Inorganic reactions and methods: 3 The formation of bonds to halogens ; Pt. 1
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| Format: | Buch |
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| Sprache: | English |
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Weinheim [u.a.]
VCH Verlagsges.
1989
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| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XXXII, 710 S. |
| ISBN: | 089573253X 352726261X |
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| 245 | 1 | 0 | |a Inorganic reactions and methods |n 3 |p The formation of bonds to halogens ; Pt. 1 |c ed. J. J. Zuckerman |
| 264 | 1 | |a Weinheim [u.a.] |b VCH Verlagsges. |c 1989 | |
| 300 | |a XXXII, 710 S. | ||
| 336 | |b txt |2 rdacontent | ||
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| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Halogene |0 (DE-588)4158874-5 |2 gnd |9 rswk-swf |
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| 700 | 1 | |a Zuckerman, Jerry J. |e Sonstige |4 oth | |
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| adam_text | INORGANIC REACTIONS AND METHODS VOLUME 3 THE FORMATION OF BONDS TO
HALOGENS (PART 1) FOUNDING EDITOR J.J. ZUCKERMAN EDITOR A.P. HAGEN
CONTENTS OF VOLUME 3 HOW TO USE THIS BOOK XIX PREFACE TO THE SERIES XXV
EDITORIAL CONSULTANTS TO THE SERIES XXIX CONTRIBUTORS TO VOLUME 3 XXXI
2. FORMATION OF BONDS TO HALOGENS (PART 1) 1 2.1. INTRODUCTION 2 2.2.
FORMATION OF HALOGEN-HALOGEN BONDS 3 2.2.1. INTRODUCTION 3 2.2.2.
PREPARATION OF THE ELEMENTAL HALOGENS 3 2.2.2.1. BY ANODIC OXIDATION 3
2.2.2.1.1. OF FLUORIDE ION. 3 2.2.2.1.2. OF CHLORIDE ION. 6 2.2.2.1.3.
OF BROMIDE ION. 10 2.2.2.1.4. OF LODIDE ION. 12 2.2.2.2. BY CHEMICAL
OXIDATION 12 2.2.2.2.1. OF FLUORIDE. 13 2.2.2.2.2. OF CHLORIDE. 14
2.2.2.2.3. OF BROMIDE. 16 2.2.2.2.4. OF LODIDE. 17 2.2.2.3. BY
REDUCTION. 19 2.2.2.4. BY DISSOCIATION OF HALIDES. 20 2.2.2.5.
DIASTATINE SYNTHESIS. 21 2.2.3. PREPARATION OF CATIONIC POLYHALOGENS
(HOMONUCLEAR AND HETERONUCLEAR) 22 2.2.3.1. BY HALIDE-ANION TRANSFER IN
ACID-BASE REACTIONS. 22 2.2.3.2. BY OXIDATION OF ELEMENTAL HALOGENS OR
INTERHALOGENS. 24 2.2.4. PREPARATION OF NEUTRAL INTERHALOGENS 26 VI
CONTENTS OF VOLUME 3 2.2. FORMATION OF HALOGEN-HALOGEN BONDS 2.2.4.1.
FROM THE ELEMENTS. 27 2.2.4.1.1. BY FLUORINATION OF CL 2 , BR 2 AND L 2
. 27 2.2.4.1.2. BY CHLORINATION OF BR 2 AND L 2 . 29 2.2.4.1.3. BY
BROMINATION OF L 2 . 29 2.2.4.2. FROM THE OXIDATION OF ANIONIC HALIDES.
29 2.2.4.3. FROM THE OXIDATION OF ORGANOIODIDES 30 2.2.4.3.1. BYF 2 ORCI
2 . 30 2.2.4.3.2. BY OXIDIZING FLUORINATING AGENTS (EXCLUDING F 2 ). 31
2.2.4.4. 2.2.5. 2.2.5.1. 2.2.5.2. 2.2.5.3. 2.2.5.4. 2.2.5.5. 2.2.6.
2.2.6.1. 2.2.6.2. 2.2.6.3. 2.2.7. 2.2.7.1. 2.2.7.2. 2.2.7.3. 2.2.7.4.
2.2.7.5. 2.2.7.6. 2.2.7.7. PREPARATION OF NEUTRAL AND CATIONIC
INTERHALOGEN COMPOUNDS CONTAINING ASTATINE PREPARATION OF ARYLIODO
FLUORIDES FROM ARYLIODO OXIDES FROM ARYLIODOSO AND ARYLIODO COMPOUNDS
AND HF. FROM ARYLIODO COMPOUNDS AND SF 4 . BY ELECTROCHEMICAL
FLUORINATION OF ARYLIODO COMPOUNDS. FROM ARYLIODO COMPOUNDS AND XEF 2 .
FROM ARYLIODO COMPOUNDS AND F 2 . PREPARATION OF ANIONIC POLYHALIDES
(HOMONUCLEAR AND HETERONUCLEAR) FROM ELEMENTAL HALOGENS WITH HALIDE
ANION. FROM INTERHALOGEN COMPOUNDS WITH HALIDE ANION. PREPARATION OF
ANIONIC POLYHALIDES CONTAINING ASTATINE. PREPARATION OF HALOGEN
OXYFLUORIDES FROM HALOGEN OXIDES WITH F 2 . FROM HALOGEN OXIDES WITH
FLUORINATING AGENTS OTHER THAN F 2 . FROM HALOGEN OXYFLUORIDES WITH
FLUORINATING AGENTS. BY DISPROPORTIONATION OF HALOGEN OXYFLUORIDES. FROM
POSITIVE HALOGEN COMPOUNDS WITH FLUORINATING AGENTS. FROM HALOGEN
OXYACIDS AND THEIR SALTS WITH FLUORINATING AGENTS. BY ELIMINATION. 31 32
32 33 33 33 34 34 35 36 38 39 39 40 42 43 44 45 48 CONTENTS OF VOLUME 3
VII 2.3. FORMATION OF BONDS BETWEEN HALOGENS AND GROUP-VB (O, S, SE, TE,
PO) ELEMENTS 50 2.3.1. INTRODUCTION 50 2.3.2. FROM THE ELEMENTS 50
2.3.2.1. FROM HALOGENATION BY ELEMENTAL HALOGENS 50 2.3.2.1.1. TO GIVE
THE OXYGEN-HALOGEN BOND. 50 2.3.2.1.2. TO GIVE THE SULFUR-HALOGEN BOND.
51 2.3.2.1.3. TO GIVE THE SE-HALOGEN BOND. 56 2.3.2.1.4. TO GIVE THE
TE-HALOGEN BOND. 58 2.3.2.1.5. TO GIVE THE PO-HALOGEN BOND. 60 2.3.2.2.
FROM HALOGENATION BY HYDROGEN HALIDES. 61 2.3.2.3. FROM HALOGENATION BY
OXIDIZING HALIDES 62 2.3.2.3.1. TO GIVE THE OXYGEN-HALOGEN BOND. 62
2.3.2.3.2. TO GIVE THE SULFUR-HALOGEN BOND. 62 2.3.2.3.3. TO GIVE THE
SE-HALOGEN BOND. 65 2.3.2.3.4. TO GIVE THE TE-HALOGEN BOND. 67 2.3.2.4.
FROM HALOGENATION BY ORGANIC HALIDES. 68 2.3.2.5. FROM OXIDATION OF
ELEMENTAL HALOGENS BY OZONE. 69 2.3.3. FROM CLEAVAGE OF THE GROUP VIB-
HYDROGEN BOND (EXCLUDING POLONIUM) 70 2.3.3.1. BY HALOGENS 70 2.3.3.2.
BY OXIDIZING HALIDES. 72 2.3.4. FROM CLEAVAGE OF THE GROUP VIB-CARBON
BOND 74 2.3.4.1. BY HALOGENS. 74 2.3.4.2. BY OXIDIZING HALIDES OR
ELECTROCHEMICAL FLUORINATION. 75 2.3.5. FROM CLEAVAGE OF THE GROUP
VIB-GROUP IVB ELEMENT BOND 75 2.3.5.1. BY HALOGENS. 75 2.3.5.2. BY
OXIDIZING HALIDES. 76 2.3.6. FROM CLEAVAGE OF THE GROUP VIB-OXYGEN BOND
77 2.3.6.1. BY HALOGENS. 77 2.3.6.1.1. TO GIVE THE SULFUR-HALOGEN BOND.
77 2.3.6.1.2. TO GIVE THE SE-HALOGEN BOND. 78 2.3.6.1.3. TO GIVE THE
TE-HALOGEN BOND. 79 2.3.6.2. BY HYDROGEN HALIDES 79 VIII CONTENTS OF
VOLUME 3 2.3. FORMATION OF BONDS BETWEEN HALOGENS AND GROUP-VB (O, S,
SE, TE, PO) ELEMENTS 2.3.6.2.1. TO GIVE THE SULFUR-HALOGEN BOND. 79
2.3.6.2.2. TO GIVE THE SI-HALOGEN BOND. 80 2.3.6.2.3. TO GIVE THE
TE-HALOGEN BOND. 82 2.3.6.2.4. TO GIVE THE PO-HALOGEN BOND. 84 2.3.6.3.
BY ORGANIC HALIDES 85 2.3.6.3.1. TO GIVE THE SULFUR-HALOGEN BOND. 85
2.3.6.3.2. TO GIVE THE SE-HALOGEN BOND. 87 2.3.6.3.3. TO GIVE THE TE-
AND PO-HALOGEN BOND. 87 2.3.6.4. BY METAL HALIDES 87 2.3.6.4.1. TO GIVE
THE SULFUR-HALOGEN BOND. 87 2.3.6.4.2. TO GIVE THE SE-HALOGEN BOND. 89
2.3.6.4.3. TO GIVE THE TE-HALOGEN BOND. 90 2.3.6.5. BY NONMETAL HALIDES
90 2.3.6.5.1. TO GIVE THE SULFUR-HALOGEN BOND. 90 2.3.6.5.2. TO GIVE THE
SE-HALOGEN BOND. 96 2.3.6.5.3. TO GIVE THE TE-HALOGEN AND PO-HALOGEN
BOND. 99 2.3.7. BY HALOGENATION OF GROUP-VIB OXIDES AND OXOANIONS 101
2.3.7.1. WITH ELEMENTAL HALOGENS 101 2.3.7.1.1. TO GIVE THE
SULFUR-HALOGEN BOND. 101 2.3.7.1.2. TO GIVE THE SE-, TE-, PO-HALOGEN
BOND. 104 2.3.7.2. WITH HALOGEN HALIDES 105 2.3.7.2.1. TO GIVE THE
SULFUR-HALOGEN BOND. 105 2.3.7.2.2. TO GIVE THE SE-, TE-, PO-HALOGEN
BOND. 106 2.3.7.3. WITH NONMETAL HALIDES 107 2.3.7.3.1. TO GIVE THE
SULFUR-HALOGEN BOND. 107 2.3.7.3.2. TO GIVE THE SE- AND TE-HALOGEN
BONDS. 112 2.3.7.4. WITH METAL HALIDES 114 2.3.7.4.1. TO GIVE THE
SULFUR-HALOGEN BOND. 114 2.3.7.4.2. TO GIVE SE- AND TE-HALOGEN BOND. 116
2.3.8. FROM CLEAVAGE OF THE GROUP-VIB-GROUP VIB ELEMENT BOND 118
2.3.8.1. BY ELEMENTAL HALOGENS 118 2.3.8.1.1. TO GIVE THE OXYGEN-HALOGEN
BOND. 118 2.3.8.1.2. TO GIVE THE SULFUR-HALOGEN BOND. 119 CONTENTS OF
VOLUME 3 IX 2.3.8.1.3. TO GIVE THE SE- AND TE-HALOGEN BOND. 121 2.3.8.2.
BY HYDROGEN HALIDES. 122 2.3.8.3. FROM CLEAVAGE OF THE GROUP VIB-ELEMENT
BOND BY OTHER HALIDES 122 2.3.8.3.1. TO GIVE THE OXYGEN-HALOGEN BOND.
122 2.3.8.3.2. TO GIVE THE SULFUR-HALOGEN BOND. 123 2.3.8.3.3. TO GIVE
THE SE-HALOGEN BOND. 124 2.3.8.3.4. TO GIVE THE TE-HALOGEN BOND. 125
2.3.9. FROM CLEAVAGE OF THE GROUP VIB-NITROGEN BOND 126 2.3.9.1. BY
HALOGENS 126 2.3.9.2. BY HYDROGEN HALIDES. 130 2.3.9.3. BY OTHER
HALIDES. 132 2.3.10. FROM CLEAVAGE OF THE GROUP VIB-GROUP VB BONDS 135
2.3.10.1. BY HALOGENS. 135 2.3.10.2. BY HYDROGEN HALIDES 136 2.3.10.3.
BY OTHER HALIDES 136 2.3.11. FROM FURTHER OXIDATIVE ADDITION OF LOW
OXIDATION STATE GROUP-VIB COMPOUNDS 137 2.3.11.1. WITH ELEMENTAL
HALOGENS 137 2.3.11.1.1. TO GIVE THE SULFUR-HALOGEN BOND. 137
2.3.11.1.2. TO GIVE THE SE-HALOGEN BOND. 146 2.3.11.1.3. TO GIVE THE TE-
AND PO-HALOGEN BOND. 149 2.3.11.2. WITH HYDROGEN HALIDES. 150 2.3.11.3.
WITH NONMETAL HALIDES 150 2.3.11.3.1. TO GIVE THE SULFUR-HALOGEN BOND.
150 2.3.11.3.2. TO GIVE THE SE-HALOGEN BOND. 162 2.3.11.3.3. THE TE- AND
PO-HALOGEN BONDS. 164 2.3.11.4. WITH METAL HALIDES 166 2.3.11.4.1. TO
GIVE THE SULFUR-HALOGEN BOND. 166 2.3.11.4.2. TO GIVE THE SE-, TE-AND
PO-HALOGEN BOND. 168 2.3.11.5. WITH ORGANIC HALIDES. 169 2.3.12. FROM
METATHETICAL REACTIONS (HALOGEN-HALOGEN EXCHANGE) 170 2.3.12.1. BY
HALOGENATION WITH METAL HALIDES 170 2.3.12.1.1. TO GIVE THE
OXYGEN-HALOGEN BOND. 170 2.3.12.1.2. TO GIVE THE SULFUR-HALOGEN BOND.
171 2.3.12.1.3. TO GIVE THE SE-HALOGEN BOND. 177 2.3.12.1.4. TO GIVE THE
TE-HALOGEN BOND. 178 X CONTENTS OF VOLUME 3 2.3.12.2. 2.3.12.2.1,
2.3.12.2.2 2.3.12.2.3. 2.3.12.2.4 2.3.13. 2.3.13.1. 2.3.13.2. 2.3.
FORMATION OF BONDS BETWEEN HALOGENS AND GROUP-VB (O, S, SE, TE, PO)
ELEMENTS BY HALOGENATION WITH NONMETAL HALIDES 179 TO GIVE THE
OXYGEN-HALOGEN BOND. 179 TO GIVE THE SULFUR-HALOGEN BOND. 180 TO GIVE
THE SE-HALOGEN BOND. 189 TO GIVE THE TE-HALOGEN BOND. 190 PREPARATION OF
ASTATINE-GROUP-VIB ELEMENT BONDS 191 PREPARATION OF ASTATINE-OXYGEN
BONDS. 191 OTHER ASTATINE-GROUP-VIB ELEMENT BONDS. 192 2.4. FORMATION OF
BONDS BETWEEN HALOGENS AND GROUP-VB (N, P, AS, SB, BI) ELEMENTS 194
2.4.1. INTRODUCTION 194 2.4.2. FROM THE ELEMENTS 194 2.4.2.1. TO GIVE
GROUP-VB FLUORIDES. 194 2.4.2.2. TO GIVE GROUP-VB CHLORIDES. 194
2.4.2.3. TO GIVE GROUP-VB BROMIDES. 195 2.4.2.4. TO GIVE GROUP-VB
LODIDES. 195 2.4.3. FROM HALOGENATION OF GROUP-VB ELEMENTS 196 2.4.3.1.
BY HYDROGEN FLUORIDE TO GIVE GROUP- VB FLUORIDES. 196 2.4.3.2. BY OTHER
INORGANIC HALIDES TO GIVE GROUP-VB HALIDES 196 2.4.3.2.1. FROM
GROUP-IIIB HALIDES. 196 2.4.3.2.2. FROM GROUP-IVB HALIDES. 197
2.4.3.2.3. FROM GROUP-VB HALIDES. 197 2.4.3.2.4. FROM GROUP-VIB HALIDES.
197 2.4.3.2.5. FROM GROUP-VIIB HALIDES. 197 2.4.3.3. BY ORGANIC HALIDES
TO GIVE GROUP-VB HALIDES 197 2.4.3.3.1. FROM ALKYL HALIDES. 199
2.4.3.3.2. FROM ARYL HALIDES. 199 2.4.4. FROM CLEAVAGE OF THE GROUP-
VB-HYDROGEN BOND 199 2.4.4.1. BY HALOGENS 199 2.4.4.1.1. TO GIVE
GROUP-VB FLUORIDES. 199 CONTENTS OF VOLUME 3 XI 2.4.4.1.2. 2.4.4.1.3.
2.4.4.1.4. 2.4.4.2. 2.4.4.2.1. 2.4.4.2.2. 2.4.4.2.3. 2.4.4.2.4.
2.4.4.2.5. 2.4.4.2.6. 2.4.4.2.7. 2.4.4.2.8. 2.4.5. 2.4.5.1. 2.4.5.1.1.
2.4.5.1.2. 2.4.5.1.3. 2.4.5.1.4. 2.4.5.2. 2.4.5.2.1. 2.4.5.2.2.
2.4.5.2.3. 2.4.5.2.4. 2.4.5.3. 2.4.5.3.1. 2.4.5.3.2. 2.4.5.3.3.
2.4.5.3.4. 2.4.5.3.5. 2.4.5.3.6. 2.4.5.4. 2.4.6. 2.4.6.1. 2.4.6.1.1. TO
GIVE GROUP-VB CHLORIDES. TO GIVE GROUP-VB BROMIDES. TO GIVE GROUP-VB
LODIDES. BY OTHER HALIDES TO GIVE GROUP-VB HALIDES FROM HYPOHALITES. TO
GIVE GROUP-VB HALIDES FROM HYDROGEN HALIDES. TO GIVE GROUP-VB HALIDES
FROM GROUP-IIIB HALIDES. TO GIVE GROUP-VB HALIDES FROM GROUP-IVB
HALIDES. TO GIVE GROUP-VB HALIDES FROM GROUP-VB HALIDES. TO GIVE
GROUP-VB HALIDES FROM GROUP-VIB HALIDES. TO GIVE GROUP-VB HALIDES FROM
GROUP-VIIB HALIDES. TO GIVE GROUP-VB HALIDES FROM TRANSITION-METAL
HALIDES. FROM CLEAVAGE OF THE GROUP VB-CARBON BOND BY HALOGENS TO GIVE
GROUP-VB FLUORIDES. TO GIVE GROUP-VB CHLORIDES. TO GIVE GROUP-VB
BROMIDES. TO GIVE GROUP-VB LODIDES. BY HYDROGEN HALIDES TO GIVE GROUP-VB
FLUORIDES. TO GIVE GROUP-VB CHLORIDES. TO GIVE GROUP-VB BROMIDES. TO
GIVE GROUP-VB LODIDES. BY OTHER INORGANIC HALIDES OF GROUP HIB. OF GROUP
IVB. OF GROUP VB. OF GROUP VIB. OF GROUP VIIB. OF TRANSITION-METAL
HALIDES. BY ORGANIC HALIDES. FROM CLEAVAGE OF THE GROUP VB-OTHER GROUP
IVB ELEMENT BOND BY HALOGENS TO GIVE NITROGEN HALIDES. 201 202 204 204
204 207 207 208 209 211 212 213 213 213 213 213 214 214 215 215 215 216
216 217 217 217 217 219 219 220 220 220 220 220 XH CONTENTS OF VOLUME 3
2.4. FORMATION OF BONDS BETWEEN HALOGENS AND GROUP-VB (N, P, AS, SB, BI)
ELEMENTS TO GIVE PHOSPHORUS HALIDES. 221 TO GIVE AS AND BI HALIDES. 222
BY HYDROGEN HALIDES 222 TO GIVE BISMUTH CHLORIDES. 222 BY OTHER HALIDES
223 TO GIVE NITROGEN HALIDES. 223 TO GIVE PHOSPHORUS HALIDES. 223 TO
GIVE AS HALIDES. 225 FROM CLEAVAGE OF THE GROUP VB-OXYGEN BOND 225 BY
HALOGENS. 225 BY HYDROGEN HALIDES 226 TO GIVE THE NITROGEN-HALOGEN BOND.
226 TO GIVE PHOSPHORUS-HALOGEN BOND. 227 TO GIVE THE ARSENIC-HALOGEN
BOND. 227 TO GIVE THE SB- AND BI-HALOGEN BOND. 229 BY OTHER HALIDES. 231
FROM CLEAVAGE OF THE GROUP VB-OTHER GROUP VIB ELEMENT BOND 234 BY
HALOGENS. 234 BY HYDROGEN HALIDES. 235 BY OTHER HALIDES 236 TO GIVE
PHOSPHORUS FLUORIDES FROM P*S AND P*SE BONDS. 236 TO GIVE
GROUP-VB-CHLORINE BONDS. 236 TO GIVE GROUP-VB*BR AND *I BOND. 238 FROM
CLEAVAGE OF THE GROUP VB-NITROGEN BOND 238 BY HALOGENS. 238 BY HYDROGEN
HALIDES. 239 BY OTHER HALIDES. 240 FROM CLEAVAGE OF THE GROUP VB-OTHER
GROUP VB ELEMENT BOND 242 BY HALOGENS 242 TO GIVE PHOSPHORUS HALIDES.
242 TO GIVE AS, SB AND BI HALIDES. 244 BY HYDROGEN HALIDES 245 TO GIVE
PHOSPHORUS HALIDES. 245 TO GIVE AS AND SB HALIDES. 246 2.4.6.1.2.
2.4.6.1.3. 2.4.6.2. 2.4.6.2.1. 2.4.6.3. 2.4.6.3.1. 2.4.6.3.2. 2.4.6.3.3.
2.4.7. 2.4.7.1. 2.4.7.2. 2.4.7.2.1. 2.4.7.2.2. 2.4.7.2.3. 2.4.7.2.4.
2.4.7.3. 2.4.8. 2.4.8.1. 2.4.8.2. 2.4.8.3. 2.4.8.3.1. 2.4.8.3.2.
2.4.8.3.3. 2.4.9. 2.4.9.1. 2.4.9.2. 2.4.9.3. 2.4.10. 2.4.10.1.
2.4.10.1.1 2.4.10.1.2 2.4.10.2. 2.4.10.2.1 2.4.10.2.2 CONTENTS OF VOLUME
3 XIII 2.4.10.3 BY OTHER HALIDES 246 2.4.10.3.1. TO GIVE PHOSPHORUS
HALIDES. 246 2.4.10.3.2. TO GIVE AS AND SB HALDIES. 249 2.4.11. BY
HALIDE-HALIDE EXCHANGE (METATHESIS) (WITH OR WITHOUT CONCOMITANT REDOX)
252 2.4.11.1. BY METAL HALIDES 252 2.4.11.1.1. OF GROUP IA. 252
2.4.11.1.2. OF OTHER THAN GROUP IA. 254 2.4.11.2. BY NONMETAL HALIDES.
255 2.4.11.3. BY FLUORINE DERIVATIVES 256 2.4.11.3.1. OF HYDROGEN,
AMMONIUM AND POTASSIUM. 256 2.4.11.3.2. OF ALKALI METALS. 257
2.4.11.3.3. OFANTIMONY. 258 2.4.11.3.4. OF ARSENIC(LLL). 259 2.4.11.3.5.
OF OTHER METALS. 260 2.4.11.3.6. OF POTASSIUM SULFINATE. 261 2.4.11.3.7.
OF OTHER NONMETALS. 262 2.4.12. FROM CLEAVAGE OF OTHER ELEMENT-GROUP VB
BONDS (INCLUDING SCRAMBLING) 262 2.4.12.1. BY HALOGENS. 262 2.4.12.2. BY
OTHER HALIDES FROM SCRAMBLING. 262 2.4.13. BY OXIDATIVE HALOGENATION OF
LOW- VALENT GROUP-VB COMPOUNDS 263 2.4.13.1. BY HALOGENS 263 2.4.13.1.1.
TO GIVE THE NITROGEN-HALOGEN BOND. 263 2.4.13.1.2. TO GIVE THE GROUP
VB-FLUORINE BOND. 264 2.4.13.1.3. TO GIVE THE PHOSPHORUS-CHLORINE BOND.
264 2.4.13.1.4. TO GIVE THE AS*CL BOND. 265 2.4.13.1.5. TO GIVE THE SB-
AND BI-CHLORINE BOND. 267 2.4.13.1.6. TO GIVE THE PHOSPHORUS-BROMINE
BOND. 268 2.4.13.1.7. TO GIVE THE AS*BR BOND. 269 2.4.13.1.8. TO GIVE
THE SB- OR BI-BR BOND. 270 2.4.13.1.9. TO GIVE THE GROUP VB-IODINE BOND.
271 2.4.13.2. BY HYDROGEN HALIDES. 272 2.4.13.3. BY OTHER HALIDES 273
2.4.13.3.1. TO GIVE THE FLUORINE-GROUP-VB BOND. 273 2.4.13.3.2. TO GIVE
THE CHLORINE-GROUP-VB BOND. 274 XIV CONTENTS OF VOLUME 3 2.4. FORMATION
OF BONDS BETWEEN HALOGENS AND GROUP-VB (N, P, AS, SB, BI) ELEMENTS
2.4.13.3.3. TO GIVE BR AND I GROUP-VB BONDS. 275 2.4.14. PREPARATION OF
ASTATINE*GROUP-VB ELEMENT BONDS 276 2.5. THE FORMATION OF THE
HALOGEN-GROUP- IVB (C, SI, GE, SN, PB) ELEMENT BOND 277 2.5.1. 2.5.2.
2.5.3. 2.5.3.1. 2.5.3.2. 2.5.3.3. 2.5.3.3.1. 2.5.3.3.2. 2.5.3.3.3.
2.5.3.3.4. 2.5.4. 2.5.5. 2.5.5.1. 2.5.5.2. 2.5.5.3. 2.5.6. 2.5.6.1.
2.5.6.1.1. 2.5.6.1.2. 2.5.6.1.3. 2.5.6.2. 2.5.6.2.1. 2.5.6.2.2.
2.5.6.2.3. 2.5.6.3. 2.5.6.3.1. 2.5.6.3.2. 2.5.6.3.3. 2.5.6.3.4.
INTRODUCTION FROM THE ELEMENTS. FROM HALOGENATION OF THE GROUP-IVB
ELEMENTS BY HYDROGEN HALIDES. BY VARIOUS HALIDES. BY ORGANIC HALIDES
WITH ELEMENTAL SI. WITH ELEMENTAL GE. WITH ELEMENTAL TIN. WITH LEAD
METAL. BY OTHER HALOGENATING AGENTS. FROM CLEAVAGE OF THE GROUP-
IVB-HYDROGEN BOND BY HALOGENS. BY HYDROGEN HALIDES. BY OTHER HALIDES.
FROM CLEAVAGE OF THE GROUP IVB-CARBON BOND THE SI-CARBON BOND BY
HALOGENS. BY HYDROGEN AND ALKYL HALIDES. BY OTHER HALIDES. THE GE-CARBON
BOND BY HALOGENS. BY HYDROGEN AND ALKYL HALIDES. BY OTHER HALIDES.
CLEAVAGE OF THE TIN-CARBON BOND BY HALOGENS. BY HYDROGEN HALIDES. BY
ORGANIC HALIDES. BY OTHER HALIDES. 277 277 279 279 281 282 282 283 284
285 285 287 287 289 290 293 293 293 295 297 298 299 302 304 305 305 306
306 307 CONTENTS OF VOLUME 3 XV 2.5.6.4. 2.5.6.4.1. 2.5.6.4.2.
2.5.6.4.3. 2.5.7. 2.5.7.1. 2.5.7.2. 2.5.7.3. 2.5.7.4. 2.5.7.5. 2.5.7.6.
2.5.7.6.1. 2.5.7.6.2. 2.5.7.7. 2.5.7.7.1. 2.5.7.7.2. 2.5.7.7.3. 2.5.8.
2.5.8.1. 2.5.8.1.1. 2.5.8.1.2. 2.5.8.1.3. 2.5.8.1.4. 2.5.8.1.5. 2.5.8.2.
2.5.8.2.1. 2.5.8.2.2. 2.5.8.2.3. 2.5.8.3. 2.5.8.3.1. 2.5.8.3.2. 2.5.8.4.
2.5.9. 2.5.9.1. 2.5.9.2. 2.5.9.3. 2.5.10. 2.5.10.1. 2.5.10.2. OF THE
LEAD-CARBON BOND BY HALOGENS. BY HYDROGEN AND ALKYL HALIDES. BY OTHER
HALIDES. FROM CLEAVAGE OF THE GROUP IVB-OTHER GROUP-IVB ELEMENT BOND THE
SI-SI BOND. THE SI-SN BOND. THE GE-GE BOND. THE GE-SN BOND. THE GE-PB
BOND. THE SN-SN BOND BY HALOGENS. BY HYDROGEN, ALKYL AND OTHER HALIDES.
THE PB-PB BOND. BY HALOGENS. BY HYDROGEN HALIDES. BY OTHER HALIDES. FROM
CLEAVAGE OF THE OXYGEN- SI BOND BY HALOGENS. BY HALOGENS IN THE PRESENCE
OF A REDUCING AGENT. BY HYDROGEN HALIDES. BY ORGANIC HALIDES. BY OTHER
HALIDES. GE BOND BY HYDROGEN HALIDES. BY ORGANIC HALIDES. BY OTHER
HALIDES. SN BOND BY HYDROGEN HALIDES. BY OTHER HALIDES. PB BOND. FROM
CLEAVAGE OF THE GROUP-IVB-GROUP- VIB ELEMENT BOND BY HALOGENS. BY
HYDROGEN HALIDES. BY OTHER HALIDES. FROM CLEAVAGE OF GROUP-IVB-NITROGEN
BOND BY HALOGENS. BY HYDROGEN HALIDES. 309 309 309 311 311 311 315 315
316 316 316 316 318 319 319 319 320 322 322 322 322 323 323 326 340 340
341 341 342 342 343 344 344 344 345 345 347 347 347 XVI CONTENTS OF
VOLUME 3 2.5. THE FORMATION OF THE HALOGEN-GROUP- IVB (C, SI, GE, SN,
PB) ELEMENT BOND 2.5.10.3. BY OTHER HALIDES. 349 2.5.11. FROM CLEAVAGE
OF THE GROUP-IVB-GROUP- VB ELEMENT BOND 350 2.5.11.1. BY HALOGENS. 350
2.5.11.2. BY HYDROGEN HALIDES. 351 2.5.11.3. BY OTHER HALIDES. 352
2.5.12. GROUP-IVB HALIDES BY HALIDE-HALIDE EXCHANGE REACTIONS
(METATHESIS) 353 2.5.12.1. BY METAL HALIDES 353 2.5.12.1.1. OF THE
ALKALI OR ALKALINE EARTHS. 353 2.5.12.1.2. BY SILVER AND OTHER
TRANSITION-METAL HALIDES. 356 2.5.12.1.3. BY HALIDES. 358 2.5.12.2. BY
METATHESIS USING NONMETAL HALIDES 360 2.5.12.2.1. EXCHANGE WITH HALOGENS
OR INTERHALOGEN COMPOUNDS. 360 2.5.12.2.2. BY HYDROGEN HALIDES. 362
2.5.12.2.3. BY OTHER NONMETAL HALIDES INCLUDING EXCHANGE REDISTRIBUTION.
363 2.5.12.3. BY FLUORINATING AGENTS 368 2.5.12.3.1. THAT UTILIZE SBF 3
OR ANTIMONY(V) HALIDES. 368 2.5.12.3.2. BY HF. 371 2.5.12.3.3. BY OTHER
METAL-FLUORINE DERIVATIVES AND NH 4 F. 372 2.5.12.3.4. BY FLUORINE
EXTRACTION FROM FLUORINE- CONTAINING ANIONS. 375 2.5.12.3.5. WITH
COVALENT FLUORIDES. 376 2.5.13. CLEAVAGE OF OTHER GROUP-IVB ELEMENT
BONDS (CLEAVAGE OF GROUP-IVB ELEMENT-METAL BONDS) 377 2.5.13.1. BY
HALOGENS. 377 2.5.13.1.1. CLEAVAGE OF CARBON-METAL BONDS. 377
2.5.13.1.2. WITH COMPOUNDS THAT CONTAIN LOWER GROUP-IVB
ELEMENT-TRANSITION-METAL BONDS 378 2.5.13.1.3. HYDROGEN HALIDES WITH
LOWER GROUP-IVB ELEMENT-METAL BONDS 383 2.5.13.1.4. HG(LL) HALIDES WITH
LOWER GROUP-IVB-METAL BONDS. 387 2.5.13.1.5. OF COVALENT HALIDES WITH
GROUP-IVB- METAL BONDS. 389 CONTENTS OF VOLUME 3 XVII 2.5.14. FROM
OXIDATIVE HALOGENATION OF COMPOUNDS OF LOW-VALENT GROUP-IVB ELEMENTS
(INCLUDING ADDITION REACTIONS TO C-C MULTIPLE BONDS) 395 2.5.14.1. BY
HALOGENS. 395 2.5.14.2. BY HYDROGEN HALIDES. 399 2.5.14.3. BY OTHER
COVALENT HALIDES. 403 2.5.15. HALIDES OF LOW-VALENT GROUP-IVB ELEMENTS
412 2.5.15.1. DIVALENT CARBON HALIDES 412 2.5.15.1.1. MONO-AND
DI-HALOCARBENES 412 2.5.15.1.2. ALKYL AND ARYL HALOCARBENES. 416
2.5.15.2. DIVALENT SILICON HALIDES (DIHALOSILYLENES, SILICON DIHAIIDES)
417 2.5.15.2.1. BY REDUCTION. 417 2.5.15.2.2. BY THERMAL AND OTHER
METHODS. 418 2.5.15.3. DIVALENT G RMANIUM HALIDES (DIHALOGERMYLENES,
GERMANIUM DIHAIIDES, ORGANOHALOGERMYLENES. 418 2.5.15.4. DIVALENT SN
HALIDES. 420 2.5.16. LEAD(LL) HALIDES, PBX 2 (X = F, CL, BR, I) AND
ORGANOLEAD(LL) HALIDES. 421 2.5.17. PREPARATION OF ASTATINE-GROUP-IVB
ELEMENT BONDS 423 2.5.17.1. PREPARATION OF ASTATI NE-CARBON BONDS 423
2.5.17.1.1. BY HOMOGENEOUS AND HETEROGENEOUS HALOGEN EXCHANGE 423
2.5.17.1.2. BY DECOMPOSITION OF DIAZONIUM SALTS. 424 2.5.17.1.3. FROM
ORGANOMETALLIC COMPOUNDS 424 2.5.17.1.4. BY ELECTROPHILIC SUBSTITUTION
AFTER CHEMICAL OR ELECTROCHEMICAL OXIDATION. 425 2.5.17.1.5. HOT-ATOM
REACTIONS. 426 2.5.17.2. PREPARATION OF ASTATINE-LEAD BONDS. 426 LIST OF
ABBREVIATIONS 427 AUTHOR INDEX 433 COMPOUND INDEX 493 SUBJECT INDEX 687
|
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| id | DE-604.BV004142531 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T16:09:00Z |
| institution | BVB |
| isbn | 089573253X 352726261X |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-002584575 |
| oclc_num | 643268942 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-12 DE-384 DE-29T DE-703 DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-634 DE-11 |
| owner_facet | DE-91G DE-BY-TUM DE-12 DE-384 DE-29T DE-703 DE-355 DE-BY-UBR DE-19 DE-BY-UBM DE-634 DE-11 |
| physical | XXXII, 710 S. |
| publishDate | 1989 |
| publishDateSearch | 1989 |
| publishDateSort | 1989 |
| publisher | VCH Verlagsges. |
| record_format | marc |
| spelling | Inorganic reactions and methods 3 The formation of bonds to halogens ; Pt. 1 ed. J. J. Zuckerman Weinheim [u.a.] VCH Verlagsges. 1989 XXXII, 710 S. txt rdacontent n rdamedia nc rdacarrier Halogene (DE-588)4158874-5 gnd rswk-swf Halogene (DE-588)4158874-5 s DE-604 Zuckerman, Jerry J. Sonstige oth (DE-604)BV002395307 3 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002584575&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Inorganic reactions and methods Halogene (DE-588)4158874-5 gnd |
| subject_GND | (DE-588)4158874-5 |
| title | Inorganic reactions and methods |
| title_auth | Inorganic reactions and methods |
| title_exact_search | Inorganic reactions and methods |
| title_full | Inorganic reactions and methods 3 The formation of bonds to halogens ; Pt. 1 ed. J. J. Zuckerman |
| title_fullStr | Inorganic reactions and methods 3 The formation of bonds to halogens ; Pt. 1 ed. J. J. Zuckerman |
| title_full_unstemmed | Inorganic reactions and methods 3 The formation of bonds to halogens ; Pt. 1 ed. J. J. Zuckerman |
| title_short | Inorganic reactions and methods |
| title_sort | inorganic reactions and methods the formation of bonds to halogens pt 1 |
| topic | Halogene (DE-588)4158874-5 gnd |
| topic_facet | Halogene |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=002584575&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV002395307 |
| work_keys_str_mv | AT zuckermanjerryj inorganicreactionsandmethods3 |