Crystal chemistry of high T c superconducting copper oxides:
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Berlin u.a.
Springer
1991
|
| Series: | Springer series in materials science
15 |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | X, 331 S. Ill., graph. Darst. |
| ISBN: | 3540515453 0387515453 |
Staff View
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Record in the Search Index
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*. RAVEAU *. MICHEL *. HERVIEU D. GROULT CRYSTAL CHEMISTRY OF HIGH-T C
SUPERCONDUCTING COPPER OXIDES WITH 320 FIGURES SPRINGER-VERLAG BERLIN
HEIDELBERG NEW YORK LONDON PARIS TOKYO HONG KONG BARCELONA BUDAPEST
CONTENTS 1. INTRODUCTION: SUPERCONDUCTIVITY IN OXIDES BEFORE 1986 1 2.
PHASES OF THE SYSTEMS A-LA-CA-CU-O AND A-Y-CA-CU-O (A = CA, SR, BA):
STRUCTURAL ASPECTS 7 2.1 COPPER CHEMISTRY IN OXIDES: OXIDATION STATES
AND COORDINATION 7 2.2 THE TERNARY SYSTEMS LA-CU-O AND A-CU-O (A =
CA,SR,BA) . 11 2.3 THE PSEUDOTERNARY SYSTEMS A-LA-CU-O (A = CA,SR,BA)
. 16 2.3.1 PHASES WITH OXYGEN-DEFICIENT PEROVSKITE STRUCTURES . 17
A) BALA 4 CU 5 0 13+{ 17 B) LA 8 . X SR X CU 8 O 20 . 20 C) LA 3 BA 3 CU
6 0 14 AND LABA 2 CU 3 0 7 _,5 21 2.3.2 THE INTERGROWTHS BETWEEN
PEROVSKITE AND ROCK-SALT-TYPE STRUCTURES 22 A) THE OXIDES LA 2 _ X A X
CU0 4 _ X / 2+A 22 B) THE OXIDES LA 2 _ X A 1+X CU 2 0 6 _ X/2+(S 28 C )
LA 4 . 2X BA 2+2X CU 2 . X O 10 . 2X 31 2.4 THE PSEUDOTERNARY SYSTEM
Y-BA-CU-O 32 2.4.1 THE ORTHORHOMBIC 92 * SUPERCONDUCTOR YBA 2 CU 3 0 7
_J . 32 2.4.2 THE TETRAGONAL PHASES YBA 2 CU 3 0 7 . 6 34 2.4.3 PROBLEMS
OF MICROTWINNING IN THE ORTHORHOMBIC YBA 2 CU 3 0 7 _ 5 43 2.4.4 THE
"GREEN PHASE" Y 2 BACU0 5 47 2.4.5 OTHER PHASES OF THE SYSTEM Y-BA-CU-O
48 2.5 THE SYSTEMS LN-SR-CU-0 (LN * LA) 48 3. ELECTRON TRANSPORT
PROPERTIES CONNECTED WITH OXYGEN NONSTOICHIOMETRY 52 3.1 ELECTRON
TRANSPORT PROPERTIES IN CUPRATES RELATED TO THE PEROVSKITE: GENERAL
CONSIDERATIONS 52 3.2 OXIDES WITH THE K 2 NIF 4 -TYPE STRUCTURE 55 3.2.1
LA 2 CU0 4 55 A) "NORMAL" PROPERTIES 55 B) SUPERCONDUCTING PROPERTIES 57
3.2.2 THE OXIDES LA 2 . X A X CU0 4 _ X/2+5 (A = BA,CA,SR) 58 A)
ELECTRON TRANSPORT PROPERTIES ABOVE 77 * 59 B) SUPERCONDUCTING
PROPERTIES 64 VII 3.2.3 SUBSTITUTIONS FOR LANTHANUM IN THE
SUPERCONDUCTING OXIDE LA 18 SR 02 CUO 4 _ Y 67 A) RARE-EARTH
SUBSTITUTIONS 67 B) BISMUTH SUBSTITUTION 68 3.2.4 OTHER CUPRATES WITH
THE K 2 NIF 4 STRUCTURE 70 3.3 OXIDES WITH THE OXYGEN-DEFICIENT SR 3 TI
2 0 7 -TYPE STRUCTURE . 71 3.3.1 THE OXIDES LA 2 _ X A 1+X CU 2 0 6 _ X
/ 2+5 (A = SR,CA) 71 3.3.2 THE OXIDES LN 2 _ X SR 1+X CU 2 0 6 _ X / 2
73 A) LN = PR, ND; X = 0.14 74 B) LN = EU, SM, GD; X = 0.9 74 3.4 OXIDES
WITH THE OXYGEN-DEFICIENT PEROVSKITE STRUCTURE 74 3.4.1
NONSUPERCONDUCTING OXIDES 74 A) LACUO S 74 B) BALA 4 CU 5 0 13+TF AND LA
8 _ X SR X CU 8 O 20 _ E 75 C) BA 3 LA 3 CU 6 0 14+5 77 3.4.2
SUPERCONDUCTING OXIDES: PROPERTIES OF YBA 2 CU 3 0 7 . (5 . . 80 A) THE
"STOICHIOMETRIC" OXIDE 80 B) INFLUENCE OF THE OXYGEN NONSTOICHIOMETRY 82
C) SUBSTITUTION FOR YTTRIUM AND BARIUM 86 4. SUBSTITUTIONS IN LA 2 CU0 4
-TYPE AND YBA 2 CU 3 0 7 -TYPE SUPERCONDUCTORS 91 4.1 SUBSTITUTION ON
THE RARE-EARTH SITES 91 4.1.1 LA 2 CU0 4 -TYPE OXIDES 91 4.1.2 YBA 2 CU
3 0 7 -TYPE OXIDES 93 4.2 SUBSTITUTION ON THE COPPER SITES 94 4.2.1 LA 2
CU0 4 -TYPE OXIDES 96 4.2.2 YBA 2 CU 3 0 7 -TYPE OXIDES 98 A) NICKEL
SUBSTITUTION 98 B) IRON SUBSTITUTION 101 C) OTHER TRANSITION ELEMENT
SUBSTITUTIONS 109 D) OTHER SUBSTITUTIONS 110 4.3 SUBSTITUTIONS ON OTHER
SITES 112 4.3.1 SUBSTITUTION FOR BARIUM 112 4.3.2 FLUORINATION OF YBA 2
CU 3 0 7 .^ 112 5. BISMUTH, THALLIUM AND LEAD SUPERCONDUCTING CUPRATES
. 113 5.1 BISMUTH ALKALINE-EARTH SUPERCONDUCTING CUPRATES 113 5.2
THALLIUM ALKALINE-EARTH SUPERCONDUCTING CUPRATES 123 5.3 LEAD
ALKALINE-EARTH SUPERCONDUCTING CUPRATES 140 5.4 LAYERED CUPRATES
INVOLVING DOUBLE FLUORITE-**** LAYERS . . 145 5.5 STRUCTURAL
RELATIONSHIPS 150 6. EXTENDED DEFECTS IN SUPERCONDUCTING OXIDES:
HIGH-RESOLUTION ELECTRON MICROSCOPY 155 6.1 YBA 2 CU 3 0 7 -TYPE
SUPERCONDUCTORS: ORDERING IN THE PEROVSKITE FRAMEWORK 156 VIII 6.1.1 YBA
2 CU 3 0 7 _ 6 156 A) HREM IMAGES 156 B) 92 * ORTHORHOMBIC
SUPERCONDUCTOR (0 6 0.1) . 159 C) ORDER-DISORDER PHENOMENA: THE 60 *
SUPERCONDUCTOR YBA 2 CU 3 0 7 ^ (0.37 5 0.45) . 174 D)
NONSUPERCONDUCTING TETRAGONAL PHASES YBA 2 CU S 0 7 _G 184 E) ORDERING
OF OXYGEN VACANCIES: CONCLUDING REMARKS 188 6.1.2 LA 3 . X BA 3+X CU 6 0
14+Y PHASES 189 A) LABA 2 CU 3 0 7 _ 5 189 B) LA 3 BA 3 CU 6 0 14+Y 192
6.2 NATURE AND ORDERING OF THE STACKED LAYERS: INTERGROWTH MECHANISMS
198 6.2.1 STRUCTURAL CONSIDERATIONS FOR HREM STUDIES 198 6.2.2 THE
BISMUTH FAMILY 201 6.2.3 THALLIUM FAMILIES: THE CLASSICAL DEFECTS 207 A)
PEROVSKITE LAYERS 207 B) ROCK-SALT-TYPE LAYERS 211 6.2.4 THE
NONSUPERCONDUCTING TLBA 2 NDCU 2 0 7 : A NEW MECHANISM 215 A) CLASSICAL
DEFFECTS 218 B) VARIATIONS IN THE FLUORITE-**** LAYERS 219 6.2.5 LEAD
OXIDES 222 6.2.6 THE RARE EARTH OXIDES 227 6.3 LAYER INTERCONNECTIONS
232 6.4 EXTRA SPOTS IN ED PATTERNS: AN AMAZING VARIETY 239 6.4.1
SUBSTITUTED BISMUTH OXIDES 240 6.4.2 THALLIUM OXIDES 247 6.4.3 LEAD
OXIDES 249 6.5 DOMAINS AND BOUNDARIES 256 7. IRRADIATION EFFECTS IN THE
HIGH-T C SUPERCONDUCTING OXIDES . 263 7.1 RADIATION DAMAGE IN SOLIDS 264
7.1.1 ELECTRONIC AND NUCLEAR STOPPING POWERS 264 7.1.2 MATERIAL
MODIFICATIONS 266 A) ELECTRONIC ENERGY LOSS EFFECTS 267 B) NUCLEAR
ENERGY LOSS EFFECTS 267 7.2 RADIATION DAMAGE BY ELECTRONS AND FAST
NEUTRONS IN COPPER OXIDE SUPERCONDUCTORS 269 7.2.1 DEFECT STRUCTURES
PRODUCED BY ELECTRON IRRADIATION . . . 269 7.2.2 CHANGES INDUCED BY FAST
NEUTRON IRRADIATION 273 7.3 PHASE TRANSFORMATIONS INDUCED BY FAST HEAVY
IONS IN THE HIGH-T C COPPER OXIDES 277 7.3.1 IMPROVEMENT OF T C IN THE
GRAIN SURFACE SUPERCONDUCTOR LA 2 CU0 4 278 IX 7.3.2 HEAVY-ION-INDUCED
CHANGES OF SUPERCONDUCTING AND NORMAL PROPERTIES OF POLYCRYSTALLINE
CERAMICS YBA 2 CU 3 0 7 _ 5 AND BI 2 SR 2 CACU 2 0 8 281 7.3.3 ION
IMPLANTATION EFFECTS IN THIN FILMS OF COPPER OXIDE SUPERCONDUCTORS 290
7.4 CONCLUSIONS 294 8. CONCLUDING REMARKS 296 8.1 LOW DIMENSIONALITY OF
THE STRUCTURE 296 8.2 MIXED VALENCE OF COPPER AND HOLE DELOCALIZATION
296 8.3 THE MODEL OF COPPER DISPROPORTIONATION 297 8.4 ROLE OF THE LONE
PAIR CATIONS AND OF THE ALKALINE EARTH ELEMENTS 300 REFERENCES 303
SUBJECT INDEX 327 X |
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| id | DE-604.BV004373458 |
| illustrated | Illustrated |
| indexdate | 2024-09-05T00:08:44Z |
| institution | BVB |
| isbn | 3540515453 0387515453 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-002714557 |
| oclc_num | 246790963 |
| open_access_boolean | |
| owner | DE-384 DE-12 DE-91 DE-BY-TUM DE-355 DE-BY-UBR DE-29T DE-83 DE-188 DE-11 |
| owner_facet | DE-384 DE-12 DE-91 DE-BY-TUM DE-355 DE-BY-UBR DE-29T DE-83 DE-188 DE-11 |
| physical | X, 331 S. Ill., graph. Darst. |
| publishDate | 1991 |
| publishDateSearch | 1991 |
| publishDateSort | 1991 |
| publisher | Springer |
| record_format | marc |
| series | Springer series in materials science |
| series2 | Springer series in materials science |
| spelling | Crystal chemistry of high T c superconducting copper oxides B. Raveau ... Berlin u.a. Springer 1991 X, 331 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in materials science 15 Cuprate (DE-588)4148399-6 gnd rswk-swf Hochtemperatursupraleitung (DE-588)4200190-0 gnd rswk-swf Kupferoxide (DE-588)4166141-2 gnd rswk-swf Hochtemperatursupraleiter (DE-588)4220922-5 gnd rswk-swf Züricher Oxide (DE-588)4222260-6 gnd rswk-swf Kristallchemie (DE-588)4165759-7 gnd rswk-swf Züricher Oxide (DE-588)4222260-6 s Kristallchemie (DE-588)4165759-7 s DE-604 Hochtemperatursupraleiter (DE-588)4220922-5 s Kupferoxide (DE-588)4166141-2 s Cuprate (DE-588)4148399-6 s Hochtemperatursupraleitung (DE-588)4200190-0 s DE-188 Raveau, Bernard Sonstige oth Springer series in materials science 15 (DE-604)BV000683335 15 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002714557&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Crystal chemistry of high T c superconducting copper oxides Springer series in materials science Cuprate (DE-588)4148399-6 gnd Hochtemperatursupraleitung (DE-588)4200190-0 gnd Kupferoxide (DE-588)4166141-2 gnd Hochtemperatursupraleiter (DE-588)4220922-5 gnd Züricher Oxide (DE-588)4222260-6 gnd Kristallchemie (DE-588)4165759-7 gnd |
| subject_GND | (DE-588)4148399-6 (DE-588)4200190-0 (DE-588)4166141-2 (DE-588)4220922-5 (DE-588)4222260-6 (DE-588)4165759-7 |
| title | Crystal chemistry of high T c superconducting copper oxides |
| title_auth | Crystal chemistry of high T c superconducting copper oxides |
| title_exact_search | Crystal chemistry of high T c superconducting copper oxides |
| title_full | Crystal chemistry of high T c superconducting copper oxides B. Raveau ... |
| title_fullStr | Crystal chemistry of high T c superconducting copper oxides B. Raveau ... |
| title_full_unstemmed | Crystal chemistry of high T c superconducting copper oxides B. Raveau ... |
| title_short | Crystal chemistry of high T c superconducting copper oxides |
| title_sort | crystal chemistry of high t c superconducting copper oxides |
| topic | Cuprate (DE-588)4148399-6 gnd Hochtemperatursupraleitung (DE-588)4200190-0 gnd Kupferoxide (DE-588)4166141-2 gnd Hochtemperatursupraleiter (DE-588)4220922-5 gnd Züricher Oxide (DE-588)4222260-6 gnd Kristallchemie (DE-588)4165759-7 gnd |
| topic_facet | Cuprate Hochtemperatursupraleitung Kupferoxide Hochtemperatursupraleiter Züricher Oxide Kristallchemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002714557&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000683335 |
| work_keys_str_mv | AT raveaubernard crystalchemistryofhightcsuperconductingcopperoxides |