NMR techniques and applications in geochemistry and soil chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Oxford u. a.
Pergamon Pr.
1987
|
| Ausgabe: | 1. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XI, 353 S. graph. Darst. |
| ISBN: | 0080348521 |
Internformat
MARC
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Datensatz im Suchindex
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| adam_text | Titel: NMR techniques and applications in geochemistry and soil chemistry
Autor: Wilson, Michael A.
Jahr: 1987
Contents
Page
1. Elementary n.m.r. theory applicable to geochemistry ?
1. Basic Concepts 1
2. The Rotating Frame 4
3. The Bloch Equations and Concept of Pulse Angle 6
4. Spin-Spin and Spin Lattice Relaxation and Frequency and Time Domain 10
Spectra
5. Chemical Shift 15
2. Elementary n.m.r. practice applicable to geochemistry 23
1. Introduction 23
2. The Magnet 25
3. The Sample and Probe 28
4. Setting Spectral Width, Acquisition Time and Number of Data Points 31
5. Choice of Pulse Angle 33
6. Receiver and Transmitter 34
7. Computer and Resolution Enhancement 34
3. Solution n.m.r. 38
1. Introduction 38
2. The Decoupler 38
3. Measurement of Relaxation Times 40
4. Relaxation Mechanisms 46
5. Nuclear Overhauser Effects 48
6. Subspectra—GASPE and Related Techniques 50
7. Polarisation Transfer in Solution—INEPT and DEPT 54
8. Two-dimensional n.m.r. 56
4. Solid State n.m.r. 62
1. Introduction 62
2. Removal of Dipolar Interactions 64
3. Removal of Chemical Shift Anisotropy 68
4. Relaxation in the Rotating Frame and Cross-polarisation 70
5. Pulse Programmes in Solid State Experiments 73
6. Quantification in Experiments on Geochemical Samples 75
7. Dipolar Dephasing 77
8. 13C Rotating Frame Spin Lattice Relaxation 82
9. l3C Spin Lattice Relaxation 83
10. I3C Spin-Spin Relaxation 84
11. Proton Spin Lattice Relaxation through Carbon 84
12. Flip-Back 85
13. Spin Diffusion 85
14. Sideband Analysis 86
15. Isotropie Chemical Shifts in the Solid State 87
¡x
; CONTENTS
5. Minerals and their structure 95
1. Introduction g-?
2 N.M.R. of Quadrupolar Nuclei ?6
3. Si N.M.R. 9°
4. Silicates °0
5. Aqueous Systems—Silicon lu
6. Aqueous Systems—Aluminium 11
7. Poorly Ordered Aluminosilicates 13
8. Glasses ^
9. Ordered Systems 16
9.1 Anisotropy 11 °
9.2 Loewenstein s Rule and Cordierite 121
9.3 1:1 Type Phyllosilicates 128
9.4 2:1 Type Phyllosilicates I29
9.5 Pillared Clays 132
6. Precursors to organic matter in the geosphere 139
1. Introduction 139
2. Lignins 140
3. Polysaccharides 150
4. Proteins 156
5. Lipids 157
6. Whole Detritus 157
7. Whole soil n.m.r. 161
1. Introduction 161
2. Soil Organic Matter 161
3. Soil Phosphorus 175
4. Soil Nitrogen 176
5. Soil Silicon 177
6. Soil Aluminium 178
8. Humic substances 182
1. Introduction 182
2. ¹ N.M.R. Studies in Solution 182
3. 13C N.M.R. Studies in Solution 186
4. C N.M.R. Studies in the Solid State 199
5. Structural Variation among Humic Extracts from Different Sources 203
9. Oil shale 217
1. Precursors 217
2. Aromaticity 221
3. Inorganic Resonances 224
4. Broad Line ¹ Measurements 224
5. Mechanism of Shale Pyrolysis 228
6. Structure of Oil and Changes in Composition with Pyrolysis Conditions 232
CONTENTS xi
10. Peat 237
1. Structure 237
2. Relaxation Data 243
11. Coal 248
1. Introduction 248
2. Brown Coal (Lignite) Components 250
3. Carbon Aromaticity of Whole Coals 252
4. Structural Features of I3C Spectra of Whole Coals 260
5. Macerais of More Mature Coals 263
6. Proton Aromaticity 265
7. Quantification in Cross-polarisation Experiments 266
8. Molecular Motion in Coal 270
9. Inorganic Phases in Coal 272
12. Coal derivatives 278
1. Introduction 278
2. Reactions of Coal in Nature 278
3. Functional Group Analysis by Solution ? N.M.R. 280
4. Functional Group Analysis by Solution 13C N.M.R. 284
5. Derivatisation 289
13. Coal conversion 295
1. Introduction 295
2. Recent Proton Studies 296
3. Aromaticity Balances during Pyrolysis 308
4. Coal Hydrogénation 311
5. Fate of Aromatic Carbon 313
6. Fate of Alkyl Groups 319
7. Hydrogen Transfer Studies using 2H N.M.R. 324
8. Structure of Donor Vehicles and Oils by N.M.R. 329
9. Intermediates - Asphaltenes and Preasphaltenes 329
Reviews on N.M.R. in Geoscience 335
Credits for Figures 337
List of Symbols 341
Index 346
|
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| discipline | Geologie / Paläontologie Geographie |
| edition | 1. ed. |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T16:39:15Z |
| institution | BVB |
| isbn | 0080348521 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-003807770 |
| oclc_num | 15521228 |
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| owner | DE-703 |
| owner_facet | DE-703 |
| physical | XI, 353 S. graph. Darst. |
| publishDate | 1987 |
| publishDateSearch | 1987 |
| publishDateSort | 1987 |
| publisher | Pergamon Pr. |
| record_format | marc |
| spelling | Wilson, Michael A. Verfasser aut NMR techniques and applications in geochemistry and soil chemistry 1. ed. Oxford u. a. Pergamon Pr. 1987 XI, 353 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Analytical geochemistry Energy minerals Analysis Nuclear magnetic resonance Soil chemistry NMR-Spektroskopie (DE-588)4075421-2 gnd rswk-swf Geochemie (DE-588)4020198-3 gnd rswk-swf Bodenchemie (DE-588)4146134-4 gnd rswk-swf Bodenchemie (DE-588)4146134-4 s NMR-Spektroskopie (DE-588)4075421-2 s DE-604 Geochemie (DE-588)4020198-3 s HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003807770&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wilson, Michael A. NMR techniques and applications in geochemistry and soil chemistry Analytical geochemistry Energy minerals Analysis Nuclear magnetic resonance Soil chemistry NMR-Spektroskopie (DE-588)4075421-2 gnd Geochemie (DE-588)4020198-3 gnd Bodenchemie (DE-588)4146134-4 gnd |
| subject_GND | (DE-588)4075421-2 (DE-588)4020198-3 (DE-588)4146134-4 |
| title | NMR techniques and applications in geochemistry and soil chemistry |
| title_auth | NMR techniques and applications in geochemistry and soil chemistry |
| title_exact_search | NMR techniques and applications in geochemistry and soil chemistry |
| title_full | NMR techniques and applications in geochemistry and soil chemistry |
| title_fullStr | NMR techniques and applications in geochemistry and soil chemistry |
| title_full_unstemmed | NMR techniques and applications in geochemistry and soil chemistry |
| title_short | NMR techniques and applications in geochemistry and soil chemistry |
| title_sort | nmr techniques and applications in geochemistry and soil chemistry |
| topic | Analytical geochemistry Energy minerals Analysis Nuclear magnetic resonance Soil chemistry NMR-Spektroskopie (DE-588)4075421-2 gnd Geochemie (DE-588)4020198-3 gnd Bodenchemie (DE-588)4146134-4 gnd |
| topic_facet | Analytical geochemistry Energy minerals Analysis Nuclear magnetic resonance Soil chemistry NMR-Spektroskopie Geochemie Bodenchemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003807770&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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