Holdings: Surfactant aggregation

Surfactant aggregation:

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Bibliographic Details
Main Author:	Clint, John H. (Author)
Format:	Book
Language:	English
Published:	Glasgow [u.a.] Blackie 1992
Edition:	1. publ.
Subjects:	Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff Oberflächenchemie
Online Access:	Inhaltsverzeichnis
Physical Description:	XI, 283 S. Ill., graph. Darst.
ISBN:	0216929059

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MARC


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Record in the Search Index

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adam_text	SURFACTANT AGGREGATION JOHN H. CLINT, BSC, PHD RESEARCH ASSOCIATE (COLLOID SCIENCE) BP RESEARCH CENTRE SUNBURY-ON-THAMES BLACKIE GLASGOW AND LONDON PUBLISHED IN THE USA BY CHAPMAN AND HALL NEW YORK CONTENTS 1 NATURE OF SURFACTANTS 1 1.1 INTRODUCTION TO SURFACTANTS 1 1.2 NATURAL SURFACTANTS 1 1.3 SYNTHETIC SURFACTANTS 3 1.4 TYPES OF SURFACTANT 4 1.4.1 HYDROPHILIC GROUPS 4 1.4.2 HYDROPHOBIE GROUPS 5 1.5 SURFACE ACTIVITY 6 1.5.1 SELF-ASSOCIATION 7 1.5.2 THE HYDROPHOBIC EFFECT 9 REFERENCES 11 2 ADSORPTION AT LIQUID INTERFACES 13 2.1 INTRODUCTION 13 2.2 DIRECT MEASUREMENT OF AMOUNT ADSORBED 13 2.3 ADSORPTION STUDIED VIA SURFACE AND INTERFACIAL TENSION MEASUREMENT 14 2.4 ADSORPTION OF IONIC SURFACTANTS 17 2.4.1 NO ADDED ELECTROLYTE 17 2.4.2 IONIC SURFACTANT WITH EXCESS ELECTROLYTE 17 2.5 EQUATIONS OF STATE FOR ADSORBED SURFACTANTS 18 2.6 ADSORPTION AT THE LIQUID/LIQUID INTERFACE 20 2.7 ULTRA-LOW INTERFACIAL TENSIONS 23 2.7.1 PREDICTION OF EMULSION TYPE FROM PACKING GEOMETRY 24 2.7.2 PHASE INVERSION 25 2.7.3 TENSIONS AT CURVED AND PLANAR INTERFACES 26 2.7.4 INTERACTIONS BETWEEN ADSORBED MONOLAYERS 27 2.7.5 PRACTICAL APPLICATIONS OF ULTRA-LOW TENSION SYSTEMS 28 2.8 PHYSICAL PROPERTIES OF ADSORBED MONOLAYERS 28 2.9 DYNAMIC ASPECTS OF ADSORBED SURFACTANTS 29 2.9.1 THE MARANGONI EFFECT 30 REFERENCES 31 3 INSOLUBLE MONOLAYERS 33 3.1 INTRODUCTION 33 3.2 HISTORICAL BACKGROUND 33 3.2.1 THE LANGMUIR TROUGH AND ITS ORIGIN 34 3.2.2 USE OF THE LANGMUIR TROUGH 35 3.3 PHASE CHANGES AND TYPES OF FILM 36 3.3.1 GASEOUS FILMS 37 3.3.2 THE LE + G REGION 38 3.3.3 THE LIQUID-EXPANDED REGION 39 3.3.4 THE TRANSITION REGION 40 VLLL CONTENTS 3.3.5 THE LIQUID-CONDENSED REGION 41 3.3.6 THE SOLID REGION 42 3.4 IONISED MONOLAYERS 42 3.4.1 EFFECT OF POLYVALENT COUNTERIONS 44 3.5 X-RAY AND NEUTRON SCATTERING 44 3.5.1 HORIZONTAL SCATTERING 45 3.5.2 VERTICAL SCATTERING 46 3.5.3 NEUTRON SCATTERING 49 3.6 DYNAMIC EFFECTS 51 3.6.1 INTERFACIAL SHEAR RHEOLOGY 52 3.6.2 INTERFACIAL DILATATIONAL RHEOLOGY 53 3.6.3 MEASUREMENT OF SURFACE SHEAR VISCOSITY FOR INSOLUBLE MONOLAYERS 53 3.6.4 MEASUREMENT OF SURFACE DILATATIONAL RHEOLOGICAL PROPERTIES 54 3.7 PRACTICAL APPLICATIONS OF INSOLUBLE MONOLAYERS 55 REFERENCES 57 4 LANGMUIR-BLODGETT MULTILAYERS 59 4.1 INTRODUCTION 59 4.2 HISTORICAL BACKGROUND 59 4.3 TYPES OF MONOLAYER DEPOSITION 62 4.3.1 X-, Y-AND Z-FILMS 62 4.3.2 INCOMPLETE DEPOSITION 64 4.3.3 ASYMMETRICAL FILMS 64 4.3.4 POLYMERIE SYSTEMS 65 4.4 STRUCTURE OF MULTILAYERS 66 4.4.1 CHARACTERISATION BY SIMPLE TECHNIQUES 67 4.4.2 LOW-ANGLE X-RAY DIFFRACTION 68 4.4.3 SPECTROSCOPIC METHODS 70 4.4.4 LONG-RANGE ORDER AND HOMOGENEITY 70 4.5 APPLICATIONS OF LB FILMS 71 4.5.1 DEVICES EXPLOITING THE INSULATING PROPERTIES OF THE FILM 72 4.5.2 APPLICATIONS COMBINING ULTRA-THIN PROPERTY WITH USEFUL CHEMISTRY 72 4.5.3 MULTILAYERS REQUIRING NON-CENTROSYMMETRICAL STRUETURES 73 4.5.4 SUPERMOLECULAR ASSEMBLIES AND MOLECULAR ELECTRONICS 74 4.5.5 SENSORS 76 4.6 SELF-ASSEMBLY SYSTEMS 77 4.6.1 SELF-ASSEMBLY MONOLAYERS 77 4.6.2 SELF-ASSEMBLY MULTILAYERS 78 REFERENCES 79 5 MICELLE FORMATION 82 82 84 84 84 85 94 98 100 102 105 105 106 5.1 5.2 5.3 5.4 EVIDENCE FOR MICELLE FORMATION STRUCTURE OF MICELLES 5.2.1 HARTLEY S MODEL FOR SPHERICAL MICELLES 5.2.2 SIMPLE GEOMETRIC FACTORS 5.2.3 SPHERICAL MICELLES 5.2.4 CYLINDRICAL MICELLES 5.2.5 COUNTERION BINDING DYNAMICS OF MICELLAR AGGREGATION 5.3.1 THE MULTIPLE EQUILIBRIUM MODEL THE CRITICAL MICELLE CONCENTRATION (CMC) 5.4.1 IONIC SURFACTANTS 5.4.2 NON-IONIC SURFACTANTS CONTENTS IX 5.4.3 FACTORS AFFECTING THE CMC 107 5.4.4 METHODS FOR MEASURING THE CMC 110 5.5 THERMODYNAMICS OF MICELLE FORMATION 112 5.5.1 SIMPLE THERMODYNAMIC THEORY 113 5.5.2 EXPERIMENTAL DATA FOR THE THERMODYNAMIC PARAMETERS OF MICELLISATION 114 5.5.3 MECHANISM OF MICELLE FORMATION 115 5.6 SOLUBILISATION 118 5.6.1 POLAR SOLUBILISATES 119 5.6.2 EFFECT OF TEMPERATURE AND ELECTROLYTE ADDITION 120 5.7 APPLICATIONS OF MICELLAR SOLUTIONS 120 5.7.1 DETERGENCY 120 5.7.2 APPLICATION OF CYLINDRICAL MICELLES 122 5.7.3 SOLUBILISATION 123 5.7.4 MICELLAR-ENHANCED ULTRAFILTRATION 123 5.7.5 MICELLAR CATALYSIS 123 REFERENCES 126 6 MIXED-MICELLE FORMATION 130 6.1 QUALITATIVE OBSERVATIONS 130 6.2 THERMODYNAMICS OF MIXED-MICELLE FORMATION 131 6.2.1 SURFACE TENSIONS OF SURFACTANT SOLUTIONS 133 6.3 THERMODYNAMICS OF NON-IDEAL MIXED-MICELLE FORMATION 134 6.3.1 MIXTURES WHERE ONE COMPONENT DOES NOT FORM MICELLES 135 6.3.2 NON-IDEALITY IN THE INTERFACE 137 6.4 SOME MAJOR FINDINGSSURFACTANT SYNERGISMS 138 6.5 FURTHER EXAMPLES OF MIXED-MICELLE FORMATION 143 6.6 POSITIVE DEVIATIONS FROM IDEALITYMIXTURES OF PERFLUORO AND HYDROCARBON 144 SURFACTANTS REFERENCES 146 7 GENERAL PHASE BEHAVIOUR OF SURFACTANTS 147 7.1 GENERAL FEATURES OF SURFACTANT PHASE BEHAVIOUR 147 7.2 THE KRAFFT BOUNDARY 148 7.2.1 DESIGN OF SURFACTANTS FOR USE IN HARD WATER 149 7.2.2 PRODUCTS MAKING USE OF KRAFFT BOUNDARY EFFECTS 152 7.2.3 DEPENDENCE OF KRAFFT TEMPERATURE ON SURFACTANT STRUCTURE 153 7.3 THE CLOUD POINT 154 7.3.1 MECHANISM OF PHASE SEPARATION 155 7.3.2 NATURE OF THE SEPARATED PHASES 156 7.3.3 PRACTICAL IMPORTANCE OF CLOUD POINT PHENOMENA 157 7.4 MESOMORPHIC PHASES 158 7.4.1 QUANTITATIVE PHASE DIAGRAM CUTS 159 7.4.2 QUANTITATIVE PHASE CUTS* DIFFUSIVE INTERFACIAL TRANSPORT 160 7.4.3 GENERAL DISPOSITION OF MESOMORPHIC PHASES 160 7.4.4 HEXAGONAL PHASES H T AND H 2 162 7.4.5 LAMELLAR PHASE L* 164 7.4.6 CUBIC PHASES 165 7.4.7 FLUCTUATIONS CLOSE TO PHASE BOUNDARIES 166 7.4.8 PHYSICAL STATE OF MOLECULES IN LIQUID-CRYSTAL PHASES 166 7.4.9 THE SURFACTANT MOLECULES 167 7.4.10 THE STATE OF WATER MOLECULES 168 7.4.11 OTHER LYOTROPIC LIQUID-CRYSTALLINE PHASES 169 7.4.12 APPLICATIONS OF SURFACTANT PHASE INFORMATION 170 REFERENCES 171 CONTENTS DISPERSIONS OF SURFACTANT AGGREGATES 173 8.1 INTRODUCTION 173 8.2 VESICLES AND LIPOSOMES 173 8.2.1 BIOLOGICAL MEMBRANES 175 8.2.2 SYNTHETIC MEMBRANE-FORMING SURFACTANTS 176 8.2.3 PREPARATION OF LIPOSOMES AND VESICLES 176 8.2.4 STABILITY OF VESICLES AND LIPOSOMES 177 8.2.5 PROPERTIES OF LIPOSOMES 178 8.3 APPLICATIONS OF LIPOSOMES 180 8.3.1 DRUG CARRIERS 180 8.3.2 REACTION MICROENVIRONMENTS 181 8.3.3 FREEZE-DRIED LIPOSOMES 182 8.3.4 FABRIC AND HAIR CONDITIONERS 182 8.3.5 STABILITY OF LIPOSOME DISPERSIONS 185 8.4 DISPERSIONS OF CRYSTALS 186 8.4.1 SURFACTANT GELS 187 8.4.2 USE IN DETERGENT PRODUCTS 188 8.4.3 HARD-SURFACE CLEANERS 189 REFERENCES 190 ADSORPTION ON SOLIDS 192 9.1 INTRODUCTION 192 9.1.1 EXPERIMENTAL DETERMINATION OF AMOUNT ADSORBED 194 9.1.2 ADSORPTION ISOTHERMS 196 9.1.3 THERMODYNAMICS OF ADSORPTION ONTO SOLIDS 199 9.2 ADSORPTION AT VERY LOW CONCENTRATION 200 9.3 LATERAL INTERACTIONS BETWEEN ADSORBED SURFACTANT MOLECULES 202 9.3.1 NATURE OF THE ADSORBED LAYER 203 9.3.2 ADSORPTION AT HIGHER CONCENTRATIONS 204 9.4 EFFECT OF SURFACTANT STRUCTURE ON ADSORPTION 204 9.4.1 NON-IONIC SURFACTANTS ON HYDROPHOBIC SURFACES 204 9.4.2 NON-IONIC SURFACTANTS ON HYDROPHILIC SURFACES 206 9.4.3 ZWITTERIONIC SURFACTANTS ON HYDROPHILIC SURFACES 207 9.4.4 IONIC SURFACTANTS ON HYDROPHOBIC SURFACES 209 9.4.5 IONIC SURFACTANTS ON HYDROPHILIC SURFACES 210 9.5 STABILISATION OF DISPERSIONS 211 9.5.1 FORCES BETWEEN PARTICLES 211 9.5.2 COMBINED DISPERSION AND ELECTROSTATIC FORCES 214 9.5.3 COMBINED DISPERSION AND STERIC FORCES 215 9.6 OTHER APPLICATIONS 216 9.6.1 FROTH FLOTATION 216 9.6.2 DETERGENCY 217 9.6.3 CORROSION INHIBITION 217 9.6.4 WATER PURIFICATION 218 9.6.5 ADMICELLAR CHROMATOGRAPHY 218 9.6.6 ENHANCED OIL RECOVERY 220 REFERENCES 220 MICROEMULSIONS 222 10.1 DEFINITION OF MICROEMULSIONS 222 10.2 USE OF CO-SURFACTANTS 225 10.3 INTERFACIAL TENSION IN MICROEMULSIONS 227 10.4 PROPERTIES OF MICROEMULSIONS 230 CONTENTS XI 10.4.1 CHARACTERISATION OF MICROEMULSIONS 231 10.4.2 SIMPLE GEOMETRIC CONSIDERATIONS 231 10.4.3 ELECTRON MICROSCOPIC OBSERVATIONS 232 10.4.4 SCATTERING TECHNIQUES 234 10.4.5 SELF-DIFFUSION MEASUREMENTS 238 10.5 APPLICATIONS OF MICROEMULSIONS 239 10.5.1 MICROEMULSIONS AS PRODUCTS 239 10.5.2 MICROEMULSIONS AS PHYSICAL PROCESS AIDS 241 10.5.3 MICROEMULSIONS AS CHEMICAL REACTION MEDIA 241 10.5.4 SURFACTANT-ENHANCED OIL RECOVERY 244 REFERENCES 247 11 SURFACTANT BIIAYERS, FOAMS AND EMULSIONS 250 11.1 INTRODUCTION 250 11.2 SOAPFILMS 252 11.2.1 FILMDRAINAGE 252 11.2.2 FACTORS AFFECTING DRAINAGE RATE 253 11.2.3 STRUCTURE OF DRAINED FILMS 256 11.3 MEASUREMENT OF FILM THICKNESS 258 11.3.1 FACTORS AFFECTING FILM THICKNESS 260 11.3.2 THIN-FILM TENSIONS 262 11.3.3 FILM STABILITY 263 11.4 FOAMS AND FOAM STABILITY 264 11.4.1 BULK VISCOSITY 265 11.4.2 SURFACE VISCOSITY 266 11.4.3 ANTIFOAMS 266 11.4.4 NON-AQUEOUS FOAMS 267 11.5 LIPID BIIAYERS 267 11.5.1 PERMEABILITY OF BILAYER LIPID MEMBRANES 268 11.6 FORMATION AND STABILITY OF EMULSIONS 269 11.6.1 COALESCENCE 271 11.6.2 EMULSION TYPE 271 11.6.3 MIXED EMULSIFIERS 272 11.6.4 HIGH INTERNAL PHASE RATIO (HIPR) EMULSIONS 274 11.6.5 DEMULSIFICATION 275 REFERENCES 276 INDEX 279
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spelling	Clint, John H. Verfasser aut Surfactant aggregation John H. Clint 1. publ. Glasgow [u.a.] Blackie 1992 XI, 283 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Grenzflächenaktiver Stoff (DE-588)4158138-6 s DE-604 Oberflächenchemie (DE-588)4126166-5 s GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003845789&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Clint, John H. Surfactant aggregation Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd Oberflächenchemie (DE-588)4126166-5 gnd
subject_GND	(DE-588)4158138-6 (DE-588)4126166-5
title	Surfactant aggregation
title_auth	Surfactant aggregation
title_exact_search	Surfactant aggregation
title_full	Surfactant aggregation John H. Clint
title_fullStr	Surfactant aggregation John H. Clint
title_full_unstemmed	Surfactant aggregation John H. Clint
title_short	Surfactant aggregation
title_sort	surfactant aggregation
topic	Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd Oberflächenchemie (DE-588)4126166-5 gnd
topic_facet	Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff Oberflächenchemie
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