Principles of organometallic chemistry:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London [u.a.]
Chapman and Hall
1988
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XV, 414 S. |
| ISBN: | 0412275805 0412275902 |
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| 100 | 1 | |a Powell, Paul |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Principles of organometallic chemistry |c P. Powell |
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| 264 | 1 | |a London [u.a.] |b Chapman and Hall |c 1988 | |
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Record in the Search Index
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| adam_text | P POWELL
Principles of
Organometallic
Chemistry
Second
edition
London New York
CHAPMAN AND HALL
Contents
Foreword ix
Preface xi
Periodic table of the elements xiii
1 General survey 1
1 1 Introduction 1
1 2 Historical background 1
1 3 Properties 2
1 4 Classification of organometallic compounds by bond type 2
1 5 The stability of organometallic compounds 9
1 6 References 13
2 Methods of formation of metal-carbon bonds of the main
group elements 15
2 1 The reaction between a metal and an organic halogen
compound 15
2 2 Metal exchange: the reaction between a metal and an
organometallic compound of another metal 19
2 3 Reactions of organometallic compounds with metal halides 20
2 4 Addition of metal hydrides to alkenes and alkynes 22
2 5 Formation of metal-carbon bonds by other insertion
reactions 25
2 6 Reactions of diazo compounds 25
2 7 Decarboxylation of heavy B-metal salts 27
2 8 References 28
3 Organometallic compounds of elements of the first three
periodic groups 29
3 1 Introduction 29
3 2 Structures 31
3 3 Alkali-metal derivatives 39
3 4 Grignard reagents 50
v
Contents
3 5 Beryllium^ 54
3 6 Calcium, strontium and barium 56
3 7 Zinc, cadmium and mercury 57
3 8 Organoboron compounds 65
3 9 Organometallic compounds of Al, Ga In and Tl 80
3 10 Organocopper and -silver compounds 87
3 11 Complexes of main group elements with unsaturated
hydrocarbons 90
3 12 References 94
Problems 95
4 Organometallic compounds of elements of main Groups IV
and V 98
4 1 Introduction 98
4 2 Tetra-alkyls and -aryls of the elements of Group IV 99
4 3 Organohalides of the elements of Group IV 102
4 4 Silicones 109
4 5 Hydrolysis of organohalides of germanium, tin and lead 116
4 6 Catenated organic derivatives of the elements of Group IV 117
4 7 Divalent organic compounds of the elements of Group IV 121
4 8 pn—pn Bonding in compounds of Groups IV and V 124
4 9 Organic derivatives of the elements of Group V 125
4 10 References 144
Problems 145
5 Some transition metal chemistry relevant to organometallic
chemistry 148
5 1 The 18-electron rule 148
5 2 Transition metal carbonyls 152
5 3 Some general reactions of transition metal complexes 173
5 4 References 186
Problems 187
6 Organometallic compounds of the transition elements
Classification of ligands and theories of bonding 191
6 1 Classification of ligands 191
6 2 Molecular orbital theory 194
6 3 References 211
Problems 211
7 Organotransition metal chemistry AlkyI and alkylidene
derivatives Complexes of alkenes and alkynes 213
7 1 Alkyls and aryls 213
7 2 Alkylidene and alkylidyne (carbene and carbyne)
complexes 232
vi
Contents
7 3 Complexes of alkenes 237
7 4 Complexes of alkynes 243
7 5 References 248
Problems 249
8 AUyl and diene complexes of the transition elements 253
8 1 Allyl (-enyl) complexes 253
8 2 Diene complexes 263
8 3 References 272
Problems 272
9 Five electron ligands 278
9 1 Introduction 278
9 2 Bis(cyclopentadienyl) complexes - the metallocenes 279
9 3 Cyclopentadienylmetal carbonyls 292
9 4 Open-chain (acyclic) pentadienyl complexes 301
9 5 Cyclohexadienyltricarbonyliron salts 303
9 6 References 304
Problems 305
10 Complexes of arenes 311
10 1 Bis(arene)complexes 311
10 2 Arene(tricarbonyl)chromium complexes 316
10 3 Chemistry of some arene complexes of iron 320
10 4 Nucleophilic attack on organotransition metal complexes 321
10 5 q -Cycloheptatriene and ^ -tropylium complexes 330
10 6 References 331
Problems 332
11 Cluster compounds 335
11 1 Introduction 335
11 2 Structure and bonding 335
11 3 Carboranes 340
11 4 Metallocarboranes and metalloboranes 344
11 5 Transition metal clusters 348
11 6 Clusters and catalysis 352
11 7 References 355
Problems 355
12 Mechanisms of industrial processes clarified by studies of
homogeneous catalysis by complexes of transition elements 357
12 1 Introduction 357
12 2 Resources 361
12 3 Catalysis of reactions of alkenes by transition metal
complexes 361
vii
Contents
12 4 Chemistry based on synthesis gas
12 5 Conclusion
12 6 References
Problems
13 Some complexes of the Ianthanides and actinides
13 1 Introduction—Ianthanides
13 2 Introduction—actinides
13 3 Cyclopentadienyls
13 4 Cyclooctatetraene complexes
13 5 References
Index 405
viii
|
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| illustrated | Not Illustrated |
| indexdate | 2024-07-09T15:43:28Z |
| institution | BVB |
| isbn | 0412275805 0412275902 |
| language | English |
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| spelling | Powell, Paul Verfasser aut Principles of organometallic chemistry P. Powell 2. ed. London [u.a.] Chapman and Hall 1988 XV, 414 S. txt rdacontent n rdamedia nc rdacarrier Organometallic chemistry Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 s DE-604 HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001505522&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Powell, Paul Principles of organometallic chemistry Organometallic chemistry Metallorganische Verbindungen (DE-588)4038906-6 gnd |
| subject_GND | (DE-588)4038906-6 |
| title | Principles of organometallic chemistry |
| title_auth | Principles of organometallic chemistry |
| title_exact_search | Principles of organometallic chemistry |
| title_full | Principles of organometallic chemistry P. Powell |
| title_fullStr | Principles of organometallic chemistry P. Powell |
| title_full_unstemmed | Principles of organometallic chemistry P. Powell |
| title_short | Principles of organometallic chemistry |
| title_sort | principles of organometallic chemistry |
| topic | Organometallic chemistry Metallorganische Verbindungen (DE-588)4038906-6 gnd |
| topic_facet | Organometallic chemistry Metallorganische Verbindungen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001505522&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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