Catalysis of gas reactions by metals:
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Logos Pr.
1970
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 182 S. |
| ISBN: | 0236308726 |
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MARC
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| 100 | 1 | |a Robertson, Andrew J. B. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Catalysis of gas reactions by metals |
| 264 | 1 | |a London |b Logos Pr. |c 1970 | |
| 300 | |a XI, 182 S. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Catalysis | |
| 650 | 4 | |a Gases | |
| 650 | 4 | |a Metal catalysts | |
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| _version_ | 1804116735982305280 |
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| adam_text | Titel: Catalysis of gas reactions by metals
Autor: Robertson, Andrew J. B
Jahr: 1970
Contents
PAGE
Preface
...........
xi
Chapter
i.
Historical
Introduction
.....
i
A.
Early
work
on
heterogeneous
catalytic
oxidation
...
i
B.
Early
hypotheses
on
the
mode
of
action
of
catalysts
.
.
4
C.
The
catalytic
synthesis
of
ammonia
.....
7
D.
The
catalysis
of
organic
reactions
by
metals
....
8
References
.........
10
Chapter
2.
The
Development
of
Modern
Ideas
.
.
.
.
11
A.
Early
work
of
Langmuir
on
catalytic
reactions
and
adsorption.
11
1.
Formation
of
atomic
hydrogen
by
dissociation
of
molecular
hydrogen
on
incandescent
tungsten
filaments
.
.
.
11
2.
Adsorption
isotherms
.
.
.
.
.
.
.
12
(a)
Adsorption
of
molecules
without
dissociation
on
crystal
surfaces
.
.
.
.
.
.
.
12
(
b
)
Adsorption
with
dissociation
on
crystal
surfaces
.
.
13
B.
Kinetics
of
catalytic
reactions
.
.
.
.
.
14
1.
The
diffusion
theory
of
Nernst
.
.
.
.
14
2.
The
Langmuir-Hinshelwood
mechanism.
.
.
15
3.
The
absolute
rate
of
heterogeneous
gas
reactions
.
.
17
4.
The
Rideal
mechanism
.
.
.
.
.
.
.
18
5.
The
possibility
of
chain
reactions
at
a
catalytic
surface
.
19
C.
Active
centres
on
catalytic
surfaces
.
.
.
.
.
21
D.
Catalysis
and
adsorption
.
.
.
.
.
.
.25
1.
The
hypothesis
of
activated
adsorption
....
27
2.
The
surface
mobility
of
adsorbed
layers
....
32
(a)
Mobility
and
Langmuir-Hinshelwood
kinetics
.
.
33
(
b
)
Surface
mobility
of
metal
atoms
induced
by
catalytic
reactions
and
by
adsorption
of
gases
...
34
V
CONTENTS
vi
PAGE
E.
Discussion
of
adsorption
and
desorption
processes
with
the
help
of
potential
energy
curves
.....
37
1.
Kinetics
of
desorption
of
ions
and
potential
energy
curves
.
41
(a)
Comparison
of
calculated
results
for
ionic
desorption
with
experimental
results
obtained
with
a
cleaned
tungsten
surface
and
a
modulated
molecular
beam
of
impinging
atoms
.......
43
2.
Transition
state
theory
and
desorption
kinetics
...
49
3.
Potential
energy
curves
and
endothermic
adsorption
.
.
52
4.
Potential
energy
curves
and
weak
chemisorption
.
.
53
F.
Ionisation
and
catalysis
.
.
.
.
.
.
-55
G.
The
electronic
factor
in
catalysis
.....
57
H.
The
geometric
factor
in
catalysis
.....
60
i.
Catalytic
reactions
on
single
crystal
planes
...
62
References
.........
64
Chapter
3.
The
Use
of
Ultra-high
Vacuum
in
Research
on
Catalysis
by
Metals
........
68
A.
Pumping
speed
in
vacuum
systems
.....
69
B.
Ionisation
gauges
for
measurement
of
low
gas
pressures
.
70
1.
The
Bayard-Alpert
gauge
......
72
2.
Other
ion
gauges
for
ultra-high
vacuum
....
73
(a)
The
Helmer
gauge
......
73
(b)
The
inverted
magnetron
gauge
.....
74
C.
The
production
of
ultra-high
vacuum
in
the
laboratory
.
.
75
i.
Special
pumps
for
ultra-high
vacuum
systems
...
75
(a)
Molecular
sieve
pumping
.....
77
D.
Analysis
of
residual
gases
in
ultra-high
vacuum
systems
.
78
E.
Examples
of
ultra-high
vacuum
apparatus
used
for
research
on
the
catalysis
of
gas
reactions
by
metals
....
80
1.
The
static
system
used
by
R.
W.
Roberts
...
80
2.
The
flow
system
used
by
E.
M.
A.
Willhoft
...
81
References
.........
82
Chapter
4.
The
Preparation
of
Clean
Metal
Surfaces
.
.
84
A.
Evaporation
of
metal
on
to
a
substrate
....
84
B.
High
temperature
heating
.......
86
C.
Chemical
reaction
........
86
D.
Ion
bombardment
........
86
E.
Field
desorption
........
87
F.
Preparation
of
single-crystal
metal
surfaces
....
87
References
.........
88
CONTENTS
VÜ
PAGE
Chapter
5.
The
Nature
and
Properties
of
Metal
Surfaces
.
89
A.
The
arrangement
of
atoms
at
an
ideal
surface
...
89
B.
The
investigation
of
the
surfaces
of
metals
by
field
ion
microscopy
.........
90
1.
Field
ionisation
........
90
2.
The
field
ion
microscope
in
practice
....
92
C.
Terraces,
steps,
kinks,
adatoms
and
vacancies
at
metal
surfaces
.........
94
D.
Intersection
of
edge
and
screw
dislocations
with
metal
surfaces
95
E.
Surfaces
of
real
metals
.......
97
F.
The
investigation
of
the
structure
of
crystal
surfaces
by
low-energy
electron
diffraction
.....
97
i.
The
actual
arrangement
of
atoms
at
metal
crystal
surfaces
98
References
.........
99
Chapter
6.
Supported
Metal
Catalysts
.
.
.
.
.101
A.
Preparation
of
supported
catalysts
.
.
.
.
.101
B.
Determination
of
the
surface
area
of
metal
in
a
supported
metal
catalyst
.........
102
C.
Influence
of
the
nature
of
the
support
and
of
crystallite
size
on
specific
activity
.
.
.
.
.
.
.
.103
References
.........
105
Chapter
7.
Physical
Methods
for
the
Investigation
of
Adsorbed
Layers
on
Metal
Surfaces
.
.
.
.
.
.
.107
A.
The
thermal
accommodation
coefficient
.
.
.
.107
B.
Auger
neutralisation
and
Auger
de-excitation
.
.
.109
C.
Sticking
probability
.
.
.
.
.
.
.
.109
D.
Flash
desorption
.
.
.
.
.
.
.
.110
E.
Heats
of
adsorption
.
.
.
.
.
.
.
.111
F.
Surface
potentials
.
.
.
.
.
.
.
.112
G.
Field
emission
.
.
.
.
.
.
.
.
.113
1.
The
Fowler-Nordheim
equation
.
.
.
.
.113
2.
Field
emission
microscopy
.
.
.
.
.
.114
3.
Field
emission
work
function
measurements
.
.
.115
CONTENTS
viii
PAGE
H.
Field
ion
microscopy
.
.
.
•
•
•
.116
I.
Low-energy
electron
diffraction
.
.
.
.117
J.
The
infrared
spectra
of
adsorbed
gases
.
.
.
.
117
K.
Electric
and
magnetic
measurements
.
.
.
.
.118
1
.
The
electrical
resistance
of
metal
films
.
.
.
.
118
2.
Ferromagnetism
of
small
crystals
.
.
.
.
.118
L.
Ion
and
electron
bombardment
.
.
.
.
.
.119
References
.
.
.
.
.
•
-
•
.119
Chapter
8.
The
Interpretation
of
the
Kinetics
of
Catalytic
Reactions
in
Terms
of
Adsorbed
Layers
and
Adsorption
Isotherms
..........
122
A.
Decomposition
of
a
single
reactant
discussed
in
terms
of
the
Langmuir
isotherm
.
.
.
.
.
.
.123
i.
The
probability
of
reaction
at
a
single
collision
of
a
reactant
molecule
with
the
catalytic
surface
.
.
.
.124
B.
Reactions
involving
two
reactants
.
.
.
.
.125
i.
The
power
rate
law
in
heterogeneous
catalysis
.
.
126
C.
The
logarithmic
(or
Temkin)
adsorption
isotherm
.
.
126
D.
The
kinetics
of
the
catalytic
decomposition
of
ammonia
.
128
i.
Kinetics
of
the
decomposition
of
ammonia
on
platinum
at
low
pressures
.
.
.
.
.
.
.129
References
.
.
.
.
.
.
.
.
.132
Chapter
9.
The
Absolute
Rate
of
Catalytic
Reactions
Involving
One
and
Two
Reactants
.
.
.
.
.
.
133
A.
First-order
decomposition
of
a
single
reactant
.
.
133
1.
Immobile
transition
state
.
.
.
.
.
133
(a)
Comparison
with
experiment
.
.
.
.
.136
2.
Mobile
transition
state
.......
136
3.
Symmetry
number
of
the
transition
state
.
.
.137
B.
Evaporation
of
molecules
formed
by
a
collision
of
two
mobile
adsorbed
atoms
.
.
.
.
.
.
.
.137
C.
Reactions
involving
two
reactants
.
.
.
.
.138
1.
Adjacent
interaction
forming
an
immobile
transition
state
.
138
2.
Two
reactants
forming
a
mobile
transition
state
.
.
139
3.
Collision
yield
in
a
reaction
involving
two
reactants
.
.
140
References
.........
140
CONTENTS
IX
PAGE
Chapter
io.
The
Possible
Importance
of
Active
Sites
in
Catalysis
by
Metals
..........
141
A.
Some
experimental
investigations
on
active
sites
.
.
.
141
1.
Use
of
thin
metal
sheets
as
catalysts
in
an
ultra-high
vacuum
system
.........
141
(a)
Hydrogenation
of
ethylene
.....
141
(
b
)
Hydrogen-deuterium
exchange
on
nickel
.
.
.142
2.
The
decomposition
of
formic
acid
on
single
crystal
faces
of
silver
.........
143
3.
The
decomposition
of
formic
acid
on
silver
films
.
.
143
B.
The
annealing
of
extra
activity
ascribed
to
active
centres
.
144
C.
Effects
of
pre-treament
of
the
wire
on
the
decomposition
of
formic
acid
on
nickel
and
platinum
wires
.
.
.
.144
1.
Decomposition
on
nickel
......
145
2.
Decomposition
on
platinum
......
147
D.
Effects
of
ionising
radiation
on
the
catalytic
activity
of
metals
148
E.
Active
sites
in
adsorption
and
in
catalysis
....
149
References
.........
149
Chapter
i
i
.
The
Electronic
Factor
in
Catalysis
by
Metals
.
151
A.
The
importance
of
the
compensation
effect
when
catalytic
activity
is
related
to
some
property
of
the
metal.
.
.
151
B.
Holes
in
the
d-band
.
.
.
.
.
.
.
.152
1.
Gibbs
free
energy
per
electron
.
.
.
.
.154
2.
Intermediates
in
catalysis
and
electron
transfer
.
.
155
C.
The
resonating-valence-bond
theory
.
.
.
.
.156
D.
More
detailed
considerations
of
the
electronic
factor
and
of
surface
bonding
.
.
.
.
.
.
.
.157
1.
The
possible
importance
of
w-bonded
intermediates
in
metal-
catalysed
reactions
.
.
.
.
.
.
157
References
.
.
.
.
.
.
•
.
.158
Chapter
12.
Decomposition
Reactions
of
Some
Gases
on
Metal
Catalysts
at
Low
Pressures
.
.
.
.
.
.
.159
A.
Investigations
with
field
emission
and
field
ionisation
.
.
159
B.
Investigation
of
reactions
in
a
time
which
is
short
compared
with
the
time
of
monolayer
formation
.
.
.
.
161
1.
Use
of
flow
systems
.......
161
2.
Use
of
static
systems
.......
161
C.
Determination
of
collision
yield
in
a
flow
system
.
.
.
162
X
CONTENTS
PAGE
D.
Results
of
some
reaction
studies
using
flow
methods
.
.
163
1.
Some
reactions
on
a
platinum
wire
.
.
.
.
.163
2.
Some
reactions
on
a
niobium
wire
.
.
.
.
.164
E.
Influence
of
contamination
of
the
surface
on
Arrhenius
para¬
meters
.........
165
References
.........
166
Author
Index
..........
169
Subject
Index
..........
174
|
| any_adam_object | 1 |
| author | Robertson, Andrew J. B. |
| author_facet | Robertson, Andrew J. B. |
| author_role | aut |
| author_sort | Robertson, Andrew J. B. |
| author_variant | a j b r ajb ajbr |
| building | Verbundindex |
| bvnumber | BV002277876 |
| callnumber-first | Q - Science |
| callnumber-label | QD501 |
| callnumber-raw | QD501 |
| callnumber-search | QD501 |
| callnumber-sort | QD 3501 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VE 7000 |
| classification_tum | CHE 167f |
| ctrlnum | (OCoLC)93042 (DE-599)BVBBV002277876 |
| dewey-full | 541.33 541/.395 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.33 541/.395 |
| dewey-search | 541.33 541/.395 |
| dewey-sort | 3541.33 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| id | DE-604.BV002277876 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T15:43:14Z |
| institution | BVB |
| isbn | 0236308726 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001496593 |
| oclc_num | 93042 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-29T DE-19 DE-BY-UBM DE-83 DE-188 |
| owner_facet | DE-355 DE-BY-UBR DE-29T DE-19 DE-BY-UBM DE-83 DE-188 |
| physical | XI, 182 S. |
| psigel | TUB-nveb |
| publishDate | 1970 |
| publishDateSearch | 1970 |
| publishDateSort | 1970 |
| publisher | Logos Pr. |
| record_format | marc |
| spelling | Robertson, Andrew J. B. Verfasser aut Catalysis of gas reactions by metals London Logos Pr. 1970 XI, 182 S. txt rdacontent n rdamedia nc rdacarrier Catalysis Gases Metal catalysts Gas (DE-588)4019320-2 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf Metall (DE-588)4038860-8 gnd rswk-swf Gas (DE-588)4019320-2 s Metall (DE-588)4038860-8 s Katalyse (DE-588)4029921-1 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001496593&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Robertson, Andrew J. B. Catalysis of gas reactions by metals Catalysis Gases Metal catalysts Gas (DE-588)4019320-2 gnd Katalyse (DE-588)4029921-1 gnd Metall (DE-588)4038860-8 gnd |
| subject_GND | (DE-588)4019320-2 (DE-588)4029921-1 (DE-588)4038860-8 |
| title | Catalysis of gas reactions by metals |
| title_auth | Catalysis of gas reactions by metals |
| title_exact_search | Catalysis of gas reactions by metals |
| title_full | Catalysis of gas reactions by metals |
| title_fullStr | Catalysis of gas reactions by metals |
| title_full_unstemmed | Catalysis of gas reactions by metals |
| title_short | Catalysis of gas reactions by metals |
| title_sort | catalysis of gas reactions by metals |
| topic | Catalysis Gases Metal catalysts Gas (DE-588)4019320-2 gnd Katalyse (DE-588)4029921-1 gnd Metall (DE-588)4038860-8 gnd |
| topic_facet | Catalysis Gases Metal catalysts Gas Katalyse Metall |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001496593&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT robertsonandrewjb catalysisofgasreactionsbymetals |