The chemistry and technology of cellulosic copolymers:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin
Springer
1981
|
| Series: | Polymers.
4. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII, 351 S. Ill., graph. Darst. |
| ISBN: | 0387101640 3540101640 |
Staff View
MARC
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| 100 | 1 | |a Hebeish, Ali |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The chemistry and technology of cellulosic copolymers |c Ali Hebeish ; James T. Guthrie |
| 264 | 1 | |a Berlin |b Springer |c 1981 | |
| 300 | |a XII, 351 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Polymers. |v 4. | |
| 650 | 4 | |a Cellulose | |
| 650 | 4 | |a Copolymères greffés | |
| 650 | 4 | |a Cellulose | |
| 650 | 4 | |a Graft copolymers | |
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| 700 | 1 | |a Guthrie, James T. |e Verfasser |4 aut | |
| 830 | 0 | |a Polymers. |v 4. |w (DE-604)BV000015104 |9 4. | |
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Record in the Search Index
| _version_ | 1804116723819872256 |
|---|---|
| adam_text | A Hebeish • J T Guthrie
The Chemistry and
Technology of
Cellulosic Copolymers
With 91 Figures
f
Springer-Verlag
Berlin Heidelberg New York 1981
Table of Contents
1 The Homopolymeric Species 1
1 1 Introduction 1
1 2 Cellulose 2
121 Structural Features of Cellulose 3
122 Reactivity of Cellulose 7
1 3 Synthetic Polymers 11
131 Radical Addition Polymerization 11
1311 Free Radical Initiation 11
1312 Propagation 12
1313 Termination 12
132 Kinetics of Polymerization 13
1321 Initiation 13
1322 Propagation 15
1323 Termination 16
1324 Steady State 17
1325 Degree of Polymerization 18
1326 Transfer Reactions 20
1327 Effect of Temperature 21
1328 Rate Constants 22
1329 Initiation Rates 23
1 4 Vinyl Copolymerization 23
141 Copolymer Formation 23
142 Kinetics of Copolymerization 26
1 5 Molecular Mass Distribution 29
1 6 Polymer Structure 29
References 30
2 Vinyl Graft Copolymerization onto Cellulose 32
2 1 Introduction 32
2 2 Conditions Affecting Grafting 34
221 Chemical Conditions 34
222 Physical Condition? 35
223 Nature of Substrate 37
2 3 Grafting Reactions 41
2 4 Mechanism of Free Radical Formation on Cellulose 42
241 Chain Transfer 43
IX
Table of Contents
242 Physical Activation 43
243 Chemical Activation 44
2 5 Charge-Transfer Mechanism of Grafting 46
2 6 Grafting by Chain Transfer 47
2 7 Grafting by Mechanochemical Activation of Cellulose 50
2 8 Uncatalyzed Grafting 51
2 9 The Kinetics of Radiation-Induced Grafting onto Cellulosics 54
References 61
3 Radiation-Induced Grafting onto Cellulosics 64
3 1 Introduction 64
311 Radiation Units; The Concept of Dose and Dosimetry 66
3 2 Grafting by High Energy Radiation 68
321 Energy Transfer in the Irradiation of Cellulose 71
322 The Radiation Protection of Cellulose 72
323 The Radiation Chemistry of Cellulose 76
3231 Molecular and Structural Properties of Irradiated Cellulose 77
3232 Chemical Properties of Irradiated Cellulose 82
3233 Effect on Storage on the Properties of Irradiated Cellulose 85
3234 Location of the Free Radicals in the Cellulose Structure after
Irradiation 87
3235 Mechanisms of Radiation-Induced Reactions in Cellulose 91
324 High Energy, Radiation-Induced Grafting of Cellulosics 96
3241 Radiochemical Yields of Irradiated Cellulose 97
3242 Radiochemical Yield of Irradiation Grafting 98
3243 Techniques of Radiation-Induced Grafting 100
3244 Mechanisms of Irradiation Grafting 121
3 3 Grafting by low Energy Radiation in the Presence of Sensitizers 127
331 Photo-tendering in Ultraviolet-Light-Sensitized Grafting 128
332 Photoionitiated Grafting Reactions 132
References 138
4 Grafting by Chemical Activation of Cellulose 146
4 1 Introduction 146
4 2 Free-Radical Initiation 146
421 Persulfate Initiation 146
422 Hydroxyl Radical Initiation 152
423 CeIV Ion Initiation 155
424 Initiation by Pentavalent Vanadium 168
425 Initiation by Manganese111 Ions 168
426 Initiation by ManganeseIV 169
427 Initiation by Ozone-Oxygen Mixtures 171
428 Initiation by Periodate Ions 172
429 Initiation by Aryl Diazonium Groups 173
4 2 10 Initiation by Radical Attack on Unsaturated Groups 175
4 2 11 Initiation by Dimethylaniline 176
X
Table of Contents
4 3 Ionic Initiation 179
431 Cationic Grafting 179
432 Anionic Grafting 180
References 183
5 Grafting of other Types of Monomers onto Cellulose 187
5 1 Introduction 187
5 2 Step-Growth Polymerization of Cyclic Compounds 187
5 3 Preformed Polymers 190
References 194
6 Grafting on Chemically Modified Celluloses 196
6 1 Introduction 196
6 2 Grafting on Cellulose Xanthogenate 198
6 3 Grafting on Acetylated Cellulose 202
6 4 Grafting on Cyanoethylated Cellulose 206
6 5 Grafting on Partially Carboxymethylated Cellulose 212
6 6 Grafting on Acrylamidomethylated Cellulose 223
6 7 Grafting on Cellulose Treated with N-Methylolacrylamide in an
Alkaline Medium 225
6 8 Grafting on Carbamoylethylated Cellulose 227
6 9 Grafting on Cellulose Bearing Carboxymethyl and Cyanoethyl
Groups 228
6 10 Grafting on Cellulose Bearing Cyanoethyl and Carboxyethyl Groups 229
6 11 Grafting on Phosphorylated Cellulose 231
6 12 Grafting on Crosslinked Cellulose 235
6 13 Grafting on Aldehyde Cellulose 237
6 14 Grafting onto Methylol Cellulosics 238
References 241
7 Characterization and Properties of Cellulose Graft Copolymers 245
7 1 Introduction 245
7 2 Proof of Grafting 246
7 3 Molecular Structure 250
731 Molecular Mass of Cellulose Backbone 250
732 Molecular Masses of Grafted Branches 251
733 Average Molecular Masses of ‘True’ Cellulosic Copolymers 257
734 Preferential Adsorption by Cellulosic Copolymers in
Mixed Solvents 261
735 Molecular Mass Distribution of Grafted Branches 262
736 Frequency of Branching 262
737 Site of Branch Attachment 262
7 4 Morphology 262
7 5 Fine Structure 276
7 6 Properties 277
761 Textile Properties of Cellulose Graft Copolymers 278
762 New Cellulosic Materials 311
XI
Table of Contents
763 Properties of Grafted Paper 313
764 Properties of Grafted Pulp and Timber 316
References 322
8 Industrial Application of Cellulose Graft Copolymers 326
8 1 Introduction 326
8 2 Wood-Plastic Composites (WPC) 326
821 The Geographical Distribution of WPC Development 329
822 Uses and Properties 332
8 3 Grafted Textile Products 334
8 4 Grafted Pulps and Papers 336
8 5 Miscellaneous Examples 337
References 338
XII
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| discipline | Chemie / Pharmazie Physik Werkstoffwissenschaften |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T15:43:03Z |
| institution | BVB |
| isbn | 0387101640 3540101640 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-001489117 |
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| physical | XII, 351 S. Ill., graph. Darst. |
| publishDate | 1981 |
| publishDateSearch | 1981 |
| publishDateSort | 1981 |
| publisher | Springer |
| record_format | marc |
| series | Polymers. |
| series2 | Polymers. |
| spelling | Hebeish, Ali Verfasser aut The chemistry and technology of cellulosic copolymers Ali Hebeish ; James T. Guthrie Berlin Springer 1981 XII, 351 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymers. 4. Cellulose Copolymères greffés Graft copolymers Cellulosecopolymere (DE-588)4147459-4 gnd rswk-swf Cellulosecopolymere (DE-588)4147459-4 s DE-604 Guthrie, James T. Verfasser aut Polymers. 4. (DE-604)BV000015104 4. HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001489117&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hebeish, Ali Guthrie, James T. The chemistry and technology of cellulosic copolymers Polymers. Cellulose Copolymères greffés Graft copolymers Cellulosecopolymere (DE-588)4147459-4 gnd |
| subject_GND | (DE-588)4147459-4 |
| title | The chemistry and technology of cellulosic copolymers |
| title_auth | The chemistry and technology of cellulosic copolymers |
| title_exact_search | The chemistry and technology of cellulosic copolymers |
| title_full | The chemistry and technology of cellulosic copolymers Ali Hebeish ; James T. Guthrie |
| title_fullStr | The chemistry and technology of cellulosic copolymers Ali Hebeish ; James T. Guthrie |
| title_full_unstemmed | The chemistry and technology of cellulosic copolymers Ali Hebeish ; James T. Guthrie |
| title_short | The chemistry and technology of cellulosic copolymers |
| title_sort | the chemistry and technology of cellulosic copolymers |
| topic | Cellulose Copolymères greffés Graft copolymers Cellulosecopolymere (DE-588)4147459-4 gnd |
| topic_facet | Cellulose Copolymères greffés Graft copolymers Cellulosecopolymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001489117&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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