Surfactant aggregation:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Glasgow [u.a.]
Blackie
1992
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| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 283 S. Ill., graph. Darst. |
| ISBN: | 0216929059 |
Internformat
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Datensatz im Suchindex
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| adam_text | SURFACTANT AGGREGATION JOHN H. CLINT, BSC, PHD RESEARCH ASSOCIATE
(COLLOID SCIENCE) BP RESEARCH CENTRE SUNBURY-ON-THAMES BLACKIE GLASGOW
AND LONDON PUBLISHED IN THE USA BY CHAPMAN AND HALL NEW YORK CONTENTS 1
NATURE OF SURFACTANTS 1 1.1 INTRODUCTION TO SURFACTANTS 1 1.2 NATURAL
SURFACTANTS 1 1.3 SYNTHETIC SURFACTANTS 3 1.4 TYPES OF SURFACTANT 4
1.4.1 HYDROPHILIC GROUPS 4 1.4.2 HYDROPHOBIE GROUPS 5 1.5 SURFACE
ACTIVITY 6 1.5.1 SELF-ASSOCIATION 7 1.5.2 THE HYDROPHOBIC EFFECT 9
REFERENCES 11 2 ADSORPTION AT LIQUID INTERFACES 13 2.1 INTRODUCTION 13
2.2 DIRECT MEASUREMENT OF AMOUNT ADSORBED 13 2.3 ADSORPTION STUDIED VIA
SURFACE AND INTERFACIAL TENSION MEASUREMENT 14 2.4 ADSORPTION OF IONIC
SURFACTANTS 17 2.4.1 NO ADDED ELECTROLYTE 17 2.4.2 IONIC SURFACTANT WITH
EXCESS ELECTROLYTE 17 2.5 EQUATIONS OF STATE FOR ADSORBED SURFACTANTS 18
2.6 ADSORPTION AT THE LIQUID/LIQUID INTERFACE 20 2.7 ULTRA-LOW
INTERFACIAL TENSIONS 23 2.7.1 PREDICTION OF EMULSION TYPE FROM PACKING
GEOMETRY 24 2.7.2 PHASE INVERSION 25 2.7.3 TENSIONS AT CURVED AND PLANAR
INTERFACES 26 2.7.4 INTERACTIONS BETWEEN ADSORBED MONOLAYERS 27 2.7.5
PRACTICAL APPLICATIONS OF ULTRA-LOW TENSION SYSTEMS 28 2.8 PHYSICAL
PROPERTIES OF ADSORBED MONOLAYERS 28 2.9 DYNAMIC ASPECTS OF ADSORBED
SURFACTANTS 29 2.9.1 THE MARANGONI EFFECT 30 REFERENCES 31 3 INSOLUBLE
MONOLAYERS 33 3.1 INTRODUCTION 33 3.2 HISTORICAL BACKGROUND 33 3.2.1 THE
LANGMUIR TROUGH AND ITS ORIGIN 34 3.2.2 USE OF THE LANGMUIR TROUGH 35
3.3 PHASE CHANGES AND TYPES OF FILM 36 3.3.1 GASEOUS FILMS 37 3.3.2 THE
LE + G REGION 38 3.3.3 THE LIQUID-EXPANDED REGION 39 3.3.4 THE
TRANSITION REGION 40 VLLL CONTENTS 3.3.5 THE LIQUID-CONDENSED REGION 41
3.3.6 THE SOLID REGION 42 3.4 IONISED MONOLAYERS 42 3.4.1 EFFECT OF
POLYVALENT COUNTERIONS 44 3.5 X-RAY AND NEUTRON SCATTERING 44 3.5.1
HORIZONTAL SCATTERING 45 3.5.2 VERTICAL SCATTERING 46 3.5.3 NEUTRON
SCATTERING 49 3.6 DYNAMIC EFFECTS 51 3.6.1 INTERFACIAL SHEAR RHEOLOGY 52
3.6.2 INTERFACIAL DILATATIONAL RHEOLOGY 53 3.6.3 MEASUREMENT OF SURFACE
SHEAR VISCOSITY FOR INSOLUBLE MONOLAYERS 53 3.6.4 MEASUREMENT OF SURFACE
DILATATIONAL RHEOLOGICAL PROPERTIES 54 3.7 PRACTICAL APPLICATIONS OF
INSOLUBLE MONOLAYERS 55 REFERENCES 57 4 LANGMUIR-BLODGETT MULTILAYERS 59
4.1 INTRODUCTION 59 4.2 HISTORICAL BACKGROUND 59 4.3 TYPES OF MONOLAYER
DEPOSITION 62 4.3.1 X-, Y-AND Z-FILMS 62 4.3.2 INCOMPLETE DEPOSITION 64
4.3.3 ASYMMETRICAL FILMS 64 4.3.4 POLYMERIE SYSTEMS 65 4.4 STRUCTURE OF
MULTILAYERS 66 4.4.1 CHARACTERISATION BY SIMPLE TECHNIQUES 67 4.4.2
LOW-ANGLE X-RAY DIFFRACTION 68 4.4.3 SPECTROSCOPIC METHODS 70 4.4.4
LONG-RANGE ORDER AND HOMOGENEITY 70 4.5 APPLICATIONS OF LB FILMS 71
4.5.1 DEVICES EXPLOITING THE INSULATING PROPERTIES OF THE FILM 72 4.5.2
APPLICATIONS COMBINING ULTRA-THIN PROPERTY WITH USEFUL CHEMISTRY 72
4.5.3 MULTILAYERS REQUIRING NON-CENTROSYMMETRICAL STRUETURES 73 4.5.4
SUPERMOLECULAR ASSEMBLIES AND MOLECULAR ELECTRONICS 74 4.5.5 SENSORS 76
4.6 SELF-ASSEMBLY SYSTEMS 77 4.6.1 SELF-ASSEMBLY MONOLAYERS 77 4.6.2
SELF-ASSEMBLY MULTILAYERS 78 REFERENCES 79 5 MICELLE FORMATION 82 82 84
84 84 85 94 98 100 102 105 105 106 5.1 5.2 5.3 5.4 EVIDENCE FOR MICELLE
FORMATION STRUCTURE OF MICELLES 5.2.1 HARTLEY S MODEL FOR SPHERICAL
MICELLES 5.2.2 SIMPLE GEOMETRIC FACTORS 5.2.3 SPHERICAL MICELLES 5.2.4
CYLINDRICAL MICELLES 5.2.5 COUNTERION BINDING DYNAMICS OF MICELLAR
AGGREGATION 5.3.1 THE MULTIPLE EQUILIBRIUM MODEL THE CRITICAL MICELLE
CONCENTRATION (CMC) 5.4.1 IONIC SURFACTANTS 5.4.2 NON-IONIC SURFACTANTS
CONTENTS IX 5.4.3 FACTORS AFFECTING THE CMC 107 5.4.4 METHODS FOR
MEASURING THE CMC 110 5.5 THERMODYNAMICS OF MICELLE FORMATION 112 5.5.1
SIMPLE THERMODYNAMIC THEORY 113 5.5.2 EXPERIMENTAL DATA FOR THE
THERMODYNAMIC PARAMETERS OF MICELLISATION 114 5.5.3 MECHANISM OF MICELLE
FORMATION 115 5.6 SOLUBILISATION 118 5.6.1 POLAR SOLUBILISATES 119 5.6.2
EFFECT OF TEMPERATURE AND ELECTROLYTE ADDITION 120 5.7 APPLICATIONS OF
MICELLAR SOLUTIONS 120 5.7.1 DETERGENCY 120 5.7.2 APPLICATION OF
CYLINDRICAL MICELLES 122 5.7.3 SOLUBILISATION 123 5.7.4
MICELLAR-ENHANCED ULTRAFILTRATION 123 5.7.5 MICELLAR CATALYSIS 123
REFERENCES 126 6 MIXED-MICELLE FORMATION 130 6.1 QUALITATIVE
OBSERVATIONS 130 6.2 THERMODYNAMICS OF MIXED-MICELLE FORMATION 131 6.2.1
SURFACE TENSIONS OF SURFACTANT SOLUTIONS 133 6.3 THERMODYNAMICS OF
NON-IDEAL MIXED-MICELLE FORMATION 134 6.3.1 MIXTURES WHERE ONE COMPONENT
DOES NOT FORM MICELLES 135 6.3.2 NON-IDEALITY IN THE INTERFACE 137 6.4
SOME MAJOR FINDINGS*SURFACTANT SYNERGISMS 138 6.5 FURTHER EXAMPLES OF
MIXED-MICELLE FORMATION 143 6.6 POSITIVE DEVIATIONS FROM
IDEALITY*MIXTURES OF PERFLUORO AND HYDROCARBON 144 SURFACTANTS
REFERENCES 146 7 GENERAL PHASE BEHAVIOUR OF SURFACTANTS 147 7.1 GENERAL
FEATURES OF SURFACTANT PHASE BEHAVIOUR 147 7.2 THE KRAFFT BOUNDARY 148
7.2.1 DESIGN OF SURFACTANTS FOR USE IN HARD WATER 149 7.2.2 PRODUCTS
MAKING USE OF KRAFFT BOUNDARY EFFECTS 152 7.2.3 DEPENDENCE OF KRAFFT
TEMPERATURE ON SURFACTANT STRUCTURE 153 7.3 THE CLOUD POINT 154 7.3.1
MECHANISM OF PHASE SEPARATION 155 7.3.2 NATURE OF THE SEPARATED PHASES
156 7.3.3 PRACTICAL IMPORTANCE OF CLOUD POINT PHENOMENA 157 7.4
MESOMORPHIC PHASES 158 7.4.1 QUANTITATIVE PHASE DIAGRAM CUTS 159 7.4.2
QUANTITATIVE PHASE CUTS* DIFFUSIVE INTERFACIAL TRANSPORT 160 7.4.3
GENERAL DISPOSITION OF MESOMORPHIC PHASES 160 7.4.4 HEXAGONAL PHASES H T
AND H 2 162 7.4.5 LAMELLAR PHASE L* 164 7.4.6 CUBIC PHASES 165 7.4.7
FLUCTUATIONS CLOSE TO PHASE BOUNDARIES 166 7.4.8 PHYSICAL STATE OF
MOLECULES IN LIQUID-CRYSTAL PHASES 166 7.4.9 THE SURFACTANT MOLECULES
167 7.4.10 THE STATE OF WATER MOLECULES 168 7.4.11 OTHER LYOTROPIC
LIQUID-CRYSTALLINE PHASES 169 7.4.12 APPLICATIONS OF SURFACTANT PHASE
INFORMATION 170 REFERENCES 171 CONTENTS DISPERSIONS OF SURFACTANT
AGGREGATES 173 8.1 INTRODUCTION 173 8.2 VESICLES AND LIPOSOMES 173 8.2.1
BIOLOGICAL MEMBRANES 175 8.2.2 SYNTHETIC MEMBRANE-FORMING SURFACTANTS
176 8.2.3 PREPARATION OF LIPOSOMES AND VESICLES 176 8.2.4 STABILITY OF
VESICLES AND LIPOSOMES 177 8.2.5 PROPERTIES OF LIPOSOMES 178 8.3
APPLICATIONS OF LIPOSOMES 180 8.3.1 DRUG CARRIERS 180 8.3.2 REACTION
MICROENVIRONMENTS 181 8.3.3 FREEZE-DRIED LIPOSOMES 182 8.3.4 FABRIC AND
HAIR CONDITIONERS 182 8.3.5 STABILITY OF LIPOSOME DISPERSIONS 185 8.4
DISPERSIONS OF CRYSTALS 186 8.4.1 SURFACTANT GELS 187 8.4.2 USE IN
DETERGENT PRODUCTS 188 8.4.3 HARD-SURFACE CLEANERS 189 REFERENCES 190
ADSORPTION ON SOLIDS 192 9.1 INTRODUCTION 192 9.1.1 EXPERIMENTAL
DETERMINATION OF AMOUNT ADSORBED 194 9.1.2 ADSORPTION ISOTHERMS 196
9.1.3 THERMODYNAMICS OF ADSORPTION ONTO SOLIDS 199 9.2 ADSORPTION AT
VERY LOW CONCENTRATION 200 9.3 LATERAL INTERACTIONS BETWEEN ADSORBED
SURFACTANT MOLECULES 202 9.3.1 NATURE OF THE ADSORBED LAYER 203 9.3.2
ADSORPTION AT HIGHER CONCENTRATIONS 204 9.4 EFFECT OF SURFACTANT
STRUCTURE ON ADSORPTION 204 9.4.1 NON-IONIC SURFACTANTS ON HYDROPHOBIC
SURFACES 204 9.4.2 NON-IONIC SURFACTANTS ON HYDROPHILIC SURFACES 206
9.4.3 ZWITTERIONIC SURFACTANTS ON HYDROPHILIC SURFACES 207 9.4.4 IONIC
SURFACTANTS ON HYDROPHOBIC SURFACES 209 9.4.5 IONIC SURFACTANTS ON
HYDROPHILIC SURFACES 210 9.5 STABILISATION OF DISPERSIONS 211 9.5.1
FORCES BETWEEN PARTICLES 211 9.5.2 COMBINED DISPERSION AND ELECTROSTATIC
FORCES 214 9.5.3 COMBINED DISPERSION AND STERIC FORCES 215 9.6 OTHER
APPLICATIONS 216 9.6.1 FROTH FLOTATION 216 9.6.2 DETERGENCY 217 9.6.3
CORROSION INHIBITION 217 9.6.4 WATER PURIFICATION 218 9.6.5 ADMICELLAR
CHROMATOGRAPHY 218 9.6.6 ENHANCED OIL RECOVERY 220 REFERENCES 220
MICROEMULSIONS 222 10.1 DEFINITION OF MICROEMULSIONS 222 10.2 USE OF
CO-SURFACTANTS 225 10.3 INTERFACIAL TENSION IN MICROEMULSIONS 227 10.4
PROPERTIES OF MICROEMULSIONS 230 CONTENTS XI 10.4.1 CHARACTERISATION OF
MICROEMULSIONS 231 10.4.2 SIMPLE GEOMETRIC CONSIDERATIONS 231 10.4.3
ELECTRON MICROSCOPIC OBSERVATIONS 232 10.4.4 SCATTERING TECHNIQUES 234
10.4.5 SELF-DIFFUSION MEASUREMENTS 238 10.5 APPLICATIONS OF
MICROEMULSIONS 239 10.5.1 MICROEMULSIONS AS PRODUCTS 239 10.5.2
MICROEMULSIONS AS PHYSICAL PROCESS AIDS 241 10.5.3 MICROEMULSIONS AS
CHEMICAL REACTION MEDIA 241 10.5.4 SURFACTANT-ENHANCED OIL RECOVERY 244
REFERENCES 247 11 SURFACTANT BIIAYERS, FOAMS AND EMULSIONS 250 11.1
INTRODUCTION 250 11.2 SOAPFILMS 252 11.2.1 FILMDRAINAGE 252 11.2.2
FACTORS AFFECTING DRAINAGE RATE 253 11.2.3 STRUCTURE OF DRAINED FILMS
256 11.3 MEASUREMENT OF FILM THICKNESS 258 11.3.1 FACTORS AFFECTING FILM
THICKNESS 260 11.3.2 THIN-FILM TENSIONS 262 11.3.3 FILM STABILITY 263
11.4 FOAMS AND FOAM STABILITY 264 11.4.1 BULK VISCOSITY 265 11.4.2
SURFACE VISCOSITY 266 11.4.3 ANTIFOAMS 266 11.4.4 NON-AQUEOUS FOAMS 267
11.5 LIPID BIIAYERS 267 11.5.1 PERMEABILITY OF BILAYER LIPID MEMBRANES
268 11.6 FORMATION AND STABILITY OF EMULSIONS 269 11.6.1 COALESCENCE 271
11.6.2 EMULSION TYPE 271 11.6.3 MIXED EMULSIFIERS 272 11.6.4 HIGH
INTERNAL PHASE RATIO (HIPR) EMULSIONS 274 11.6.5 DEMULSIFICATION 275
REFERENCES 276 INDEX 279
|
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| id | DE-604.BV006089907 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:40:07Z |
| institution | BVB |
| isbn | 0216929059 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-003845789 |
| oclc_num | 246923510 |
| open_access_boolean | |
| owner | DE-703 DE-188 |
| owner_facet | DE-703 DE-188 |
| physical | XI, 283 S. Ill., graph. Darst. |
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| publisher | Blackie |
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| spelling | Clint, John H. Verfasser aut Surfactant aggregation John H. Clint 1. publ. Glasgow [u.a.] Blackie 1992 XI, 283 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Grenzflächenaktiver Stoff (DE-588)4158138-6 s DE-604 Oberflächenchemie (DE-588)4126166-5 s GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003845789&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Clint, John H. Surfactant aggregation Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| subject_GND | (DE-588)4158138-6 (DE-588)4126166-5 |
| title | Surfactant aggregation |
| title_auth | Surfactant aggregation |
| title_exact_search | Surfactant aggregation |
| title_full | Surfactant aggregation John H. Clint |
| title_fullStr | Surfactant aggregation John H. Clint |
| title_full_unstemmed | Surfactant aggregation John H. Clint |
| title_short | Surfactant aggregation |
| title_sort | surfactant aggregation |
| topic | Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| topic_facet | Aggregation (Chemistry) Surface active agents Grenzflächenaktiver Stoff Oberflächenchemie |
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