Valency and molecular structure:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
Butterworth
1961
|
| Edition: | 2. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XI, 294 S. zahlr. Ill. |
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Record in the Search Index
| _version_ | 1804116647368196096 |
|---|---|
| adam_text | VALENCY AND
MOLECULAR STRUCTURE
E CARTMELL, B Sc ,ARIC
Lecturer in Inorganic Chemistry
University of Southampton
and
GWA FOWLES, B Sc , PH D
Senior Lecturer in Inorganic Chemistrj
University of Southampton
SECOND EDITION
LONDON
BUTTERWORTHS
i
CONTENTS
PREFACE TO THE SECOND EDITION V
PREFACE TO THE FIRST EDITION vii
I—QUANTUM THEORY AND ATOMIC STRUCTURE
1—THE EXPERIMENTAL FOUNDATION OF THE QUANTUM
THEORY 3
Black-body radiation 3
The photoelectric effect 6
The Bohr theory of the hydrogen atom 7
Energy units and the magnitudes of energy quanta 10
2—ATOMIC STRUCTURE AND THE QUANTUM THEORY—I 12
The Bohr theory—circular orbits 12
Extensions of the Bohr theory 15
The spinning electron 18
3—ATOMIC STRUCTURE AND THE QUANTUM THEORY—II 20
Particles and waves 20
The uncertainty principle 21
Waves and wave equations 24
The wave equation for electrons 29
The interpretation of ^ 30
4—THE HYDROGEN ATOM 33
The Schrodinger equation in polar co-ordinates 33
Solution of the 0 equation 36
Solutions of the 0 and R equations 37
The physical significance of the s orbitals 38
The physical significance of the p orbitals 41
The physical significance of the d orbitals 44
Orbitals and probability distributions 46
Energy levels 47
5—QUANTUM THEORY AND THE PERIODIC CLASSIFICATION 49
The wave equation for many-electron atoms 49
Energy levels 50
Electron spin 51
The exclusion principle 52
The building-up principle and the periodic classification 54
Transition series 57
CONTENTS
II—QUANTUM THEORY OF VALENCY
6—HISTORICAL INTRODUCTION 65
7—THE MOLECULAR-ORBITAL METHOD 72
Introduction 72
The LCAO method 72
Homonuclear diatomic molecules 79
Heteronuclear diatomic molecu les 83
Bond strength 86
8—THE VALENCE-BOND METHOD 87
Introduction 87
The hydrogen molecule ion 87
The hydrogen molecule 90
Comparison of the molecular-* n bital and valence-bond
methods 92
Resonance 94
Resonance—some misconceptions and some guiding
principles 98
9—DIRECTED VALENCY 100
The criterion of maximum overlapping 100
Hybrid orbitals 102
Localized and delocalized orbi als 109
spd hybridization 111
Non-equivalent orbitals 113
Bond energies 114
10—IONIC, METALLIC AND HYDROGEM BONDS 116
Introduction 116
Ionic bonds 116
Ionization potential 116
Electron affinity 118
The size of ions 119
Ionic structures 122
Electronegativity 125
The hydrogen bond 129
Metallic bonds 134
The molecular or van der VVa; Is bond 137
III—THE APPLICATION OF THE PRINCIPLES OF
CHEMICAL BONDING
11—THE STRUCTURES OF SOME SIMPLJ INORGANIC COMPOUNDS 141
Bond lengths 141
Calculated bond lengths 141
x
CONTENTS
Bond configuration for first row elements 143
Lithium and the alkali metals 146
Beryllium and the alkaline earth metals 147
Boron and the group IIIB elements 152
Carbon and the group IVB elements 155
Nitrogen and the group VB elements 161
Oxygen and the group VIB elements 176
Fluorine and the group VIIB elements 185
12—COMPLEX COMPOUNDS 192
Introduction and nomenclature 192
Bonding in complex compounds 193
Experimental determination of configuratii n 202
Co-ordination number 2 208
Co-ordination number 3 210
Co-ordination number 4 212
Co-ordination number 5 222
Co-ordination number 6 227
Co-ordination number 7 236
Co-ordination number 8 237
Carbonyls, nitrosyl carbonyls, and carbonyi hydrides 239
Substituted carbonyi compounds 245
c f/opentadienc complexes 246
Olefin complexes 251
The stability of complex compounds 254
The reactivity of complex compounds 257
The reactivity of complexes of co-ordinatio a number 4
(the trans-effect ) 262
13—ELECTRON-DEFICIENT MOLECULES 269
Introduction 269
The structure of diborane 269
The structures of the higher hydrides of boron 275
The structures of the borohydrides 279
The metal alkyls , 280
AUTHOR INDEX 285
SUBJECT INDEX 289
x i
|
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| physical | XI, 294 S. zahlr. Ill. |
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| spelling | Cartmell, Edward Verfasser aut Valency and molecular structure Edward Cartmell ; Gerald W. Fowles 2. ed. London Butterworth 1961 XI, 294 S. zahlr. Ill. txt rdacontent n rdamedia nc rdacarrier Molekülstruktur Valenz <Chemie> Valenz Chemie (DE-588)4187347-6 gnd rswk-swf Molekülstruktur (DE-588)4170383-2 gnd rswk-swf 1\p (DE-588)4151278-9 Einführung gnd-content Valenz Chemie (DE-588)4187347-6 s DE-604 Molekülstruktur (DE-588)4170383-2 s Fowles, Gerald W. Verfasser aut HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=001439857&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Cartmell, Edward Fowles, Gerald W. Valency and molecular structure Molekülstruktur Valenz <Chemie> Valenz Chemie (DE-588)4187347-6 gnd Molekülstruktur (DE-588)4170383-2 gnd |
| subject_GND | (DE-588)4187347-6 (DE-588)4170383-2 (DE-588)4151278-9 |
| title | Valency and molecular structure |
| title_auth | Valency and molecular structure |
| title_exact_search | Valency and molecular structure |
| title_full | Valency and molecular structure Edward Cartmell ; Gerald W. Fowles |
| title_fullStr | Valency and molecular structure Edward Cartmell ; Gerald W. Fowles |
| title_full_unstemmed | Valency and molecular structure Edward Cartmell ; Gerald W. Fowles |
| title_short | Valency and molecular structure |
| title_sort | valency and molecular structure |
| topic | Molekülstruktur Valenz <Chemie> Valenz Chemie (DE-588)4187347-6 gnd Molekülstruktur (DE-588)4170383-2 gnd |
| topic_facet | Molekülstruktur Valenz <Chemie> Valenz Chemie Einführung |
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