsche, Carl D. Redmore, Derek Carbocyclic ring expansion reactions Advances in alicylic chemistry Carbone - Composés Chimie - Réactions Organic cyclic compounds Ring formation (Chemistry) Organische Verbindungen (DE-588)4043816-8 gnd Umlagerung (DE-588)4061594-7 gnd Carbocyclen (DE-588)4131204-1 gnd Ringerweiterung Chemie (DE-588)4115769-2 gnd |
| subject_GND | (DE-588)4043816-8 (DE-588)4061594-7 (DE-588)4131204-1 (DE-588)4115769-2 |
| title | Carbocyclic ring expansion reactions |
| title_auth | Carbocyclic ring expansion reactions |
| title_exact_search | Carbocyclic ring expansion reactions |
| title_full | Carbocyclic ring expansion reactions C. David Gutsche and Derek Redmore |
| title_fullStr | Carbocyclic ring expansion reactions C. David Gutsche and Derek Redmore |
| title_full_unstemmed | Carbocyclic ring expansion reactions C. David Gutsche and Derek Redmore |
| title_short | Carbocyclic ring expansion reactions |
| title_sort | carbocyclic ring expansion reactions |
| topic | Carbone - Composés Chimie - Réactions Organic cyclic compounds Ring formation (Chemistry) Organische Verbindungen (DE-588)4043816-8 gnd Umlagerung (DE-588)4061594-7 gnd Carbocyclen (DE-588)4131204-1 gnd Ringerweiterung Chemie (DE-588)4115769-2 gnd |
| topic_facet | Carbone - Composés Chimie - Réactions Organic cyclic compounds Ring formation (Chemistry) Organische Verbindungen Umlagerung Carbocyclen Ringerweiterung Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=004513425&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV006649978 |
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