The chemistry of technetium and rhenium:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Amsterdam
Elsevier
1966
|
| Series: | Topics in inorganic and general chemistry.
6. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 137 S. |
Staff View
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| 245 | 1 | 0 | |a The chemistry of technetium and rhenium |c Raymond Dixon Peacock* |
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Record in the Search Index
| _version_ | 1804116737313996800 |
|---|---|
| adam_text | THE CHEMISTRY OF
TECHNETIUM AND RHENIUM
BY
R D PEACOCK
Professor of Inorganic Chemistry
The University of Leicester (Great Britain)
ELSEVIER PUBLISHING COMPANY
AMSTERDAM/LONDON/NEWYORK
Contents
Foreword v
Chapter 1 Discovery and isolation of rhenium and technetium 1
Rhenium 1
Technetium 5
; References 11
Chapter 2 General and elementary properties 13
Isotopes and atomic weight 13
General properties 14
Differences between rhenium and technetium 20
Preparation and properties of the elements 21
References 23
Chapter 3 Oxides 25
Rhenium heptoxide 25
Technetium heptoxide 26
Trioxides 27
Dioxides 28
Mixed oxides 29
References 30
Chapter 4 Oxoacids and oxosalts 32
Perrhenic and pertechnetic acids 32
Perrhenates and pertechnetates 36
Meso- and ortho-perrhenates 38
Rhenates(VI) 40
Substituted per-salts 41
References 42
Chapter 5 Halides and oxide halides 44
Introduction 44
Fluorides 44
Oxide fluorides 48
Halides 49
Oxide halides 53
References 55
Chapter 6 Complex halides, complex oxide halides and complex hydrides 57
Introduction 57
Fluorides and oxide fluorides 57
Complex halides 63
Complex hydroxide and oxide halides 72
Complex hydrides 74
References 76
Chapter 7 Chalcogenides and compounds with non-metals and metalloids,
alloys 79
Sulphides 79
Disulphides 81
Selenides and tellurides 82
Refractory materials 82
Alloys 83
References 84
Chapter 8 Complex cyanides and related compounds 87
Complex cyanides 87
Octacyanorhenate(V) ion 87
Octacyanorhenate(VI) ion 89
Heptacyanonitrosylrhenate(IV) ion 90
Hexacyanorhenate(III) ion 90
Hexacyanorhenate(I) ion 91
Dioxotetracyanorhenate(V) ion 91
Dioxotetracyanorhe nate(IV) ion 92
Trihydroxytricyanorhenate(III) ion 93
Other rhenium cyano-complexes 93
Hexacyanotechnetate(I) ion 93
Trihydroxytetracyanotechnetate(IV) ion 94
Hexacyanotechnetate(IV) 95
General 95
Rhenium oxothiocyanate 96
Complex thiocyanates 96
Isonitrile complexes 97
References 97
Chapter 9 Carbonyls and organometallic derivatives 99
Carbonyls 99
Carbonyl halides 102
Carbonyl hydrides 104
Carbonyl anions and cations 105
Other carbonyl derivatives 105
Cyclopentadienyl and related complexes 107
Olefin and acetylene derivatives 109
Aromatic compounds 110
References 110
Chapter 10 Compounds with group V and group VI ligands 112
Reactions with ammonia 112
Complexes with amines 112
Phosphine derivates 114
Arsine derivatives 117
Oxygen ligands 119
Sulphur ligands 120
References 121
Chapter 11 Analysis 122
Analytical methods 122
i) Gravimetric 122
ii) Spectrophotometric 123
References 125
Appendices
I The laboratory handling of technetium 126
II Bibliography 127
III Further references 128
Subject index 132
|
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie Werkstoffwissenschaften |
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| language | English |
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| spelling | Peacock, Raymond D. Verfasser aut The chemistry of technetium and rhenium Raymond Dixon Peacock* Amsterdam Elsevier 1966 137 S. txt rdacontent n rdamedia nc rdacarrier Topics in inorganic and general chemistry. 6. Eigenschappen gtt Metais E Seus Compostos (Quimica) larpcal Organometaalverbindingen gtt Renium gtt Technetium gtt Rhenium Technetium Technetiumverbindungen (DE-588)4184561-4 gnd rswk-swf Rheniumverbindungen (DE-588)4178010-3 gnd rswk-swf Rhenium (DE-588)4177995-2 gnd rswk-swf Technetium (DE-588)4184557-2 gnd rswk-swf Technetiumverbindungen (DE-588)4184561-4 s DE-604 Technetium (DE-588)4184557-2 s Rheniumverbindungen (DE-588)4178010-3 s Rhenium (DE-588)4177995-2 s Topics in inorganic and general chemistry. 6. (DE-604)BV001888756 6. HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001497408&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Peacock, Raymond D. The chemistry of technetium and rhenium Topics in inorganic and general chemistry. Eigenschappen gtt Metais E Seus Compostos (Quimica) larpcal Organometaalverbindingen gtt Renium gtt Technetium gtt Rhenium Technetium Technetiumverbindungen (DE-588)4184561-4 gnd Rheniumverbindungen (DE-588)4178010-3 gnd Rhenium (DE-588)4177995-2 gnd Technetium (DE-588)4184557-2 gnd |
| subject_GND | (DE-588)4184561-4 (DE-588)4178010-3 (DE-588)4177995-2 (DE-588)4184557-2 |
| title | The chemistry of technetium and rhenium |
| title_auth | The chemistry of technetium and rhenium |
| title_exact_search | The chemistry of technetium and rhenium |
| title_full | The chemistry of technetium and rhenium Raymond Dixon Peacock* |
| title_fullStr | The chemistry of technetium and rhenium Raymond Dixon Peacock* |
| title_full_unstemmed | The chemistry of technetium and rhenium Raymond Dixon Peacock* |
| title_short | The chemistry of technetium and rhenium |
| title_sort | the chemistry of technetium and rhenium |
| topic | Eigenschappen gtt Metais E Seus Compostos (Quimica) larpcal Organometaalverbindingen gtt Renium gtt Technetium gtt Rhenium Technetium Technetiumverbindungen (DE-588)4184561-4 gnd Rheniumverbindungen (DE-588)4178010-3 gnd Rhenium (DE-588)4177995-2 gnd Technetium (DE-588)4184557-2 gnd |
| topic_facet | Eigenschappen Metais E Seus Compostos (Quimica) Organometaalverbindingen Renium Technetium Rhenium Technetiumverbindungen Rheniumverbindungen |
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