Modelling phase equilibria: thermodynamic backgrounds and practical tools
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New York u.a.
Wiley
1992
|
| Edition: | 1. print. |
| Series: | Wiley series in chemical engineering
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIV, 311 S. graph. Darst. |
| ISBN: | 0471571032 |
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Record in the Search Index
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| adam_text | MODELLING PHASE EQUILIBRIA THERMODYNAMIC BACKGROUND AND PRACTICAL TOOLS
STANISLAW MALANOWSKI ANDRZEJ ANDERKO INSTITUTE OF PHYSICAL CHEMISTRY
POLISH ACADEMY OF SCIENCES WARSZAWA, POLAND §) JOHN WILEY & SONS, INC.
NEW YORK * CHICHESTER * BRISBANE * TORONTO * SINGAPORE CONTENTS PREFACE
XI 1. THERMODYNAMIC PRINCIPLES 1 1.1. INTRODUCTION 1 1.2. FUNDAMENTALS
OF PHENOMENOLOGICAL THERMODYNAMICS 1 1.2.1. INTRODUCTION 1 1.2.2.
THEOREMS OF THERMODYNAMICS 3 1.2.3. TRADITIONAL REPRESENTATION OF THE
LAWS OF THERMODYNAMICS 5 1.2.4. INTRODUCTION OF THE GIBBS FUNDAMENTAL
EQUATION 7 1.2.5. PROPERTIES OF THE GIBBS FUNDAMENTAL EQUATION 13 1.2.6.
THERMODYNAMIC POTENTIALS 16 1.2.7. THE GIBBS-HELMHOLTZ EQUATION 23
1.2.8. THE GIBBS-DUHEM EQUATION 25 1.2.9. THE PHASE RULE. CONDITIONS OF
PHASE EQUILIBRIA 27 1.2.10. COMPUTATION OF RELATIONS BETWEEN
THERMODYNAMIC FUNCTIONS 35 1.2.11. EQUATIONS OF STATE AND PARTIAL MOLAR
PROPERTIES 45 1.2.12. PROPERTIES OF MIXTURES 50 1.3. OUTLINE OF SOME
USEFUL THEORETICAL CONCEPTS 58 REFERENCES 64 VII VUEI CONTENTS 2.
PURE-COMPONENT PROPERTIES RELEVANT TO PHASE EQUILIBRIUM CALCULATIONS 67
2.1. COEXISTENCE OF TWO PHASES AND VAPOR PRESSURE OF A PURE COMPONENT 67
2.2. VAPOR VOLUME 79 2.3. LIQUID VOLUME 88 REFERENCES 89 3. THE
GAMMA-PHI METHOD 93 3.1. THERMODYNAMIC FRAMEWORK OF VAPOR-LIQUID,
LIQUID-LIQUID AND SOLID-LIQUID EQUILIBRIA 93 3.2. MODELLING THE VAPOR
PHASE OF A MULTICOMPONENT MIXTURE 99 3.3. MODELLING THE LIQUID PHASE OF
A MULTICOMPONENT MIXTURE 101 3.3.1. INTRODUCTION 101 3.3.2. POLYNOMIAL
EQUATIONS 103 3.3.3. LOCAL COMPOSITION MODELS 105 3.3.4. THE SUM OF
SYMMETRIE FUNCTIONS EQUATION 111 3.3.5. COMPARISON OF ACTIVITY
COEFFICIENT MODELS 113 3.3.6. EXPLICIT TREATMENT OF ASSOCIATION IN
ACTIVITY COEFFICIENT MODELS 117 3.4. ESTIMATION OF LIQUID PHASE EXCESS
FUNCTIONS 127 3.4.1. INTRODUCTION 127 3.4.2. THE REGULAER SOLUTION MODEL
129 3.4.3. APPLICATION OF INFINITE-DILUTION ACTIVITY COEFFICIENTS 133
3.4.4. GROUP CONTRIBUTION METHODS 136 REFERENCES 146 4.
EQUATION-OF-STATE METHODS 153 4.1. INTRODUCTION 153 4.2. PURE-COMPONENT
EQUATIONS OF STATE 157 4.2.1. VAN DER WAALS-TYPE EQUATIONS OF STATE 157
4.2.2. VIRIAL-TYPE EQUATIONS OF STATE 178 4.2.3. EQUATIONS OF STATE IN A
CORRESPONDING-STATES FORMAT 181 4.2.4. NONCLASSICAL CORRECTIONS IN THE
NEAR-CRITICAL REGION 186 4.3. MIXTURES 187 4.3.1. CLASSICAL QUADRATIC
MIXING RULES AND OTHER MIXING RULES OF NONPOLAR MIXTURES 187 CONTENTS IX
4.3.2. MIXING RULES FOR EOS IN THE CORRESPONDING-STATES FORMAT 193
4.3.3. MIXING RULES FOR EXCESS GIBBS ENERGY MODELS 198 4.3.4. SIMPLE
COMPOSITION-DEPENDENT COMBINING RULES 203 4.3.5. DENSITY-DEPENDENT
MIXING RULES 209 4.3.6. IMPROVED CLASSICAL MIXING RULES FOR STRONGLY
NONIDEAL MIXTURES 221 4.3.7. EXPLICIT TREATMENT OF ASSOCIATION AND
POLARITY 223 4.4. CLOSING REMARKS 243 REFERENCES 247 5. THERMODYNAMIC
CONSISTENCY 259 5.1. INTRODUCTION 259 5.2. CONSISTENCY WITH RESPECT TO
THE GIBBS-DUHEM EQUATION 260 5.2.1. TESTS BASED ON INTEGRAL FORMS OF THE
GIBBS- DUHEM EQUATION 261 5.2.2. TESTING CONSISTENCY BY DATA REDUCTION
265 5.3. CONSISTENCY WITH RESPECT TO THE GIBBS-HELMHOLTZ EQUATION 275
5.4. CONCLUDING REMARKS 277 REFERENCES 279 APPENDIX A. DEFINITIONS OF
SOME IMPORTANT THERMODYNAMIC CONCEPTS 283 APPENDIX B. BASIC MATHEMATICAL
DEFINITIONS AND THEOREMS 285 B.L. SOME FEATURES OF VECTOR SPACES 285
B.2. ELEMENTS OF DIFFERENTIAL AND INTEGRAL CALCULUS 287 B.3.
TRANSFORMATIONS OF COORDINATE SYSTEMS 292 B.4. SOME PROPERTIES OF
FUNCTIONS 297 REFERENCE 299 LIST OF SYMBOLS 301 INDEX 307
|
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| id | DE-604.BV005618058 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:32:19Z |
| institution | BVB |
| isbn | 0471571032 |
| language | English |
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| owner_facet | DE-12 DE-91G DE-BY-TUM DE-703 DE-634 DE-83 |
| physical | XIV, 311 S. graph. Darst. |
| publishDate | 1992 |
| publishDateSearch | 1992 |
| publishDateSort | 1992 |
| publisher | Wiley |
| record_format | marc |
| series2 | Wiley series in chemical engineering |
| spelling | Malanowski, Stanisław Verfasser aut Modelling phase equilibria thermodynamic backgrounds and practical tools Stanisław Malanowski ; Andrzej Anderko 1. print. New York u.a. Wiley 1992 XIV, 311 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Wiley series in chemical engineering Thermodynamik (DE-588)4059827-5 gnd rswk-swf Phasengleichgewicht (DE-588)4132145-5 gnd rswk-swf Phasengleichgewicht (DE-588)4132145-5 s Thermodynamik (DE-588)4059827-5 s DE-604 Anderko, Andrzej Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003515980&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Malanowski, Stanisław Anderko, Andrzej Modelling phase equilibria thermodynamic backgrounds and practical tools Thermodynamik (DE-588)4059827-5 gnd Phasengleichgewicht (DE-588)4132145-5 gnd |
| subject_GND | (DE-588)4059827-5 (DE-588)4132145-5 |
| title | Modelling phase equilibria thermodynamic backgrounds and practical tools |
| title_auth | Modelling phase equilibria thermodynamic backgrounds and practical tools |
| title_exact_search | Modelling phase equilibria thermodynamic backgrounds and practical tools |
| title_full | Modelling phase equilibria thermodynamic backgrounds and practical tools Stanisław Malanowski ; Andrzej Anderko |
| title_fullStr | Modelling phase equilibria thermodynamic backgrounds and practical tools Stanisław Malanowski ; Andrzej Anderko |
| title_full_unstemmed | Modelling phase equilibria thermodynamic backgrounds and practical tools Stanisław Malanowski ; Andrzej Anderko |
| title_short | Modelling phase equilibria |
| title_sort | modelling phase equilibria thermodynamic backgrounds and practical tools |
| title_sub | thermodynamic backgrounds and practical tools |
| topic | Thermodynamik (DE-588)4059827-5 gnd Phasengleichgewicht (DE-588)4132145-5 gnd |
| topic_facet | Thermodynamik Phasengleichgewicht |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003515980&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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