Contribution of clusters physics to materials science and technology: from isolated clusters to aggregated materials
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Dordrecht u.a.
Nijhoff
1986
|
| Series: | NATO: [Advanced science institutes series / E]
104 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 646 S. Ill., graph. Darst. |
| ISBN: | 9024732794 |
Staff View
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Record in the Search Index
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| adam_text | IMAGE 1
CONTRIBUTION OF CLUSTERS
PHYSICS TO MATERIALS SCIENCE AND TECHNOLOGY FROM ISOLATED CLUSTERS TO
AGGREGATED MATERIALS
EDITED BY
J. DAVENAS
DEPARTEMENT DE PHYSIQUE DES MATERIAUX UNIVERSITE CLAUDE BERNARD LYON I
43 BD DU 11 NOVERNBRE 1918 69622 VILLEURBANNE CEDEX FRANCE
P.M. RABETTE LABORATOIRE DE CHIMIE DES SOLIDES
UNIVERSITE PIERRE ET MARIE CURIE
4 PLACE JUSSIEU 75230 PARIS CEDEX 05 FRANCE
UNIVERSITATSBIBLIOTHEK HANNOVER TECHNISCHE INFORMATIONSBIBLIOTHEK
1986 MARTINUS NIJHOFF PUBLISHERS DORDRECHT / BOSTON / LANCASTER
PUBLISHED IN COOPERATION WITH NATO SCIENTIFIC AFFAIRS DIVISION
IMAGE 2
CONTENTS
PROPERTIES OF CLUSTERS IN THE GAS PHASE, L. WOSTE 1
1. INTRODUCTION
]
2. CLUSTER PRODUCTION 2
3. MASS SPECTROMETRIC DETECTION 9
4. EXPERIMENTS ON CLUSTERS IN THE GAS PHASE 20
5. LASER SPECTROSCOPY OF FREE CLUSTERS 24
6. FUTURE DEVELOPMENTS 46
METAL CLUSTER BEAMS AND ELECTRON DIFFRACTION: DEVIATIONS FROM THE BULK
STATES OF MATTER, G.D. STEIN 51
1. INTRODUCTION 52
2. THE CLUSTER NUCLEATION PROCESS 53
3. CLUSTER BEAMS 60
4. CLUSTER ELECTRON DIFFRACTION 69
5. METAL CLUSTER RESULTS 72
GENERATION OF BEAMS OF REFRACTORY METAL CLUSTERS, S. WEXLER, S.J. RILEY,
E.K. PARKS, C.R. MAO, L.G POBO 85
AN INTRODUCTION TO THE FIELD OF CATALYSIS BY MOLECULAR
CLUSTERS, J.M. BASSET 91
1. AN INTRODUCTION TO MOLECULAR CLUSTERS 92
1.1 DEFINITION 92
1.2 BONDING IN MOLECULAR CLUSTERS 106
1.3 DYNAMIC BEHAVIOUR OF MOLECULAR CLUSTERS 111
IMAGE 3
1.4 REACTIVITY OF MOLECULAR CLUSTERS 115
1.5 MOLECULAR CLUSTERS AS STRUCTURAL MODELS OF INTER
MEDIATES OR CHEMISORBED SPECIES IN SURFACE SCIENCE 120
2. CATALYSIS BY MOLECULAR CLUSTERS 125
2.1 THE RELATIONSHIP BETWEEN MOLECULAR CLUSTERS AND
SMALL METAL PARTICLES 125
2.2 HOMOGENEOUS CLUSTER CATALYZED REACTIONS 127
2.3 CATALYSIS BY SUPPORTED MOLECULAR CLUSTERS 130
2.4 SUPPORTED CLUSTERS AND HETEROGENEOUS CATALYSIS:
SURFACE ORGANOMETALLIC CHEMISTRY 133
QUANTUM CHEMISTRY FOR METAL CLUSTERS, D.R. SALAHUB 143
1. GENERALITIES - CLUSTER SCIENCE 144
2. QUANTUM CHEMICAL METHODS 145
3. COMPARISONS OF HARTREE-FOCK WITH X (LSD) RESULTS 167
4. ELECTRONIC AND MAGNETIC STRUCTURE OF TRANSITION
METAL CLUSTERS 180
5. CONCLUDING REMARKS - NEED FOR EXPERIMENTS ON ISOLATED
CLUSTERS 188
ELECTRONIC STRUCTURE OF METAL CLUSTERS, R.C. BAETZOLD 195
1. INTRODUCTION 195
2. RESULTS 196
2.1 GENERAL CONSIDERATIONS 196
2.2 COMPUTATIONAL APPROACHES 199
2.3 GEOMETRY 202
2.4 CHARGE SEPARATION 204
2.5 ODD-EVEN EFFECTS 206
2.6 IONIZATION POTENTIAL 207
2.7 DENSITY OF STATES 208
2.8 SUBSTRATE EFFECTS 208
3. EXPERIMENTAL RESULTS 208
IMAGE 4
CHARACTERIZATION OF SUPPORTED METAL PARTICLES IN HETEROGENEOUS
CATALYSTS:
I. STUDIES OF HIGH SURFACE AREA MATERIALS,
J.A. DUMESIC, G. CONNELL 215
1. INTRODUCTION 215
2. STRATEGIES FOR CHARACTERIZATION OF METAL PARTICLES ON ON HIGH SURFACE
AREA SUPPORTS 217
3. X-RAY DIFFRACTION AND SCATTERING 219
4. EXTENDED X-RAY ABSORPTION FINE STRUCTURE 224
5. MOSSBAUER SPECTROSCOPY 230
6. MAGNETIC SUSCEPTIBILITY 236
7. FERROMAGNETIC RESONANCE 242
8. VIBRATIONAL SPECTROSCOPY 246
CHARACTERIZATION OF SUPPORTED METAL PARTICLES IN HETEROGENEOUS
CATALYSTS:
II.STUDIES OF LOW SURFACE AREA, MODEL MATERIALS, G.B. RAUPP, T.J.
UDOVIC, J.A. DUMESIC 255
1. INTRODUCTION 255
2. STRATEGIES FOR CHARACTERIZATION OF METAL PARTICLES ON
LOW SURFACE AREA, MODEL SUPPORTS 256
3. EXPERIMENTAL TECHNIQUES 258
4. APPLICATIONS OF STUDIES USING MODEL SUPPORTED METAL
SAMPLES 268
5. CONCLUDING REMARKS 291
PECULIAR ASPECTS OF HETEROGENEOUS NUCLEATION AND GROWTH PROCESSES
RELATED TO METAL SUPPORTED CATALYST, A. MASSON 295
1. INTRODUCTION 295
2. KEVNOTES FOR HETEROGENEOUS NUCLEATION 297
3. MASS TRANSFER MECHANISMS 298
4. EPITAXY POST NUCLEATION PHENOMENON 305
5. MISCELLANEOUS 308
IMAGE 5
FORMATION, ACTION, AND PROPERTIES OF CLUSTERS IN THE PHOTOGRAPHIC
PROCESS, E. MOISAR 311
1. INTRODUCTION 31)
2. BASIC PRINCIPLES OF THE PHOTOGRAPHIC PROCESS 311
2.1 GENERAL DESCRIPTION 311
2.2 CRYSTALLOGRAPHY OF THE SILVER HALIDES 314
2.3 THE PHOTOGRAPHIC PROCESS 316
2.4 DEVELOPMENT 320
3. THEORY OF THE PHOTOGRAPHIC PROCESS 322
3.1 EXPERIMENTAL FRAME OF THE THEORIES 322
3.2 ATOMISTIC THEORIES OF THE PHOTOGRAPHIC PROCESS 325
3.3 THE PHOTOGRAPHIC PROCESS AS AN EVENT OF PHASE
FORMATION 327
4. OUTLOOK 339
FORMATION OF CLUSTERS IN BULK MATERIALS, A.E. HUGHES 343 1. INTRODUCTION
343
2. METAL-EXCESS ALKALI HALIDES 344
3. EXPERIMENTAL METHODS FOR THE STUDY OF COLLOIDS 346
4. NUCLEATION OF COLLOIDS FROM F CENTRES 352
5. GROWTH OF COLLOIDS 353
6. PARTICLE COARSENING 357
7. FORMATION OF CLUSTERS BY IRRADIATION 362
8. SUMMARY 367
OPTICAL PROPERTIES OF SMALL PARTICLES IN INSULATING MATRICES, U. KREIBIG
373
1. INTRODUCTION 373
2. OPTICAL MATERIAL PROPERTIES OF SMALL PARTICLES 376
2.1 MATERIAL FUNCTIONS OF THE BULK LIKE MATTER 377
2.2 MATERIAL FUNCTIONS OF SMALL PARTICLES 379
2.3 MATERIAL FUNCTIONS OF SOLID-STATE-CLUSTERS 384
IMAGE 6
3. OPTICAL EXTINCTION AND DISPERSION OF ONE PARTICLE 387 3.1
QUASI-STATIC CASE (ELLIPSOIDAL PARTICLES) 387
3.2 GENERAL CASE (SPHERICAL PARTICLES) 390
3.3 PHYSICS BEHIND THE RESONANCES 398
3.4 VOLUME PLASMONS IN SPHERICAL METAL PARTICLES 400 3.5 OPTICAL
PROPERTIES OF PARTICLES OF VARIOUS SHAPES 400 3.6 SUMMARY OF OPTICAL
SINGLE PARTICLE POLARIZABILITIES 403
4. OPTICAL PROPERTIES OF SYSTEMS OF MANY PARTICLES 404
4.1 SIZE DISTRIBUTION 405
4.2 SHAPE AND ORIENTATION DISTRIBUTION 406
4.3 MULTIPLE EXTINCTION EFFECTS 407
4.4 INTERACTION AMONG PARTICLES 408
4.5 SUMMARY 421
INTRODUCTION TO PERCOLATION THEORY, R. BLANC 425
1. TWO EXAMPLES 426
2. FORMAL DEFINITION-SITE PERCOLATION - BOND PERCOLATION 436 3.
DEFINITION AND BEHAVIOUR OF THE CHARACTERISTIC QUANTITIES 438 4.
THERMODYNAMIC ANALOGY 441
5. SCALING LAWS 446
6. EXACT RESULTS 449
7. APPROXIMATE RESULTS 454
8. THE EXPONENT OF THE CONDUCTIVITY 465
9. PERCOLATION AND MACROSCOPIC RANDOM MEDIA 474
ELECTRONIC AND TRANSPORT PROPERTIES OF GRANULAR MATERIALS 1. EFFECTIVE
MEDIUM THEORIES OF TRANSPORT IN INHOMOGENEOUS
MATERIALS, MORREL H. COHEN 479
1. INTRODUCTION 480
2. EFFECTIVE MEDIUM THEORY FOR RANDOM RESISTOR NETWORKS 481
3. THE MULTIPLE SCATTERING FORMALISM 486
4. THE HIERARCHY OF EFFECTIVE MEDIUM APPROXIMATIONS 492
5. EMA FOR CONTINUOUS RANDOM SYSTEMS 495
6. EFFECTS OF SPATIAL CORRELATION 495
IMAGE 7
7. EMA FOR OTHER PHYSICAL PROPERTIES 496
II. SPECIFIC INHOMOGENEOUS MATERIALS, MORREL H. COHEN 501
1. INTRODUCTION 502
2. MACROSCOPICALLY INHOMOGENEOUS MATERIALS 502
3. MICROSCOPICALLY INHOMOGENEOUS MATERIALS 503
4. LOCAL ELECTRONIC PROPERTIES 508
5. THE INHOMOGENEOUS METAL-NONMETAL TRANSITION 512
6. POROUS MEDIA 515
III.THE ORIGINS OF CLUSTERING, MORREL H. COHEN 519
1. INTRODUCTION 520
2. DENSITY FLUCTUATIONS IN EXPANDED LIQUID HG 520
3. CONCENTRATION FLUCTUATIONS IN METAL-AMMONIA SOLUTIONS 529
4. VALENCE FLUCTUATIONS IN TE, SE AND SETE ALLOYS 531
5. DENSITY FLUCTUATIONS AS CLUSTERING IN GLASSES 533
OPTICAL PROPERTIES AND SOLAR SELECTIVITY OF METAL-INSULATOR
COMPOSITES, G.A. NIKLASSON, C.G. GRANQVIST 539
1. INTRODUCTION 539
2. EFFECTIVE MEDIUM THEORIES 541
3. BOUNDS ON THE EFFECTIVE DIELECTRIC PERMEABILITY 557
4. SIZE LIMITS FOR VALIDITY OF EFFECTIVE MEDIUM THEORIES 563
5. CASE STUDY ONE: OPTICAL PROPERTIES AND SOLAR SELECTIVITY
OF COEVAPORATED CO-AL*0. FILMS 569
6. CASE STUDY TWO: ELECTROLYTICALLY COLOURED ANODIC A1*0.
COATINGS 579
7. SUMMARY AND REMARKS 586
ADHESION AND SINTERING OF SMALL PARTICLES, A.R. THOLEN 601 1.
INTRODUCTION 601
2. PRODUCTION OF PARTICLES 602
3. GENERAL OBSERVATIONS 603
IMAGE 8
4. DYNAMICS ASPECTS OF CONTACT 609
5. OTHER ASPECTS OF ADHESION 610
6. SINTERING OF SMALL PARTICLES 611
7. CONCLUSION 613
PHYSICS ON THE BEACH OR THE THEORY OF WINDSURFING, A.R. THBLEN 617
SUBJECT INDEX 619
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| spelling | Contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials ed. by J. Davenas ... Dordrecht u.a. Nijhoff 1986 646 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier NATO: [Advanced science institutes series / E] 104 Materials Congresses Particles Congresses Cluster (DE-588)4010318-3 gnd rswk-swf (DE-588)1071861417 Konferenzschrift 1982 Cap d'Agde gnd-content Cluster (DE-588)4010318-3 s DE-604 Davenas, J. Sonstige oth E] NATO: [Advanced science institutes series 104 (DE-604)BV000007015 104 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=003467382&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials Materials Congresses Particles Congresses Cluster (DE-588)4010318-3 gnd |
| subject_GND | (DE-588)4010318-3 (DE-588)1071861417 |
| title | Contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials |
| title_auth | Contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials |
| title_exact_search | Contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials |
| title_full | Contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials ed. by J. Davenas ... |
| title_fullStr | Contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials ed. by J. Davenas ... |
| title_full_unstemmed | Contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials ed. by J. Davenas ... |
| title_short | Contribution of clusters physics to materials science and technology |
| title_sort | contribution of clusters physics to materials science and technology from isolated clusters to aggregated materials |
| title_sub | from isolated clusters to aggregated materials |
| topic | Materials Congresses Particles Congresses Cluster (DE-588)4010318-3 gnd |
| topic_facet | Materials Congresses Particles Congresses Cluster Konferenzschrift 1982 Cap d'Agde |
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