Unified equilibrium calculations:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | Undetermined |
| Published: |
New York u.a.
Wiley
1991
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| Series: | A Wiley-interscience publication
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XV, 313 S. graph. Darst. |
| ISBN: | 047153854X |
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Record in the Search Index
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| adam_text | UNIFIED EQUILIBRIUM CALCULATIONS WILLIAM BENTON GUENTHER THE UNIVERSITY
OF THE SOUTH, SEWANEE, TENNESSEE A WILEY-INTERSCIENCE PUBLICATION JOHN
WILEY & SONS, INC. NEW YORK * CHICHESTER . BRISBANE * TORONTO *
SINGAPORE CONTENTS PREFACE IX I DEFINITIONS AND GENERAL CONCEPTS 1 1-1.
SYMBOLS AND BASIC RELATIONS, 1 1-2. THE NET ACID-BASE FUNCTION, C AB , 6
1-3. PROGRAMMING FUNCTIONS, 7 1-4. EXPLICATION OF K A AND ACTIVITIES:
SPREADSHEETS, 9 1-5. A NOTE ON SYMBOLS, PLOTS, AND EXERCISES, 14 1-6.
LIST OF SYMBOLS, 15 SUMMARY, 16 II MONOPROTIC ACID-BASES, 19 II-1.
DEFINITIONS AND EXPLANATIONS OF TERMS, 19 II-2. INTRODUCTORY DIAGRAMS
FOR ACID-BASE RELATIONS, 21 II-3. GENERAL RELATIONS: A AND CHARLOT
EQUATIONS, 28 II-4. RATIO OF CONJUGATES, 32 II-5. TREATMENT OF VARIOUS
MONOPROTIC SYSTEMS, 33 II-6. MIXTURES OF SYSTEMS, 40 II-7. WEAK-STRONG
MIXTURES, 46 II-8. DILUTION OF WEAK ACIDS, 49 II-9. CONJUGATE BASE
SOLUTIONS AND COMPLETE CUBIC EQUATIONS, 52 V CONTENTS 11-10. APPROXIMATE
PH CALCULATIONS: GETTING ESTIMATES OF PH REGION TO USE IN RIGOROUS
CALCULATIONS, 56 SUMMARY, 57 EXERCISES, 57 REFERENCES, 58 POLYPROTIC
ACID-BASE EQUILIBRIUM III-L. H RELATIONS, 59 III-2. POLYPROTIC DIAGRAMS
AND BALANCES, 64 III-3. SUMMARY OF METHODS, 68 III-4. FEATURES AND USES
OF A-PH DIAGRAMS, 69 III-5. REVIEW OF APPROXIMATE PH CALCULATIONS
ESTIMATING THE PH, 71 III-6. CHOICE OF STARTING CONCENTRATION TERMS:
EQUIVALENT SOLUTIONS, 72 III-7. NUMERICAL SOLUTIONS TO PH PROBLEMS, 75
III-8. THE COMPLETE N FUNCTION: FURTHER EXAMPLES OF N, N
INTERSECTIONS, 83 III-9. CORRECT AMPHOLYTE RELATIONS USING THE COMPLETE
APPROACH, 86 111-10. MIXED SYSTEMS, 89 III-L 1. CONCENTRATION DEPENDENCE
OF PH IN POLYPROTIC SYSTEMS, 93 111-12. FURTHER EXAMPLE CALCULATIONS, 96
SUMMARY, 101 EXERCISES, 102 REFERENCES, 105 BUFFERS, ACID-BASE
TITRATIONS, LABORATORY STRATEGIES AND K A DETERMINATIONS IV-1. TITRATION
EQUATIONS, 107 IV-2. EFFECT OF PK SPACING AND CONCENTRATIONS, 110 IV-3.
WEAK ACID-WEAK BASE MIXTURES, 111 IV-4. STATISTICAL EFFECTS IN
TITRATIONS, 118 IV-5. SLOPE, BUFFER CAPACITY, AND METHODS FOR
DETERMINATION OF EQUIVALENCE POINT BY LINEAR FUNCTIONS (GRAN PLOTS), 119
IV-6. PRACTICAL ASPECTS: IONIC STRENGTH CONTROL, 128 IV-7. K A
DETERMINATIONS, 130 IV-8. FURTHER BUFFER TOPICS, 134 SUMMARY, 139
CONTENTS VUE EXERCISES, 139 REFERENCES, 140 V METAL-LIGAND EQUILIBRIA 141
INTRODUCTION, 141 V-L. FUNDAMENTAL RELATIONS, 142 V-2. TYPICAL SYSTEMS:
MONODENTATE LIGANDS, 144 V-3. INTERACTION OF PROTON AND ML EQUILIBRIA,
149 V-4. EXPERIMENTAL DETERMINATION OF N AND THE FORMATION CONSTANTS,
154 V-5. BJERRUM S METHOD, 156 V-6. SLOPES OF II CURVES, 157 V-7. F 0 OR
A 0 METHODS, 162 V-8. PROTONATED LIGAND, POLYNUCLEAR, AND MIXED
COMPLEXING, 167 V-9. HYDROXIDE COMPLEXES AND POLYNUCLEAR CASES, 170
V-10. THE MIXED SYSTEM: CU(II)-NH 3 -OH, 180 SUMMARY, 186 EXERCISES, 186
REFERENCES, 187 VI SOLUBILITY 189 VI-1. DEFINITIONS AND SIMPLE CASES,
189 VI-2. EXPERIMENTAL DETERMINATION OF K S0 , 192 VI-3. IONIC AND
MOLECULAR SOLUBILITY, 196 VI-4. SOLUBILITY WITH MULTIPLE COMPLEXING:
COMPLEXING WITH ADDED COMMON ION, 200 VI-5. GENERAL SOLUBILITY DIAGRAMS,
204 VI-6. SOLUBILITIES OF MX WITH ADDED LIGAND L THAT IS NOT THE COMMON
ION, X, 208 VI-7. SOLUBILITY WITH PROTON REACTIONS, 211 VI-8.
POLYNUCLEAR HYDROXIDE SOLUBILITIES, 226 SUMMARY, 229 EXERCISES, 230
REFERENCES, 231 APPENDIX A ASPECTS OF SOLUTION CHEMISTRY 233 APPENDIX B
MATHEMATICAL TACTICS 243 APPENDIX C EXPERIMENTAL AIDS AND PREPARATIONS
265 VIII CONTENTS APPENDIX D TABLES OF VALUES OF EQUILIBRIUM FUNCTIONS
283 KEY POINTS - 301 ANNOTATED BIBLIOGRAPHY 307 INDEX 311
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| id | DE-604.BV004705599 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T16:16:24Z |
| institution | BVB |
| isbn | 047153854X |
| language | Undetermined |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-002891193 |
| oclc_num | 246844817 |
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| owner_facet | DE-12 DE-355 DE-BY-UBR DE-188 |
| physical | XV, 313 S. graph. Darst. |
| publishDate | 1991 |
| publishDateSearch | 1991 |
| publishDateSort | 1991 |
| publisher | Wiley |
| record_format | marc |
| series2 | A Wiley-interscience publication |
| spelling | Guenther, William B. Verfasser aut Unified equilibrium calculations William Benton Guenther New York u.a. Wiley 1991 XV, 313 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier A Wiley-interscience publication Chemisches Gleichgewicht (DE-588)4147642-6 gnd rswk-swf Berechnung (DE-588)4120997-7 gnd rswk-swf Chemisches Gleichgewicht (DE-588)4147642-6 s DE-604 Berechnung (DE-588)4120997-7 s GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002891193&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Guenther, William B. Unified equilibrium calculations Chemisches Gleichgewicht (DE-588)4147642-6 gnd Berechnung (DE-588)4120997-7 gnd |
| subject_GND | (DE-588)4147642-6 (DE-588)4120997-7 |
| title | Unified equilibrium calculations |
| title_auth | Unified equilibrium calculations |
| title_exact_search | Unified equilibrium calculations |
| title_full | Unified equilibrium calculations William Benton Guenther |
| title_fullStr | Unified equilibrium calculations William Benton Guenther |
| title_full_unstemmed | Unified equilibrium calculations William Benton Guenther |
| title_short | Unified equilibrium calculations |
| title_sort | unified equilibrium calculations |
| topic | Chemisches Gleichgewicht (DE-588)4147642-6 gnd Berechnung (DE-588)4120997-7 gnd |
| topic_facet | Chemisches Gleichgewicht Berechnung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002891193&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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